WO1992015119A1 - Solar energy system - Google Patents

Solar energy system Download PDF

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Publication number
WO1992015119A1
WO1992015119A1 PCT/US1992/001437 US9201437W WO9215119A1 WO 1992015119 A1 WO1992015119 A1 WO 1992015119A1 US 9201437 W US9201437 W US 9201437W WO 9215119 A1 WO9215119 A1 WO 9215119A1
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WO
WIPO (PCT)
Prior art keywords
photovoltaic
solar energy
prefiltering
band
active area
Prior art date
Application number
PCT/US1992/001437
Other languages
English (en)
French (fr)
Inventor
William E. Horne
Original Assignee
United Solar Technologies, Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by United Solar Technologies, Inc. filed Critical United Solar Technologies, Inc.
Priority to AU14644/92A priority Critical patent/AU659141B2/en
Priority to EP92907351A priority patent/EP0573557B1/en
Priority to AT92907351T priority patent/ATE231289T1/de
Priority to KR1019930702526A priority patent/KR100244419B1/ko
Priority to DE69232897T priority patent/DE69232897T2/de
Publication of WO1992015119A1 publication Critical patent/WO1992015119A1/en

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Classifications

    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B19/00Condensers, e.g. light collectors or similar non-imaging optics
    • G02B19/0033Condensers, e.g. light collectors or similar non-imaging optics characterised by the use
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24SSOLAR HEAT COLLECTORS; SOLAR HEAT SYSTEMS
    • F24S20/00Solar heat collectors specially adapted for particular uses or environments
    • F24S20/20Solar heat collectors for receiving concentrated solar energy, e.g. receivers for solar power plants
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B19/00Condensers, e.g. light collectors or similar non-imaging optics
    • G02B19/0004Condensers, e.g. light collectors or similar non-imaging optics characterised by the optical means employed
    • G02B19/0028Condensers, e.g. light collectors or similar non-imaging optics characterised by the optical means employed refractive and reflective surfaces, e.g. non-imaging catadioptric systems
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B19/00Condensers, e.g. light collectors or similar non-imaging optics
    • G02B19/0033Condensers, e.g. light collectors or similar non-imaging optics characterised by the use
    • G02B19/0038Condensers, e.g. light collectors or similar non-imaging optics characterised by the use for use with ambient light
    • G02B19/0042Condensers, e.g. light collectors or similar non-imaging optics characterised by the use for use with ambient light for use with direct solar radiation
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/04Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
    • H01L31/054Optical elements directly associated or integrated with the PV cell, e.g. light-reflecting means or light-concentrating means
    • H01L31/056Optical elements directly associated or integrated with the PV cell, e.g. light-reflecting means or light-concentrating means the light-reflecting means being of the back surface reflector [BSR] type
    • HELECTRICITY
    • H02GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
    • H02SGENERATION OF ELECTRIC POWER BY CONVERSION OF INFRARED RADIATION, VISIBLE LIGHT OR ULTRAVIOLET LIGHT, e.g. USING PHOTOVOLTAIC [PV] MODULES
    • H02S40/00Components or accessories in combination with PV modules, not provided for in groups H02S10/00 - H02S30/00
    • H02S40/40Thermal components
    • H02S40/44Means to utilise heat energy, e.g. hybrid systems producing warm water and electricity at the same time
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/40Solar thermal energy, e.g. solar towers
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy
    • Y02E10/52PV systems with concentrators
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/60Thermal-PV hybrids

