WO1992014871A1 - Elongate member production method - Google Patents
Elongate member production method Download PDFInfo
- Publication number
- WO1992014871A1 WO1992014871A1 PCT/GB1992/000261 GB9200261W WO9214871A1 WO 1992014871 A1 WO1992014871 A1 WO 1992014871A1 GB 9200261 W GB9200261 W GB 9200261W WO 9214871 A1 WO9214871 A1 WO 9214871A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- fibre
- elongate member
- bath
- water
- solvent
- Prior art date
Links
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F2/00—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof
Definitions
- This invention relates to methods of manufacturing elongate members and has particular reference to methods of manufacturing elongate members of cellulose, further particularly but not exclusively cellulosic fibres.
- Cellulosic fibres are formed from polymer molecules consisting of large numbers of anhydro glucose units joined together. Some cellulose fibres are natural, such as cotton; other cellulosic fibres, such as rayon, are produced by regeneration from fibres of vegetable origin such as wood.
- Viscose rayon fibre is a regenerated cellulosic fibre produced by the treatment of cellulose by caustic soda and subsequent xanthation to form sodium cellulose xanthate as an intermediate chemical compound. This compound will dissolve in caustic soda and produce a viscose dope.
- the viscose dope consists of the chemical compound of cellulose, i.e. the sodium cellulose xanthate, in solution in the caustic soda. After filtering, the viscose dope is extruded or spun into an acid bath to produce the fibre. In the acid bath the sodium cellulose xanthate decomposes to regenerate the cellulose.
- amine oxides tertiary amine-N-oxides
- the fibre 5 is passed through a series of water baths to remove the residual amine oxide still in the cellulose and through bleach and wash baths to produce a cellulosic fibre from which the amine oxide has been removed virtually completely.
- the wash baths the fibre is dried in a conventional 10 drying oven to produce a tow for subsequent processing.
- Fibrillation comprises the partial breaking up of the fibre in a longitudinal direction with the formation of small hairs on the fibre. These hairs tend to twist and 25 give the fibre, when looked at under the microscope, a hairy appearance. These hairs, or fibrils, on the fibre give rise to two significant problems; the first problem is the appearance of the fabric and the second problem is the tendency of the fabric to form pills on its surface.
- the fibres can be dyed loose, or fabrics woven from undyed material can be dyed in one of two ways.
- the fabric can either be open-width dyed, which means that the material is dyed on a continuous basis, or the fabric can be rope dyed, which means that the fabric is dyed in a batchwise exhaust-dyeing process.
- the fabric After dyeing, the fabric has a white-looking surface, a fibrillated or frosted finish which is unacceptable in many cases, particularly if the fabric is dyed to a dark colour, such as dark navy or black, when the fibrils show up as a light white frosting on a dark background. Further washing of the fabric after use can then make the fibrillation effect worse until the garment made from the fabric is visually unacceptable, although physically quite useable.
- a dark colour such as dark navy or black
- material which has fibrillated during the dyeing process tends to fibrillate further during washing processes, and after repeated washing the fibrils ball up and pill.
- cellulosic fibres formed from solvent systems are inherently strong, the pills are held onto the fibres and do not fall off the fabric. Again this can reduce the attractiveness of fabrics and garments made from fibrillated fibres.
- the present invention provides a method of manufacturing a solvent-spun cellulosic elongate member including the steps of:-
- the elongate member may be a fibre or a film or a tube,
- the elongate member may be treated with water at a pH of 7 or less and, prior to drying, the elongate member is not exposed to aqueous solutions having a pH greater than 8.5.
- the solvent for the cellulose is a water- compatible amine oxide.
- Typical of the amine oxides which will dissolve cellulose and are soluble in water are N,N- dimethyl-cyclohexylamine N-oxide, N,N-dimethylethanolamine N-oxide, N-methylmorpholine-N-oxide, and N,N- dimethylbenzylamine-N-oxide.
- the dope may further include water.
