WO1994007682A1 - Method for making a lineal member - Google Patents

Method for making a lineal member Download PDF

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Publication number
WO1994007682A1
WO1994007682A1 PCT/US1993/009239 US9309239W WO9407682A1 WO 1994007682 A1 WO1994007682 A1 WO 1994007682A1 US 9309239 W US9309239 W US 9309239W WO 9407682 A1 WO9407682 A1 WO 9407682A1
Authority
WO
WIPO (PCT)
Prior art keywords
resin
lineal
curing
lineal member
die
Prior art date
Application number
PCT/US1993/009239
Other languages
English (en)
French (fr)
Inventor
Terry R. Beaver
Arthur Blinkhorn
George R. Smith
Original Assignee
Owens-Corning Fiberglas Corporation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Owens-Corning Fiberglas Corporation filed Critical Owens-Corning Fiberglas Corporation
Priority to EP93922427A priority Critical patent/EP0619775A1/de
Priority to JP6509266A priority patent/JPH07501996A/ja
Publication of WO1994007682A1 publication Critical patent/WO1994007682A1/en

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C43/00Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
    • B29C43/22Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor of articles of indefinite length
    • B29C43/28Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor of articles of indefinite length incorporating preformed parts or layers, e.g. compression moulding around inserts or for coating articles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C35/00Heating, cooling or curing, e.g. crosslinking or vulcanising; Apparatus therefor
    • B29C35/02Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould
    • B29C35/0277Apparatus with continuous transport of the material to be cured
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/28Shaping operations therefor
    • B29C70/40Shaping or impregnating by compression not applied
    • B29C70/50Shaping or impregnating by compression not applied for producing articles of indefinite length, e.g. prepregs, sheet moulding compounds [SMC] or cross moulding compounds [XMC]
    • B29C70/52Pultrusion, i.e. forming and compressing by continuously pulling through a die
    • B29C70/523Pultrusion, i.e. forming and compressing by continuously pulling through a die and impregnating the reinforcement in the die
    • EFIXED CONSTRUCTIONS
    • E06DOORS, WINDOWS, SHUTTERS, OR ROLLER BLINDS IN GENERAL; LADDERS
    • E06BFIXED OR MOVABLE CLOSURES FOR OPENINGS IN BUILDINGS, VEHICLES, FENCES OR LIKE ENCLOSURES IN GENERAL, e.g. DOORS, WINDOWS, BLINDS, GATES
    • E06B3/00Window sashes, door leaves, or like elements for closing wall or like openings; Layout of fixed or moving closures, e.g. windows in wall or like openings; Features of rigidly-mounted outer frames relating to the mounting of wing frames
    • E06B3/04Wing frames not characterised by the manner of movement
    • E06B3/06Single frames
    • E06B3/08Constructions depending on the use of specified materials
    • E06B3/20Constructions depending on the use of specified materials of plastics
    • E06B3/205Constructions depending on the use of specified materials of plastics moulded or extruded around a core
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/001Combinations of extrusion moulding with other shaping operations
    • B29C48/0012Combinations of extrusion moulding with other shaping operations combined with shaping by internal pressure generated in the material, e.g. foaming
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/03Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
    • B29C48/12Articles with an irregular circumference when viewed in cross-section, e.g. window profiles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/15Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor incorporating preformed parts or layers, e.g. extrusion moulding around inserts
    • B29C48/154Coating solid articles, i.e. non-hollow articles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/16Articles comprising two or more components, e.g. co-extruded layers
    • B29C48/18Articles comprising two or more components, e.g. co-extruded layers the components being layers
    • B29C48/21Articles comprising two or more components, e.g. co-extruded layers the components being layers the layers being joined at their surfaces
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2105/00Condition, form or state of moulded material or of the material to be shaped
    • B29K2105/04Condition, form or state of moulded material or of the material to be shaped cellular or porous
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29LINDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2031/00Other particular articles
    • B29L2031/001Profiled members, e.g. beams, sections
    • B29L2031/003Profiled members, e.g. beams, sections having a profiled transverse cross-section

