WO1993021289A1 - Composition de matiere lubrifiante contenant un melange d'agents modifiant le frottement - Google Patents

Composition de matiere lubrifiante contenant un melange d'agents modifiant le frottement Download PDF

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Publication number
WO1993021289A1
WO1993021289A1 PCT/US1993/003378 US9303378W WO9321289A1 WO 1993021289 A1 WO1993021289 A1 WO 1993021289A1 US 9303378 W US9303378 W US 9303378W WO 9321289 A1 WO9321289 A1 WO 9321289A1
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Prior art keywords
composition
carbon atoms
amine
oil
hydrocarbyl
Prior art date
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PCT/US1993/003378
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English (en)
Inventor
Ricardo Alfredo Bloch
Andrew James Dalziel Ritchie
Jack Ryer
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Exxon Chemical Patents Inc.
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Application filed by Exxon Chemical Patents Inc. filed Critical Exxon Chemical Patents Inc.
Priority to CA002132523A priority Critical patent/CA2132523C/fr
Priority to JP5518516A priority patent/JPH07508049A/ja
Priority to EP93909306A priority patent/EP0638117A1/fr
Publication of WO1993021289A1 publication Critical patent/WO1993021289A1/fr

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Definitions

  • This invention relates to lubricaring oil compositions which exhibit enhanced fuel economy and which contain a minor amount of the friction modifier combination of an alkylated phenol sulfide and an alkoxylated hydrocarbyl amine.
  • 3,352,215 which discloses S-carboxy-alkylene hydrocarbyl succinimide, S-carboxyalkylene hydrocarbyl succinic acid and mixtures thereof;
  • U.S. Patent 3,879,306 which discloses N-(hydroxy-alkyl) alkenyl-succinamic acids or succinimides;
  • U.S. Patent No. 3,932,290 which discloses reaction products of di- (lower alkyl) phosphites and ep ⁇ xide ⁇ ;
  • U.S. Patent No. 4,028,258 which discloses the alkylene oxide adduct of phosphosulfurized N-(hydroxyalkyl) alkenyl succinimides.
  • Another known category of friction modifiers includes alkoxylated hydrocarbyl mono or polyamines such as generally illustrated by formulas 1 and 2 below.
  • These amines include materials such as N,N-bis(2-hydroxyalkyl) hydrocarbyl amines such as disclosed in U.S. Patents 3,711,406, 2,796,662, 3,533,659, 4,010,106, 4,129,508, 4,170,560, 4,231,883 and 4,795,583.
  • U.S. Patent 4,086,172 discloses an additive combination for lubricating oils comprising a mixture of an oil soluble hydroxy amine such as an alkoxylated fatty amine and an oil soluble antioxidant component such as an aromatic sulfide. The mixture is said to impart improved antioxidant properties into the oil.
  • U.S. Patent 4,938,880 discloses lubricant compositions which may contain a metal salt of a phenol sulfide and a friction modifier.
  • U.S. Patent 4,764,294 discloses a lubricating oil additive combination comprising a metal phosphate, a metal carbamate and an alkyl hydroxyl aryl sulfide (nonyl phenol sulfide). The combination of these three additives is said to provide a synergistic improvement in imparting anti-wear and friction reducing properties.
  • U.S. Patent 4,587,026 discloses an oil additive useful for friction reduction and improved stability.
  • This additive is an amine sulfurized concentrate prepared by forming the reaction product of an alkylated phenol sulfide, a boron-containing compound and an alkoxylated amine which may include bis (2-hydroxy ethyl) oleamide.
  • the evident structure of the reaction product is shown in claim 22 of this patent.
  • the present invention is based on the discovery that a combination of one or more alkoxylated hydrocarbylamines and one or more alkylated phenol sulfides, as defined herein, added to lubricating oil compositions in specific proportions imparts a more enhanced friction modifying property to the lubricant than an equivalent quantity of either component alone.
  • the present invention provides an improved lubricating oil composition for automotive internal combustion engines and transmissions which comprises an oil of lubricating viscosity having admixed therewith a minor amount of friction modifier composition which reduces the coefficient of friction between moving mechanical parts, thereby providing for enhanced fuel economy.
  • the friction modifier composition comprises a combination of an alkoxylated hydrocarbyl amine and an alkylated phenol sulfide. This combination of components provides for synergistic fuel economy effects, particularly when used as components in automotive crankcase lubricants also containing conventional additive packages, which effects are not observed in oil which contains one or the other of these components alone.
