WO1994004125A1 - Preparations de colorants capillaires et procedes associes - Google Patents

Preparations de colorants capillaires et procedes associes Download PDF

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Publication number
WO1994004125A1
WO1994004125A1 PCT/US1993/007889 US9307889W WO9404125A1 WO 1994004125 A1 WO1994004125 A1 WO 1994004125A1 US 9307889 W US9307889 W US 9307889W WO 9404125 A1 WO9404125 A1 WO 9404125A1
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WO
WIPO (PCT)
Prior art keywords
copper
hair
composition
dye
chloride
Prior art date
Application number
PCT/US1993/007889
Other languages
English (en)
Inventor
Terry Gerstein
Marvin E. Goldberg
Original Assignee
Revlon Consumer Products Corporation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Revlon Consumer Products Corporation filed Critical Revlon Consumer Products Corporation
Priority to AU50861/93A priority Critical patent/AU5086193A/en
Publication of WO1994004125A1 publication Critical patent/WO1994004125A1/fr

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34—Alcohols
    • A61K8/347—Phenols
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/41—Amines
    • A61K8/411—Aromatic amines, i.e. where the amino group is directly linked to the aromatic nucleus
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/41—Amines
    • A61K8/415—Aminophenols
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/10—Preparations for permanently dyeing the hair