Definitions

  • This invention pertains to making building components, particularly structural members having relatively low thermal conductivity.
  • reinforcement fibers are dipped into a liquid resinous bath and pulled through a die to produce the desired cross-sectional shape.
  • the compressed fibers and resin are then passed through a curing die during which the temperature of the resin is raised to a temperature sufficient to initiate the cure of the resin.
  • Pultrusion of lineal members having a porous glass wool core is different from traditional pultrusion processes.
  • the glass wool core is not dipped into a liquid bath of resin because of the need to limit the resin to the outer edges of the glass wool core.
  • the glass wool core is pulled through a die in which resin is injected at a relatively low pressure in order to apply resin only in the outer portion of the glass wool core.
  • the coated lineal member is passed through a curing die which initiates curing of the resin.
  • the resin is a polyester resin.
  • porous core lineal material In the case of a porous core lineal material, however, the relatively dense resinous area of the lineal is merely in the periphery of the cross-sectional area, and there is not enough residual heat in the pultruded lineal member to continue the curing process to completion in the ambient conditions of the manufacturing facility. Therefore, a problem in the manufacture of porous core, resin coated lineal material is that the materials are not completely cured as they are manufactured.
  • the resin material which is typically a polyester material, produces styrene gas.
  • the styrene is offgassed during the curing process.
  • the problem with an undercured lineal member is that when it is heated up for subsequent process steps, the styrene will continue to offgas, thereby potentially affecting later processes.
  • a method for making a lineal member having a porous core comprising feeding a shaped, elongated porous core, through a resin-encasing die wherein resin is injected under pressure to encase the core, through a curing die having a cross-sectional shape coinciding with and in contact with the resin-encased lineal member, with the curing die imparting sufficient heat to the lineal member to initiate cure of the resin, and through a curing chamber which is maintained at a temperature sufficient to complete the cure of the resin without substantial contact with the lineal member.
  • the present invention solves the problem of incomplete cure of the pultruded, porous core lineal member by providing a curing chamber which immediately follows the curing die and in which the lineal member is maintained at a temperature sufficient to complete the cure of the resin without substantial contact with the lineal member.
  • the fact that there is no substantial contact with the lineal member means that the curing chamber does not apply significant additional drag force onto the lineal member, thereby subjecting the lineal member to breaking due to forces exceeding the tensile strength of the lineal member.
  • the porous core has density less than about 320 kg/m 3 (20 lbs./ft 3 ) .
  • the porous core has a density within the range of from about 96 kg/m 3 (6 lbs./ft 3 ) to about 192 kg/m 3 (12 lbs./ft 3 ) .
  • the encased lineal is subjected to an additional coating step, preferably a painting step, which includes heating the encased lineal to temperature of at least 60°C (140°F) after the encased lineal is coated.
  • an additional coating step preferably a painting step, which includes heating the encased lineal to temperature of at least 60°C (140°F) after the encased lineal is coated.
  • the resin is injected under pressure lower than about 207 kPa (30 psi) to encase the core.
  • the curing chamber applies a drag force of less than about 2.27 kg (5 lbs.) on the lineal member.
  • the drag force applied by the curing chamber is less than about 0.91 kg (2 lbs.).
  • FIG. 2 is a schematic cross-sectional view in elevation of the curing die, taken along line 2-2.
  • FIG. 3 is a schematic cross-sectional view in elevation of the curing chamber taken along lines 3-3.
  • FIG. 4 is a schematic elevational view of the lineal painting process.
  • porous core 10 is pulled through various coating and curing equipment by puller 12 to form lineal member 14.
  • the puller can be any mechanical device, commonly known in the art, for pulling materials in a pultrusion process.
  • the porous core is preferably of mineral fibers, and most preferably is comprised of glass wool containing a resinous binder of urea phenol formaldehyde.
  • the porous core is preferably less than about 320 kg/m 3 (20 lbs./ft 3 ) , and more preferably has a density within the range of from about 96 kg/m 3 (6 lbs./ft 3 ) to about 192 kg/m 3 (12 lbs./ft 3 ) .
  • the density of the glass wool porous core is approximately 160 kg/m 3 (10 lbs./ft 3 ) .
  • the resin coating process is generally carried out as a two stage process.
  • the primer resin coat is applied first to the outer periphery of the porous core.
  • Resin impregnating die 16 connected with primer resin supply 18 can be used to apply a primer coat to the porous core.
  • Primer curing oven 20 can be positioned next in line in order to cure the primer resin.
  • the resin impregnated porous core is then passed through the coating apparatus which is comprised of coating resin supply 22 and resin encasing die 24. In this way, the porous core is first treated with a primer resin and then treated with an outer coating resin. It is to be understood that the invention could be used with a single resin application rather than a double resin application.
  • the curing die 26 Immediately following the resin encasing die is the curing die 26.
  • the curing die as shown in FIG. 2, has an inner surface with a cross-sectional shape coinciding with and in contact with the resin encased lineal member.
  • Curing dies are well known in the art. Typically, they are heated with a heating means, such as electric heaters 30. In a typical use of the invention, the curing die imparts sufficient heat to the lineal member to initiate cure of the resin.
  • the cure initiation temperature for a polyester resin is approximately 110°C (230 ⁇ F) . Since the curing die is in close contact with the lineal member passing through it, a significant amount of drag force is applied to the lineal member.
  • the lineal member As shown in FIG. 3, after the lineal member is passed through the curing die, it travels through curing chamber 32 which is maintained at a temperature substantially equal to or greater than the temperature of the resin at the exit end of the curing die.
  • the heat applied to the lineal member in the curing chamber is primarily accomplished through hot air convection heat transfer.
  • the hot air is supplied by any suitable heating means, such as heater 34, and driven by fan 36. It is to be understood that any other means for maintaining the temperature of the lineal member at a temperature sufficient to complete the cure can be used.
  • the curing chamber must be long enough and hot enough to enable the resin to be either completely cured or sufficiently advanced in cure so that the cure will be completed in the ambient plant conditions shortly after the lineal member exits the curing chamber.
  • the lineal member is supported in the curing chamber by a series of rollers, such as support rollers 38. It can be seen that the support rollers provide little, if any, substantial contact with the lineal member so that the drag force is not substantially increased. Any other suitable means for supporting the lineal member within the curing chamber can be used. It can be seen in FIG. 3 that the cross-sectional view of the lineal member shows that a substantial portion of the area is the porous core, and only a minor portion of the area is resin coating 40. Preferably, the porous portion of the cross-sectional area is at least 75% of the total cross-sectional area of the lineal member.
  • the porous core portion of the lineal member is at least 85% of the total cross-sectional area of the lineal member.
  • the density of the resin coating is in excess of 800 kg/m 3 (50 lbs./ft 3 ) .
  • the temperature of the resin will increase while the resin passes through the curing die from a entry temperature of about 93.3 ⁇ C (200 ⁇ F) to an exit temperature of about 154°C (310°F) .
  • the temperature of the hot gases in the curing chamber is preferably maintained within the range of from about 148.9"C (300 ⁇ F) to about 162.78"C (325 ⁇ F).
  • Porous-cored, resin-encased lineal members are often subjected to additional process steps which involve heating the lineal to temperatures as high as 60°C (140°F) and possibly as high as 82"C (180"F) or higher.
  • a subsequent process step for the lineal member is the painting process.
  • the lineal member is fed through paint die 42 and subsequently passes through paint oven 44 to produce painted lineal 46.
  • These processes are conventional in painting of glass fiber cored window lineals, for example. While in the paint oven, the lineal member will experience temperatures of approximately 93.3°C (200°F).
  • lineal member passing through the paint oven has uncured polyester resin in the resin coating, then the resin may offgas styrene, thereby creating bubbles and other surface defects in the surface of the lineal.
  • lineal members passing through a curing chamber according to the invention will have completely cured resin, and will not be subject to offgasing of styrene during a subsequent step, such as a painting process.

