WO1992006458A1 - Procede d'entrainement et articles correspondants - Google Patents

Procede d'entrainement et articles correspondants Download PDF

Info

Publication number
WO1992006458A1
WO1992006458A1 PCT/GB1990/001542 GB9001542W WO9206458A1 WO 1992006458 A1 WO1992006458 A1 WO 1992006458A1 GB 9001542 W GB9001542 W GB 9001542W WO 9206458 A1 WO9206458 A1 WO 9206458A1
Authority
WO
WIPO (PCT)
Prior art keywords
sensible
emission
gas
training
detector
Prior art date
Application number
PCT/GB1990/001542
Other languages
English (en)
Inventor
David Robert Ward
Original Assignee
Ward David R
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to GB898904549A priority Critical patent/GB8904549D0/en
Priority to GB9004304A priority patent/GB2230126B/en
Priority to US07/983,555 priority patent/US5413482A/en
Priority to JP2514801A priority patent/JPH06501781A/ja
Priority to DE69032651T priority patent/DE69032651D1/de
Priority to AU66201/90A priority patent/AU649633C/en
Application filed by Ward David R filed Critical Ward David R
Priority to PCT/GB1990/001542 priority patent/WO1992006458A1/fr
Priority to EP90915796A priority patent/EP0552145B1/fr
Priority to CA002088919A priority patent/CA2088919A1/fr
Publication of WO1992006458A1 publication Critical patent/WO1992006458A1/fr
Priority to NO93930362A priority patent/NO930362L/no
Priority to FI930833A priority patent/FI930833A/fi

Links

Classifications

    • G—PHYSICS
    • G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09B—EDUCATIONAL OR DEMONSTRATION APPLIANCES; APPLIANCES FOR TEACHING, OR COMMUNICATING WITH, THE BLIND, DEAF OR MUTE; MODELS; PLANETARIA; GLOBES; MAPS; DIAGRAMS
    • G09B9/00—Simulators for teaching or training purposes
    • G—PHYSICS
    • G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09B—EDUCATIONAL OR DEMONSTRATION APPLIANCES; APPLIANCES FOR TEACHING, OR COMMUNICATING WITH, THE BLIND, DEAF OR MUTE; MODELS; PLANETARIA; GLOBES; MAPS; DIAGRAMS
    • G09B23/00—Models for scientific, medical, or mathematical purposes, e.g. full-sized devices for demonstration purposes
    • G09B23/06—Models for scientific, medical, or mathematical purposes, e.g. full-sized devices for demonstration purposes for physics
    • G09B23/20—Models for scientific, medical, or mathematical purposes, e.g. full-sized devices for demonstration purposes for physics for atomic physics or neucleonics

