WO1992015481A1 - Method and a device for the collection of oil slicks on a water surface - Google Patents
Method and a device for the collection of oil slicks on a water surface Download PDFInfo
- Publication number
- WO1992015481A1 WO1992015481A1 PCT/NO1992/000041 NO9200041W WO9215481A1 WO 1992015481 A1 WO1992015481 A1 WO 1992015481A1 NO 9200041 W NO9200041 W NO 9200041W WO 9215481 A1 WO9215481 A1 WO 9215481A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- water
- oil
- collection container
- collection
- bow section
- Prior art date
Links
Classifications
-
- E—FIXED CONSTRUCTIONS
- E02—HYDRAULIC ENGINEERING; FOUNDATIONS; SOIL SHIFTING
- E02B—HYDRAULIC ENGINEERING
- E02B15/00—Cleaning or keeping clear the surface of open water; Apparatus therefor
- E02B15/04—Devices for cleaning or keeping clear the surface of open water from oil or like floating materials by separating or removing these materials
- E02B15/048—Oil collectors moved over the water skimming the water surface
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B63—SHIPS OR OTHER WATERBORNE VESSELS; RELATED EQUIPMENT
- B63B—SHIPS OR OTHER WATERBORNE VESSELS; EQUIPMENT FOR SHIPPING
- B63B35/00—Vessels or similar floating structures specially adapted for specific purposes and not otherwise provided for
- B63B35/32—Vessels or similar floating structures specially adapted for specific purposes and not otherwise provided for for collecting pollution from open water
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A20/00—Water conservation; Efficient water supply; Efficient water use
- Y02A20/20—Controlling water pollution; Waste water treatment
- Y02A20/204—Keeping clear the surface of open water from oil spills
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S210/00—Liquid purification or separation
- Y10S210/918—Miscellaneous specific techniques
- Y10S210/922—Oil spill cleanup, e.g. bacterial
- Y10S210/923—Oil spill cleanup, e.g. bacterial using mechanical means, e.g. skimmers, pump
Definitions
- the present invention relates to a method and a device for the collection of oil slicks on a water surface, using a floating collection container in the form of a barge or similar with a receiving bow section and a collection device, such as an oil boom, designed to collect at least some portions of an oil slick.
- An oil boom consists of a long floating member, e.g. a plastic pipe, which on its underside has a skirt with weights at its lower edge so that this hangs down in the water from the floating member.
- An oil boom consists of a long floating member, e.g. a plastic pipe, which on its underside has a skirt with weights at its lower edge so that this hangs down in the water from the floating member.
- With sufficient lengths of such oil booms it is possible to limit the spread of an oil slick on the water under favourable weather conditions.
- practical use of oil booms have shown that even a moderate current with a speed of one knot will force the oil down under the skirt of the oil boom. Should there be waves of one meter or higher, the use of oil booms will represent great difficulties.
- US patent No. 3.684.095 shows a barge-based collection system for an oil slick. The barge is used together with booms.
- US patent No. 3.726.406 shows a capturing system by using oil booms, as well as water nozzles which are located under the water surface in order to channel a captured oil slick across an edge for collection. Further examples of the state of the art are shown in US patent No. 3.662.891, US patent No. 3.847.815, DE-3.416.683, GB-2.064.971 A and SU-95 85 83.
- the purpose of the present invention is to give instructions for a method and a device for the collection of oil, also heavy, viscous oil, where the said drawbacks are avoided so that the collection device is not fouled up by heavy, viscous oil.
- this is achieved by a method of the formerly mentioned art, which is characterized in that the collection container is located downstream of and adjacent to the collection device and the oil slick on the water surface is forced to move toward the receiving section of the bow and that a limited water layer immediately below the oil slick in front of the receiving bow section is set in a flow that is directed upward and downstream so that the water layer is raised from the surrounding water level, entraining the supernatant oil slick and transferring it over a threshold in the receiving bow section and down into the collection container.