Definitions

  • the invention is in the field of oxidation hair dyes.
  • oxidation dyes which are also known as “permanent” hair dyes, "permanent” meaning that the hair color does not wash out with shampooing.
  • permanent hair dyes "permanent” meaning that the hair color does not wash out with shampooing.
  • Dye precursors also known as primary intermediates
  • dye couplers also known as secondary intermediates
  • the mixture of the dye precursors and dye couplers in an alkaline vehicle is mixed with hydrogen peroxide immediately prior to use.
  • the mixture is then applied to the hair and left on for a specified period of time in order to allow the dye molecules to penetrate into the hair shaft.
  • the hydrogen peroxide serves to oxidize the dye precursors into large colored molecules.
  • the dye couplers join the reaction to modify the large molecules and their color.
  • the hair color is "permanent".
  • the alkaline pH is important in this hair color process.
  • the alkalinity helps swell the hair fiber to allow penetration of the initially small precursor dye molecules. It activates the hydrogen peroxide which is supplied stabilized in acid media. It produces a suitable environment for the chemical reaction of the dyes with the hair.
  • a major disadvantage of most oxidative dye systems is the employment of the hydrogen peroxide oxidizing agent which not only has the potential to damage the hair structure when used improperly, but also is known to cause other undesirable side effects such as skin irritation and burning in certain sensitive individuals.
  • Other oxidative dye systems have been developed which use peracid oxidizing agents, but these substances also present certain other problems.
  • oxidative dye systems which rely on air oxidation have been developed. These systems are commercially viable, although they tend to produce color development at a slow rate thus mandating that the dye mixture be left on the hair for extended periods of time.
  • SUBSTITUTE SHEET The invention is also directed to a method for imparting permanent color to human hair comprising applying to the hair the above mentioned composition.
  • the copper II salts in accordance with the invention include copper II sulfate, copper II chloride, copper II oleate, copper II pyridinethione, copper II acetate, copper 11 phosphate, copper II gluconate, copper II glycinate, copper II stearate, etc., or mixtures thereof.
  • copper II sulfate and copper II chloride are preferred.
  • dye blend means the combination of dye intermediates used for producing color.
  • die mixture means the component of the invention containing the dye blend in a vehicle formulated with other ingredients such as solvents, surfactants, conditioning agents, stabilizers, etc.
  • die composition means the dye mixture together with the catalyst-oxidizing agent.
  • each intermediate is the color it imparts to hair: p-phenylenediamine (dark brown/black) , 2,5-diaminotoluene (reddish brown), 2- chloro-p-phenylenediamine (brown) , N-phenyl-p- phenylenediamine (dark gray/black), N,N-bis-(2- hydroxyethyl) -p-phenylenediamine (brown) , p- a inophenol (light auburn) , N-methyl-p-aminophenol (pale blond) , or mixtures thereof.
  • Suitable dye couplers are resorcinol, 4- chlororesorcinol, 2-methylresorcinol, 1-naphthol, 1,5- dihydroxynaphthalene, 1,7-dihydroxynaphthalene, 2,5- dihydroxypyridine, m-aminophenol, 4-methyl-5- aminophenol, 4-methyl-5-(2-hydroxyethyl)aminophenol, m-phenylenediamine, 2 ,4-diaminophenoxyethanol, 2,6- diaminopyridine, o-aminophenol, or mixtures thereof.
  • the dye composition of the invention may be administered to hair in a number of different product modes.
  • the traditional manner is preferred, wherein the hair dye blend in a surfactant vehicle together with the copper II catalyst-oxidizing agent are applied to the hair for a specified period of time and color is allowed to develop before the dye composition is removed from the hair.
  • the dye couplers and intermediates found in the dye mixture are small molecules which are able to penetrate the hair shaft.
  • the copper II catalyst- oxidizing agent initiates reaction of the dye molecules which causes the molecules to complex to form larger polymers within the hair shaft. The co plexed molecules become too large to escape from the hair shaft and permanent color is thus obtained.
  • Suitable hair dye compositions in accordance with the invention comprise 0.0001-5% of the copper II catalyst-oxidizing agent as set forth herein, 0.001-5% of the dye blend, 0.01-30% surfactant, 0.01-10% conditioners, 30-70% water.
  • the copper II catalyst- oxidizing agent is copper sulfate or copper chloride.
  • the surfactants which are suitable in the composition of the invention may be anionic, cationic, nonionic, or amphoteric.
  • Suitable anionic surfactants include fatty acid soaps, salts of alkyl sulfates, salts of alkyl ether sulfates, N-acyl sarcosinates, salts of fatty acid amide sulfonic acids, salts and/or esters of alkyl phosphates, salts of fatty sulfosuccinates, alkyl benzene sulfonate salts, salts of N-acyl glutamate, salts of fatty sulfoacetates, alpha olefin sulfonate salts, or mixtures thereof.