Definitions

  • This invention relates to training methods and to articles which can be used in such methods.
  • the invention is particularly, but not exclusively, concerned with training personnel in the use of equipment for detecting hazardous emissions, e.g. ionising (radio-active) radiations, so-called war gases or nerve gases, and poisonous gaseous emissions from toxic chemicals.
  • hazardous emissions e.g. ionising (radio-active) radiations, so-called war gases or nerve gases, and poisonous gaseous emissions from toxic chemicals.
  • Sources of uncontrolled release of ionising radiation in industry, transportation and military operations are a major health concern to those responsible for safety in these areas.
  • a number of instruments are available to detect such radiations, and are suitable for use by the armed forces and by civilian rescue operations. Invariably such instruments detect one or more of the various radiations likely to be encountered and have very great sensitivity, enabling exceedingly low levels of contamination to be detected.
  • a radiation hazard may be set in motion.
  • the source of the radiation is a piece of solid metal, it may be placed in a container, and likewise for liquids, following absorption into a solid.
  • many sources of contamination will take the form of particulate material, e.g. dust, for instance following a fire in a radiochemical laboratory, or fallout onto a vehicle, e.g. a ship, from a nuclear weapon or other explosion.
  • washing by use of sprinkler systems or hoses may be used to decontaminate the building or vehicle, an instrument being used to monitor the progress and efficiency of the washing process.
  • the present invention provides a method of training an operator in the use of first detection apparatus responsive to a first sensible emission, said method being characterised by training said operator in the use of an alternative second detection apparatus responsive to a second sensible emission that is not electrical and not magnetic and not ultra-sonic.
  • This training method is particularly advantageous where the first said sensible emission is of a hazardous nature, e.g. comprises radio-active or ionising radiations and/or comprises emitted vapour of a toxic nature from war gases, nerve gases or other poisonous chemicals.
  • said method includes the step of depositing a material capable of emitting said second sensible emission.
  • said material permits a dimunition of said second sensible emissions when subjected to a liquid diluent or reagent, e.g. water.
  • a method of training an operator in the use of first detection apparatus responsive to a first sensible emission said method being characterised by the step of depositing a material capable of emitting a second sensible emission, and training said operator in the use of an alternative second detection apparatus responsive to said second sensible emission, the said material permitting a dimunition of said second sensible emissions when subjected to a liquid diluent or reagent, e.g. water.
  • Said material may be miscible with the said liquid so as to be washed away therewith or, as is preferred, may be soluble therein.
  • said material is contained in a so-called molecular sieve.
  • the latter may be coated to reduce the rate of said second sensible emissions of said material and, in this case, the coating is preferably soluble in said liquid.
  • material for use in a training method according to this invention comprising a porous body having a gas absorbed therein, the evolution rate of said gas from the body being determined by a coating applied upon the surface of said body.
  • said coating is water-soluble.
  • said body is a molecular sieve.
  • a chemical compound is provided in or on physical support means (such as dust, grease, or the droplets of a liquid spray), this compound being adapte to provide sensible non-hazardous emissions, e.g. a fluorescent compound emitting ultra-violet light (or othe electromagnetic radiations in or near to the visibl spectrum) or a readily vaporisable or gaseous compound, an a detector is also provided for the non-hazardous emissions, the detector being "calibrated” in units of radiation.
  • the compound can liberate a gaseous or vapour phas chemical that is detected by a portable gas chromatograph, IR spectrometer, or other sensor, that is "calibrated” i units of radiation.
  • Such an arrangement can provide tha water washing would remove the chemical, thus simulatin radioactive dust removal during decontamination operations.
  • the chemical compound is one which provides volatile liquid or gas and which, over a period of say a hour, may be easily and sensitively detected by a hand-hel instrument.
  • the gaseous emissions may result from either chemical reaction, or by gas release from a cavity or from solid absorbent of the gas.
  • Gas generating reactions may be exemplified by compound such as 2-chlorethyl phosophoric acid and related molecule which generate ethylene.
  • compound such as 2-chlorethyl phosophoric acid and related molecule which generate ethylene.
  • organo-silicon compounds which undergo hydrolysis to for hydrochloric acid and a hydrocarbon gas.
  • Other, mor complex gas generating systems may require the mixing o several components immediately prior to use, or th application of heat. Such complexities may be too great fo acceptable use and it is therefore considered that a arrangement providing for gas release may be commerciall preferable.
  • Exemplary embodiments of the present invention will now be described in greater detail with reference to the accompanying drawings.
  • Figures 1 and 2 are respectively perspective and longitudinally cross- sectioned views of a cavity device simulating the appearance of a nut or bolt, and for effecting the said gas release.
  • the illustrated cavity device 10 may be a unitary (one- piece) molding of plastics material to provide a small chamber 12 containing the gas, e.g. held in an absorbant 15, and connected to atmosphere by a small pore 14.
  • the device 10 may have a magnetic back 18 to secure it in a lifelike position on, for instance, a ship's bulkhead.
  • the pore 1 provides a restricted orifice for the cavity's outlet. This is formed by a plug of a water-soluble wax, such as polyethylene oxide (PEO), that allows the gas to diffuse through, and which is rapidly disintegrated by any washing operation thus to provide a total loss of the simulated "radiation" signal.
  • the plug 14 is thus a soluble mass having a diffusing section.