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Civil Engineering (AREA)
  • Structural Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Health & Medical Sciences (AREA)
  • Oral & Maxillofacial Surgery (AREA)
  • Thermal Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Composite Materials (AREA)
  • Moulding By Coating Moulds (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
PCT/US1993/009239 1992-10-05 1993-09-29 Method for making a lineal member WO1994007682A1 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
EP93922427A EP0619775A1 (de) 1992-10-05 1993-09-29 Verfahren zum Herstellen eines geradlinigen Elements
JP6509266A JPH07501996A (ja) 1992-10-05 1993-09-29 線状部材の製造方法

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US95652492A 1992-10-05 1992-10-05
US07/956,524 1992-10-05

Publications (1)

Publication Number Publication Date
WO1994007682A1 true WO1994007682A1 (en) 1994-04-14

Family

ID=25498332

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US1993/009239 WO1994007682A1 (en) 1992-10-05 1993-09-29 Method for making a lineal member

Country Status (3)

Country Link
EP (1) EP0619775A1 (de)
JP (1) JPH07501996A (de)
WO (1) WO1994007682A1 (de)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1996031330A1 (en) * 1995-04-07 1996-10-10 Arnold Guettler Process and device for the manufacture of pultruded building elements

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2541629A1 (fr) * 1983-02-24 1984-08-31 Singer Edouard Procede de stratification en continu et filiere pour la mise en oeuvre de ce procede
WO1987001986A1 (en) * 1985-10-07 1987-04-09 Owens-Corning Fiberglas Corporation Structural member and method of making
WO1990003877A1 (en) * 1988-10-13 1990-04-19 Weyerhaeuser Company Pultrusion system for condensation resin injection
GB2245893A (en) * 1990-07-10 1992-01-15 Shaw John Ltd Fibre reinforced plastic composites

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2455807A (en) * 1945-09-11 1948-12-07 American Cyanamid Co Preparation of substituted cyanoguanidine
JPS61223023A (ja) * 1985-03-28 1986-10-03 Nitto Electric Ind Co Ltd エポキシ樹脂用硬化剤組成物
ATE70261T1 (de) * 1987-09-02 1991-12-15 Ciba Geigy Ag Oligomere cyanoguanidine.

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2541629A1 (fr) * 1983-02-24 1984-08-31 Singer Edouard Procede de stratification en continu et filiere pour la mise en oeuvre de ce procede
WO1987001986A1 (en) * 1985-10-07 1987-04-09 Owens-Corning Fiberglas Corporation Structural member and method of making
WO1990003877A1 (en) * 1988-10-13 1990-04-19 Weyerhaeuser Company Pultrusion system for condensation resin injection
GB2245893A (en) * 1990-07-10 1992-01-15 Shaw John Ltd Fibre reinforced plastic composites

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1996031330A1 (en) * 1995-04-07 1996-10-10 Arnold Guettler Process and device for the manufacture of pultruded building elements

Also Published As

Publication number Publication date
EP0619775A1 (de) 1994-10-19
JPH07501996A (ja) 1995-03-02

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