WO1991007266A1 - Process for the production of conventionally non-deformable tubular cavities in injection-moulded plastics articles - Google Patents
Process for the production of conventionally non-deformable tubular cavities in injection-moulded plastics articles Download PDFInfo
- Publication number
- WO1991007266A1 WO1991007266A1 PCT/DE1990/000797 DE9000797W WO9107266A1 WO 1991007266 A1 WO1991007266 A1 WO 1991007266A1 DE 9000797 W DE9000797 W DE 9000797W WO 9107266 A1 WO9107266 A1 WO 9107266A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- plastic
- cavities
- injection
- tubular cavities
- hollow bodies
- Prior art date
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/14—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles
- B29C45/14598—Coating tubular articles
- B29C45/14614—Joining tubular articles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
- B29C70/68—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts by incorporating or moulding on preformed parts, e.g. inserts or layers, e.g. foam blocks
- B29C70/70—Completely encapsulating inserts
Definitions
- the invention relates to a method for producing conventionally non-demoldable cavities, according to the preamble of the main claim.
- Plastic molded parts with tubular cavities are required in many ways.
- the vehicle construction is to be mentioned here, namely both the inner and outer parts and functional elements. These include, for example, fuel distributors of injection engines.
- molded plastic parts with tubular cavities in the furniture sector are required, for example in armrests and fittings, in components of sports equipment or toys, in household appliances and household goods in a wide variety of designs.
- these cavities can be closed at the end, bent in many ways, or have different lateral connecting pieces.
- vehicle construction such as in the case of fuel distributors, it is necessary for the respective cavity to be absolutely gas-tightly sealed at internal pressure.
- different pipe sections are produced separately by the cavities in the pipe sections being formed by corresponding cores. These pipe sections can still be demolded in the longitudinal direction, such as aluminum pipes manufactured in an extrusion process.
- the end product is then created by assembling the individual pipe sections using, for example, appropriate flanges and seals. This process is complicated and time-consuming.
- so-called "lost" cores are used. These cores have the dimensions of the cavity and consist, for example, of low-melting metal alloys, but also of salt or plastic-metal mixtures. Such cores are, for example, inserted into the molding space of an injection molding machine and extrusion-coated with plastic. The finished product is then placed in a melting device, for example in a tempered bath, and the core or cores are melted out by strong inductive support.
- This method is also complex, since for this purpose a "lost" core must first be produced, which, apart from creating a cavity, can no longer serve any other purpose.
- a gas for example nitrogen
- a gas for example nitrogen
- connection of two tubes lying against one another with their flanges is also known, the two flanges lying against one another being extrusion-coated in the form of a “barrel tire”.
- this encapsulation poses further sealing problems.
- preformed hollow bodies are joined to form the desired cavities, placed in a molding space for the plastic molded part and then the plastic is introduced into the molding space, in particular injected.
- connection steps no additional work steps, in particular connection steps, are necessary compared to the known first production process. There is also no need to seal any connection points, for example flange connections. A mechanically stable and tight connection is created, which is ensured by the extrusion-coated plastic.
- the present invention stands out due to geometrically precisely defined cavities.
- the present invention is intended primarily for entire systems of pipe sections.
- the individual parts are put together before being inserted into the molding space, it being possible to use corresponding connecting elements, such as T-pieces, branches or the like.
- the joints need 'only so closely to lie to each other that no flowing around Kunststoff ⁇ polymer melt -' n penetrates the cavities.
- the complete sealing of the entire system is achieved by overmoulding the inserted hollow body system after the melt has solidified. It also does not require a mechanically fixed connection between the individual elements of the system. This is also done by the overmolded plastic.
- Metal is preferably used for straight or slightly curved pipe sections.
- connecting pieces or connecting elements or also sharp deflections can be made of plastic. There should be no limit to the inventive idea here.
- the system with the hollow bodies should be kept at a sufficient distance from the inner wall of the molding space, so that it is ensured that every hollow body is actually encapsulated with plastic.
- the surface of the inserted hollow body should not penetrate through the outer skin of the extrusion coating, since this could possibly lead to sealing problems.
- the inserted hollow bodies are preferably fixed within the injection molding tool by means of movable tool cores which engage in connection openings in the hollow bodies. Corresponding sealing surfaces are formed on the extrusion coating around these connection openings, on which neighboring components are sealed off for encapsulation.
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Chemical & Material Sciences (AREA)
- Composite Materials (AREA)
- Injection Moulding Of Plastics Or The Like (AREA)
- Moulds For Moulding Plastics Or The Like (AREA)
Abstract
The process of the invention calls for hollow preforms to be joined to form the required cavities, placed in a mould cavity for the plastics article and the plastic subsequently introduced into the mould cavity, in particular by injection.