  • solid materials can be used as an absorbent body 15 within the cavity 12 and to provide the chemically inert, physical support for the gaseous chemical.
  • Typical examples of the solid materials which have the property of absorbing gases are activated carbon, silica gel and molecular sieves. All of these can retain water more strongly than hydrocarbons, and provide for rapid gas dispersal on washing.
  • the pore size of the material determines the size of molecule that can be hosted, and molecules in size from methane up to C__ can be accommodated in various materials.
  • the gas absorbed is released on release of pressure, with various factors affecting the rate of evolution.
  • the addition of water to any of these absorbants usually results in a very rapid replacement of the gas by water molecules.
  • any of the above-mentioned absorbants may be suitable, those preferred (because they are available in the most standardised form) are molecular sieves.
  • the cavity device may have an external shape simulating a pebble or stone rather than the nut illustrated in Figs 1 and 2.
  • the molecular sieve can be supplied as a brown-white powder or sand so that, in use for training in accord with this invention, it can be spread as a 'dust' (in which case it may need to be coloured by addition of, say, a black pigment).
  • the powder or sand of the molecular sieve material can be formulated into a pseudo-grease by, say, combining it with similar sized particles of a sticky- gel. In such a gel form, it can be smeared on walls,
  • a large number of portable analytical systems and instruments are available to detect gases. These fall into three major, potentially suitable, classes, namely: explosive atmosphere monitors, sensitive gas leak detectors, and specific gas monitors.
  • Explosive atmosphere monitors are readily available for the determination of the explosive limits of common gases in air. They are invariably small portable instruments, designed to monitor primarily methane in the 1-5% range. Their sensing systems are based on thermistors, hot wires or pellistors, but most manufacturers are not prepared to guarantee accurate performance below about 1-2000 ppm.
  • Sensitive gas leak detectors are more expensive but they have the major advantage that they can easily detect hydrocarbons down to 1 ppm. These instruments function or a gas chromatographic principle, and therefore use a flame ionisation detector, with or without a column. They incorporate a small hydrogen cylinder, and are more bulky than the usual explosive atmosphere monitor. Specific gas monitors are the most expensive and several versions are hand held instruments. They can be readily used for the detection of exceedingly low levels of chemical compounds, for instance highly toxic chemcals, war gases and the like.
  • Tests were performed using a high sensitivity gas leak detector, namely a portable flame ionisation detector available from Research Engineers Ltd under the Trade Mark "GAS-TEC”. This was used to monitor the emissions, simulating ionising radiations, emanating from a butane- charged 13x molecular sieve material - firstly uncoated and loaded with butane, and secondly with the molecular sieve coated with 0.5% PEO and also loaded with butane. It should be noted that the "GAS-TEC” pumps in the sampled air at 1.5L/min, in effect gathering up the butane in the area being sampled.
  • the tests consisted of taking measurements of gas evolution at five points *A', 'B*, 'C', 'D' and *E' at 1 metre intervals along a line on a carpeted floor, the central point 'C* being occupied by a petri dish. Initially, to obtain a blank reading, each point was monitored in turn by the "GAS-TEC" instrument, and all were found to give values of less than 1 ppm. About 3g of butane-filled 13X molecular sieve was then poured into the petri dish, and the monitoring repeated at 1, 5, 10, 15 etc. minutes from the start. Only one reading was taken at stations A, B, D and E, if initially found to be zero; while three sequential readings were taken at C. Tables 1 and 2 show the results of this experiment on respectively the uncoated and the coated molecular sieve.
  • butane concentration can be increased, probably by increasing the sample size (i.e. the molecular sieve) or by utilising a modified absorbent system.
  • commercial training apparatus embodying this invention can be supplied consisting of two components: a supply of source material and a gas detector.
  • the source material can comprise a gas absorbed in a molecular sieve, disguised as dust or grease. It will be packed in, say, 5g quantities in sealed tubes, which will be opened only at the point of use.
  • the above- described and illustrated hollow bolt 10, or the above- described simulation of a pebble or stone may be used on occasion to vary the training scheme.
  • the gas detector can be a commercially available hand-held device, with the readout modified to read in radiation units rather than in gas concentration.
  • the training supervisor can distribute the source material in the training area by either opening the sealed tube and spreading the contents in a random manner, or by appropriately adhering, e.g. magnetically (via the magnetic rubber backing 18), the simulated hollow bolt 10 to a wall, ceiling, floor or other structure and removing its thin rubber sealing cap 20 (from its sealing position shown by broken lines in Fig 2) to activate the device 10.
  • the person under instruction can then enter the area, and search for the "radiation” by observing the readout on the gas monitor. Having located it, the trainee can then carry out an appropriate "decontamination” exercise, e.g. by washing or hosing down the area. Re-examination of the area will then demonstrate the effectiveness of the decontamination drill.
  • system can provide a viable period of about one hour for the above training programme.
  • Such a training method simulates or mimics the detection of ionising radiation but is entirely safe to use in training situation. Furthermore it can provide a training period of the order of 1 hour using commercially available gas detection instruments (trivially modified to provide a readout in units of radiation) together with easily prepared materials.
  • the present invention is not limited to the methods of, and articles for use in, training personnel to detect ionising radiation.
  • the present invention may be applied to training for the detection of other hazardous emissions, e.g. war gases, nerve gases and poisonous gaseous emissions from toxic chemicals, by utilising an article to emit a (relatively) non-hazardous gas in simulation of such a hazardous emission.