  • alkoxylated amines which are suitable as one component of the friction modifier composition of this invention have the general formula 1;
  • R 1 is a branched or straight chain hydrocarbyl group containing from about 8 to about 30 carbon atoms
  • R 2 and R 3 are independently the same or different branched or straight chain alkylene radicals containing 1 to 6 carbon atoms
  • R 4 , R 5 and R 6 are independently the same or different alkylene radicals containing from 2 to 4 carbon atoms
  • X is oxygen or sulfur
  • p is 0 or an integer ranging from 1 to 20
  • t is independently 0 or 1
  • a, b and c are independently integers ranging from 1 to 4.
  • R 1 is a saturated or ethylenically unsaturated hydrocarbyl group containing from 12 to 24 carbon atoms
  • R 2 and R 3 independently contain 2-4 carbon atoms
  • R 4 , R 5 and R 6 independently contain 2 or 3 carbon atoms
  • X is oxygen and a, b and c are independently integers of 1 or 2.
  • both p and t may be 1 or either p or t may be 1 when the other of them is 0, or p may be
  • the alkoxylated amine is a monoamine subgenus of formula 1, where p and t are each 0, having the formula 2 :
  • R 1 , R 4 , R 5 , a and b are as set forth above.
  • Illustrative of more preferred alkoxylated amines within the scope of this invention include N,N',N'-tri(2-hydroxyethyl) N-octadecyl propylene diamine, N,N',N'-tri(2-hydroxyethyl) N-octadecenyl propylene diamine, N,N',N'-tri(2-hydroxyethyl) N-hexadecyl propylene diamine, N,N',N'-tri(3-hydroxypropyl) N-octadecadienyl propylene diamine, N,N',N'-tri(2-hydroxyethyl) N-octadecyl ethylene diamine, N,N',N'-tri(2-hydroxyethyl) N-octadecenyl ethylene diamine, N,N' ,N'-tri(2-hydroxyethyl) N-tetradecyl propylene diamine, N
  • N,N-di(2-hydroxyethyl)-n-dodecyloxpropylamine N,N-di(2-hydroxyethyl)-stearyloxypropylamine
  • N,N-di(2-hydroxyethyl)-dodecylthiopropylamine N,N-di(2-hydroxyethyl)-hexadecylthioethylamine, N,N-di(2-hydroxyethyl)-hexadecylthiopropylamine, N-2-hydroxyethyl,N-[N',N'-bis(2-hydroxyethyl) ethylamine]-octadecylamine,
  • alkoxylated amines are those of formula 2 and wherein R 4 and R 5 each have 2 carbon atoms and include:
  • the hydroxyl amine compounds may be used as such. However they may also be used in the form of an adduct or reaction product with a boron compound, such as a boric oxide, a boron halide, a metaborate, boric acid, or a mono-, di-, or triorgano borate, such as a mono-, di-, and trialkyl borate.
  • a boron compound such as a boric oxide, a boron halide, a metaborate, boric acid, or a mono-, di-, or triorgano borate, such as a mono-, di-, and trialkyl borate.
  • a boronation agents include boric acid and boric acid esters, e.g., tributyl borate.
  • a stoichiometric amount of the boronating agent relative to the hydroxy groups present in the amine can be used or an excess of boronating agent of up to a 50-100% excess or more can be used and is often desirable for certain applications.
  • boronation can be complete or partial.
  • boronation levels vary from about 0.05 to about 7 weight % of boron in the boronated derivative.
  • the boronated derivatives are prepared in the presence of an alcoholic or hydrocarbon solvent.
  • a solvent is not essential, however. If one is used, it may be reactive or non-reactive.
  • Suitable non-reactive solvents include benzene, toluene, xylene and the like.
  • Suitable reactive solvents include isopropanol, butanol, the pentanols and the like. Reaction temperatures may vary from about 70 to abut 250°C with about 110° to about 170oC being preferred.
  • the second essential component of the friction modifier composition of this invention is one or a mixture of hydrocarbyl phenol sulfides having the following general formula 3:
  • R 7 and R 8 may be hydrogen or the same or different hydrocarbyl radicals containing from about 5 to 40 carbon atoms, at least one of R 7 or
  • R 8 being a hydrocarbyl radical
  • x is an integer of from 1 to 4
  • n is 0 or an integer of from 1 to 4.
  • R 7 is an alkyl group of sufficient chain length to render the phenol sulfide compound oil soluble and preferably contains an average of from about 8 to 20 carbon atoms
  • n is 0, 1 or 2
  • x is 1 or 2
  • R 8 is hydrogen.
  • R 7 is located in a position para to the hydroxyl group and sulfur is linked to the aromatic nucleus at positions ortho to the hydroxyl group.
  • hydrocarbyl phenol sulfides are known materials which have been used in lubricant compositions primarily as antioxidants . They may be readily prepared by the direct sulfurization of hydrocarbyl phenols or by reaction with a sulfur halide such as sulfur dichloride or sulfur monochloride.
  • the reaction product generally comprises mixed phenol sulfide isomers, with the specific isomers described above forming the major component of the mixture.
