WO1992009760A1 - Translucent thermal insulation - Google Patents

Translucent thermal insulation Download PDF

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Publication number
WO1992009760A1
WO1992009760A1 PCT/FI1991/000352 FI9100352W WO9209760A1 WO 1992009760 A1 WO1992009760 A1 WO 1992009760A1 FI 9100352 W FI9100352 W FI 9100352W WO 9209760 A1 WO9209760 A1 WO 9209760A1
Authority
WO
WIPO (PCT)
Prior art keywords
thermal insulation
fibers
translucent
light
glass
Prior art date
Application number
PCT/FI1991/000352
Other languages
English (en)
French (fr)
Inventor
Pentti Raunio
Original Assignee
E.I. Du Pont De Nemours And Company Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by E.I. Du Pont De Nemours And Company Inc. filed Critical E.I. Du Pont De Nemours And Company Inc.
Priority to EP91920020A priority Critical patent/EP0557358B1/en
Priority to AU89024/91A priority patent/AU658154B2/en
Priority to DE69120964T priority patent/DE69120964T2/de
Publication of WO1992009760A1 publication Critical patent/WO1992009760A1/en

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/12Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04BGENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
    • E04B1/00Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
    • E04B1/62Insulation or other protection; Elements or use of specified material therefor
    • E04B1/74Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls
    • E04B1/76Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls specifically with respect to heat only
    • E04B1/78Heat insulating elements
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04CSTRUCTURAL ELEMENTS; BUILDING MATERIALS
    • E04C2/00Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels
    • E04C2/02Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials
    • E04C2/26Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials composed of materials covered by two or more of groups E04C2/04, E04C2/08, E04C2/10 or of materials covered by one of these groups with a material not specified in one of the groups
    • E04C2/284Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials composed of materials covered by two or more of groups E04C2/04, E04C2/08, E04C2/10 or of materials covered by one of these groups with a material not specified in one of the groups at least one of the materials being insulating
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04CSTRUCTURAL ELEMENTS; BUILDING MATERIALS
    • E04C2/00Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels
    • E04C2/54Slab-like translucent elements
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04DROOF COVERINGS; SKY-LIGHTS; GUTTERS; ROOF-WORKING TOOLS
    • E04D3/00Roof covering by making use of flat or curved slabs or stiff sheets
    • E04D3/02Roof covering by making use of flat or curved slabs or stiff sheets of plane slabs, slates, or sheets, or in which the cross-section is unimportant
    • E04D3/06Roof covering by making use of flat or curved slabs or stiff sheets of plane slabs, slates, or sheets, or in which the cross-section is unimportant of glass or other translucent material; Fixing means therefor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/10Inorganic fibres
    • B32B2262/101Glass fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/10Properties of the layers or laminate having particular acoustical properties
    • B32B2307/102Insulating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/30Properties of the layers or laminate having particular thermal properties
    • B32B2307/304Insulating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/40Properties of the layers or laminate having particular optical properties
    • B32B2307/412Transparent
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/40Properties of the layers or laminate having particular optical properties
    • B32B2307/414Translucent
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2410/00Agriculture-related articles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2419/00Buildings or parts thereof

