WO1994003288A1 - Procede d'elimination du dioxyde de carbone - Google Patents
Procede d'elimination du dioxyde de carbone Download PDFInfo
- Publication number
- WO1994003288A1 WO1994003288A1 PCT/SE1993/000649 SE9300649W WO9403288A1 WO 1994003288 A1 WO1994003288 A1 WO 1994003288A1 SE 9300649 W SE9300649 W SE 9300649W WO 9403288 A1 WO9403288 A1 WO 9403288A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- carbon dioxide
- disposal
- dry ice
- bodies
- water
- Prior art date
Links
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 title claims abstract description 105
- 239000001569 carbon dioxide Substances 0.000 title claims abstract description 44
- 229910002092 carbon dioxide Inorganic materials 0.000 title claims abstract description 44
- 238000000034 method Methods 0.000 title claims abstract description 8
- 235000011089 carbon dioxide Nutrition 0.000 claims abstract description 16
- 239000013535 sea water Substances 0.000 claims abstract description 8
- 239000007787 solid Substances 0.000 claims abstract description 6
- 230000001427 coherent effect Effects 0.000 claims abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 15
- 238000002485 combustion reaction Methods 0.000 claims description 5
- 239000007789 gas Substances 0.000 claims description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 4
- 229910052799 carbon Inorganic materials 0.000 claims description 4
- 239000003546 flue gas Substances 0.000 claims description 3
- 238000009833 condensation Methods 0.000 claims description 2
- 230000005494 condensation Effects 0.000 claims description 2
- 238000011109 contamination Methods 0.000 claims description 2
- 238000001816 cooling Methods 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims description 2
- 241000282465 Canis Species 0.000 claims 1
- KRTSDMXIXPKRQR-AATRIKPKSA-N monocrotophos Chemical compound CNC(=O)\C=C(/C)OP(=O)(OC)OC KRTSDMXIXPKRQR-AATRIKPKSA-N 0.000 claims 1
- 239000004576 sand Substances 0.000 claims 1
- 239000002982 water resistant material Substances 0.000 claims 1
- 239000000463 material Substances 0.000 abstract description 8
- 239000007788 liquid Substances 0.000 description 8
- 239000010410 layer Substances 0.000 description 3
- 238000009825 accumulation Methods 0.000 description 2
- 230000035508 accumulation Effects 0.000 description 2
- 159000000014 iron salts Chemical class 0.000 description 2
- 239000002344 surface layer Substances 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- 241000282320 Panthera leo Species 0.000 description 1
- RJKFOVLPORLFTN-LEKSSAKUSA-N Progesterone Chemical group C1CC2=CC(=O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H](C(=O)C)[C@@]1(C)CC2 RJKFOVLPORLFTN-LEKSSAKUSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000004826 seaming Methods 0.000 description 1
- 239000013049 sediment Substances 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 238000000859 sublimation Methods 0.000 description 1
- 230000008022 sublimation Effects 0.000 description 1
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C1/00—Pressure vessels, e.g. gas cylinder, gas tank, replaceable cartridge
- F17C1/007—Underground or underwater storage
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09B—DISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
- B09B1/00—Dumping solid waste
- B09B1/002—Sea dumping
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2201/00—Vessel construction, in particular geometry, arrangement or size
- F17C2201/01—Shape
- F17C2201/0176—Shape variable
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2203/00—Vessel construction, in particular walls or details thereof
- F17C2203/06—Materials for walls or layers thereof; Properties or structures of walls or their materials
- F17C2203/0634—Materials for walls or layers thereof
- F17C2203/0658—Synthetics
- F17C2203/066—Plastics
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2221/00—Handled fluid, in particular type of fluid
- F17C2221/01—Pure fluids
- F17C2221/013—Carbone dioxide
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2223/00—Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel
- F17C2223/01—Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel characterised by the phase
- F17C2223/0146—Two-phase
- F17C2223/0176—Solids and gas
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2223/00—Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel
- F17C2223/01—Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel characterised by the phase
- F17C2223/0192—Three-phase, e.g. CO2 at triple point
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2260/00—Purposes of gas storage and gas handling
- F17C2260/04—Reducing risks and environmental impact
- F17C2260/044—Avoiding pollution or contamination
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2270/00—Applications
- F17C2270/01—Applications for fluid transport or storage
- F17C2270/0102—Applications for fluid transport or storage on or in the water
- F17C2270/0118—Offshore
- F17C2270/0128—Storage in depth
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
- Y02C20/00—Capture or disposal of greenhouse gases
- Y02C20/40—Capture or disposal of greenhouse gases of CO2
Definitions
- the present invention relates to. a method for the riddance of carbon dioxide by disposal into deep sea water of carbon di ⁇ oxide being brought to be present in solid form at a low tempera ⁇ ture at atmospheric pressure, so called dry ice.