Landscapes

  • Engineering & Computer Science (AREA)
  • Theoretical Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Business, Economics & Management (AREA)
  • Educational Administration (AREA)
  • Educational Technology (AREA)
  • Computational Mathematics (AREA)
  • Algebra (AREA)
  • Mathematical Analysis (AREA)
  • Mathematical Optimization (AREA)
  • Mathematical Physics (AREA)
  • Pure & Applied Mathematics (AREA)
  • Sampling And Sample Adjustment (AREA)
  • Measurement Of Radiation (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

Procédé d'entraînement destiné à un opérateur en vue de l'utilisation d'un premier dispositif de détection réagissant à une première émission sensible de nature dangereuse, comprenant, par exemple, des radiations radioactives ou ionisantes de gaz ou de vapeurs toxiques provenant de gaz utilisés en cas de guerre ou agissant sur les nerfs; ledit procédé comprend l'entraînement dudit opérateur à l'utilisation d'un deuxième dispositif alternatif de détection réagissant à une deuxième émission sensible de nature non dangereuse. La mise en application dudit procédé comprend en combinaison: un dispositif mobile et autonome d'alimentation en produit chimique, par exemple, un produit gazeux dégageant une deuxième émission sensible, en utilisation, et un détecteur sensible auxdites deuxièmes émissions sensibles et fournissant une indication en rapport avec le niveau de ces émissions, ladite indication étant fournie en fonction des unités de mesure de ladite première émission sensible. Le dispositif mobile et autonome d'alimentation peut comprendre un ou plusieurs des éléments suivants: carbone activé, gel de silice, tamis moléculaire, écrous et boulons, matériau en particules (poussière ou poudre, par exemple), imitation de pierres ou de graviers, graisse ou liquide à pulvériser. Le matériau gazeux peut comprendre: éthylène ou butane, hydrocarbure chloré ou fluoré, par exemple, chloroforme. Le détecteur de gaz peut comprendre un détecteur d'atmosphère explosive ou sensible aux fuites de gaz, un système de surveillance d'un gaz spécifique ou un détecteur de capture d'électrons.
PCT/GB1990/001542 1989-02-28 1990-10-08 Procede d'entrainement et articles correspondants WO1992006458A1 (fr)

Priority Applications (11)

Application Number Priority Date Filing Date Title
GB898904549A GB8904549D0 (en) 1989-02-28 1989-02-28 Training method and articles,inter alia,therefor
GB9004304A GB2230126B (en) 1989-02-28 1990-02-27 Training method and articles therefor
JP2514801A JPH06501781A (ja) 1989-02-28 1990-10-08 訓練方法およびそのための物
DE69032651T DE69032651D1 (de) 1989-02-28 1990-10-08 Ausbildungsverfahren und gegenstände dafür
AU66201/90A AU649633C (en) 1990-10-08 Training method and articles therefor
US07/983,555 US5413482A (en) 1989-02-28 1990-10-08 Method of training an operator in the use of detection apparatus
PCT/GB1990/001542 WO1992006458A1 (fr) 1989-02-28 1990-10-08 Procede d'entrainement et articles correspondants
EP90915796A EP0552145B1 (fr) 1989-02-28 1990-10-08 Procede d'entrainement et articles correspondants
CA002088919A CA2088919A1 (fr) 1989-02-28 1990-10-08 Methode de formation et articles a cet effet
NO93930362A NO930362L (no) 1989-02-28 1993-02-02 Fremgangsmaate for opptrening, samt artikler for dette
FI930833A FI930833A (fi) 1989-02-28 1993-02-24 Traeningsfoerfarande och -artiklar