  • amphoteric surfactants which are useful in the compositions of the present invention may be ampholytic or zwitterionic and include betaines, sultaines, imidazolines, phosphobetaines, phosphitaines and pyrophosphobetaines, and also include glycinates, beta amino propionates, and other surface active amino acid derivatives.
  • Suitable-cationic surfactants include halogen and sulfate salts such as benzalkonium chloride, stearalkonium chloride, laurtrimonium chloride, cetri onium chloride. , soytrimonium chloride, steartrimonium chloride, dicocodimonium chloride, quaternium 18, distearyldimonium chloride, tallowdimonium propyltrimonium dichloride, tricetylmonium chloride, PEG-2 cocomonium chloride, PEG-2 oleamonium chloride, PEG-15 stearmonium chloride, as well as pyridiniu , morpholinium, imidazolinum salts, and various salts of long chain primary, secondary, and tertiary amines.
  • halogen and sulfate salts such as benzalkonium chloride, stearalkonium chloride, laurtrimonium chloride, cetri onium chloride. ,
  • lipophilic and hydrophilic nonionic surfactants such as sorbitan fatty acid esters, alkyl ether glycosides, ethoxylated/propoxylated long chain alcohols, and acids, ethoxylates of long chain mono and diglycerides, long chain amine oxides, alkanolamides, lanolin derived ethoxylates and so on.
  • surfactants in accordance with the invention are salts of isostearic acid and oleic acid, PEG-2 cocoamine, ceteareth-4- phosphate, sulfated castor oil, nonoxynol-l, PEG-5 oleate, ceteareth-10, cocobetaine, sodium lauryl sulfate, ammonium laureth sulfate, ammonium lauroyl sarcosinate, stearamine oxide, cetrimonium chloride, cocoamidopropyl betaine, behenyldimethylamine hydrochloride, nonoxynol-121 potassium coco-hydrolyzed animal protein, sodium cocoyl isethionate, polyglyceryl-4-stearate, PPG-8- ceteth-10, sodium cocoyl glutamate, caprylyl/capryl
  • SUBSTITUTESHEET glucoside sodium cocamphoacetate, cocosultaine, stearalkonium chloride, ceteareth-15, lauramide DEA, stearamidopropyldimethylamine hydrochloride, dicetyldi onium chloride, C u . 15 pareth-20 and others of the like.
  • Suitable auxiliary ingredients which also provide conditioning effects include hydrolyzed animal/vegetable protein, propylene glycol, sorbitol, PPG-40 butyl ether, stearic acid, panthenol, vitamin E palmitate, dimethicone, propylene glycol monostearate, ethylene glycol distearate, amodimethicone, dimethiconol, dimethicone copolyol, ethylene glycol stearate, isopropyl myristate, cetyl lactate, cetearyl alcohol, cetyl alcohol, butylene glycol, aloe vera gel, acetamide MEA, oleyl alcohol, cyclomethicone, decyl oleate, mineral oil, lanolin alcohol or mixtures thereof.
  • the composition is left on the hair for an appropriate period of time, generally 5-45 minutes.
  • the hair is then rinsed with water and dried.
  • the hair may be treated in a two step process with the dye mixture first, then removed, then followed by post-dye hair treatment products which contain the copper II catalyst-oxidizing agent. Application of such post- treatment products containing copper II will act to oxidize unreacted dye molecules within the hair shaft, causing color development instantly.
  • the dye composition of the invention can also be administered in the form of mousse, which when regularly used will result in more intense color development with each subsequent treatment.
  • a suitable mousse composition comprises 0.1-20% of a hair fixative, 0.01-20% surfactant, 0.01-10% thickeners, 0.001-5% dye blend, 0.0001-5% copper II
  • SUBSTITUTESHEET catalyst-oxidizing agent 30-70% water, and 25-75% solvent.
  • This composition is then mixed with a suitable propellant.
  • a suitable propellant Generally 70-98 parts of the above composition and about 2-30 parts of propellant are suitable.
  • Suitable propellants include dimethyl ether, n-butane, isobutane, difluoroethane, chlorodifluoroethane, chlorodifluoromethane, other chlorofluorocarbons, or mixtures thereof.
  • the dye mixture it is possible for the dye mixture to be administered to the hair first, followed by the application of a second vehicle which contains the copper II catalyst-oxidizing agent.
  • the dye mixture in the form of a lotion, creme, shampoo or alternative vehicle is initially applied to the hair and allowed to remain for a period of time long enough to ensure that the dye molecules penetrate the hair shaft.
  • the dye mixture is then rinsed out of the hair.
  • a second composition such as a shampoo, conditioner, or treatment product which acts as a vehicle for the copper II catalyst-oxidizing agent is then applied to the hair. After an appropriate period of time relative to the nature of the composition, it is washed out of the hair. Hair is left colored instantly to a new shade.
  • Hair which has been colored according to the invention can be subsequently maintained with the application of various post-dye conditioning products such is shampoos, spritzers, hair sprays, conditioners, and the like.
  • These products contain the copper II catalyst-oxidizing agent which act to ensure total and prolonged color intensification and stabilization.
  • Such a suitable shampoo useful as a post-dye treatment product includes 10-60% anionic, amphoteric, or betaine surfactants or mixtures thereof, 0.01-15% conditioners, 0.01-5% thickener, and 0.0001-5% copper