Definitions

  • the present invention relates to systems for converting solar energy Into electrical energy, using photovoltaic cells.
  • Photovoltaic cells are often the most expensive components of solar energy systems.
  • one prior approach to building solar energy systems has been to use large quantities of low-cost cells, e.g., polycrystalline thin film cells, of the type designed to operate on unconcentrated sunlight.
  • this approach yields very low conversion efficiency, and has not proved economic.
  • a second and generally more efficient approach to solar energy systems has been to use concentrators to concentrate the solar energy onto relatively high performance (and high cost) photovoltaic cells, such as GaAa/GaSb cells.
  • concentrators presents a number of new problems. For example, virtually all known photovoltaic cells operate less efficiently as their temperature increases. The use of concentrators tends to cause the cells to operate at a higher temperature, thereby decreasing system efficiency. This creates a difficult tradeoff between cost and conversion efficiency.
  • the intensity makes it difficult to take advantage of all of the incident sunlight, because some of the area in the intense light field is required for Interconnecting conductors and geometric cell mounting considerations. The result is poor utilization of expensive photovoltaic cells.
  • the large currents generated by the intense light field require heavy contact rid lines on the cells, and for interconnecting conductors.
  • the nonuniformity of the illumination results in different temperatures, currents, and voltages in the individual photovoltaic cells.
  • the cells in concentrator arrangements are subject to rapid thermal damage if coolant is lost, or if hot spots are formed by flaws in the concentrator.
  • Tandem photovoltaic cells have been developed to increase conversion efficiency in solar energy systems.
  • solar radiation that passes through a primary cell is incident on a secondary cell that typically has a wavelength absorbing region different from that of the primary cell.
  • the secondary cell can utilize some of the radiation not converted by the primary cell, thereby increasing the overall conversion efficiency.
  • the secondary cell costs as much as the primary cell, but only produces a fraction (e.g., 30 percent) of the amount of electricity produced by the primary cell.
  • the electrical energy produced per unit cost is often quite low In tandem designs.
  • the system comprises photovoltaic means and prefiltering means.
  • the photovoltaic means comprises an active area and a pair of electrodes, and absorbs electromagnetic radiation incident upon the active area within a response band of wavelengths. A portion of the absorbed electromagnetic radiation is converted into an electrical potential difference between the electrodes.
  • the prefiltering means comprises means for absorbing a substantial fraction of electromagnetic radiation incident upon the prefiltering means within a prefiltering band. At least a portion of the prefiltering band lies outside of the response band of the photovoltaic means, but within, the solar band of the incident solar energy.
  • the photovoltaic means and the prefiltering means are positioned such that the solar energy must pass through the prefiltering means to strike the active area of the photovoltaic means. Thus, some of the solar energy outside of the response band is absorbed by the prefiltering means, and is not incident upon the photovoltaic means. By removing some of the out of band energy, the prefiltering means lets the photovoltaic means operate at a lower temperature, thereby increasing the conversion efficiency.
  • the solar energy system of the present Invention comprises primary concentrator means and a receiver.
  • the concentrator means receives the incident solar energy, and focuses it toward a focal spot.
  • the receiver is positioned substantially at the focal spot, and comprises a plurality of photovoltaic cells positioned such that each photovoltaic cell receives approximately the same solar energy flux (energy per unit area) from the concentrator means.
  • the photovoltaic cells are arranged in a plurality of rings. The photovoltaic cells of each ring are at a constant radius from a central axis common to all rings, and the active surfaces of the photovoltaic cells face outward, away from the central axis.
  • the present invention provides a photovoltaic module for converting solar energy Into electrical energy.
  • the module comprises a substrate having a relatively large first surface and a relatively small second surface.
  • a first photovoltaic cell is mounted to the first surface, the first photovoltaic cell having a first response band.
  • the module is positioned such that the solar energy la incident onto the active area of the first photovoltaic cell.
  • a second photovoltaic cell substantially smaller than the first photovoltaic cell is mounted to the second surface of the substrate.
  • the substrate is formed such that a portion of the solar energy transmitted by the first photovoltaic cell into the substrate is directed onto the active area of the second photovoltaic cell. Because of the smaller area of the second photovoltaic cell, the cost per unit cell area is lower than in conventional tandem designs.