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB898904549A GB8904549D0 (en) 1989-02-28 1989-02-28 Training method and articles,inter alia,therefor
PCT/GB1990/001542 WO1992006458A1 (fr) 1989-02-28 1990-10-08 Procede d'entrainement et articles correspondants

Publications (1)

Publication Number Publication Date
WO1992006458A1 true WO1992006458A1 (fr) 1992-04-16

Family

ID=37312001

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/GB1990/001542 WO1992006458A1 (fr) 1989-02-28 1990-10-08 Procede d'entrainement et articles correspondants

Country Status (9)

Country Link
US (1) US5413482A (fr)
EP (1) EP0552145B1 (fr)
JP (1) JPH06501781A (fr)
CA (1) CA2088919A1 (fr)
DE (1) DE69032651D1 (fr)
FI (1) FI930833A (fr)
GB (2) GB8904549D0 (fr)
NO (1) NO930362L (fr)
WO (1) WO1992006458A1 (fr)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB8904549D0 (en) * 1989-02-28 1989-04-12 Ward David R Training method and articles,inter alia,therefor
GB9010872D0 (en) * 1990-05-15 1990-07-04 Coleman Frederick J Ionising radiation contamination training simulator
US5427530A (en) * 1992-09-14 1995-06-27 Taggart; Judith F. Model kit and method for simulating water pollution
GB2295261A (en) * 1994-11-15 1996-05-22 Cambridge Consultants Training for detection of hazardous emissions
GB9519098D0 (en) * 1995-09-19 1995-11-22 Pike Steven D Contamination training simulator
US11270600B2 (en) * 2017-05-16 2022-03-08 United States Department Of Energy Method and device for passive detection of physical effects

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR969785A (fr) * 1948-07-30 1950-12-26 Procédé et appareil pour détecter des gaz
US2755388A (en) * 1951-12-12 1956-07-17 Socony Mobil Oil Co Inc Method for detecting hydrocarbon gas
US2900740A (en) * 1953-08-21 1959-08-25 Optomechanisms Inc Simulated radioactive radiation meter
US3363329A (en) * 1964-09-04 1968-01-16 Navy Usa Electrical circuit for a simulated radioactive radiation detector
US4657872A (en) * 1984-11-13 1987-04-14 Cornell Research Foundation, Inc. Laser-enhanced flame ionization detection
GB2230126A (en) * 1989-02-28 1990-10-10 Ward David R Hazardous emission detection training

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3096387A (en) * 1960-04-06 1963-07-02 Bodenseewerk Perkin Elmer Co Radioactivity detection training
US3208159A (en) * 1963-08-26 1965-09-28 Alexander M Filipov Simulated radiation detector
DE1472315A1 (de) * 1965-12-06 1969-01-23 Inst Energetik Ausbildungsanlage (Trainer),insbesondere fuer Kraftwerke
US3636641A (en) * 1969-04-07 1972-01-25 Samuel W Daskam Radiological training device
GB1311615A (en) * 1971-03-26 1973-03-28 Marconi Co Ltd Simulated radio-activity monitoring arrangements
US4500295A (en) * 1983-05-26 1985-02-19 The United States Of America As Represented By The Secretary Of The Navy Personal alpha contamination simulator and detector
GB8720413D0 (en) * 1987-08-28 1987-10-07 Boid P G Training apparatus
WO1989008905A1 (fr) * 1988-03-12 1989-09-21 Steven Derek Pike Dispositif d'entrainement pour simuler la detection de radioactivite

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR969785A (fr) * 1948-07-30 1950-12-26 Procédé et appareil pour détecter des gaz
US2755388A (en) * 1951-12-12 1956-07-17 Socony Mobil Oil Co Inc Method for detecting hydrocarbon gas
US2900740A (en) * 1953-08-21 1959-08-25 Optomechanisms Inc Simulated radioactive radiation meter
US3363329A (en) * 1964-09-04 1968-01-16 Navy Usa Electrical circuit for a simulated radioactive radiation detector
US4657872A (en) * 1984-11-13 1987-04-14 Cornell Research Foundation, Inc. Laser-enhanced flame ionization detection
GB2230126A (en) * 1989-02-28 1990-10-10 Ward David R Hazardous emission detection training