- the pH of the water-containing bath(s), especially the wash bath(s), is maintained at a figure of greater than 3, preferably greater than 4 or greater than 4.5 or greater than 5, and less than 6.5. Further preferably the pH is maintained at less than 6.0 and even further preferably it is maintained at less than 5.5 or between 5 and 6.
- the fibre may be bleached, after drying, in a bleach bath to produce a bleached fibre.
- a suitable acid for maintaining the pH of the bath(s) below 7 is formic acid, acetic acid, hydrochloric acid or sulphuric acid.
- Figure 1 is a schematic cross-section of part of a cellulosic fibre production line
- Figure 2 is a graph of Fibrillation Index Number (F) against pH.
- Cellulose in the form of wood pulp may be dissolved in amine oxide in any suitable manner such as is described in US Patent 4,144,080 or in UK Patent Specification 2,007,147, the contents of both of which are incorporated herein by way of reference.
- the resulting solution typically contains 23.8% by weight of cellulose in amine oxide and typically has added to it 10.5% by weight of water to form a suitable dope for spinning.
- the dope may be spun, i.e. extruded, in any suitable known manner such as by spinning into a water-containing spin bath, for example by spinning with an air gap as is described in US Patent 4,246,221, the contents of which are incorporated herein by way of reference, to produce an elongate form consisting essentially of a gel of cellulose in amine oxide.
- the shape of the elongate member will be principally determined by the shape of the hole through which the dope is spun. If the hole is a slit a film will be formed, if it is an annulus a tube will be formed and if it is circular or near circular a circular or near circular fibre will be formed.
- the gel coagulates, and the amine oxide diffuses out of the coagulating elongate form so that the dissolved cellulose reforms into the elongate member.
- More than one fibre may be produced by using a spinnerette with a plurality of holes.
- the next stage in the production of a useable fibre is to pass the amine-oxide-loaded cellulose fibre or filament from the spin bath through a series of water-containing wash baths to remove the residual amine oxide.
- this shows a fibre 1 still containing residual amine oxide entering into the wash line from the spinnerette and initial spin bath system.
- the fibre 1 will be formed of a series of individual filaments; many hundreds or thousands of filaments or strands may form the fibre 1.
- the fibre then passes round a series of rollers such as roller 2 into a plurality of water-containing wash baths such as wash baths 3, 4, 5, 6 and 7.
- the fibre then enters a drying oven 10, essentially comprising a series of heated rollers 11, 12, 13 through which hot air is passed to dry the fibre in a conventional manner.
- the production line illustrated schematically in the drawing is a standard production line in terms of its physical structure.
- Optional elements may be incorporated, such as hot stretching or steam stretching, as required.
- one of the baths 3 to 7 encountered by the fibre 1 would be a bleach bath, the function of which is to bleach out the coloured impurities from the _ibre.
- an alkaline bleach bath is used to bleach the fibre; typically, sodium hypochlorite is used in the alkaline bath, having a pH of about 10 to 11 to bleach the fibre, before subsequent washing steps further down the demineralised water line. It has now unexpectedly been found that if the fibre is not contacted with an alkali of greater than pH 8.5 before it is dried in the drying oven 10 then the tendency of the fibre to fibrillate in later wet processing after it has been dried is very significantly reduced.
- the pH of the spin bath in which the bulk of the amine oxide is removed, is 8.5.
- the dope In this bath the dope is converted to a cellulosic fibre.
- the pH of the baths in the washing line then gradually decreases from about pH 8.5 until it reaches a pH of approximately 5.5 in the final bath 7 where demineralised water is fed into the wash line.
- the reason the pH of the demineralised water is about 5.5 rather than 7 is that it is normally not the case that carbon dioxide is removed from the demineralised water used as the feed, and the carbon dioxide in the water makes it slightly acidic.
- cellulose fibre not in accordance with the invention which has been produced by dissolving cellulose in amine oxide, spinning and bleaching using alkaline bleaches of pH greater than 8.5 on the never- dried fibre, the fibre emerging from the drying line is not fibrillated at that stage. Furthermore, such fibre not in accordance with the invention does not fibrillate if treated only in the dry, even if subjected to considerable mechanical work and abrasion.