  • the shampoo composition may additionally contain 0.01-10% silicone such as dimethicone, dimethicone copolyol, amodimethicone, cyclomethicone or mixtures thereof. It may also be desired to add 0.1-5% antidandruff ingredients such as selenium sulfide, zinc pyridinethione, copper II pyridinethione, etc. Use of such a shampoo composition after hair has been dyed in accordance with the invention may result in a gradual color enhancement of the hair until all of the unreacted dye molecules have been activated.
  • Suitable creme rinse formulations comprise 0.01-10% of a cationic surfactant, 0.01-20% conditioners, 0.001-5% thickening agents, 0.0001-5% copper II oxidizing agent, and the remainder water.
  • Suitable cationic surfactants include stearalkonium chloride, cetrimonium chloride, dicetyl dimonium chloride, or mixtures thereof.
  • Suitable conditioners are many, and include cetearyl alcohol, cetyl alcohol, panthenol, aloe vera gel, dimethicone, dimethicone copolygl, amodimethicone, ceteareth, hydrolyzed vegetable proteins, oleyl aldohol, cyclomethicone, lanolin, mineral oil, lanolin alcohol, or mixtures thereof.
  • Aerosol hair sprays or pump hair sprays may also act as a post-dye treatment vehicle.
  • Suitable hair spray formulations comprise 0.01-10% hair fixative resin, 0.001-10% conditioner, 25-90% organic or aqueous solvent, 0.0001-5% copper II oxidizing agent.
  • the hair spray may also contain 0.001-5% fragrance, as well as other constituents. If the hair spray is an aerosol, generally about 50-90 parts of the hair spray mixture is combined with 10-50 parts of propellant as set forth herein. If the hair spray composition is used in a pump spray it is generally desired to include about 0.01-45% water.
  • Suitable hair fixative polymers include acrylate/acrylamide copolymer, esters of polyvinyl methyl ether/maleic anhydride (PVM/MA) copolymer, octylacrylamide/acrylates/butylaminoethyl methacrylate copolymer, octylacrylamide/acrylates copolymer, polyquaternium-4, polyquaternium-7, polyguaternium-10, polyquaternium-ll, polyvinyl pyrrolidone (PVP) , polyvinyl pyrrolidone vinyl acetate (PVP/VA) copolymer, shellac, vinyl acetate/crotonic acid copolymer, vinyl acetate/crotonic acid/vinyl neodecanoate copolymer, and so on.
  • PVM/MA polyvinyl methyl ether/maleic anhydride
  • PVP polyvinyl pyrrolidone
  • PVP/VA polyvinyl pyr
  • Hair styling gels may also be suitable for post- dye treatment vehicles.
  • Suitable hair gels comprise 0.001-10% hair fixative resin, 0.01-15% conditioner, 30-70% solvent, 30-70% water, and 0.0001-5% copper II catalyst-oxidizing agent.
  • the invention is directed to a method for imparting permanent color to human hair comprising applying to the hair an oxidizing agent selected from the group consisting of copper II sulfate, copper II chloride, copper II oleate, copper II pyridinethione, copper II acetate, copper II phosphate, copper II gluconate, copper II glycinate, copper II stearate, or mixtures thereof; and a dye mixture comprised of a primary intermediate and a coupler wherein the primary intermediate is selected from the group consisting of p-phenylenediamine, 2,5-diaminotoluene, 2-chloro-p- phenylenediamine, N-phenyl-p-phenylenediamine, N,N- bis-(2-hydroxyethyl)-p-phenylenediamine, p-aminophenol, N-methyl-p-aminophenol, or mixtures thereof; and the couplers from the group resorcinol, 4-chlororesorcinol
  • a composition containing both the dye mixture and the copper II catalyst-oxidizing agent is applied to the hair and allowed to remain for 5-45 minutes. The composition is then rinsed from the hair and the hair is towel dried. The hair is left colorized to a new shade.
  • various post-dye treatment maintenance products containing the catalyst-oxidizing agent may be used on a regular basis in order to cause any unaffected dye molecules to colorize. The hair color will continue to gradually intensify until all of the dye molecules have reacted within the hair shaft.
  • Suitable vehicles to hold the catalyst-oxidizing agent for a two step process include shampoo, conditioner, etc.
  • compositions and methods of the invention provide an excellent method for coloring human hair without the use of hydrogen peroxide.
  • the methods and compositions of the invention are particularly useful in coloring gray hair.
  • SUBSTITUTESHEET Example 1 A hair dye composition suitable for a one step treatment in accordance with the invention is shown as follows: w/w5
  • the above composition was applied directly to dry hair and worked into a creamy rich lather with the fingertips so that hair was thoroughly saturated.
  • the product was left on the hair for 25 minutes.
  • a small amount of water was added and the lather worked up before rinsing out with water.
  • the hair is washed with a standard conditioning shampoo.
  • the hair is left colored to another shade. If desired, the hair can be routinely shampooed with the post- treatment shampoos taught herein.
  • Example 2 A hair dye composition suitable for one step treatment in accordance with the invention was made as follows: w/w%
  • composition is applied in accordance with the method set forth in Example 1.