Description
Verfahren zum Herstellen von konventionell nicht entform¬ baren, rohrförmigen Hohlräumen in Kunststoff-Spritzgieß- formteilenMethod for producing conventionally non-demoldable, tubular cavities in plastic injection molded parts
Stand der TechnikState of the art
Die Erfindung betrifft ein Verfahren zum Herstellen von konventionell nicht entformbaren Hohlräumen, entsprechend dem Oberbegriff des Hauptanspruches.The invention relates to a method for producing conventionally non-demoldable cavities, according to the preamble of the main claim.
Kunststoff-Formteile mit rohrförmigen Hohlräumen werden vielfältig benötigt. Zu erwähnen ist hier der Fahrzeug¬ bau und zwar sowohl die Innen- wie auch Außenteile sowie Funktionselemente. Beispielsweise zählen hierzu Kraftstoff¬ verteiler von Einspritzmotoren- Ferner werden Kunststoff- Formteile mit rohrförmigen Hohlräumen im Möbelsektor, beispielsweise bei Armlehnen und Beschlagteilen, bei Kompo¬ nenten von Sportgeräten bzw. Spielwaren, bei Hausgeräten und Haushaltswaren in vielfältiger Ausführung benötigt.Plastic molded parts with tubular cavities are required in many ways. The vehicle construction is to be mentioned here, namely both the inner and outer parts and functional elements. These include, for example, fuel distributors of injection engines. Furthermore, molded plastic parts with tubular cavities in the furniture sector are required, for example in armrests and fittings, in components of sports equipment or toys, in household appliances and household goods in a wide variety of designs.
Je nach Anwendungsgebiet können diese Hohlräume endwärtig verschlossen, vielfältig gebogen sein oder auch verschiedene seitliche Anschlußstutzen haben. Insbesondere im Fahrzeug¬ bau, wie beispielsweise bei den Kraftstoffverteilern, ist es notwendig, daß der jeweilige Hohlraum bei Innendruck absolut gasdicht verschlossen ist.
In einem ersten bekannten Fertigungsverfahren werden ver¬ schiedene Rohrabschnitte getrennt hergestellt, indem die Hohlräume in den Rohrabschnitten durch entsprechende Kerne gebildet werden. Diese Rohrabschnitte sind noch in Längs- richtung entformbar, wie beispielsweise im Strangpreßver- f-ahren hergestellte Aluminiumrohre. Das Endprodukt entsteht dann durch Zusammenbau der einzelnen Rohrabschnitte mittels beispielsweise entsprechenden Flanschen und Dichtungen. Dieses Verfahren ist kompliziert und aufwendig.Depending on the field of application, these cavities can be closed at the end, bent in many ways, or have different lateral connecting pieces. In vehicle construction in particular, such as in the case of fuel distributors, it is necessary for the respective cavity to be absolutely gas-tightly sealed at internal pressure. In a first known manufacturing process, different pipe sections are produced separately by the cavities in the pipe sections being formed by corresponding cores. These pipe sections can still be demolded in the longitudinal direction, such as aluminum pipes manufactured in an extrusion process. The end product is then created by assembling the individual pipe sections using, for example, appropriate flanges and seals. This process is complicated and time-consuming.
In einem zweiten Fertigungsverfahren werden sogenannte "verlorene" Kerne verwendet. Diese Kerne weisen die Maße des Hohlraumes auf und bestehen beispielsweise aus niedrig¬ schmelzenden Metallegierungen, aber auch aus Salz oder Kunststoff-Metall-Mischungen. Derartige Kerne werden bei¬ spielsweise in den Formraum einer Spritzgieß aschine einge¬ legt und mit Kunststoff umspritzt. Das fertige Produkt wird dann in eine Ausschmelzeinrichtung, beispielsweise in ein temperiertes Bad gegeben und durch starke induktive Unterstützung der Kern bzw. die Kerne ausgeschmolzen.In a second manufacturing process, so-called "lost" cores are used. These cores have the dimensions of the cavity and consist, for example, of low-melting metal alloys, but also of salt or plastic-metal mixtures. Such cores are, for example, inserted into the molding space of an injection molding machine and extrusion-coated with plastic. The finished product is then placed in a melting device, for example in a tempered bath, and the core or cores are melted out by strong inductive support.
Auch dieses Verfahren ist aufwendig, da hierzu ein "ver¬ lorener" Kern erst hergestellt werden muß, der außer der Erzeugung eines Hohlraumes keinen weiteren Zweck mehr erfüllen kann.This method is also complex, since for this purpose a "lost" core must first be produced, which, apart from creating a cavity, can no longer serve any other purpose.