- the fibre would be passed to a crimper and cut to form staple material. The staple material would then be carded and formed into a sliver for spinning into yarn. The yarn could then be knitted or woven in the dry without producing any significant fibrillation of the fibre.
- fibres produced in accordance with the invention either for weaving or knitting and subsequently to rope-dye or exhaust-dye the materials in a batchwise process without producing significant quantities of fibril.
- a series of fibres having nil and increasing amounts of fibrillation was identified.
- a standard length of fibre was then measured and the number of fibrils (fine hairy spurs extending from the main body of the fibre) along the standard length was counted.
- the length of each fibril was measured microscopically, and an arbitrary number, being the product of the number of fibrils multiplied by the average length of each fibril, was determined for each fibre.
- the fibre having the highest number for the product was then identified as the most fibrillated fibre and was assigned the arbitrary Fibrillation Index Number of 10.
- the wholly unfibrillated fibre was assigned a Fibrillation Index Number of zero, and the remaining fibres were ranged from 1 to 10 based on the arbitrary numbers determined for them.
- each fibre of a sample of five or ten fibres was visually compared under the microscope with a set of graded fibres and an index number determined. The visually determined index numbers were then averaged to give a Fibrillation Index Number for the sample having received a given treatment. It will be appreciated that visual determination and averaging is many times quicker than measurement, and it has been found that skilled fibre technologists are consistent in their rating of the fibres.
- fibrillation standard generated by the applicants is a somewhat arbitrary standard but has the advantage of enabling quantitative comparison between fibres to take place.
- Ig of fibre was placed in a stainless steel dyeing tube in a Roaches bath. To the bath was added an aqueous scouring solution comprising: 2g/l anionic detergent (Detergyl)
- the fibre in the tube was bleached in an aqueous solution comprising: 15ml/l H 2 0 2
- the fibre was then dyed using an aqueous dye solution comprising:
- the fibre was dyed at 80°C for 60 minutes. Whilst still in the dyeing tube the fibre was washed to remove loose dye using a 2ml/l aqueous solution of Sandopur SR for 20 minutes at 100°C.
- the fibre was then rinsed in cold water and air-dried at 90°C. Small samples of the fibre treated at different pH's were then visually examined to determine the Fibrillation Index.
- the Fibrillation Index Number is shown in Figure 2 of the accompanying drawings. It can be seen that as the pH varies between 4 and 6 the fibrillation effect of the fibre is very low; however as the pH increases above 6 the Fibrillation Index Number significantly increases.
- the acid used to maintain the fibre at a pH below 6.5 in the first bath is a buffered acetic acid such as the acid "Sandacid BS" available from Sandoz.
- the new treatment therefore produces an elongate member, particularly fibre, having enhanced resistance to fibrillation without any significant effect on extensibility or tenacity. It is cheap to use in that it omits the alkaline treatment of the fibre and therefore reduces the length of the treatment line required for the production of the fibre.
- the omission of the bleaching stage removes the need for hyprochlorite usage which is an environmentally useful step to take.
- the unbleached fibre has a slightly yellower look than bleached fibre but is quite acceptable as a dyeing-base colour; its whiteness is comparable to that of bleached cotton.