  • the preferred phenol sulfides for use in this invention are based primarily on C 8 through C 16 phenol monosulfides and include para nonylphenol monosulfide and para dodecylphenol monosulfide as the primary isomers.
  • the lubricating oil base into which the friction modifier composition of this invention may be incorporated includes automotive crankcase and transmission oils of lubricating viscosity for both diesel and gasoline engines, including natural and synthetic lubricating oils and mixtures thereof.
  • Natural oils include animal oils and vegetable oils such as castor oil or lard oil, liquid petroleum oils and hydrorefined oils, solvent-treated or acid-treated mineral lubricating oils of the paraffinic, naphthenic and mixed paraffinic-naphthenic types. Oils of lubricating viscosity derived from coal or shale are also useful base oils.
  • Synthetic lubricating oils include hydrocarbon and halo-substituted hydrocarbon oils such as polymerized and interpolymerized olefins (e.g., polybutylenes, polypropylenes, propylene-isobutylene copolymers, chlorinated polybutylenes, poly(1-hexenes), poly (1-octenes), poly(1-decenes); alkylbenezenes (e.g., dodecylbenzenes, tetradecylbenzenes, dinonylbenzenes, di(2-ethylhexyl) benzenes); and polyphenyls (e.g., biphenyls, terphenyls, alkylated polyphenois).
  • polymerized and interpolymerized olefins e.g., polybutylenes, polypropylenes, propylene-isobutylene copolymers, chlorinated
  • Alkylene oxide polymers and interpolymers and derivatives thereof where the terminal hydroxyl groups have been modified by esterification or etherification constitute another class of known synthetic lubricating oils. These are exemplified by polyoxylalkylene polymers prepared by polymerization of ethylene oxide or propylene oxide, and include the alkyl and aryl ethers of these poly ⁇ xyalkylene polymers such as methyl-polyisopropylene glycol ether having an average molecular weight of 1000, diphenyl ether of polyethylene glycol having a molecular weight of 500-1000, diethyl ether of polypropylene glycol having a molecular weight of 1000-1500, and mono-and polycarboxylic esters thereof such as acetic acid esters, mixed C 3 to C 6 fatty acid esters and the C 13 Oxo acid diester of tetraethylene glycol.
  • Another suitable class of synthetic lubricating oils comprises one or more esters of dicarboxylic acids (e.g., phthalic acid, succinic acid, alkyl succinic acids and alkenyl succinic acids, maleic acid, azelaic acid, suberic acid, sebasic acid, fumaric acid, adipic acid, linoleic acid dimer, malonic acid, alkylmalonic acids and alkenyl malonic acids) with a variety of alcohols (e.g., butyl alcohol, hexyl alcohol, dodecyl alcohol, 2-ethylhexyl alcohol, ethylene glycol, diethylene glycol monoether and propylene glycol).
  • dicarboxylic acids e.g., phthalic acid, succinic acid, alkyl succinic acids and alkenyl succinic acids, maleic acid, azelaic acid, suberic acid, sebasic acid, fumaric acid, adipic acid, lin
  • esters include dibutyl adipate, di(2-ethylhexyl) sebacate, di-n-hexyl fumarate, dioctyl sebacate, diisooctyl azelate, diisodecyl azelate, dioctyl phthalate, dodecyl phthalate, dieicosyl sebacate, the 2-ethylhexyl diester of linoleic acid dimer, and the complex ester formed by reacting one mole of sebacic acid with two moles of tetraethylene glycol and two moles of 2-ethylhexanoic acid.
  • Esters useful as synthetic oils also include those made from C 5 to C 12 monocarboxylic acids and polyols and polyol ethers such as neopentyl glycol, trimethylolpropane, pentaerythritol, dipentaerythritol and tripentaerythritol.
  • Silicon-based oils such as the polyalkyl, polyaryl-polyalkoxy-, or polyaryloxysiloxane oils and silicate oils comprise another useful class ofsynthetic lubricants. These include tetraethyl silicate, tetraisopropyl silicate, tetra-(2-ethylhexyl) silicate, tetra-(4-methyl-2-ethylhexyl) silicate tetra-(p-tert-butyl-phenyl) silicate, hexa-(4-methyl-2-pentoxy) disiloxane, poly(methyl) siloxanes and poly(methylphenyl) siloxanes.
  • Other synthetic lubricating oils include liquid esters of phosphorus-containing acids (e.g., tricresyl phosphate, trioctyl phosphate, diethyl ester of decylphosphonic acid) and polymeric tetrahydrofurans.
  • Unrefined, refined and rerefined oils can be used in the lubricants of the present invention.
  • Unrefined oils are those obtained directly from a natural or synthetic source without further purification treatment.
  • a shale oil obtained directly from retorting operations a petroleum oil obtained directly from distillation or ester oil obtained directly from an esterification process and used without further treatment would be an unrefined oil.