Definitions

  • the present invention relates to a light or other radiation transmitting fibrous thermal insulation which comprises at least one coating layer of transparent and/or translucent material, such as glass, plastics, plastics composite or some combination of these, and an insulating layer attached to the coating layer or inserted between the coating layers.
  • Translucent thermal insulations may comprise, e.g., multiple coatings or a combination of coatings and insulating material inserted therebetween.
  • glass or plastics are used as coatings.
  • translucent insulating materials are used, for example, different .silicon gels or the like and different materials treated with blowing agents, for example, urea formaldehyde, phenol formaldehyde, polycarbonate, polystyrene, polystyrene copolymer or polyethylene.
  • blowing agents for example, urea formaldehyde, phenol formaldehyde, polycarbonate, polystyrene, polystyrene copolymer or polyethylene.
  • Prior art arrangements are disclosed, e.g., in DE patents 29 06 259, 23 14 622, 32 14 421 and in EP patent 353 397. Typical to earlier known structures is that their manufacturing costs are high and that their utility is poor in practice, and often they are not aesthetic in appearance.
  • an optimum composition of the above described thermal insulation is: a 50 mm thick insulating layer, consisting of weakly light scattering and weakly heat absorbing fibers with a diameter of about 20 to 30 ⁇ m and density of 10 kg/m 3 and of non- coated glass pane as a cover.
  • a 50 mm thick insulating layer consisting of weakly light scattering and weakly heat absorbing fibers with a diameter of about 20 to 30 ⁇ m and density of 10 kg/m 3 and of non- coated glass pane as a cover.
  • light transmission is mainly effected through the glass material of the fibers.
  • the object of the present invention is to provide a thermal insulation with a high thermal insulation capacity, sufficient light transmissivity, and aesthetic appearance and which consists of at least one coating layer and an insulating layer with or between the coating layers.
  • the coating layer may be of glass, plastics, plastics composite or some combination of these.
  • An arrangement according to the invention may be utilized in wall and roof structures, roof hatches of cars, dormers, other windows, doors, and as prefabricated elements of light wells, outdoor sheds, stairways, greenhouses, spas, swimming pools etc.
  • the object of the invention is achieved with a thermal insulatio having a characteristic feature of being formed of thin fibers with an average diameter less than 12 urn.
  • the insulating layer of the translucent thermal insulation according to the invention comprises thin fibers, especially glass fibers, produced by methods known per se, and it is characteristic to these fibers that, when the fiber diameter is reduced, the share of light and other radiation transmitted through the structure of the same thickness and density does not significantly decrease, although the thermal conductivity of the insulation, measured with standard methods, is considerably reduced.
  • the thermal insulation according to the inventon has an excellent thermal insulation capacity. It also has an expedient light transmission capacity which depends especially on the thickness and density of the fiber layer.
  • fibers made of glass are typically less than 12 ⁇ m, preferably less than 4 ⁇ , in diameter, and the bulk density of the glass fibers is typically less than 50 kg/m 3 , preferably 2 to 20 kg/m 3 .
  • light is transmitted, e.g., through a weakly light scattering fiber layer, which is comprised of fibers with a diameter of about 20 to 30 ⁇ m, mainly through the glass material of the fibers.
  • the fiber thickness decreases, the light scattering area of the structure increases.
  • Luminous and other radiation transmitted through the insulating layer most obviously proceeds in this kind of matting or like structure formed by thin fibers mainly in the gaps between the fibers, by being reflected from the fiber surfaces.
  • the translucent insulation of the invention comprising, e.g., matting of thin fibers + coating layers of glass panes, also has excellent back-reflecting properties. Thus, it does not strongly absorb heat energy, but reflects it back. Advantages of high back-reflecting of heat and other radiation are described later in connection with example No. 2.
  • Fibers may also be treated with different coating materials, e.g, for increasing reflection.
  • the insulating layer according to the invention may also be made of other fibers, such as slag, mineral or polymeric fibers, which have the above-described properties.