- the same treatment can be given to films or tubes of solvent-spun cellulose.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Artificial Filaments (AREA)
Abstract
Description
Claims
Priority Applications (8)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1019930702374A KR930703489A (en) | 1991-02-15 | 1992-02-13 | Long material manufacturing method |
US08/090,113 US5403530A (en) | 1991-02-15 | 1992-02-13 | Elongate member production method |
SK850-93A SK85093A3 (en) | 1991-02-15 | 1992-02-13 | Enlogate member production method |
JP4504179A JPH06505060A (en) | 1991-02-15 | 1992-02-13 | Manufacturing method of elongated material |
CS931582A CZ282253B6 (en) | 1991-02-15 | 1992-02-13 | Process for preparing an elongated cellulose element by spinning a cellulose solution in a solvent |
RU9293052397A RU2083734C1 (en) | 1991-02-15 | 1992-02-13 | Method of manufacture of drawn product (versions) |
BR9205616A BR9205616A (en) | 1991-02-15 | 1992-02-13 | Manufacturing process of an elongated solvent-spun cellulosic element |
FI933587A FI933587A0 (en) | 1991-02-15 | 1993-08-13 | FRAMEWORK FOR FRAMSTAELLNING AV ETT FOERLAENGT STYCKE |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB9103297.9 | 1991-02-15 | ||
GB919103297A GB9103297D0 (en) | 1991-02-15 | 1991-02-15 | Fibre production method |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1992014871A1 true WO1992014871A1 (en) | 1992-09-03 |
Family
ID=10690122
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/GB1992/000261 WO1992014871A1 (en) | 1991-02-15 | 1992-02-13 | Elongate member production method |
Country Status (13)
Country | Link |
---|---|
US (1) | US5403530A (en) |
EP (1) | EP0571460A1 (en) |
JP (1) | JPH06505060A (en) |
KR (1) | KR930703489A (en) |
AU (1) | AU1241092A (en) |
BR (1) | BR9205616A (en) |
CZ (2) | CZ282253B6 (en) |
FI (1) | FI933587A0 (en) |
GB (1) | GB9103297D0 (en) |
IN (1) | IN185158B (en) |
RU (1) | RU2083734C1 (en) |
SK (1) | SK85093A3 (en) |
WO (1) | WO1992014871A1 (en) |
Cited By (23)
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WO1994009191A1 (en) * | 1992-10-21 | 1994-04-28 | Courtaulds Fibres (Holdings) Limited | Fibre treatment |
WO1995035399A1 (en) * | 1994-06-22 | 1995-12-28 | Courtaulds Fibres (Holdings) Limited | Lyocell fibre and a process for its manufacture |
US5543101A (en) * | 1993-07-08 | 1996-08-06 | Lenzing Aktiengesellschaft | Process of making cellulose fibres |
DE19509291A1 (en) * | 1995-03-15 | 1996-09-19 | Akzo Nobel Nv | Measurement of cellulose@ concn. in soln. of tert. amine-N-oxide |
US5601771A (en) * | 1994-09-05 | 1997-02-11 | Lenzing Aktiengesellschaft | Process for the production of cellulose fibres |
WO1997023668A1 (en) * | 1995-12-21 | 1997-07-03 | Courtaulds Fibres (Holdings) Limited | Manufacture of cellulosic articles |
WO1997023666A1 (en) * | 1995-12-22 | 1997-07-03 | Lenzing Aktiengesellschaft | Cellulose moulded article and method of producing same |
WO1997025462A1 (en) * | 1996-01-09 | 1997-07-17 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Process for producing cellulose fibres and fibres produced thereby |
US5653931A (en) * | 1993-12-10 | 1997-08-05 | Lenzing Aktiengesellschaft | Process for the production of cellulose moulded bodies |
WO1997045574A1 (en) * | 1996-05-30 | 1997-12-04 | Courtaulds Fibres (Holdings) Limited | Fibre manufacture |