- the water and the oil in the collection container is advantageously separated countinuously in an upper oil phase and a lower water phase which is continuously led out of the collection container after first having been mixed.
- the collection container and the collection device may be kept in a stationary position and the current in the water will advantageously produce a relative movement between the collection container and the surrounding water surface.
- the surrounding water surface may be mainly without a current and the collection container and the collection device are towed across the water surface and produce the said relative movement between the collection container and the surrounding water surface.
- a device of the art mentioned in the introduction which is characterized in that the collection container is placed downstream of and adjacent to the collection device in such a manner that the oil slick on the water surface is channelled toward the receiving bow section, and that in front of the bow there is placed a device substantially under the water surface, designed to produce a flow in an upward and downstream direction in a limited water level immediately below the oil slick in front of the receiving bow section.
- a threshold is placed in the receiving bow section over which threshold the flow of the limited water level is led, entraining the supernatant oil slick.
- the device for producing the directed flow may be one under the waterline operable paddle wheel with its rotation axis running across the longitudinal axis of the collection container, alternatively a number of water nozzles, positioned in a predetermined pattern and with regard to direction.
- the device for bringing about the directed flow is advantageously positioned in a house which is partly closed, which house has portions designed according to flow-dynamic principles and which has at least one slit through which a water layer created by the device is led for entrainment of the limited water layer and the supernatant oil slick.
- the collection container may advantageously include adjustable screen devices for adjusting the draught of the collection container.
- the receiving bow section may also advantageously have a number ofbaffles, which may be adjustable, and which divert the water current that does not move across the threshold, past the house.
- Fig. 1 schematically shows an embodiment of the device according to the invention .
- Fig. 2 shows a top plan view of a barge to be used with the device,
- Fig. 3 shows a cross section through the barge in Fig. 2 along the line III-III.
- Fig. 4 shows a longitudinal section through a modified embodiment for a barge.
- Fig. 5 shows a top plan view of a second embodiment of the collection container or the barge according the invention
- Fig. 6 shows a schematic side view of the barge according to Fig. 5,
- Fig. 7 shows a schematic side view of the barge according to Fig. 6 in an alternative embodiment
- Fig. 8 shows a schematic side view and in large scale the receiving bow section of the barge, but not in operation
- Fig. 9 shows the same side view as Fig. 8, but in operation
- Fig. 10 shows an alternative embodiment of the receiving bow section shown in Fig. 8 and 9,
- Fig. 11 shows schematically a collection container towed by a vessel through its booms
- Fig. 12 shows a stationary collection container positioned in a sound where there is a current and with the collection container anchored to the shore by means of its booms.
- the device shown in Fig. 1 - 4 for the collection of oil slicks on a water surface consists of a flat barge 1 with lateral tanks 2 and a central tank 3 which occupies most of the vessel.
- the bow consists of a straight transversal edge 4.
- the barge is towed by a towboat 5 across tow rope 6, 7.
- a collection oil boom is suspended, which transports any oil on the surface into the barge.
- This oil boom 8 is fastened to the bow section 4 on the port side.
- At the starboard side there is fastened an additional oil boom 9 which is towed by a smaller vessel 10. With the help of vessel 10 and boom 9 it is possible to collect oil all the way in to an uneven shore line 11.
- the device which accelerates water upwardly and rearwardly.
- the device consists of a paddle wheel 12, rotating about an axis 13 which runs transversal to the longitudinal direction of the barge.
- the paddle wheel is run by a motor, not shown, for instance a hydraulic motor and is rotating in the direction of the arrow P.
- the paddle wheel will throw the water upwardly across transversal bow section 4 and will entrain oil slick 14 which is floating on the water surface.
- the water that is thrown over bow section 4 into the barge i.e. into tank room 3, will rapidly separate from the water so that an upper oil slick 15 and a lower water level 16 are formed.
- the water will automatically be forced out through a bottom opening 17 in the tank.
- the oil slick 15 is increased in thickness, this may be transferred over to an accompanying vessel or to lateral tanks 2 by means of a pump 8.