  • Refined oils are similar to the unrefined oils except they have been further treated in one or more purification steps to improve one or more properties. Many such purification techniques, such as distillation, solvent extraction, acid or base extraction, filtration and percolation are known to those skilled in the art.
  • Rerefined oils are obtained by processes similar to those used to obtain refined oils, but applied to refined oils which have been already used in service. Such rerefined oils are also known as reclaimed or reprocessed oils and often are additionally processed by techniques for removal of spent additives and oil breakdown products.
  • the components of the friction modifier composition of this invention are each blended into the lube oil base stock in amounts which reduce the friction coefficient between the mechanical parts of the engine or other apparatus in which they are used, thereby enhancing fuel economy.
  • the amount of alkoxylated amine added to the base oil will range from about 0.05 to 1.0% by weight, more preferably from about 0.1 to 0.5% by weight.
  • the amount of hydrocarbyl phenol sulfide added to the base oil will range from about 0.1 to 2.5% by weight, more preferably from about 0.2 to 1.0% by weight.
  • the preferred weight ratio of the alkoxylated amine to the phenol sulfide is in the range of from about 0.2 to 2.5:1 respectively, more preferably from about 0.4 to 1.5:1 respectively.
  • the phenol sulfide is present in an amount in excess of the amount of the amine, preferably at least about a 2 to 1 to 5 to 1 weight excess.
  • the lubricant oil of this invention is preferably also admixed with one or more additional additives to form a fully formulated oil.
  • additional additives include dispersants, detergents, oxidation inhibitors, viscosity modifiers, corrosion inhibitors, other friction modifiers, antifoaming agents, anti wear agents and the like.
  • Suitable dispersants which may be employed are known in the art.
  • a preferred class of dispersant are the ashless dispersants which are normally nitrogen-containing, oil-soluble salts, amides, imides or esters of mono or dicarboxylic acids.
  • a particularly preferred dispersant is the reaction product of a polyolefin-substituted succinic anhydride such as polyisobutenyl succinic anhydride and an alkylene polyamine, which can be further treated with a source of boron or copper.
  • a polyolefin-substituted succinic anhydride such as polyisobutenyl succinic anhydride and an alkylene polyamine, which can be further treated with a source of boron or copper.
  • Such a material is disclosed in U.S. Patent 4,938,880, the complete disclosure of which is incorporated herein by reference.
  • Such dispersants are generally added to the oil in amounts ranging from about 0.1 to about 10% by weight.
  • Metal containing rust inhibitors and/or detergents are frequently used with ashless dispersants.
  • Such detergents and rust inhibitors include the metal salts of sulphonic acids, fatty acid esters such as glycerol mono and/or di stearate (which also function as friction modifiers), alkyl phenols, sulfurized alkyl phenols, alkyl salicylates, naphthenates, and other oil soluble mono- and di-carboxylic acids.
  • Highly basic, that is ⁇ verbased metal salts, which are frequently used as detergents include calcium or magnesium phenates, sulfurized phenates and/or sulfonates.
  • metal containing inhibitors and detergents are used in lubricating oil in amounts of about 0.01 to 10 wt. %, more preferably about 0.1 to 5 wt. %, based on the weight of the total lubricating composition.
  • Marine diesel lubricating oils typically employ such metal-containing rust inhibitors and detergents in amounts up to about 20 wt. %.
  • the lube oil may also contain one or more suitable antioxidants and/or oxidation inhibitors.
  • suitable antioxidants include phenols, hindered phenols, bis-phenols, sulfurized phenols, catechol, alkylated and sulfurized alkylated catechols, diphenylamine, alkylated diphenylamines and phenyl-l-naphthlamines, alkyl and aryl borates, phosphites and phosphates, trialkyl and triaryl dithiophosphates and the like.
  • Other antioxidants include oil soluble copper compounds.
  • the copper compound may be in the cuprous and cupric form.
  • the copper may be in the form of copper dihydrocarbyl thio- or dithio-phosphates.
  • the copper may be added as the copper salt of a synthetic or natural carboxylic acid.
  • a synthetic or natural carboxylic acid examples include C 10 to C 18 fatty acids such as stearic or palmitic.
  • Unsaturated acids such as oleic or branched carboxylic acids such as napththenic acids of molecular weight from 200 to 500 or synthetic carboxylic acids are preferred because of the improved handling and solubility properties of the resulting copper carboxylates.
  • Also useful are oil soluble copper dithiocarbamates. Copper sulphonates, phenates, and acetylacetonates may also be used.
  • the copper antioxidant can comprise a copper salt of a hydrocarbyl substituted C 4 to C 10 monounsaturated dicarboxylic acid producing reaction product, which reaction product is formed by reacting a polymer of a C 3 to C 10 monoolefin having a number average molecular weight of 900 to 1400 (e.g., 700 to 1200) substituted with a C 4 to C 10 monosaturated acid material.