WO1997046745A1 (en) * | 1996-05-30 | 1997-12-11 | Akzo Nobel N.V. | Method of producing a cellulosic yarn |
WO1998002602A1 (en) * | 1996-07-12 | 1998-01-22 | Courtaulds Fibres (Holdings) Limited | Method for the manufacture of lyocell fibre |
WO1998003707A1 (en) * | 1996-07-23 | 1998-01-29 | Acordis Fibres (Holdings) Limited | Method for the manufacture of lyocell fibre |
US5725821A (en) * | 1994-06-22 | 1998-03-10 | Courtaulds Fibres (Holdings) Limited | Process for the manufacture of lyocell fibre |
US5759210A (en) * | 1994-05-03 | 1998-06-02 | Courtaulds Fibres (Holdings) Limited | Lyocell fabric treatment to reduce fibrillation tendency |
US5779737A (en) * | 1994-04-15 | 1998-07-14 | Courtaulds Fibres Holdings Limited | Fibre treatment |
MD906C2 (en) * | 1993-04-21 | 1998-09-30 | Lenzing Aktiengesellschaft | Process for cellulose of production fibres obtaining |
US5863478A (en) * | 1996-03-04 | 1999-01-26 | Lenzing Aktiengesellschaft | Process for the manufacture of cellulose fibres |
US5919412A (en) * | 1995-10-06 | 1999-07-06 | Lenzing Aktiengesellschaft | Cellulose fibre |
US6645409B2 (en) | 1998-09-29 | 2003-11-11 | Lenzing Aktiengesellschaft | Process for the production of cellulosic fibres |
WO2015101543A1 (en) | 2014-01-03 | 2015-07-09 | Lenzing Aktiengesellschaft | Cellulose fiber |
US9963820B2 (en) | 2008-06-27 | 2018-05-08 | Lenzing Aktiengesellschaft | Cellulose fiber and process for the production thereof |
EP3536853A1 (en) | 2018-03-06 | 2019-09-11 | Lenzing Aktiengesellschaft | Lyocell fiber with decreased pill formation |
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US5882356A (en) * | 1992-10-21 | 1999-03-16 | Courtaulds Fibres (Holdings) Limited | Fibre treatment |
GB9304887D0 (en) * | 1993-03-10 | 1993-04-28 | Courtaulds Plc | Fibre treatment |
GB9410912D0 (en) * | 1994-06-01 | 1994-07-20 | Courtaulds Plc | Fibre treatment |
US6210801B1 (en) | 1996-08-23 | 2001-04-03 | Weyerhaeuser Company | Lyocell fibers, and compositions for making same |
US6306334B1 (en) | 1996-08-23 | 2001-10-23 | The Weyerhaeuser Company | Process for melt blowing continuous lyocell fibers |
US6235392B1 (en) | 1996-08-23 | 2001-05-22 | Weyerhaeuser Company | Lyocell fibers and process for their preparation |
US6221487B1 (en) | 1996-08-23 | 2001-04-24 | The Weyerhauser Company | Lyocell fibers having enhanced CV properties |
US6471727B2 (en) | 1996-08-23 | 2002-10-29 | Weyerhaeuser Company | Lyocell fibers, and compositions for making the same |
US6331354B1 (en) | 1996-08-23 | 2001-12-18 | Weyerhaeuser Company | Alkaline pulp having low average degree of polymerization values and method of producing the same |
US5783131A (en) * | 1996-08-27 | 1998-07-21 | Alfacel S.A. | Method to slowly regenerate cellulosic sausage casing |
EP0853146A3 (en) * | 1997-01-09 | 1999-03-24 | Akzo Nobel N.V. | Method of producing cellulosic fibres and cellulosic fibres |
US6096258A (en) * | 1998-01-20 | 2000-08-01 | Viskase Corporation | Method and apparatus for forming a cellulose article including solvent recovery means |
US6773648B2 (en) | 1998-11-03 | 2004-08-10 | Weyerhaeuser Company | Meltblown process with mechanical attenuation |
DE10023391A1 (en) * | 2000-05-12 | 2001-03-15 | Lurgi Zimmer Ag | Production of cellulosic articles, e.g. fibers, comprises extruding solution to produce fiber, stretching article produced, feeding it without tension to conveyor and removing it from end of conveyor under tension |