- Fig. 4 is shown a modified embodiment, in that the paddle wheel 12 is replaced by a slanting plate 19 on whose overside is mounted, upward directed, slanting nozzles 20 to which water is fed from a pump, not shown. These water flows will, simular to the embodiment according to Fig. 3, throw the water with the oil film 14 across the edge of the bow 4 and into tank 3.
- a principal advantage with the invention is that no mechanical parts come into contact with the oil film in order to channel this into the vessel's tank.
- the paddle wheel 12 or the nozzles 20 only produce a flow in the water which causes the water and oil to be thrown across the edge of bow 4 and into the tank of the barge.
- Fig. 5 shows an alternative embodiment of the collection container or barge 1 where the receiving bow section 4 is telescoped somewhat into barge 1.
- Fig. 6 shows a side view of barge 1 and shows the new positioning of paddle wheel 12 in relation to receiving party 4.
- the paddle wheel 12 is mounted in a partly enclosing house 33 which transfers water from the surrouding area in toward the paddle wheel 12.
- the receiving bow section 4 terminates in an edge or a threshold 35 whose height is a bit above the water surface.
- the reference number 37 shows schematically a wing or a foil with its adjusting organs so that the wing may be turned or tipped. Wing 37 is used to adjust the draught of the barge.
- Fig. 7 shows an alternative embodiment to the one shown in Fig. 6.
- a number of water nozzles 20 are used. These are positioned in a predetermined pattern in order to create a favourable fluid motion.
- House 33 is also designed with due regard to flow-dynamics in order to create a favourable current. House 33 is only partly closed to allow entrance of the surrounding water.
- barge 1 is kept either in a stationary position or is towed across the water by means of booms 8.
- the traction force may advantageously be transferred in a lower line or wire 8, which gives a lower point of application in barge 1.
- the wire may be fastened to the lower skirt of the boom so that the boom will not easily give way and allow the oil to get through. In other words, this is a great help in forcing the oil film toward the receiving bow section of barge 4.
- the height of boom 8 may also be designed in such a way that the highest point is near barge 1 and the lowest near the shore connection or the towboat. This is because the oil slick is concentrated toward barge 1 and is expected to be increasingly thicker as it approaches barge 1.
- the water force will be substantial and barge 8 need not withstand greater force than strictly necessary, hence this possibility of decreasing boom height upstream.
- Fig. 8 shows the receiving bow section 4 in larger scale and not in operation.
- house 33 forms an upwardly directed slit 36 through which water shall escape.
- Fig. 9 illustrates how the water and the oil slick behave during rotation of paddle wheel 12.
- Paddle wheel 12 draws water in and leads the water as illustrated by the arrows.
- the water is channelled through slit 36 and forms an inner water layer 31.
- This slit 36 is placed in such a way as to entrain a thin water slick 30 and which in turn entrains oil slick 14 over threshold 35.
- the oil scarcely comes into contact with the equipment. If plastic bags, cans, bits of wood, etc., should float on top of the oil film, this is of no importance; everything is transported across threshold 35 without any problems.
- Fig. 10 shows the alternative embodiment in a larger scale.
- a number of nozzles 20 are placed on a portion 34 of house 33, designed according to flow-dynamic principles. As illustrated by the arrows, these nozzles send a flow of water toward slit 36, similar to the embodiment shown in Fig. 8 and 9. In operation the result will be the same as shown on Fig. 9.
- the threshold height h from the water surface may be in the order of 150 - 250 mm in a practical embodiment.
- Slit 36 may for instance be located approx. 50 mm below the water surface. To prevent too much brake effect from the receiving bow section, the latter is designed with baffles which send substantial quantities of water past house 33, both latterally and below.
- paddle wheel 12 and house 33 are designed as small as possible, which means that the draught is as shallow as possible, and as mentioned, will be designed with baffles in the front, so that no large frontal wave will be formed in front of barge 1.
- baffles in the front, so that no large frontal wave will be formed in front of barge 1.