  • Exemplary are copper salts of a hydrocarbyl substituted C 4 to C 10 monounsaturated dicarboxylic acid producing reaction product, which reaction product is formed by reacting a polymer of C 2 to C 10 monoolefin having a number average molecular weight of from 900 to 1400 substituted with succinic moieties selected from the group consisting of acid, anhydride and ester groups, wherein there is an average of about 0.8 to 1.6 molar proportions of succinic moieties per molar proportion of the polymer.
  • the copper antioxidants will generally be added to the oil in an amount of from about 50-500 ppm by weight of the metal.
  • Corrosion inhibitors also known as anti-corrosive agents, reduce the degradation of the metallic parts contacted by the lubricating oil composition.
  • Illustrative of corrosion inhibitors are phosphosulfurized hydrocarbons and the products obtained by reaction of a phosphosulfurized hydrocarbon with an alkaline earth metal oxide or hydroxide, preferably in the presence of an alkylated phenol or of an alkylphenol thioester, and also preferably in the presence of carbon dioxide.
  • Phosphosulfurized hydrocarbons are prepared by reacting a suitable hydrocarbon such as a terpene, a heavy petroleum fraction of a C 2 to C 6 olefin polymer such as polyisobutylene, with from 5 to 30 weight percent of a sulfide of phosphorus for 0.5 to 15 hours, at a temperature in the range of 150° to 600°C. Neutralization of the phosphosulfurized hydrocarbon may be effected in the manner taught in U.S. Patent 1,969,324.
  • Oxidation inhibitors reduce the tendency of mineral oils to deteriorate in service which deterioration can be evidenced by the products of oxidation such as sludge and varnish-like deposits on the metal surfaces and viscosity growth.
  • oxidation inhibitors include alkaline earth metal salts of alkylphenolthioesters having preferably C 5 to C 12 alkyl side chains, calcium nonylphenol sulfide, barium t-octylphenyl sulfide, dioctylphenylamine, phenylalphanaphthylamine, phosphosulfurized or sulfurized hydrocarbons, etc.
  • Pour point depressants lower the temperature at which the oil will flow or can be poured. Such depressants are well known. Typical of those additives which usefully optimize the low temperature fluidity of the oil are C 8 -C 1 8 dialkylfumarate/vinyl acetate copolymers, polymethacrylates, and wax napthalene.
  • Foam control can be provided by an antifoamant of the polysiloxane type, e.g. silicone oil and polydimethyl siloxa ⁇ e.
  • an antifoamant of the polysiloxane type e.g. silicone oil and polydimethyl siloxa ⁇ e.
  • dihydrocarbyl dithiophosphate metal salts which are frequently used as anti-wear agents and which also provide antioxidant activity. These compounds may be generally characterized by the formula
  • R 9 and R 10 are each independently hydrocaryl groups containing from 3 to about 13 carbon atoms, M is a metal and n is an integer equal to the valence of M.
  • the hydrocarbyl groups in the phosphorodithioate structure include alkyl, cycloalkyl or alkaryl groups which may contain ether or ester linkages and which may also contain substituent groups such as halogen or nitro.
  • Illustrative alkyl groups include isopropyl, isobutyl, n-butyl, sec-butyl, amyl, n-hexyl, methylisobutyl carbinyl, heptyl, 2-ethylhexyl, diisobutyl, isooctyl, nonyl, behenyl, decyl, dodecyl, tridecyl, etc.
  • Illustrative lower alkylphenyl groups include xylyl, cresyl, butylphenyl, amylphenyl, heptyl-phenyl, etc.
  • cycloalkyl groups likewise are useful and these include chiefly cyclohexyl and the lower alkyl-cyclohexyl radicals.
  • Many substituted hydrocarbon groups may also be used, e.g., chloropentyl, dichlorophenyl, and dichlorodecyl.
  • These compounds are prepared by first forming the relevant phosphorodithioic acid and then reacting this product with a suitable metal containing compound.
  • the phosphorodithioic acids are prepared by the reaction of phosphorus pentasulfide with an alcohol or phenol or mixtures of alcohols, mixtures of phenols or mixtures of alcohols and phenols.
  • the reaction involves four moles of the alcohol or phenol per mole of phosphorus pentasulfide, and may be carried out within the temperature range from about 50°C to about 200°C, preferably from about 50oC to about 150°C.
  • the preparation of O,O-di-n-hexyl phosphorodithioic acid involves the reaction of phosphorus pentasulfide with four moles of n-hexyl alcohol at about 100°C for about two hours.