  • the insulating layer may also contain additives or fillers, such as microspheres or special fibers. These additives or fillers may be treated in many different ways. For example, they may blacken by the effect of sunlight, in other words, they may be photochromatic.
  • fibers belonging to the above-identified material groups are used as conventional heat and sound insulations in the range of 12 to 4 urn in fiber diameter and for various air and liguid filters in the range of 4 to 0.5 j m in fiber diameter.
  • the thermal insulation according to the invention may comprise one or more coating layers with the insulating layer, comprised of thin fibers, being attached to the coating layer or brought inbetween the coating layers.
  • the coating layers/coating layer both support/supports the heat insulating layer and protect/protects it against external conditions such as weather, dust, general fouling etc.
  • the outer or the inner surface of the outermost coating layer may also be provided with different sheets for adjusting or improving the thermal insulation or translucence properties of the structure. If two coating layers are used, insulation properties may be improved by arranging the fibrous insulating layer with a partial vacuum or by filling it with gas, e.g., with so-called greenhouse gas.
  • Fig. 1 is a schematic, partial cross-sectional view of a translucent thermal insulation comprising two coating layers
  • Fig. 2 is a schematic, partial cross-sectional view of a preferred embodiment of the invention
  • Fig. 3 illustrates a test arrangement in accordance with example 2
  • Fig. 4 is a graph of according to Fig.
  • layer/sheet/panel transmitting both light and heat radiation comprises one or more coating layers 2 and an insulating layer 3, which may be provided as matting, wadding or flocculated blast material.
  • flocculated fibers may be brought, e.g., onto the surface of one coating layer only and then the structure closed with another coating layer on the thus formed fiber layer.
  • binders and/or needling as used in prior art processes may also be utilized in order to provide the desired mechanical properties. Due to the above-described simple manufacturing methods, the manufacture of translucent thermal insulations according to the invention is clearly less expensive and easier in comparison with the alternatives on the market, and no expensive investments are required.
  • Fig. 2 illustrates a preferred embodiment of the invention, which is provided with one coating layer 2 only.
  • the insulating layer 3 manufactured by the above-described methods is aesthetic in appearance and, for example, in light roofing applications, it may well be completely in sight.
  • the aesthetic impression may be further added by applying various, e.g., coloured fibers among the light and other radiation transmitting insulating layer, or the insulating layer or part thereof may be stained or dyed.
  • transparent, directly light transmitting parts may also be used.
  • Such composite structures may be applied, for example, in swimming pools and spas.
  • the light and other radiation transmitted through the thermal insulation may be regulated by adjusting the thickness and density of the insulating layer.
  • Raw materials, which are light in colour and highly reflecting as to light and other radiation may be advantageously selected for the manufacture of the insulation fibers.
  • the fibers may also be coated for optimizing their reflective properties. By applying a suitable coating material either on the outer or the inner surface of the coating layer, it is possible to adjust the reflective properties of the coating layer.
  • the empty space between the fibers between the coating layers 2 may be dimensioned by adjusting the bulk density and fiber thickness of the fiber layer.
  • the fiber layers may also be so arranged that, at least one coating layer is provided with a fiber layer, whereby a space can be left between the coating layers in which there are substantially no fibers.
  • two arrangements according to Fig. 2 may be placed one on top of the other so that the insulating layers are arranged one against the other, whereby a free space dimensioned by a frame of suitable width, may be left between the insulating layers.
  • the free space between the coating layers according to the example i.e., the volume between single fibers + a separate free space may be provided with partial vacuum or it may be filled with, gas, e.g., so-called greenhouse gas, as mentioned earlier.
  • gas e.g., so-called greenhouse gas
  • Thin fibers may be bound together with binding fibers, or without a binder, for example, by needling, or they may be treated with a binder which produces a light, nearly white matting.