- Fig. 11 and 12 show two different applications of the device for collection of oil slicks.
- barge 1 is towed by vessel 25 and booms 8 are each fastened to cantilever booms 26. This type of collection is used when there is no substantial current in the water.
- stationary equipment as shown in Fig. 12 is used.
- barge 1 is stationary and fastened via booms 8 to shore connections 27.
- Such a system may also be used when tidal water is present; however, the boom must then be turned around regularly as and when the tidal water is changing direction.
Landscapes
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Health & Medical Sciences (AREA)
- Structural Engineering (AREA)
- Civil Engineering (AREA)
- Public Health (AREA)
- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Ocean & Marine Engineering (AREA)
- Cleaning Or Clearing Of The Surface Of Open Water (AREA)
- Removal Of Floating Material (AREA)
- Catching Or Destruction (AREA)
Abstract
Description
Claims
Priority Applications (8)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CA002105672A CA2105672C (en) | 1991-03-08 | 1992-03-06 | Method and a device for the collection of oil slicks on a water surface |
AU13606/92A AU650731B2 (en) | 1991-03-08 | 1992-03-06 | Method and a device for the collection of oil slicks on a water surface |
EP92905757A EP0580601B1 (en) | 1991-03-08 | 1992-03-06 | Method and a device for the collection of oil slicks on a water surface |
JP4505623A JP2858950B2 (en) | 1991-03-08 | 1992-03-06 | Method and apparatus for collecting oil slicks on water surface |
US08/117,021 US5445744A (en) | 1991-03-08 | 1992-03-06 | Method and a device for the collection of oil slicks on a water surface |
DE69207395T DE69207395T2 (en) | 1991-03-08 | 1992-03-06 | METHOD AND DEVICE FOR COLLECTING OIL LAYERS FLOATING ON THE WATER SURFACE |
FI933901A FI112518B (en) | 1991-03-08 | 1993-09-07 | Method and apparatus for collecting oil stains from the water surface |
GR960400867T GR3019480T3 (en) | 1991-03-08 | 1996-04-02 | Method and a device for the collection of oil slicks on a water surface |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
NO91910920A NO910920L (en) | 1991-03-08 | 1991-03-08 | PROCEDURE AND APPARATUS FOR COLLECTING OIL POLLUTION ON A WATER SURFACE. |
NO910920 | 1991-03-08 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1992015481A1 true WO1992015481A1 (en) | 1992-09-17 |
Family
ID=19893933
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/NO1992/000041 WO1992015481A1 (en) | 1991-03-08 | 1992-03-06 | Method and a device for the collection of oil slicks on a water surface |
Country Status (13)
Country | Link |
---|---|
US (1) | US5445744A (en) |
EP (1) | EP0580601B1 (en) |
JP (1) | JP2858950B2 (en) |
AT (1) | ATE132447T1 (en) |
AU (1) | AU650731B2 (en) |
CA (1) | CA2105672C (en) |
DE (1) | DE69207395T2 (en) |
DK (1) | DK0580601T3 (en) |
ES (1) | ES2084349T3 (en) |
FI (1) | FI112518B (en) |
GR (1) | GR3019480T3 (en) |
NO (1) | NO910920L (en) |
WO (1) | WO1992015481A1 (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2213624A1 (en) * | 2007-10-12 | 2010-08-04 | Utsunomiya Kogyo Co., Ltd. | Scum removing apparatus |
RU2653661C1 (en) * | 2017-01-30 | 2018-05-11 | Игорь Александрович Киш | Self-propelled vessel oil-cleaner |