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
Navy Technical Disclosure Bulletin, vol. 8, no. 2, December 1982, (Washington, US) A.H. Marshall: "Alpha field radiation survey trainer", pages 61-64 *

Also Published As

Publication number Publication date
FI930833A0 (fi) 1993-02-24
EP0552145A1 (fr) 1993-07-28
AU6620190A (en) 1992-04-28
NO930362L (no) 1993-04-05
EP0552145B1 (fr) 1998-09-09
CA2088919A1 (fr) 1992-04-09
NO930362D0 (no) 1993-02-02
AU649633B2 (en) 1994-06-02
FI930833A (fi) 1993-03-26
JPH06501781A (ja) 1994-02-24
US5413482A (en) 1995-05-09
GB9004304D0 (en) 1990-04-25
GB2230126B (en) 1993-04-28
DE69032651D1 (de) 1998-10-15
GB8904549D0 (en) 1989-04-12
GB2230126A (en) 1990-10-10

Similar Documents

Publication Publication Date Title
Ashley et al. NIOSH manual of analytical methods (NMAM)
CA2470115C (fr) Systeme detecteur de composes organiques volatils
US5409839A (en) Method of tagging and detecting drugs, crops, chemical compounds and currency with perfluorocarbon tracers (PFT'S)
US20100300221A1 (en) Aerosol particle deposition on surfaces
EP0552145B1 (fr) Procede d'entrainement et articles correspondants
Andrews et al. NIOSH manual of analytical methods (NMAM)
US4237726A (en) Process for predicting the useful life of a respirator cartridge
AU649633C (en) Training method and articles therefor
Freedman et al. Service lives of respirator cartridges versus several classes of organic vapors
Petersen et al. Assessment of fires in chemical warehouses. An overview of the TOXFIRE project
Todorovic Gases and vapours
RU2547742C1 (ru) Передвижная лаборатория мониторинга окружающей среды
VASTA Respirator cartridge evaluation for isocyanate containing Imron® and Centari® enamels
RU2117935C1 (ru) Способ определения наличия несимметричного диметилгидразина
JP4675045B2 (ja) 消臭効果のビジュアルプレゼンテーション
Bowes et al. Confined space ventilation: tracer gas analysis of mixing characteristics
Petrea et al. PROCEDURES AND MECHATRONIC DEVICE FOR THE PREPARATION OF CHEMICAL CONTAMINATED SAMPLES „ON SITE”
Rowe Monitoring in the Non-Stockpile Program
Kirk et al. Halogen compounds
ITRM980584A1 (it) Dispositivo per il campionamento diffusionale di vapori organici nello ambiente
Stull et al. Hydrogen Fluoride Exposure Testing of the US Coast Guard's Totally Encapsulated Chemical Response Suit
Samples D. GENERAL CONSIDERATIONS FOR SAMPLING AIRBORNE CONTAMINANTS by Charles S. McCammon, Ph. D., CIH, NIOSH/Denver Field Office and Mary Lynn Woebkenberg, Ph. D., NIOSH/DPSE
Murthy et al. An advanced air sampling technique for hazardous waste sites
Rowland et al. Test method and simple analysis model for off-gassing studies of military-relevant surfaces contaminated with chemical warfare agent simulants
Stanton et al. Handbook on mine occupational hygiene measurements

Legal Events

Date Code Title Description
AK Designated states

Kind code of ref document: A1

Designated state(s): AU CA FI HU JP NO SU US

AL Designated countries for regional patents

Kind code of ref document: A1

Designated state(s): AT BE CH DE DK ES FR GB IT LU NL SE

WWE Wipo information: entry into national phase

Ref document number: 2088919

Country of ref document: CA

WWE Wipo information: entry into national phase

Ref document number: 1990915796

Country of ref document: EP

WWE Wipo information: entry into national phase

Ref document number: 930833

Country of ref document: FI

WWP Wipo information: published in national office

Ref document number: 1990915796

Country of ref document: EP

WWG Wipo information: grant in national office

Ref document number: 1990915796

Country of ref document: EP