  • the preparation of the metal salt of this acid may be effected by reaction with metal oxide. Simply mixing and heating these two reactants is sufficient to cause, the reaction to take place and the resulting product is sufficiently pure for the purposes of this invention.
  • the metal salts of dihydrocarbyl phosphorodithioates which are useful in this invention include those salts containing Group I metals. Group II metals, aluminum, lead, tin, manganese, cobalt, and nickel. The Group II metals, tin, iron, cobalt, lead, manganese, nickel and copper are among the preferred metals. Zinc and copper are especially useful metals.
  • metal compounds which may be reacted with the acid include lithium oxide, lithium hydroxide, sodium hydroxide, sodium carbonate, potassium hydroxide, potassium carbonate, silver oxide, magnesium oxide, magnesium hydroxide, calcium oxide, zinc hydroxide, zinc oxide, copper oxide, strontium hydroxide, cadmium oxide, cadmium hydroxide, barium oxide, iron carbonate, copper hydroxide, lead hydroxide, tin butylate, cobalt hydroxide, nickel hydroxide, nickel carbonate and the like.
  • the incorporation of certain ingredients such as small amounts of the metal acetate or acetic acid in conjunction with the metal reactant will facilitate the reaction and result in an improved product.
  • certain ingredients such as small amounts of the metal acetate or acetic acid in conjunction with the metal reactant
  • the use of up to about 5% of zinc acetate in combination with the required amount of zinc oxide facilitates the formation of a zinc phosphorodithioate.
  • the alkyl groups R 9 and R 10 in the formula above are derived from secondary alcohols such as isopropyl alcohol, secondary butyl alcohol, 2-pentanol, 4-methyl-2-pentanol, 2-hexanol, 3-hexanol, as well as mixtures thereof.
  • viscosity modifiers impart high and low temperature operability to the lubricating oil and permit it to remain relatively viscous at elevated temperatures and also exhibit acceptable viscosity or fluidity at low temperatures.
  • Viscosity modifiers are generally high molecular weight polymers, including polyesters, polymethacrylates, polyacrylates and polyolefins. The viscosity modifiers may also be derivatized to include other properties or functions, such as the addition of dispersancy properties.
  • oil soluble viscosity modifying polymers will generally have number average molecular weights of from 10 3 to 10 6 , preferably 10 4 to 10 6 , e.g., 20,000 to 250,000, as determined by gel permeation chromotography or osmometry.
  • suitable hydrocarbon polymers include homopolymers and copolymers of two or more C 2 to C 30 olefin monomers, e.g. C 2 to C 8 olefins, including both alpha olefins and internal olefins, which may be straight or branched, aliphatic, aromatic, alkyl-aromatic, cycloaliphatic, etc.
  • Particularly preferred polymers are polyisobutylenes, homopolymers and copolymers of C 2 and hiqher aloha olefins, atactic polypropylene, hydrogenated polymers and copolymers and terpolymers of styrene, e.g. with isoprene and/or butadiene and hydrogenated derivatives thereof.
  • the polymer may be degraded in molecular weight, for example by mastication, extrusion, oxidation or thermal degradation, and may contain oxygen.
  • These viscosity modifiers are normally added to the oil composition at a level within the range of from about 0.1 to about 10% by weight.
  • additives which serves to stabilize the compatibility of lubricant compositions containing relatively high levels of friction modifiers.
  • additives include hydrocarbyl substituted succinic anhydrides, more preferably polyolefin-substituted succinic anhydride wherein the polyolefin has a number average molecular weight of from about 500 to 10,000, more preferably from about 1000 to 3000.
  • Preferred polyolefin substituent groups include polyisobutylene, polybutene-1, as well as copolymers of butene-1 with ethylene and/or propylene.
  • Polyisobutyenyl succinic anhydride is a preferred compatibilizer for this purpose.
  • This ingredient may be present in the lubricant composition at a level within the range of about 0.1 to 5% by weight, and is preferably present at about the same level as the total weight of friction modifier additives.
  • compositions which contain one or more of these numerous additives are typically blended by physical admixture into the lube oil in amounts effective to provide their normal attendant function.
  • compositions within the scope of this invention can be demonstrated using what is referred to as a Sequence VI Dynanometer Fuel economy test, more specifically described as the ASTM Sequence VI test method RR: DO-2: 1204. This test is run using a 3.8 liter Buick V-6 engine equipped with cooling means to maintain a relatively constant engine oil temperature of 150°F or 275°F, coupled to a power absorbing dynanometer such that the engine speed and power output can be tightly controlled.
  • the lubricant to be evaluated is first flushed into the engine and aged at an oil temperature of 225 deg. F for 32 hours.
  • the engine is then set to a specific speed and power output, and the test is conducted at the temperature for the two test stages of 150 deg. F and 275 deg. F.
  • the engine is calibrated prior to each candidate run, using industry standard viscosity and friction modified reference oils. At each stage the average brake specific consumption is calculated.