AT413285B (en) * | 2003-11-06 | 2006-01-15 | Chemiefaser Lenzing Ag | Washing of absorbent material, e.g. lyocell fiber tow, involves several stages in contra-flow with appreciable amounts of absorbed liquid carried to next stage |
AT413286B (en) * | 2003-11-06 | 2006-01-15 | Chemiefaser Lenzing Ag | Washing of absorbent material, e.g. lyocell fiber tow, in several contra-flow stages uses partitioned drain tanks to restrict mixing |
AT514136A1 (en) * | 2013-04-05 | 2014-10-15 | Lenzing Akiengesellschaft | Polysaccharide fiber with increased fibrillation capability and process for its preparation |
AT514137A1 (en) | 2013-04-05 | 2014-10-15 | Lenzing Akiengesellschaft | Polysaccharide fiber and process for its preparation |
AT514123B1 (en) | 2013-04-10 | 2015-06-15 | Lenzing Akiengesellschaft | Polysaccharide film and process for its preparation |
AT514468A1 (en) | 2013-06-17 | 2015-01-15 | Lenzing Akiengesellschaft | High absorbency polysaccharide fiber and its use |
AT514474B1 (en) | 2013-06-18 | 2016-02-15 | Chemiefaser Lenzing Ag | Polysaccharide fiber and process for its preparation |
KR101466692B1 (en) * | 2013-12-02 | 2014-12-01 | 동양제강 주식회사 | Apparatus for extracting solvent |
EP3467161A1 (en) * | 2017-10-06 | 2019-04-10 | Lenzing Aktiengesellschaft | Lyocell type cellulose filament production process |
SE544547C2 (en) * | 2019-02-21 | 2022-07-12 | Treetotextile Ab | A process for wet spinning of cellulose fibers from an alkaline spin bath |
EP4092185A4 (en) * | 2020-01-14 | 2023-01-25 | Asahi Kasei Kabushiki Kaisha | Fibrillated regenerated cellulose fiber, and fabric using same |
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GB2001320A (en) * | 1977-07-26 | 1979-01-31 | Akzona Inc | Process for making amine oxide solution of cellulose |
FR2407280A1 (en) * | 1977-10-31 | 1979-05-25 | Akzona Inc | PROCESS FOR COATING CELLULOSIC FILAMENTS FORMED FROM A SPINNING SOLUTION, BY A NON-SOLVENT LIQUID |
FR2450293A1 (en) * | 1979-03-02 | 1980-09-26 | Akzona Inc | PROCESS FOR THE PREPARATION OF A MOLDED CELLULOSE ARTICLE FROM A CELLULOSE SOLUTION IN A SOLVENT CONTAINING A TERTIARY AMINE OXIDE AND ARTICLE THUS OBTAINED |
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US3801551A (en) * | 1972-07-05 | 1974-04-02 | Dow Chemical Co | Making fibrillar masses of acidic copolymers |
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FI60569C (en) * | 1980-03-28 | 1982-02-10 | Valtion Teknillinen | FOERFARANDE FOER TILLVERKNING AV REGENERERADE CELLULOSAPRODUKTER OCH AOTERVINNING AV LOESNINGSKEMIKALIER |
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-
1991
- 1991-02-15 GB GB919103297A patent/GB9103297D0/en active Pending
-
1992
- 1992-02-04 IN IN82DE1992 patent/IN185158B/en unknown
- 1992-02-13 US US08/090,113 patent/US5403530A/en not_active Expired - Fee Related
- 1992-02-13 EP EP92904620A patent/EP0571460A1/en not_active Withdrawn
- 1992-02-13 JP JP4504179A patent/JPH06505060A/en active Pending
- 1992-02-13 BR BR9205616A patent/BR9205616A/en not_active Application Discontinuation
- 1992-02-13 CZ CS931582A patent/CZ282253B6/en unknown
- 1992-02-13 WO PCT/GB1992/000261 patent/WO1992014871A1/en not_active Application Discontinuation
- 1992-02-13 CZ CZ962444A patent/CZ244496A3/en unknown
- 1992-02-13 AU AU12410/92A patent/AU1241092A/en not_active Abandoned