  • a dye composition suitable for a one step treatment is shown in accordance with the following formula: w/w% Dye mixture 1.o
  • composition is applied in accordance with the method of Example 1.
  • SUBSTITUTESHEET Example 4 A hair dye composition with cationic conditioning agent suitable for a one step treatment is shown as follows: w/w
  • the composition is applied to dry hair or to hair which has just been shampooed.
  • the composition is allowed to remain on hair for approximately 25 minutes before being washed off.
  • Example 5 A hair styling mousse for gradual color development is shown as follows: w/w%
  • the mousse was obtained by mixing 92 parts of the above concentrate with 8 parts of Propellant 152A (E.I. Dupont de Nemours,Inc. , Wilmington DE) , and dispensed with aerosol packaging.
  • the mousse is applied to hair and evenly worked through with the fingers.
  • the hair is styled as usual.
  • the mousse may be used in the manner of a shampoo.
  • the mousse is liberally applied to the hair, worked in, and allowed to remain for 10-30 minutes before washing out. Examples 6, 7, and 8 show rinse-out hair color mousse compositions.
  • Example 6 A conditioning mousse composition is shown by combining 90 parts by weight of the dye composition of Example 2 with 10 parts by weight of Propellant 152A.
  • Example 7 A panthenol mousse composition is shown by combining 92.0 parts by weight of the dye composition of Example 3 with 8.0 parts by weight of Propellant 152A.
  • Example 8 A mousse with cationic conditioner was made by combining 92.0 parts by weight of the dye composition of Example 4 with 8.0 parts by weight of Propellant 152A.
  • Example 9 A high foaming shampoo useful as a post-treatment color development product is shown as follows: w/w% Sodium lauryl sulfate (28%) 25.0
  • Hair has been previously treated with the dye mixture vehicle in accordance with the invention is cleansed with the above shampoo. Hair color will develop due to activation of the dye molecules which have penetrated the hair fiber.
  • a mild shampoo useful as a post-treatment color development product is shown as follows: w/w%
  • Example 11 Two in one shampoo conditioner useful for a post- treatment color development product is shown as follows: w/w% Ammonium lauryl sulfate (28%) 35.0 Ammonium laureth sulfate (28%) 20.0
  • Cocoamidopropyl betaine (37%) 4.0
  • a mild amphoteric shampoo suitable for a post- treatment color development product is shown as follows: w/w% Copper II glycinate 2.0
  • Example 13 A conditioning shampoo suitable as a post- treatment color development product is shown as follows: w/w-i
  • Example 14 A dandruff rinse shampoo suitable as a post- treatment color development product is shown as follows: w/w% Sodium lauryl sulfate (28%) 50.0 Lauramine Oxide (25%) 8.0
  • Example 15 A creme rinse suitable as a post-treatment color development product is shown as follows: w/w% Stearalkonium chloride 2.8
  • Example 16 An extra conditioning conditioner suitable as a post-treatment color development product is shown as follows: w/w% Cetrimonium chloride 1.5
  • Example 16 An extra body conditioner suitable for use as a post-treatment color development product is shown as follows: w/w%
  • Example 17 A rinse off conditioner for ulotrichous hair suitable for use as a post-treatment color development product is shown as follows: w/w%
  • a post-dye composition treatment product in the form of a hair thickening aerosol hair spray is shown in accordance with the following formula.
  • the hair spray was intended to be applied after a dye composition treatment to sustain longevity of the hair color as well as to intensify the hue with time: w/w% PVP 2.0
  • a post-dye composition treatment hair styling gel is shown as follows: w/w%
  • a post-dye composition treatment pump spritz spray is shown as follows: w/w%
  • Example 21 A post-dye treatment sheen hair dressing is shown as follows: w w°
  • Example 23 A mousse composition was prepared by mixing 90 parts of Revlon Colorsilk Brown Hair dye which contained 1% cupric chloride, with 10 parts of Dymel 152A. Hair tresses were treated for 15 minutes each in four intervals. The tresses turned more intense brown after each treatment. Maximum color development occurred after 45 minutes (3 treatments) . A two week control mousse stored at 120° F for aging effects did not show any color differences when tested against the mousse composition stored at room temperature. A separate set of hair tresses were treated with Revlon Colorsilk Black Indigo dye in the directed manner for 20 minutes, but without the addition of hydrogen peroxide developer. Hair tresses were removed from the bath, the dye was rinsed off, and the tresses shampooed with Revlon Nintendo shampoo. One hair tress was dipped into hydrogen peroxide developer, another dipped into 3% Na 2 S0 ? solution. A
  • SUBSTITUTESHEET third tress was dried as is.
  • the hair tress dipped into developer turned deep black.
  • the hair tress treated-with 3% Na 2 S0 3 turned slightly colored with time. Hair with no further treatment turned only nominally in color and slowly intensified over a prolonged interval of time.
  • CONCLUSION CuCl, behaves similarly to H 2 0 2 in post dye treatment effects to produce hair color with oxidation dyes.