  • the present invention provides a receiver for a solar energy system that includes a phase change material.
  • the phase change material is selected such that it experiences a phase change (e.g., melting) at a temperature that is higher than the normal operating temperature range of the photovoltaic cells, but less than the temperature at which the photovoltaic cells will suffer thermal damage.
  • the phase change material reduces the possibility that the photovoltaic cells will be damaged by coolant loss.
  • FIGURE 1 is a diagram illustrating a solar energy system including a concentrator.
  • FIGURE 2 is a diagram illustrating a preferred embodiment of the receiver.
  • FIGURE 3 is a graph Illustrating the prefiltering;
  • FIGURE 4 is a cross-sectional view of the receiver
  • FIGURE 5 is a plan view of a photovoltaic cell
  • FIGURE 6 is a perspective view showing the photovoltaic cells in a single ring
  • FIGURE 7 is a graph illustrating a technique for positioning the photovoltaic cells
  • FIGURE 8 is a partial cross-sectional view showing the mounting of a cell
  • FIGURE 9 is a schematic cross-sectional view of a two cell module
  • FIGURE 10 is a schematic cross-sectional view of a three cell module
  • FIGURE 11 is a partial cross-sectional view showing the positioning of a multicell module in the receiver.
  • FIGURE 12 is a schematic cross-sectional view of a second preferred receiver design.
  • FIGURES 1-7 illustrate the construction and operation of a first preferred embodiment of the solar energy system of the present invention.
  • the overall system comprises primary concentrator 12 and receiver 14.
  • the concentrator has a shape of a three-dimensional paraboloid, with receiver 14 positioned at the focus.
  • the concentrator receives incident solar energy, symbolized by rays 18, and reflects the solar energy such that it is concentrated onto receiver 14.
  • the receiver converts portions of the solar energy into electrical energy and thermal energy.
  • the thermal energy is In the form of a fluid heated above ambient temperature.
  • FIGURE 2 A preferred embodiment of receiver 14 is illustrated in greater detail in FIGURE 2.
  • the receiver comprises a disk-shaped base 20, and hemispherical prefilter 22.
  • One surface of base 20 (the lower surface in FIGURE 2) comprises a serrated mounting surface 24 to which a plurality of photovoltaic cells 26 are mounted. The particular arrangement of the serrations and photovoltaic cells is described in greater detail below.
  • Prefilter 22 substantially surrounds the photovoltaic cells, such that the solar radiation from the concentrator (symbolized by rays 16) must pass through the prefilter before striking the cells.
  • Prefilter 22 comprises a Jacket that Includes an internal passageway 28 through which a fluid can flow. Passageway 28 communicates with paasageway 30 formed in base 20. Base passageway 30 is in turn coupled to pump 86 by central passageway 32 that Is formed by tube 34, the tube extending outwardly from the center of the base.
  • a heat transfer fluid such as water is pumped by pump 36 into tube 32, from which point the water spreads outward through a plurality of passageways 30 in the base.
  • passageways 30 are illustrated schematically in FIGURE 2, to simplify the illustration.
  • the heat transfer fluid cools the base and the attached photovoltaic cells, as further described below, and is in turn heated by the base to a first temperature above the inlet temperature.
  • the once heated fluid then flows through passageway 28 in prefilter 22, and in so doing intercepts a portion of solar radiation 18 passing through the prefilter. This raises the fluid temperature to a second temperature, above the first temperature.
  • the twice heated fluid exiting from passageway 28 forms the thermal energy output of the system.
  • This heated fluid may be used directly, for example as hot water, or may be input to a heat exchanger for other known applications.
  • curve 40 represents the spectrum of solar energy, i.e., the solar irradiance, at the earth's surface.
  • the solar spectrum has an upper (short wavelength) cutoff at about .3 microns, and has a long tall extending Into the infrared.
  • Curve 42 represents the relative response of a typical gallium arsenide photovoltaic cell. Response curve 42 lies within response band 44 that has a short wavelength limit 46 at about 0.3 microns, and a long wavelength limit 48 at about 0.9 microns.
  • a comparison of solar spectrum 40 and response curve 42 illustrates that gallium arsenide cells are a good choice for a solar energy system. However, other types of photovoltaic cells may also be used to implement the present invention.
  • Curve 50 illustrates the percentage of absorbanoe of a 0.4 inch thick film of water, such is water flowing through prefilter 22 of FIGURE 2. It can be seen that curve 50 lies within e prefiltering band 82 that has a short wavelength limit 84 very close to the long wavelength limit 48 of response band 44. The purpose of the prefiltering represented by curve 50 is to remove as much as possible of the solar radiation that lies outside of response band 44, without letting such radiation reach the photovoltaic cells.