  • a binder which produces a light, nearly white matting.
  • light derived from a spotlike source of light scatters extensively when it passes through the fiber matting, and it can be seen on the other side of the matting as a light area, not as a light spot.
  • fibers may also be used like blast wool, i.e., a suitable layer thereof may be brought in between the coating layers 2.
  • the thermal insulation according to the invention is especially advantageous, for example, in greenhouses, where single glazing is extensively used nowadays. Part of greenhouse cultivation is started early in spring when the nights are long and the quantity of sunlight varies in the .daytime. In those conditions, a lot of heating energy is consumed with existing structures.
  • the arrangement according to the invention saves a lot of heating energy, which is the greatest cost factor in greenhouse cultivation.
  • the thermal insulation according to the invention also equalizes temperatures during the hot summer time, acting to reduce heat transmission to the interior when the sun shines and gives too much heat.
  • the arrangement of the invention is also applicable to, e.g., swimming pools and other buildings with large windows. Like in greenhouses, large amounts in heating costs can be saved by replacing, for example, part of the window area by thermal insulations according to the invention.
  • thermal insulation which is appropriately translucent and has an especially high thermal insulation capacity with respect to its translucence. Being light, it is aesthetic in appearance, and it is also inexpensive.
  • thermal insulations may be used, as mentioned earlier, for example, in windows and doors as well as building elements of light wells, stairways and roofs.
  • the arrangement of the invention prevents excessive heating of the interior, still providing the premises with sufficient lighting.
  • Use of the thermal insulation of the invention as a building element of various buildings, sheds, outdoor warehouses, etc. offers an ideal arrangement, especially when the days are hot and the nights may be very cold.
  • Example 1 describes an arrangement according to the invention, in which arrangement an insulating layer was introduced between two coating layers as follows: coating layers: 2 glass panes, pane thickness
  • 3 mm insulating material glass fiber fiber density: approx. 5 kg/m 3 fiber diameter: approx. 3 ⁇ m insulating layer thickness: about 24 mm
  • This arrangement gave a translucency value of about 45 % and heat transmissivity value k «. 1.3 W/ ⁇ .2° ⁇ , which corresponds to a high quality window structure with quadruple glazing.
  • Example 2 presents properties of a thermal insulation according to the invention and compares them with an earlier known arrangement.
  • Fig. 3 presents a test arrangement for measuring the intensity of the radiation transmitted through alternative translucent insulating layers to a well insulated space 10 as well as the temperature of this well insulated space at various measuring points.
  • the walls 11 of the insulated space were of blown polyurethane.
  • a translucent insulating layer 12 in the first test was provided as a single, clear 4 mm thick glass.
  • a translucent insulating layer in the second test was provided as a thermal insulation according to the invention, which comprised two normal, 4 mm thick, clear glass panes and an approximately 24 mm thick fiber layer therebetween, which fiber layer was glass fiber in an air atmosphere. The glass fibers were about 4 ⁇ m in diameter and the fiber density of the insulating layer was about 7 kg/m .
  • As a translucent insulating layer in the third test a 4 mm thick, clear glass + 24 mm air gap + 4 mm thick, clear glass was provided. Measuring results from the third test proved insufficient for the drawing of a graph. They are, therefore, explained later in the text. Otherwise, the test arrangement itself was similar to the other two test arrangements.
  • a measuring point 13 is the gap between the glass panes (only with the thermal insulation according to the invention; the second test utilized a single glass pane).
  • an emittance sensor 14 Below the insulating layer 12, inside the insulated space 10, is arranged an emittance sensor 14 and below it a black plate 15, the bottom surface thereof being provided with two temperature detectors 16 and 17.
  • a temperature detector 18 Below the black plate 15, in insulated space 10, is disposed a temperature detector 18. External radiation is measured with a sensor 19.