- Enormous amounts of carbon dioxide are created mainly during combustion.
- the total amount of carbon dioxide received from com ⁇ bustion in the world is estimated to run up to more than 20 bil ⁇ lions ton a year. Such an amount cannot be obsorbed by growing plants and the sea water.
- the amount of carbon dioxide is instead increased in the atmosphere, probably resulting in a raise of the medium temperature on earth, the so called glass house effect.
- the pressure is so high and the temperature so low, that the carbon dioxide deposited in solid state at said depth is gradually converted to liquid state and remains thereafter in said state lying at the bottom of the sea, carbon dioxide at said pressure having a density larger than that of sea water.
- the disposal can be made not less than at a depth of fifteen hundred meters or more so that the liquid carbon di ⁇ oxide being extremely little soluable in water, will remain fore ⁇ ver at the disposal site. If really deep sea areas can be found, e.g. where the depth is ten thousand meters, it is obviously con ⁇ venient to use such depths, the costs for descending of the car ⁇ bon dioxide dry ice are the same independant of the depth in contrast to try to pump liquid carbon dioxide down to such depth. It is the purpose of the present invention to find a simple and economically defendable solution of the discussed problem.
- the method according to the invention normally implies a conveyance of the dry ice blocks and the ballast to the disposal site, the blocks are conveniently during conveyance stored in heat isolating containers with or without cooling devices.
- the mixture of carbon dioxide and any ballast is arranged to take place within or nearby the combustion plant, where the carbon dioxide and even other contaminations in the flue gases are sedi- mented by condensation or rather sublimation at low temperature.
- Figure 1 is a side view, partly in section, of a compressed body of dry ice and ballast material in an envelope of plastic material
- figure 2 shows a cross section through a heat isolating conveyance container
- figure 3 is a side view, partly in section, of carbon dioxide deposited at the bottom of the sea.
- Figure 1 shows a body 1 comprised of carbon dioxide dry ice being compressed or compacted to a block of carbon dioxide dry ice together with a mass of stones and gravel 3, distributed throughout the block volume with an accumulation at the side sur ⁇ faces and especially at the bottom 4.
- the block is surrounded by a plastic foil bag 5 being tied up at the top without being com ⁇ pletely closed.
- the block 1 is stored in a conveyance container 10 of heat isolating material according to figure 2 and with an openable bottom 11 of the same material.
- the bottom 11 of the conveyance container 10 is opened at the disposal site and the block 1 together with the appartaining envelope 5 is dumped into the water 12, in which the block and the envelope with a volume of some cubic meters is according to figur 3 swiftly and without any major heat exchange or loss of carbon dioxide to the surrounding water sinking down to the bot ⁇ tom of the sea 20.
- the carbon dioxide dry ice is under the prevailing pressure and temperature with the depth being at least fifteen hundred meters converted to liquid carbon dioxide with a density being larger than that of the water.
- the carbon dioxide not remaining in the envelope 5 runs out onto the bottom 20 and creates large accumulations 21 of liquid carbon dioxide, in time possibly being covered with a layer 22 of light, solid material continually sinking down through the water onto the bottom of the sea and forming bottom sediments.
- ballast also other materials can be baked into the blocks during their compression, such as algeols, iron salts, carbon dioxide consuming bacteria and fungi and further materials with a positive influence on the environment prevailing at the bottom of the sea, often being enriched with sulphur and poor of oxygen.