Families Citing this family (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2289633B (en) * | 1994-05-24 | 1998-03-04 | Richard John Forsey | Apparatus and method for separation of contaminants floating on the surface of a liquid |
AU5085098A (en) * | 1996-10-21 | 1998-05-15 | George W. Adams | Hydrodynamic induction bow foil plane oil skimmers |
US20050242020A1 (en) * | 2002-07-01 | 2005-11-03 | Fisk Clive S M | Oil slick harvester |
ES2249083B1 (en) * | 2003-04-30 | 2007-03-16 | Juan Soler Cintas | "SYSTEM FOR THE COLLECTION OF OIL SPILLS IN THE SEA". |
NO20041471A (en) * | 2004-04-07 | 2005-08-15 | Ide Til Produkt As | Method and device for collecting liquid waste on a water surface. |
CN101082212B (en) * | 2006-05-29 | 2010-12-08 | 申鹏 | Waterborne floating slag automatic collector |
US20090057217A1 (en) * | 2007-09-05 | 2009-03-05 | Seawax International, Inc. | Apparatus for contaminant recovery |
CN102476702A (en) * | 2010-11-29 | 2012-05-30 | 东北林业大学 | Parallel boat type device for intercepting and recycling floating oil |
US9120034B1 (en) | 2011-01-04 | 2015-09-01 | Stephen Richard Leventhal | Self-adjusting gravity separator and a method of using |
KR101369765B1 (en) * | 2013-12-11 | 2014-03-06 | 일진인터내셔날 (주) | A pollution prevention and surface layer improvement method for dredged soils |
CN103935476B (en) * | 2014-04-11 | 2017-09-29 | 珠海云洲智能科技有限公司 | Independent navigation robot for water surface cleaner |
CN106335609A (en) * | 2016-08-16 | 2017-01-18 | 邯郸学院 | Water surface garbage picking boat |
KR102332673B1 (en) * | 2021-03-16 | 2021-12-01 | 장운성 | Device for collecting spilled oil by separating oil and water, oil fence using the same, and jellyfish blocking device using the same |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2045290A5 (en) * | 1970-04-03 | 1971-02-26 | Waren Frank | Collecting appts for floating materials - such as oil slicks |
GB2038195A (en) * | 1978-12-19 | 1980-07-23 | Fram Europ | Removing oil from open water |
GB2145005A (en) * | 1983-01-10 | 1985-03-20 | Joseph John Rayner | Oil-collecting vessel |
DE3615499C2 (en) * | 1986-05-07 | 1988-04-28 | Heinrich 3450 Holzminden De Schroeter | |
NO900214L (en) * | 1990-01-16 | 1991-07-17 | Per Kaare Krumsvik | OIL RECORDER. |
Family Cites Families (14)
Publication number | Priority date | Publication date | Assignee | Title |
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US3630376A (en) * | 1969-11-03 | 1971-12-28 | Larry D Price | Oil slick removing vessel |
FR2045291A5 (en) * | 1970-04-06 | 1971-02-26 | Monsanto Co | Oxidative coupling of hydrocarbons |
US3662891A (en) * | 1970-04-22 | 1972-05-16 | Edward E Headrick | Apparatus for confining floating materials |
US3684095A (en) * | 1970-09-08 | 1972-08-15 | Ray R Ayers | Barge based skimming system for oil slicks |
US3726406A (en) * | 1971-02-09 | 1973-04-10 | C Damberger | Oil skimming apparatus |
US3716142A (en) * | 1971-06-14 | 1973-02-13 | Jbf Scient Corp | Liquid surface sweeping apparatus |
FR2171678A6 (en) * | 1972-02-04 | 1973-09-21 | Chastan Bagnis Lucien | |
FR2430350B1 (en) * | 1978-07-04 | 1981-10-23 | Ouest Ets Generaux Meca | |
GB2064971B (en) * | 1979-12-18 | 1983-12-07 | Gibson R R | Oil collector |