  • curve 56 represents the result of multiplying the abaorbanoe represented by curve 50 by solar spectrum 40.
  • the shaded region 58 represents the energy removed from the solar spectrum by a prefilter that comprises a 0.4 inch water film.
  • the prefilter enhances the performance of the receiver, by removing "out of band” infrared energy from the solar spectrum. Because prefiltering band 52 lies almost entirely outside response band 44, the removed energy represents energy that the photovoltaic cell can not convert to electricity.
  • gallium arsenide photovoltaic cells are capable of converting about 20% of the energy of incident sunlight into electricity. This leaves 8096 of the energy to appear as heat in the receiver. However, about 4096 of the incident solar energy is out of the gallium arsenide response band. In the ideal case, all of this energy is removed by prefiltering, leaving only 4096 of the incident solar energy to appear as heat in the receiver. Thus up to a 5096 reduction (8096 to 4096) of the heat generated in the receiver can be achieved.
  • the absorption of out-of-band energy in the prefilter may be enhanced by constructing the prefilter jacket from an infrared absorbing glass such as the Schott-America KG-Series glasses.
  • the prefilter is especially advantageous for a cogenerative photovoltaic system.
  • the prefilter facilitates low temperature, efficient electrical conversion, and simultaneously, enables a two-stage heat removal system capable of delivering a heated fluid at approximately twice the cell operating temperature (with respect to ambient).
  • FIGURES 4-8 illustrate further details of a preferred embodiment of base 20 to which the photovoltaic cells are mounted.
  • the disk-shaped base is shown in cross section in FIGURE 4, and is symmetric about central axis 60.
  • the receiver comprises a series of mounting faces 82(i) on which the photovoltaic cells 26 are mounted, the mounting faces being oriented vertically in FIGURE 4.
  • Each mounting face has the form of a cylindrical shell of height h that encircles axis 60 at a radius R i .
  • the different mounting faces all have different radii R i , but the same height h.
  • the mounting faces are Joined to one another by connecting faces 64 that are oriented substantially parallel to the incoming solar radiation 16 that has been reflected towards the receiver by the primary concentrator.
  • connecting faces do not blook any of the incoming radiation, and substantially all of such radiation falls on one of the mounting faces.
  • the connecting faces may therefore be coated with a reflecting material, 10 that any radiation that does strike the connecting faces is reflected onto the adjacent mounting faces.
  • each photovoltaic cell 26 comprises a rectangular body 70 having an active area 72 of height h that covers most of one side of body 70, and a pair of electrodes 74 formed adjacent to the active area.
  • the photovoltaic cell converts a portion of the solar energy incident on the active area into a potential difference between the electrodes.
  • the photovoltaic cells 26 that are mounted to a given mounting face 82(i) form a ring of radius R i , with active surfaces 72 facing outwardly away from central axis 60 of the receiver base. This design permits the use of a standard size photovoltaic cell.
  • cells 26 are positioned on mounting face 62(i) such that active areas 72 fully cover the mounting faces, with the portion of the cells containing electrodes 74 being received In slots in base 20. This arrangement maximizes the effective active area of the receiver.
  • the relative positions of mounting faces 62(i) are preferably selected such that an equal solar energy flux falls on the photovoltaic cells on all the mounting faces.
  • a method of determining the appropriate mounting face positions is illustrated in FIGURE 7, for the case in which the prefilter does not bend the incoming rays from the concentrator (e.g., a hemispherical prefilter).
  • the receiver 82 is centered at the focal point of the parabola, at coordinates (0, 5).
  • Reference numeral 62(1) designates the mounting face or, equivalently, the active areas of the cells that will be affixed to the mounting face.
  • the surface of the primary concentrator is broken up into a set of side-by-side annular areas, the boundaries between adjacent annular areas being at X coordinates x 1 , . . . x i , x i + 1 , . . . , with x 1 being the outermost edge of the primery oonoentrator.
  • the cells on a given mounting surface will be arranged to intercept all of the solar radiation r ⁇ fleoted towards the reoelver by a given annular ring.
  • the photovoltaic cells on mounting lurfaoe 62(1) will be positioned to interoept all aolar radiation refleoted from ring 86(1) that extends between oirole 88 at coordinates x i , y i , and oir ⁇ le 80 at coordinates x i+1 , y i+1 .
  • Line 82 la constructed between receiver 82 and circle 88, and line 94 is constructed between receiver 82 and circle 80.
  • the radius of the mounting aurfa ⁇ e 82(1) corresponding to ring 86(1) is R i
  • the vertical position of the base of the mounting ring is at V i