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Abstract

Composition de colorants capillaires comprenant un mélange de colorants, un agent catalyseur-oxydant au cuivre II, un tensioactif et de l'eau. Le procédé de coloration permanente des cheveux humains consiste à leur appliquer la composition de l'invention.
PCT/US1993/007889 1992-08-24 1993-08-23 Preparations de colorants capillaires et procedes associes WO1994004125A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU50861/93A AU5086193A (en) 1992-08-24 1993-08-23 Hair dye preparations and associated methods

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US93459592A 1992-08-24 1992-08-24
US934,595 1992-08-24

Publications (1)

Publication Number Publication Date
WO1994004125A1 true WO1994004125A1 (fr) 1994-03-03

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AU (1) AU5086193A (fr)
IL (1) IL106775A0 (fr)
MX (1) MX9305124A (fr)
WO (1) WO1994004125A1 (fr)
ZA (1) ZA936162B (fr)

Cited By (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0788787A3 (fr) * 1996-02-10 1997-10-22 Wella Ag Composition de teinture des cheveux par oxydation à base d'un véhicule gélifié
EP0803192A1 (fr) * 1996-04-24 1997-10-29 Nunez, Omar Cristian Produit ectoparasiticide antimycotique pour usage externe
WO1999008650A2 (fr) * 1997-08-20 1999-02-25 L'oreal Utilisation d'acide ascorbique pour des compositions destinees aux permanentes et a la coloration des cheveux
EP0918503A1 (fr) * 1995-12-29 1999-06-02 The Procter & Gamble Company Compositions pour teintures capillaires
EP0950394A1 (fr) * 1998-03-31 1999-10-20 Spring Kosmetik GmbH & Co. KG Procédé et moyens pour la teinture d'oxydation des cheveux
US5976195A (en) * 1996-09-06 1999-11-02 L'oreal Oxidation dye composition for keratin fibers containing an oxidation dye precursor and amphiphilic polymer
US5989295A (en) * 1996-09-06 1999-11-23 L'oreal Oxidation dye composition for keratin fibres, comprising an anionic amphiphilic polymer
US6010541A (en) * 1996-07-23 2000-01-04 L'oreal Oxidation dye composition for keratin fibers comprising a nonionic amphiphilic polymer
WO2001043719A1 (fr) * 1999-12-17 2001-06-21 Unilever Plc Composition de traitement capillaire contenant des tensioactifs cationiques
EP1159254A1 (fr) * 1999-03-05 2001-12-05 Milliken & Company Intermediaire aminophenol a substitution oxyalkylene
WO2003082235A1 (fr) * 2002-03-26 2003-10-09 Alberto-Culver Company Composition de conditionneur capillaire
FR2852828A1 (fr) * 2003-03-25 2004-10-01 Oreal Composition de traitement des matieres keratiniques comprenant un acide hydroxycarboxylique et un agent protecteur ou conditionneur
FR2852832A1 (fr) * 2003-03-25 2004-10-01 Oreal Composition de coloration pour fibres keratiniques comprenant un acide hydroxycarboxilique ou un sel, composition prete a l'emploi la comprenant, procede de mise en oeuvre et dispositif
WO2005063177A1 (fr) * 2003-12-19 2005-07-14 Henkel Kommanditgesellschaft Auf Aktien Agents cosmetiques a deux ou plusieurs phases presentant un meilleur comportement de melange et de separation reversible
WO2013007606A3 (fr) * 2011-07-08 2013-03-07 Unilever Plc Composition de soins capillaires
FR3060352A1 (fr) * 2016-12-21 2018-06-22 L'oreal Composes phosphates comme anti-infrarouge
US10022312B2 (en) 2014-01-24 2018-07-17 Combe Incorporated Gradual haircolor compositions and methods of using the same
EP2138154B1 (fr) 2008-06-27 2018-07-25 Beiersdorf AG Après-shampoing doté d'amphotenside et d'une stabilité de stockage particulière
FR3078488A1 (fr) * 2018-03-01 2019-09-06 L'oreal Composition cosmetique comprenant des tensioactifs non ioniques de type alcools gras polyoxyalkylenes et des tensioactifs cationiques, procede de traitement cosmetique et utilisation
IT201900008040A1 (it) 2019-06-04 2020-12-04 Pool Service S R L Composizione in gel per colorare ad ossidazione capelli ed altre fibre cheratiniche, e relativo metodo di colorazione
RU2745210C1 (ru) * 2020-05-06 2021-03-22 Юлия Васильевна Дикунова-Перцева Способ лессировочного окрашивания волос (варианты) и композиции для его осуществления