  • Fig. 4 presents the results of the tests performed on the basis of the test arrangements according to Fig. 3, by means of graphs drawn on temperature against time axes. The outdoor temperature was about 16°C during both tests. Test results with a single glass pane used in the first test are marked with a dashed line in Fig. 4. The test results with a thermal insulation according to the invention, used in the second test, are marked with a full line. Measuring points 13, 16, 17 and 18 mentioned in the explanation of Fig. 3 are shown at the graphs.
  • the outside radiation in the first test was about 850 W/m ⁇ at measuring point 19 and about 700 under the glass pane, i.e. under the insulating layer, at measuring point 14.
  • the dashed line graphs in Fig. 4 illustrating the first test clearly indicate that the temperature at measuring points 16 and 17 on the bottom surface of the black plates rises very rapidly to a considerably high level, i.e., to about 100°C in about 20 minutes from the start of the test.
  • the temperature at measuring point 18 also rises to a considerably high level, i.e., to about 82°C in about 20 minutes.
  • the outside radiation was about 900 /m ⁇ a measuring point 19 and about 200 W/m ⁇ under the insulating layer 12 of the invention at measuring point
  • the temperature is not more than about 56°C when 120 minutes have passed from the start of the test.
  • the back-reflecting thermal efficiency and transmitting light efficiency as well as heat transmissivity were measured.
  • the value of the back-reflecting thermal efficiency was about 40 % and the transmitting light efficiency about 25 %.
  • Heat transmissivity value i.e., the so-called k-value, was k ⁇ - 1.3 W/m 2o K.
  • a translucent thermal insulation was a 4 mm thick window glass + 24 mm air gap + 4 mm thick window glass.
  • the outdoor temperature was the same as before, i.e., about 16°C.
  • the efficiency of the outside radiation was about 900 / 2 and the radiation efficiency under the thermal insulation was about 650 W/irr at measuring point
  • the temperature was about 120°C when measured after 20 minutes from the start of the test.
  • glasses which are intended to protect from the sun and which have been made by coating window glasses with different, thin, reflecting covers.
  • a product catalogue of a well-known manufacturer presents a glass combination with the k-value which is near the k-value k ⁇ 1.3 W/m 2o K received from the tests performed in connection with the present invention.
  • This k-value was one of the very best among the alternatives presented in the brochure.
  • the k- value of the glass combination presented in the brochure was k , 1.4 W/m 2o K.
  • the combination consisted of three glass layers with a 12 mm air gap therebetween.
  • the glass layers were: the outermost 4 mm thick layer of solar radiation reflecting float glass with a durable and resistant surface layer + the middle layer of clear glass of 4 mm + the innermost 4 mm layer of float glass coated with selective low-emissivity layer.
  • the transmitting light efficiency was 19 % with this combination, and the back-reflecting thermal efficiency was also 19 %.
  • the absorption value of solar radiation was 69 % in the example of the brochure. Due to this high absorption value of solar radiation, there was a note in the brochure explaining that because this combination of glasses absorbs plenty of solar heat, the risks of thermal stresses have to be evaluated and that a tempered alternative prevents damages caused by these thermal stresses.
  • a common assumption In the example taken from the above-mentioned product catalogue, a common assumption
  • the level of back-reflecting radiation was 40 %, which means that a great deal of the efficiency of the incoming heat radiation is reflected back.
  • the advantage of the invention is appreciated from the solid curve illustrating the results from the second test at measuring point 13.
  • the temperature between the glass panes i.e. in the insulating layer
  • the temperature in the space between the glass panes remains at even a lower level than the temperature of the insulated space 10 at different measuring points.
  • the temperature of the space between the glass panes does not substantially rise, even though the indoor temperature has risen.
  • the present invention related to. a thermal insulation which is light and other radiation energy transmitting and which has, with respect to this property, an excellent thermal insulation capacity, provides an aesthetic arrangement which is inexpensive as to its manufacturing costs.
  • the arrangement of the invention with expedient translucence and impenetrability to eyes, and excellent thermal and sound insulation capabilities offers an opportunity of applying the invention to a number of different installations.