  • the area of the solar radiation intercepted by ring 86(i) is
  • a p ⁇ (x i 2 - x i+1 2 ) (2) while the corresponding area of the photovoltaic cells that intercept this radiation is
  • a pv 2 ⁇ R i h (3) It is desired that the ratio of A p to A pv ahould be held constant at some suitable concentration factor C.
  • Equation 5 and 6 can be solved iteratively, holding the height h constant, to determine the radii R i of the cylindrical bands on the receiver that will intercept, at a constant concentration factor C, the energy reflected from a series of annular areas 88(i) on the primary concentrator. These radii can be inserted into the equations for the corresponding lines 84 to determine the vertical positions V i of the rings.
  • FIGURE 4 A resulting receiver shape for a concentration factor of 500 is shown in FIGURE 4.
  • the disposition of the cells determined In this manner minimizes the area of the photovoltaic cells required, and solves one of the most difficult problems encountered by photovoltaics in concentrator systems, i.e., nonuniform illumination of the cells.
  • the technique for electrically interconnecting the photovoltaic cells should not block any of the incoming radiation, or cause any of active areas of the cells to be otherwise unused. This may be achieved by mounting the photovoltaic cells 26 on each mounting face 62 such that active surfaces 72 receive the incoming radiation 16, with electrodes 74 positioned in a recess 100 formed in receiver body 20. A pair of wires 104 are connected to the electrodes, and lead the electrical voltage signal out of the receiver body into a suitable utilization circuit.
  • FIGURE 8 Illustrates two additional preferred aspects of the present invention.
  • a slot 110 is formed in receiver body 88, such that the inner end of slot 110 is positioned behind mounting face 62.
  • a plug 112 is then positioned in slot 110 In the position illustrated.
  • Plug 112 may be formed of the same material (e.g., copper) as base 20, and may be held in place by a high temperature silver solder or the like.
  • the portion of the slot above plug 112 Is then filled with a phase change material 114, for example, an indium-tin alloy.
  • the portion of slot 110 below plug 112 forms a passageway 118 for a cooling fluid, such as the cooling passageway 30 schematically shown in FIGURE 2.
  • Phase change material 114 provides overheating protection for the receiver.
  • the phase change material is selected such that it experiences a phase transition at a temperature that is above the normal operating temperature range of the photovoltaic cells, but below the thermal damage threshold for the photovoltaic materials.
  • the phase of the phase change material will change, thereby absorbing a quantity of heat, while maintaining the receiver at a substantially constant temperature, until the phase change is complete.
  • the most convenient phase change material will be those having melting points in the required temperature range.
  • a typical maximum operating temperature is 85°C
  • a typical thermal damage threshold temperature is 350°C.
  • a preferred phase change material would be a material such as an Indium-tin alloy, having a melting point in this range.
  • passageways 116 just behind the photovoltaic cells 26 minimizes the distance that the heat must be conducted. If It is assumed that the heat conduction path through copper base 20 from cell 26 to cooling passageway 116 is 0.1 inches with a thermoconductivity of 3.85 watts/cm, and that the heat transfer coefficient of the cooling fluid Is 6000 BTU/hr-ft 2 °F for water flowing at 3 ft/sec, the maximum temperature difference between the cells and the fluid will be 3.8°C.
  • the main considerations for the hydraulic design of the cooling system are that the volume of flow be sufficient to carry away the excess heat with an appropriate rise in temperature; that the flow velocity be adequate to produce a film heat transfer coefficient sufficiently low to maintain the desired cell operating temperature; and that the strength of the receiver will be adequate to contain the combination of pressure produced by the fluid pump and the hydrostatic pressure produced by the rise in temperature of the fluid.
  • the temperature rise in the fluid above an assumed input temperature of 30°C may be calculated by assuming no electrical load (the worst case). The result of the calculation is a thermal heat load of 23,350 watts, a desired temperature rise of 120°C for an exit temperature of 150°C, and a flow rate of .718 gallons per minute.
  • the flow velocity is determined by the coolant channel size and the flow volume.
  • the velocity must also meet the constraint imposed by the film heat transfer confficient requirement. As described above, a flow velocity of 3 ft/sec meets the heat transfer requirements. If the cross section of passageways 116 is 0.5 cm, then the required height of the passageway may be determined to be about 1 cm.
  • the hydrostatic pressure generated by water at 150°C is about 26 psi.
  • the pumping pressure drop at a flow rate of 0.718 gallons per minute will be much less than the hydrostatic pressure. Copper walls 0.1 inch thick can easily withstand such pressures.
  • tandem solar cells have been used to increase the efficiency of the solar-to-electrical conversion process.