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3981677A (en) * 1974-01-02 1976-09-21 Clairol Incorporated Oxidative hair dye compositions containing N-substituted o-phenylenediamines and method for their use
US4992077A (en) * 1986-08-21 1991-02-12 Goldwell Gmbh Agent for the oxidative dyeing of hair, method for the preparation of the agent and use of the agent
US5112359A (en) * 1990-06-04 1992-05-12 Clairol, Inc. Hair colorants
US5173085A (en) * 1982-12-07 1992-12-22 Clairol Incorporated Hair dyeing process and compositons package
US5199954A (en) * 1992-02-25 1993-04-06 Shiseido Co., Ltd. Hair coloring dyes incorporating aryl amines and aryl aldehydes

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3981677A (en) * 1974-01-02 1976-09-21 Clairol Incorporated Oxidative hair dye compositions containing N-substituted o-phenylenediamines and method for their use
US5173085A (en) * 1982-12-07 1992-12-22 Clairol Incorporated Hair dyeing process and compositons package
US4992077A (en) * 1986-08-21 1991-02-12 Goldwell Gmbh Agent for the oxidative dyeing of hair, method for the preparation of the agent and use of the agent
US5112359A (en) * 1990-06-04 1992-05-12 Clairol, Inc. Hair colorants
US5199954A (en) * 1992-02-25 1993-04-06 Shiseido Co., Ltd. Hair coloring dyes incorporating aryl amines and aryl aldehydes