  • the lubricant in the engine is detergent flushed then flushed to an SAE 30 baseline oil and the measurements are repeated. These measurements are then used to calculate the Equivalent Fuel Economy Improvement (EFEI) of the candidate relative to the baseline oil.
  • EFEI Equivalent Fuel Economy Improvement
  • Sequence VI screener test Data reported here was collected either from the full ASTM Sequence VI test cycle or a shortened version of the Sequence VI test, referred to as a Sequence VI screener test, in which the test oil is aged for a reduced period of time.
  • a base control SAE 10W-30 formulation was prepared by mixing about 94.5 parts by volume of mineral oil with effective amounts of the following additive ingredients to total 100 parts: - Polybutenyl succinic anhydride polyamine product (borated);
  • Example 1 Control formulation + 0.5% V. mixed
  • Example 2 Control formulation + 0.2% V.
  • Example 3 Control formulation + 0.5% V. mixed
  • Example 4 Control formulation + 0.2% V.
  • Example 5 Control formulation + 0.5% V. mixed
  • Example 6 Control formulation + 0.2% V. borated

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Abstract

Cette invention concerne une composition d'huile lubrifiante destinée à la transmission et aux moteurs thermiques d'automobiles qui est constituée d'une huile à viscosité lubrifiante dans laquelle on ajoute et on mélange une faible quantité d'une composition d'agents modifiant le frottement qui permet de réduire le coefficient de frottement entre des éléments mécaniques mobiles et qui permet par conséquent de réduire encore plus la consommation de carburant. La composition d'agents modifiant le frottement est formée d'un mélange constitué d'une amine hydrocarbyle alcoxylée ou d'un dérivé boré de cette dernière et d'un sulfure de phénol hydrocarbyle. Cette association de composants produit plus spécifiquement des effets synergiques d'économie de carburant lorsqu'on les utilise comme composants de lubrifiants de carters de moteurs d'automobiles contenant également des systèmes d'additifs classiques; ces effets ne sont pas observés avec de l'huile contenant un seul de ces composants.
PCT/US1993/003378 1992-04-15 1993-04-09 Composition de matiere lubrifiante contenant un melange d'agents modifiant le frottement WO1993021289A1 (fr)

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CA002132523A CA2132523C (fr) 1992-04-15 1993-04-09 Composition lubrifiante
JP5518516A JPH07508049A (ja) 1992-04-15 1993-04-09 混合摩擦調整剤を含有する潤滑油組成物
EP93909306A EP0638117A1 (fr) 1992-04-15 1993-04-09 Composition de matiere lubrifiante contenant un melange d'agents modifiant le frottement

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EP1338641A1 (fr) * 2002-02-22 2003-08-27 Nissan Motor Company, Limited Dispositif de glissement à faible frottement
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EP1505322A1 (fr) * 2003-08-08 2005-02-09 Nissan Motor Co., Ltd. Elément de glissement et sa méthode de fabrication
CN100410354C (zh) * 2003-08-06 2008-08-13 新日本石油株式会社 具有dlc接触表面的系统、润滑该系统的方法以及用于该系统的润滑油
US7951756B2 (en) 2003-08-06 2011-05-31 Nippon Oil Corporation System having DLC contact surfaces, method of lubricating the system, and lubricant for the system
US7968502B2 (en) 2003-08-06 2011-06-28 Nippon Oil Corporation System having DLC contact surfaces, method of lubricating the system, and lubricant for the system
US8206035B2 (en) 2003-08-06 2012-06-26 Nissan Motor Co., Ltd. Low-friction sliding mechanism, low-friction agent composition and method of friction reduction
WO2012051064A3 (fr) * 2010-10-12 2012-07-19 Chevron Oronite Company Llc Composition lubrifiante contenant le sel d'amine hydroxylée multifonctionnelle d'un acide phénolique encombré
WO2012051075A3 (fr) * 2010-10-12 2012-07-26 Chevron Oronite Company Llc Composition lubrifiante contenant un sel boré multifonctionnel d'amine hydroxylée d'acide phénolique encombré
WO2015057293A1 (fr) * 2013-10-18 2015-04-23 Chevron Oronite Company Llc Composition d'huile lubrifiante servant à protéger des paliers en argent dans des moteurs diesel à vitesse moyenne
EP3299443A4 (fr) * 2015-05-16 2018-05-23 Turbulence Ltd. Additif pour huile lubrifiante, et composition d'huile lubrifiante