- 1992-02-13 KR KR1019930702374A patent/KR930703489A/en not_active Application Discontinuation
- 1992-02-13 SK SK850-93A patent/SK85093A3/en unknown
- 1992-02-13 RU RU9293052397A patent/RU2083734C1/en active
-
1993
- 1993-08-13 FI FI933587A patent/FI933587A0/en not_active Application Discontinuation
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Title |
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Cited By (30)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1994009191A1 (en) * | 1992-10-21 | 1994-04-28 | Courtaulds Fibres (Holdings) Limited | Fibre treatment |
MD906C2 (en) * | 1993-04-21 | 1998-09-30 | Lenzing Aktiengesellschaft | Process for cellulose of production fibres obtaining |
US5543101A (en) * | 1993-07-08 | 1996-08-06 | Lenzing Aktiengesellschaft | Process of making cellulose fibres |
US5653931A (en) * | 1993-12-10 | 1997-08-05 | Lenzing Aktiengesellschaft | Process for the production of cellulose moulded bodies |
US5779737A (en) * | 1994-04-15 | 1998-07-14 | Courtaulds Fibres Holdings Limited | Fibre treatment |
US5759210A (en) * | 1994-05-03 | 1998-06-02 | Courtaulds Fibres (Holdings) Limited | Lyocell fabric treatment to reduce fibrillation tendency |
US6042769A (en) * | 1994-06-22 | 2000-03-28 | Acordis Fibres (Holdings ) Limited | Lyocell fibre and a process for its manufacture |
AU702214B2 (en) * | 1994-06-22 | 1999-02-18 | Courtaulds Fibres (Holdings) Limited | Lyocell fibre and a process for its manufacture |
CN1098939C (en) * | 1994-06-22 | 2003-01-15 | 考脱沃兹纤维(控股)有限公司 | Lyocell fibre and a process for its manufacture |
WO1995035399A1 (en) * | 1994-06-22 | 1995-12-28 | Courtaulds Fibres (Holdings) Limited | Lyocell fibre and a process for its manufacture |
US5725821A (en) * | 1994-06-22 | 1998-03-10 | Courtaulds Fibres (Holdings) Limited | Process for the manufacture of lyocell fibre |
US5601771A (en) * | 1994-09-05 | 1997-02-11 | Lenzing Aktiengesellschaft | Process for the production of cellulose fibres |
DE19509291A1 (en) * | 1995-03-15 | 1996-09-19 | Akzo Nobel Nv | Measurement of cellulose@ concn. in soln. of tert. amine-N-oxide |
US5919412A (en) * | 1995-10-06 | 1999-07-06 | Lenzing Aktiengesellschaft | Cellulose fibre |
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US9963820B2 (en) | 2008-06-27 | 2018-05-08 | Lenzing Aktiengesellschaft | Cellulose fiber and process for the production thereof |
WO2015101543A1 (en) | 2014-01-03 | 2015-07-09 | Lenzing Aktiengesellschaft | Cellulose fiber |
US10883196B2 (en) | 2014-01-03 | 2021-01-05 | Lenzing Aktiengesellschaft | Cellulose fiber |
EP3536853A1 (en) | 2018-03-06 | 2019-09-11 | Lenzing Aktiengesellschaft | Lyocell fiber with decreased pill formation |
WO2019170740A1 (en) | 2018-03-06 | 2019-09-12 | Lenzing Aktiengesellschaft | Lyocell fiber with decreased pill formation |
Also Published As
Publication number | Publication date |
---|---|
SK85093A3 (en) | 1994-01-12 |
FI933587A (en) | 1993-08-13 |
RU2083734C1 (en) | 1997-07-10 |
US5403530A (en) | 1995-04-04 |
IN185158B (en) | 2000-11-25 |
CZ282262B6 (en) | 1997-06-11 |
GB9103297D0 (en) | 1991-04-03 |
EP0571460A1 (en) | 1993-12-01 |
JPH06505060A (en) | 1994-06-09 |
AU1241092A (en) | 1992-09-15 |
KR930703489A (en) | 1993-11-30 |
CZ244496A3 (en) | 1997-06-11 |
BR9205616A (en) | 1994-08-02 |
FI933587A0 (en) | 1993-08-13 |
CZ282253B6 (en) | 1997-06-11 |
CZ158293A3 (en) | 1994-02-16 |
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