SU958583A1 (en) * | 1980-09-01 | 1982-09-15 | Могилевский Проектно-Конструкторский Технологический Институт Специальной Технологической Оснастки,Автоматизации И Механизации | Method of removing floating substances off water surface |
DE3416683A1 (en) * | 1984-05-05 | 1985-11-14 | Albert 5204 Lohmar Blum | Apparatus and method of picking up contaminants floating on the surface of bodies of water |
GB2221403B (en) * | 1988-08-05 | 1992-10-28 | Alba International Limited | Method & apparatus for recovering residual tar or oil from a fluid medium |
US5030363A (en) * | 1989-11-13 | 1991-07-09 | Uls Corporation | Oil retriever with interchangeable collection tanks and method of use therefor |
US5108600A (en) * | 1991-05-30 | 1992-04-28 | Rees David W | Surface cleaning apparatus |
-
1991
- 1991-03-08 NO NO91910920A patent/NO910920L/en unknown
-
1992
- 1992-03-06 AU AU13606/92A patent/AU650731B2/en not_active Ceased
- 1992-03-06 JP JP4505623A patent/JP2858950B2/en not_active Expired - Fee Related
- 1992-03-06 DK DK92905757.8T patent/DK0580601T3/en active
- 1992-03-06 US US08/117,021 patent/US5445744A/en not_active Expired - Lifetime
- 1992-03-06 ES ES92905757T patent/ES2084349T3/en not_active Expired - Lifetime
- 1992-03-06 DE DE69207395T patent/DE69207395T2/en not_active Expired - Fee Related
- 1992-03-06 WO PCT/NO1992/000041 patent/WO1992015481A1/en active IP Right Grant
- 1992-03-06 EP EP92905757A patent/EP0580601B1/en not_active Expired - Lifetime
- 1992-03-06 CA CA002105672A patent/CA2105672C/en not_active Expired - Fee Related
- 1992-03-06 AT AT92905757T patent/ATE132447T1/en not_active IP Right Cessation
-
1993
- 1993-09-07 FI FI933901A patent/FI112518B/en active
-
1996
- 1996-04-02 GR GR960400867T patent/GR3019480T3/en unknown
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2045290A5 (en) * | 1970-04-03 | 1971-02-26 | Waren Frank | Collecting appts for floating materials - such as oil slicks |
GB2038195A (en) * | 1978-12-19 | 1980-07-23 | Fram Europ | Removing oil from open water |
GB2145005A (en) * | 1983-01-10 | 1985-03-20 | Joseph John Rayner | Oil-collecting vessel |
DE3615499C2 (en) * | 1986-05-07 | 1988-04-28 | Heinrich 3450 Holzminden De Schroeter | |
NO900214L (en) * | 1990-01-16 | 1991-07-17 | Per Kaare Krumsvik | OIL RECORDER. |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2213624A1 (en) * | 2007-10-12 | 2010-08-04 | Utsunomiya Kogyo Co., Ltd. | Scum removing apparatus |
EP2213624B1 (en) * | 2007-10-12 | 2016-03-09 | Utsunomiya Kogyo Co., Ltd. | Scum removing apparatus |
RU2653661C1 (en) * | 2017-01-30 | 2018-05-11 | Игорь Александрович Киш | Self-propelled vessel oil-cleaner |
Also Published As
Publication number | Publication date |
---|---|
FI933901A (en) | 1993-10-29 |
JPH06505213A (en) | 1994-06-16 |
DK0580601T3 (en) | 1996-05-13 |
ES2084349T3 (en) | 1996-05-01 |
ATE132447T1 (en) | 1996-01-15 |
FI933901A0 (en) | 1993-09-07 |
AU650731B2 (en) | 1994-06-30 |
FI112518B (en) | 2003-12-15 |
JP2858950B2 (en) | 1999-02-17 |
GR3019480T3 (en) | 1996-07-31 |
AU1360692A (en) | 1992-10-06 |
EP0580601A1 (en) | 1994-02-02 |
DE69207395D1 (en) | 1996-02-15 |
CA2105672C (en) | 2004-06-01 |
US5445744A (en) | 1995-08-29 |
NO910920L (en) | 1992-09-09 |
EP0580601B1 (en) | 1996-01-03 |
DE69207395T2 (en) | 1996-08-08 |
CA2105672A1 (en) | 1992-09-09 |
NO910920D0 (en) | 1991-03-08 |
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