Landscapes
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
- Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Treating Waste Gases (AREA)
Abstract
L'invention concerne un procédé d'élimination du dioxyde de carbone par immersion en mer à grande profondeur du dixoyde de carbone rendu solide à basse température à la pression atmosphérique, sous forme de neige carbonique. Pour permettre un transport rapide des blocs de neige carbonique à grandes profondeurs, le dioxyde de carbone sublimé/condensé, c'est-à-dire la neige carbonique, est compressé ou compacté avec du ballast (3) tel que du gravier ou tout autre matériau à haute densité afin d'obtenir des corps cohérents (1) présentant une densité essentiellement supérieure à celle de la neige carbonique (2). Avant de les immerger de préférence à une profondeur d'au moins 1500 mètres, lesdits corps sont enveloppés de manière appropriée dans une enveloppe en plastique perméable aux gaz (5).
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
SE9202224-3 | 1992-08-04 | ||
SE9202224A SE9202224L (sv) | 1992-08-04 | 1992-08-04 | Förfarande för kvittblivning av koldioxid |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1994003288A1 true WO1994003288A1 (fr) | 1994-02-17 |
Family
ID=20386830
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/SE1993/000649 WO1994003288A1 (fr) | 1992-08-04 | 1993-08-02 | Procede d'elimination du dioxyde de carbone |
Country Status (2)
Country | Link |
---|---|
SE (1) | SE9202224L (fr) |
WO (1) | WO1994003288A1 (fr) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1995022416A1 (fr) * | 1994-02-17 | 1995-08-24 | European Atomic Energy Community (Euratom), Commission Of The European Communities | Procede et vecteur de reduction du dioxyde de carbone atmospherique |
WO2018151907A1 (fr) * | 2017-02-15 | 2018-08-23 | Exxonmobil Research And Engineering Company | Séquestration de co2 à l'aide de calthrates |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1274051B (de) * | 1964-12-23 | 1968-08-01 | John V Dunlea Jun | Verfahren zur Auslagerung von Muell durch Verpressen des losen Muells zu Paketen undderen Versenken im Meer |
DE3924908A1 (de) * | 1989-07-27 | 1991-01-31 | Siemens Ag | Verfahren und anlage zur minderung des kohlendioxidgehalts der abgase bei fossiler verbrennung |
-
1992
- 1992-08-04 SE SE9202224A patent/SE9202224L/xx not_active Application Discontinuation
-
1993
- 1993-08-02 WO PCT/SE1993/000649 patent/WO1994003288A1/fr active Application Filing
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1274051B (de) * | 1964-12-23 | 1968-08-01 | John V Dunlea Jun | Verfahren zur Auslagerung von Muell durch Verpressen des losen Muells zu Paketen undderen Versenken im Meer |
DE3924908A1 (de) * | 1989-07-27 | 1991-01-31 | Siemens Ag | Verfahren und anlage zur minderung des kohlendioxidgehalts der abgase bei fossiler verbrennung |
Non-Patent Citations (1)
Title |
---|
Symposium on the Carbon Dioxide issue Presented Before the Division of Petroleum Chemistry, Inc., AMERICAN CHEMICAL SOCIETY, New York Meeting, 23-28 August 1981, MEYER STEINBERG: "Technologies for the Recovery and Disposal of Carbon Dioxide", pages 1038-46. * |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1995022416A1 (fr) * | 1994-02-17 | 1995-08-24 | European Atomic Energy Community (Euratom), Commission Of The European Communities | Procede et vecteur de reduction du dioxyde de carbone atmospherique |
US6190301B1 (en) | 1994-02-17 | 2001-02-20 | European Atomic Energy Community (Euratom), Commission Of The European Communities | Embedding of solid carbon dioxide in sea floor sediment |
WO2018151907A1 (fr) * | 2017-02-15 | 2018-08-23 | Exxonmobil Research And Engineering Company | Séquestration de co2 à l'aide de calthrates |
US10391445B2 (en) | 2017-02-15 | 2019-08-27 | Exxonmobil Research And Engineering Company | Sequestration of CO2 using clathrates |
Also Published As
Publication number | Publication date |
---|---|
SE9202224L (sv) | 1994-02-05 |
SE9202224D0 (sv) | 1992-08-04 |
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