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  • Engineering & Computer Science (AREA)
  • Architecture (AREA)
  • Civil Engineering (AREA)
  • Structural Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Acoustics & Sound (AREA)
  • Electromagnetism (AREA)
  • Laminated Bodies (AREA)
  • Building Environments (AREA)
  • Inorganic Insulating Materials (AREA)
  • Details Of Aerials (AREA)
  • Lubricants (AREA)
  • Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
  • Treating Waste Gases (AREA)
  • Nonwoven Fabrics (AREA)
  • Refrigerator Housings (AREA)
  • Vessels, Lead-In Wires, Accessory Apparatuses For Cathode-Ray Tubes (AREA)
PCT/FI1991/000352 1990-11-27 1991-11-26 Translucent thermal insulation WO1992009760A1 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
EP91920020A EP0557358B1 (en) 1990-11-27 1991-11-26 Translucent thermal insulation
AU89024/91A AU658154B2 (en) 1990-11-27 1991-11-26 Translucent thermal insulation
DE69120964T DE69120964T2 (de) 1990-11-27 1991-11-26 Lichtdurchlaessige waermeisolierung

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FI905834A FI87480C (fi) 1990-11-27 1990-11-27 Ljusgenomslaeppande vaermeisolering
FI905834 1990-11-27

Publications (1)

Publication Number Publication Date
WO1992009760A1 true WO1992009760A1 (en) 1992-06-11

Family

ID=8531468

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/FI1991/000352 WO1992009760A1 (en) 1990-11-27 1991-11-26 Translucent thermal insulation

Country Status (7)

Country Link
EP (1) EP0557358B1 (fi)
AT (1) ATE140504T1 (fi)
AU (1) AU658154B2 (fi)
CA (1) CA2097201A1 (fi)
DE (1) DE69120964T2 (fi)
FI (1) FI87480C (fi)
WO (1) WO1992009760A1 (fi)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0695840A1 (de) * 1994-07-04 1996-02-07 Degussa Aktiengesellschaft Verwendung eines lichtdurchlässigen Bauteils als harte Bedachung
DE4426484A1 (de) * 1994-07-26 1996-02-08 Fricke Jochen Prof Dr Wärmedämmendes Fenstersystem zur Tageslichtnutzung
WO1996023110A1 (de) * 1995-01-25 1996-08-01 Heinz Kunert Hochwärmedämmend ausgerüsteter boden-, decken- oder wandaufbau
EP0950160B2 (en) 1997-10-21 2011-05-25 Saint-Gobain Isover Facade system with a translucent porous insulating material

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2906259A1 (de) * 1979-02-19 1980-08-21 Schulze Herbert Dietrich Gmbh Wandbauplatte in sandwichbauweise
EP0353397A1 (de) * 1988-07-15 1990-02-07 Degussa Aktiengesellschaft Lichtdurchlässiges Bauteil für die harte Bedachung

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2000883C (en) * 1989-10-17 1994-12-13 Hong Yee Looi Bath or shower panel

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2906259A1 (de) * 1979-02-19 1980-08-21 Schulze Herbert Dietrich Gmbh Wandbauplatte in sandwichbauweise
EP0353397A1 (de) * 1988-07-15 1990-02-07 Degussa Aktiengesellschaft Lichtdurchlässiges Bauteil für die harte Bedachung

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0695840A1 (de) * 1994-07-04 1996-02-07 Degussa Aktiengesellschaft Verwendung eines lichtdurchlässigen Bauteils als harte Bedachung
US5726104A (en) * 1994-07-04 1998-03-10 Agomer Gesellschaft Mit Beschrankter Haftung Light-admitting component as rigid roofing
DE4426484A1 (de) * 1994-07-26 1996-02-08 Fricke Jochen Prof Dr Wärmedämmendes Fenstersystem zur Tageslichtnutzung
WO1996023110A1 (de) * 1995-01-25 1996-08-01 Heinz Kunert Hochwärmedämmend ausgerüsteter boden-, decken- oder wandaufbau
EP0950160B2 (en) 1997-10-21 2011-05-25 Saint-Gobain Isover Facade system with a translucent porous insulating material

Also Published As

Publication number Publication date
DE69120964D1 (de) 1996-08-22
FI87480C (fi) 1993-01-11
DE69120964T2 (de) 1997-01-23
AU8902491A (en) 1992-06-25
CA2097201A1 (en) 1992-05-28
EP0557358A1 (en) 1993-09-01
EP0557358B1 (en) 1996-07-17
FI87480B (fi) 1992-09-30
FI905834A (fi) 1992-05-28
FI905834A0 (fi) 1990-11-27
ATE140504T1 (de) 1996-08-15
AU658154B2 (en) 1995-04-06

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