US10059897B2 (en) 2014-11-07 2018-08-28 Turbulence Ltd. Fuel additive for internal combustion engines and fuel composition

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US5019286A (en) * 1990-02-26 1991-05-28 Exxon Chemical Patents, Inc. Low viscosity aromatic carbonate lubricating oil concentrates
WO1992002602A1 (fr) * 1990-07-31 1992-02-20 Exxon Chemical Patents Inc. Melange synergique d'agents modifiant la friction d'amine/amide et d'ester/alcool ameliorant l'economie en carburant d'un moteur a combustion interne

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EP0737735A3 (fr) * 1995-04-14 1997-01-22 Tonen Corp Composition d'huile lubrifiante ayant un coefficient de friction réduit
EP0737735A2 (fr) * 1995-04-14 1996-10-16 Tonen Corporation Composition d'huile lubrifiante ayant un coefficient de friction réduit
US7273655B2 (en) 1999-04-09 2007-09-25 Shojiro Miyake Slidably movable member and method of producing same
US6844068B1 (en) 1999-04-09 2005-01-18 Nissan Motor Co., Ltd. Slidably movable member and method of producing same
US6739238B2 (en) 2000-11-20 2004-05-25 Nissan Motor Co., Ltd. Sliding structure for a reciprocating internal combustion engine and a reciprocating internal combustion engine using the sliding structure
EP1233054A1 (fr) * 2001-02-14 2002-08-21 Ethyl Corporation Fluides pour transmissions automatiques avec des caractéristiques anti-vibration ameliorées
US6802650B2 (en) 2001-12-20 2004-10-12 Nissan Motor Co., Ltd. Sliding element, sliding structure including the sliding element, and method for producing microscopic surface structure in the sliding element
EP1338641A1 (fr) * 2002-02-22 2003-08-27 Nissan Motor Company, Limited Dispositif de glissement à faible frottement
US6806242B2 (en) 2002-02-22 2004-10-19 Nissan Motor Co., Ltd. Low-friction sliding mechanism
US6790813B2 (en) 2002-11-21 2004-09-14 Chevron Oronite Company Llc Oil compositions for improved fuel economy
CN100352968C (zh) * 2003-06-06 2007-12-05 日产自动车株式会社 发动机活塞销滑动结构
EP1484534A1 (fr) * 2003-06-06 2004-12-08 Nissan Motor Company, Limited Kolbenbolzen
US7968502B2 (en) 2003-08-06 2011-06-28 Nippon Oil Corporation System having DLC contact surfaces, method of lubricating the system, and lubricant for the system
CN100410354C (zh) * 2003-08-06 2008-08-13 新日本石油株式会社 具有dlc接触表面的系统、润滑该系统的方法以及用于该系统的润滑油
US8206035B2 (en) 2003-08-06 2012-06-26 Nissan Motor Co., Ltd. Low-friction sliding mechanism, low-friction agent composition and method of friction reduction
US7951756B2 (en) 2003-08-06 2011-05-31 Nippon Oil Corporation System having DLC contact surfaces, method of lubricating the system, and lubricant for the system
EP1990564A1 (fr) 2003-08-08 2008-11-12 Nissan Motor Co., Ltd. Élément coulissant et son procédé de fabrication
EP1505322A1 (fr) * 2003-08-08 2005-02-09 Nissan Motor Co., Ltd. Elément de glissement et sa méthode de fabrication
WO2012051064A3 (fr) * 2010-10-12 2012-07-19 Chevron Oronite Company Llc Composition lubrifiante contenant le sel d'amine hydroxylée multifonctionnelle d'un acide phénolique encombré
WO2012051075A3 (fr) * 2010-10-12 2012-07-26 Chevron Oronite Company Llc Composition lubrifiante contenant un sel boré multifonctionnel d'amine hydroxylée d'acide phénolique encombré
US8334242B2 (en) 2010-10-12 2012-12-18 Chevron Oronite Company Llc Lubricating composition containing multifunctional borated hydroxylated amine salt of a hindered phenolic acid
US8343901B2 (en) 2010-10-12 2013-01-01 Chevron Oronite Company Llc Lubricating composition containing multifunctional hydroxylated amine salt of a hindered phenolic acid
WO2015057293A1 (fr) * 2013-10-18 2015-04-23 Chevron Oronite Company Llc Composition d'huile lubrifiante servant à protéger des paliers en argent dans des moteurs diesel à vitesse moyenne
US10059897B2 (en) 2014-11-07 2018-08-28 Turbulence Ltd. Fuel additive for internal combustion engines and fuel composition
EP3299443A4 (fr) * 2015-05-16 2018-05-23 Turbulence Ltd. Additif pour huile lubrifiante, et composition d'huile lubrifiante

Also Published As

Publication number Publication date
CA2132523A1 (fr) 1993-10-28
JPH07508049A (ja) 1995-09-07
AU3976993A (en) 1993-11-18
MX9302130A (es) 1994-05-31
CA2132523C (fr) 1999-08-03
EP0638117A1 (fr) 1995-02-15

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