Cited By (37)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0918503A1 (fr) * 1995-12-29 1999-06-02 The Procter & Gamble Company Compositions pour teintures capillaires
EP0918503A4 (fr) * 1995-12-29 2000-07-12 Procter & Gamble Compositions pour teintures capillaires
EP0788787A3 (fr) * 1996-02-10 1997-10-22 Wella Ag Composition de teinture des cheveux par oxydation à base d'un véhicule gélifié
EP0803192A1 (fr) * 1996-04-24 1997-10-29 Nunez, Omar Cristian Produit ectoparasiticide antimycotique pour usage externe
JPH1053522A (ja) * 1996-04-24 1998-02-24 Omar Cristian Nunez 外用の抗真菌性及び殺虫性生成物
US6010541A (en) * 1996-07-23 2000-01-04 L'oreal Oxidation dye composition for keratin fibers comprising a nonionic amphiphilic polymer
US6344063B1 (en) 1996-07-23 2002-02-05 L'oreal Oxidation dye composition for keratin fibers comprising nonionic amphiphilic polymer
US6277155B1 (en) 1996-07-23 2001-08-21 L'oreal Oxidation dye composition for keratin fibers comprising a nonionic amphiphilic polymer
US6527814B1 (en) 1996-09-06 2003-03-04 L'oreal S.A. Oxidation dye composition for keratin fibers, comprising an anionic amphiphilic polymer
US5989295A (en) * 1996-09-06 1999-11-23 L'oreal Oxidation dye composition for keratin fibres, comprising an anionic amphiphilic polymer
US6074439A (en) * 1996-09-06 2000-06-13 L'oreal Oxidation dye composition for keratin fibers containing an oxidation dye precursor and an anionic amphiphilic polymer
US5976195A (en) * 1996-09-06 1999-11-02 L'oreal Oxidation dye composition for keratin fibers containing an oxidation dye precursor and amphiphilic polymer
WO1999008650A2 (fr) * 1997-08-20 1999-02-25 L'oreal Utilisation d'acide ascorbique pour des compositions destinees aux permanentes et a la coloration des cheveux
WO1999008650A3 (fr) * 1997-08-20 1999-05-14 Oreal Utilisation d'acide ascorbique pour des compositions destinees aux permanentes et a la coloration des cheveux
US6428580B2 (en) 1997-08-20 2002-08-06 L'oreal Use of ascorbic acid in permanent waving and hair coloring compositions
EP0950394A1 (fr) * 1998-03-31 1999-10-20 Spring Kosmetik GmbH & Co. KG Procédé et moyens pour la teinture d'oxydation des cheveux
EP1159254A1 (fr) * 1999-03-05 2001-12-05 Milliken & Company Intermediaire aminophenol a substitution oxyalkylene
EP1159254A4 (fr) * 1999-03-05 2002-10-30 Milliken & Co Intermediaire aminophenol a substitution oxyalkylene
WO2001043719A1 (fr) * 1999-12-17 2001-06-21 Unilever Plc Composition de traitement capillaire contenant des tensioactifs cationiques
US6645480B2 (en) 1999-12-17 2003-11-11 Unilever Home & Personal Care Usa, A Division Of Conopco, Inc. Hair treatment composition
CN100488487C (zh) * 1999-12-17 2009-05-20 荷兰联合利华有限公司 含有阳离子表面活性剂的头发处理组合物
WO2003082235A1 (fr) * 2002-03-26 2003-10-09 Alberto-Culver Company Composition de conditionneur capillaire
US6730641B2 (en) 2002-03-26 2004-05-04 Alberto-Culver Company Hair conditioning composition
FR2852832A1 (fr) * 2003-03-25 2004-10-01 Oreal Composition de coloration pour fibres keratiniques comprenant un acide hydroxycarboxilique ou un sel, composition prete a l'emploi la comprenant, procede de mise en oeuvre et dispositif
US7267696B2 (en) 2003-03-25 2007-09-11 L'oreal S.A. Composition for dyeing keratinous fibers, comprising a hydroxycarboxylic acid or a salt, ready-to-use composition comprising it, implementation process and device
FR2852828A1 (fr) * 2003-03-25 2004-10-01 Oreal Composition de traitement des matieres keratiniques comprenant un acide hydroxycarboxylique et un agent protecteur ou conditionneur
WO2005063177A1 (fr) * 2003-12-19 2005-07-14 Henkel Kommanditgesellschaft Auf Aktien Agents cosmetiques a deux ou plusieurs phases presentant un meilleur comportement de melange et de separation reversible
EP2138154B1 (fr) 2008-06-27 2018-07-25 Beiersdorf AG Après-shampoing doté d'amphotenside et d'une stabilité de stockage particulière
EP2138154B2 (fr) † 2008-06-27 2024-08-07 Beiersdorf AG Après-shampoing doté d'amphotenside et d'une stabilité de stockage particulière
WO2013007606A3 (fr) * 2011-07-08 2013-03-07 Unilever Plc Composition de soins capillaires
US10022312B2 (en) 2014-01-24 2018-07-17 Combe Incorporated Gradual haircolor compositions and methods of using the same
RU2679606C2 (ru) * 2014-01-24 2019-02-12 Комбе Интернэйшнл Лтд. Композиции для постепенного окрашивания волос и способы применения таких композиций
FR3060352A1 (fr) * 2016-12-21 2018-06-22 L'oreal Composes phosphates comme anti-infrarouge
FR3078488A1 (fr) * 2018-03-01 2019-09-06 L'oreal Composition cosmetique comprenant des tensioactifs non ioniques de type alcools gras polyoxyalkylenes et des tensioactifs cationiques, procede de traitement cosmetique et utilisation
IT201900008040A1 (it) 2019-06-04 2020-12-04 Pool Service S R L Composizione in gel per colorare ad ossidazione capelli ed altre fibre cheratiniche, e relativo metodo di colorazione
RU2745210C1 (ru) * 2020-05-06 2021-03-22 Юлия Васильевна Дикунова-Перцева Способ лессировочного окрашивания волос (варианты) и композиции для его осуществления
WO2021225471A1 (fr) * 2020-05-06 2021-11-11 Dikunova Pertseva Yulia Procédé de coloration des cheveux par glacis (variantes) et composition pour sa mise en oeuvre

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ZA936162B (en) 1994-03-17
IL106775A0 (en) 1993-12-08

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