  • a primary cell intercepts the incident solar energy, and converts a fraction of it to electricity. Some of the solar energy not converted to electricity produces heat
  • a second unconverted portion is transmitted through the primary cell, and strikes a secondary cell that has a response band different from that of the primary cell.
  • the secondary cell is used to generate electricity from those portions of the solar spectrum to which the primary cell is not responsive.
  • a first preferred cell module comprises a wedge-shaped substrate 120 having a pair of relatively large surfaces 122 and 124, and a pair of relatively small surfaces 126 and 128. Larger surfaces 122 and 124 are not parallel, but are oriented at a small angle (e.g., 10°) with respect to one another.
  • a primary photovoltaic cell 130 is formed on surface 122, and a secondary photovoltaic cell 132 is formed on surface 126.
  • the primary and secondary cells are preferably designed so that they have different response bands.
  • substrate 120 may comprise gallium arsenide
  • primary cell 130 may comprise a gallium arsenide photovoltaic cell
  • secondary cell 132 may comprise a silicon, GaSb, Ge, or GalnAs photovoltaic cell.
  • the cell module shown In FIGURE 9 is positioned such that solar radiation 140 la incident upon primary cell 130. A large portion of the incident solar radiation that is out-of-band with respect to the primary cell is transmitted through the primary cell into substrate 120, Because of the angle between surfaces 122 and 124, this transmitted radiation 142 is reflected back and forth between surfaces 122 and 124, toward surface 126. At surface 126, the radiation traveling through the substrate strikes secondary cell 132, and a portion of such radiation is converted into electricity. Substrate 120 in effect acts as a concentrator, since the radiation transmitted by the relatively large area primary cell is concentrated onto a much smaller secondary cell.
  • substrate 120 from a relatively high refractive index material, such as gallium arsenide, and/or to place a reflective coating on surface 124.
  • a relatively high refractive index material such as gallium arsenide
  • the area of secondary cell 132 may be 10-150 times smaller than the area of the primary cell.
  • FIGURE 10 A second preferred embodiment of a multicell module is illustrated in FIGURE 10.
  • This embodiment comprises substrate 140 having relatively large surfaces 142 and 144 and relatively small surfaces 146 and 148.
  • a first primary cell 150 and a second primary cell 152 are formed on surface 142, with cell 152 lying between cell 150 and surface 142.
  • a smaller secondary cell 154 is formed on surface 146.
  • the three cells preferably all have different response bands.
  • substrate 140 may comprise silicon
  • primary cell 150 may comprise gallium arsenide
  • primary cell 152 may comprise silicon
  • secondary cell 154 may comprise GaSb, Ga, or GaRnAs.
  • Secondary cell 154 will have a response band at least partially in the range longer than 1.1 microns.
  • the use of a high Index of refraction substrate will make the module very tolerant to angular variations in the incident radiation.
  • the incident radiation can vary up to 60 degrees from normal, and still be trapped in the substrate.
  • Conical prisms can also be used. Instead of wedges, if higher concentration factors are desired.
  • FIGURE 11 illustrates how cell modules such as those shown in FIGURES 9 and 10 may be Integrated into a receiver of the type illustrated in FIGURE 4.
  • the receiver body 160 is shaped as in FIGURE 4, except that an additional out-back or recess is formed in each mounting surface, the recess being shaped so as to receive cell module 162 such that the primary cell 164 of the cell module occupies the same position as photovoltaic cell 26 in the FIGURE 4 design.
  • the overall receiver operates in a manner similar to that described above in connection with FIGURES 1-8.
  • FIGURE 12 A further preferred embodiment for the receiver is schematically illustrated in FIGURE 12.
  • the receiver comprises a disk-shaped base 170 and prefilter 172.
  • the photovoltaic cells are mounted to base 170, in a manner generally similar to that shown in FIGURE 4.
  • prefilter 172 comprises a solid shell 174 having a nonspherical shape.
  • Base 170 is mounted in an enclosure 176 having a transparent upper surface 178.
  • a mounting block 180 underlying enclosure 176 includes passageway 182 through which a cooling fluid is pumped. Passageway 182 communicates with the volume 190 between shell 174 and enclosure 176, via condult 184.
  • the cooling fluid first cools base 170, end then passes through the prefilter, where it directly absorbs some of the out-of-band incoming radiation.
  • the prefilter also functions as a lens, to focus and therefore further concentrate incoming solar radiation 192.
  • the focusing provided will be a function of the index of refraction of the cooling fluid. Therefore in this design, it is generally desirable to use a high index fluid, such as a sillcon-based oil or mineral oil, to increase the focusing.
  • a high index fluid such as a sillcon-based oil or mineral oil

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  • Photovoltaic Devices (AREA)
  • Cultivation Of Seaweed (AREA)
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PCT/US1992/001437 1991-02-25 1992-02-24 Solar energy system WO1992015119A1 (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
AU14644/92A AU659141B2 (en) 1991-02-25 1992-02-24 Solar energy system
EP92907351A EP0573557B1 (en) 1991-02-25 1992-02-24 Solar energy system
AT92907351T ATE231289T1 (de) 1991-02-25 1992-02-24 Solarenergiesystem
KR1019930702526A KR100244419B1 (ko) 1991-02-25 1992-02-24 태양 에너지 시스템
DE69232897T DE69232897T2 (de) 1991-02-25 1992-02-24 Solarenergiesystem

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US66062391A 1991-02-25 1991-02-25
US660,623 1991-02-25

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WO1992015119A1 true WO1992015119A1 (en) 1992-09-03

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EP (1) EP0573557B1 (ko)
KR (1) KR100244419B1 (ko)
AT (1) ATE231289T1 (ko)
AU (1) AU659141B2 (ko)
DE (1) DE69232897T2 (ko)
ES (1) ES2191656T3 (ko)
WO (1) WO1992015119A1 (ko)

Cited By (9)

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WO1996018235A1 (de) * 1994-12-05 1996-06-13 Johann Zimmermann Sonnengenerator
AU706605B2 (en) * 1994-09-15 1999-06-17 Colin Francis Johnson Solar concentrator for heat and electricity
AU728400B2 (en) * 1998-02-26 2001-01-11 Hitachi Limited Photovoltaic device, photovoltaic module and establishing method of photovoltaic system
ES2168995A1 (es) * 2000-11-03 2002-06-16 Univ Madrid Politecnica Colector solar fotovoltaico de baja concentracion y optica de laminas prismaticas.
GB2401427A (en) * 2003-05-08 2004-11-10 Calidus Ltd Temperature control unit for photo-voltaic solar panel
WO2006048245A1 (de) * 2004-11-08 2006-05-11 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Photovoltaisches solarenergiemodul
DE102007008200A1 (de) * 2007-02-19 2008-08-21 Krah, Brigitte und Wilfried, Dr., als gesetzliche Vertreter des Minderjährigen Krah, Benjamin Gebündelte solare Energiegewinnung durch kombinierte Solarthermie-Fotovoltaikzelle
CN101867324A (zh) * 2010-02-05 2010-10-20 丁建东 可超千倍光率的太阳能聚光发电介质循环强制冷却系统
EP2608278A1 (en) * 2011-12-21 2013-06-26 Industrial Technology Research Institute Solar cell module

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US8584468B2 (en) * 2007-02-09 2013-11-19 Dale Robert Lutz Reliable carbon-neutral power generation system
KR100905944B1 (ko) 2009-01-06 2009-07-06 뉴엔텍(주) 태양광열 복합모듈을 이용한 해수 담수화 장치
KR102660816B1 (ko) * 2021-10-29 2024-04-24 고려대학교 산학협력단 광파장 흡수 제어가 가능한 에멀젼 스펙트럼 유체 필터 및 그 제조 방법

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US4081289A (en) * 1975-12-24 1978-03-28 Campbell Iii William Patrick Solar energy system
US4143233A (en) * 1977-06-06 1979-03-06 Monsanto Research Corporation Solar energy collector
US4236937A (en) * 1978-05-24 1980-12-02 Solarex Corporation Solar collector device
US4337758A (en) * 1978-06-21 1982-07-06 Meinel Aden B Solar energy collector and converter
US4278829A (en) * 1979-03-12 1981-07-14 Powell Roger A Solar energy conversion apparatus
US4339627A (en) * 1980-02-01 1982-07-13 Le Silicium Semiconducteur Ssc Process for cooling a solar cell and a combined photovoltaic and photothermic solar device
JPS5726478A (en) * 1980-07-23 1982-02-12 Toshiba Corp Solar energy converter
US4389533A (en) * 1981-03-09 1983-06-21 Ames Douglas A Photovoltaic device for producing electrical and heat energy
DE3226167A1 (de) * 1982-07-13 1984-01-19 Sieghard Dipl.-Phys. Dr. 8000 München Gall Sonnenenergie-umwandlungsanlage
US4892593A (en) * 1984-10-09 1990-01-09 Lew Hyok S Solar trap
WO1987001512A1 (en) * 1985-09-09 1987-03-12 Hughes Aircraft Company High efficiency photovoltaic assembly
US4976789A (en) * 1989-12-26 1990-12-11 The United States Of America As Represented By The Secretary Of The Army Power transmission device

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU706605B2 (en) * 1994-09-15 1999-06-17 Colin Francis Johnson Solar concentrator for heat and electricity
US6080927A (en) * 1994-09-15 2000-06-27 Johnson; Colin Francis Solar concentrator for heat and electricity
WO1996018235A1 (de) * 1994-12-05 1996-06-13 Johann Zimmermann Sonnengenerator
GB2311846A (en) * 1994-12-05 1997-10-08 Johann Zimmermann Solar generator
GB2311846B (en) * 1994-12-05 1999-07-07 Johann Zimmermann Solar generator
AU728400B2 (en) * 1998-02-26 2001-01-11 Hitachi Limited Photovoltaic device, photovoltaic module and establishing method of photovoltaic system
ES2168995A1 (es) * 2000-11-03 2002-06-16 Univ Madrid Politecnica Colector solar fotovoltaico de baja concentracion y optica de laminas prismaticas.
GB2401427A (en) * 2003-05-08 2004-11-10 Calidus Ltd Temperature control unit for photo-voltaic solar panel
WO2006048245A1 (de) * 2004-11-08 2006-05-11 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Photovoltaisches solarenergiemodul
DE102007008200A1 (de) * 2007-02-19 2008-08-21 Krah, Brigitte und Wilfried, Dr., als gesetzliche Vertreter des Minderjährigen Krah, Benjamin Gebündelte solare Energiegewinnung durch kombinierte Solarthermie-Fotovoltaikzelle
CN101867324A (zh) * 2010-02-05 2010-10-20 丁建东 可超千倍光率的太阳能聚光发电介质循环强制冷却系统
EP2608278A1 (en) * 2011-12-21 2013-06-26 Industrial Technology Research Institute Solar cell module

Also Published As

Publication number Publication date
ES2191656T3 (es) 2003-09-16
EP0573557A1 (en) 1993-12-15
KR100244419B1 (ko) 2000-02-01
ATE231289T1 (de) 2003-02-15
AU1464492A (en) 1992-09-15
DE69232897T2 (de) 2003-11-06
AU659141B2 (en) 1995-05-11
EP0573557A4 (en) 1997-06-18
DE69232897D1 (de) 2003-02-20
EP0573557B1 (en) 2003-01-15

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