In einem dritten Fertigungsverfahren, dem sogenannten Gasinnendruck-Prozeß, wird während der Füllung des Form¬ raumes in einer Kunststoff-Spritzgießmaschine bzw. in dem Werkzeug dieser Maschine ein Gas, beispielsweise Stick- stoff, eingeblasen, welches im durch den Kunststoff erzeug¬ ten Formteil einen Hohlraum bildet. Dieses Verfahren ist nur begrenzt anwendbar, da der durch das Gas gebildete Hohlraum geometrisch nicht definiert bzw. gesteuert werden kann.
Die Bildung von Hohlräumen durch Umspritzen von Einlege¬ teilen ist grundsätzlich ebenfalls Stand der Technik. Dabei handelt es sich jedoch um das Umspritzen einteiliger Metallrohre, die ggfs. gebogen sein können, wobei jedoch keine Abdichtung erforderlich ist, da direkt an den entspre¬ chenden aus den Formteilen herausragenden Rohrenden Schläuche befestigt werden.In a third manufacturing process, the so-called internal gas pressure process, a gas, for example nitrogen, is blown into the molded part in a plastic injection molding machine or in the tool of this machine, which gas is contained in the molded part produced by the plastic forms a cavity. This method can only be used to a limited extent since the cavity formed by the gas cannot be defined or controlled geometrically. The formation of cavities by overmoulding insert parts is basically also prior art. However, this involves the encapsulation of one-piece metal pipes, which can possibly be bent, but no sealing is required, since hoses are attached directly to the corresponding pipe ends protruding from the molded parts.
Ferner ist auch die Verbindung von zwei mit ihren Flanschen aneinanderliegenden Rohren bekannt, wobei die beiden anein- anderliegenden Flansche in Form eines "Faßreifens" umspritzt werden. Dieses Umspritzen birgt jedoch weitere Dichtprobleme in sich.Furthermore, the connection of two tubes lying against one another with their flanges is also known, the two flanges lying against one another being extrusion-coated in the form of a “barrel tire”. However, this encapsulation poses further sealing problems.
Durch all die bekannten Verfahren ist es jedoch nicht möglich, konventionell nicht entformbare rohrförmige Hohl¬ räume in Kunststoff-Spritzgießformteilen zu bilden.However, by all the known methods it is not possible to form conventionally non-demoldable tubular cavities in plastic injection moldings.
Vorteile der ErfindungAdvantages of the invention
Gemäß der vorliegenden Erfindung werden vorgeformte Hohl¬ körper zu den gewünschten Hohlräumen zusammengefügt, in einen Formraum für das Kunststoff-Formteil eingelegt und danach der Kunststoff in den Formraum eingebracht, insbe- sondere eingespritzt.According to the present invention, preformed hollow bodies are joined to form the desired cavities, placed in a molding space for the plastic molded part and then the plastic is introduced into the molding space, in particular injected.
Dies bedeutet, daß gegenüber dem bekannten ersten Ferti¬ gungsverfahren keine zusätzlichen Arbeitsschritte, insbe¬ sondere Verbindungsschritte, notwendig sind. Es müssen auch keine Verbindungsstellen, beispielsweise Flansch¬ verbindungen, abgedichtet werden. Es entsteht eine mecha¬ nisch stabile und dichte Verbindung, welche durch den umspritzten Kunststoff gewährleistet ist.This means that no additional work steps, in particular connection steps, are necessary compared to the known first production process. There is also no need to seal any connection points, for example flange connections. A mechanically stable and tight connection is created, which is ensured by the extrusion-coated plastic.
Gegenüber dem bekannten zweiten Fertigungsverfahren müssen
- h -Compared to the known second manufacturing process - H -
keine Kerne ausgeschmolzen werden, d.h. es sind auch keine aus dem Herausschmelzen folgenden Rückstände zu erwarten. Das Formteil bleibt auch in seinen Hohlräumen sauber. Ferner ist die Fertigung in vielen Fällen verbilligt.no cores are melted out, i.e. no residues resulting from the melting are also to be expected. The molded part remains clean even in its cavities. In addition, production is cheaper in many cases.
Gegenüber dem Gasinnendruck-Prozeß hebt sich die vorliegende Erfindung durch geometrisch genau definiert erzeugte Hohl¬ räume hervor.Compared to the gas pressure process, the present invention stands out due to geometrically precisely defined cavities.
Gedacht ist die vorliegende Erfindung vor allem für ganze Systeme von Rohrstücken. Die Einzelteile werden vor dem Einlegen in den Formraum zusammengefügt, wobei entsprechende Verbindungselemente, wie T-Stücke, Abzweigungen od. dgl. benutzt werden können. Die Fügestellen brauchen ' lediglich so eng beieinander zu liegen, daß keine umfließende Kunst¬ stoffschmelze -'n die Hohlräume eindringt. Die vollkommene Abdichtung des gesamten Systems wird durch das Umspritzen des eingelegten Höhlkörpersystems nach Erstarrung der Schmelze erreicht. Auch benötigt es keine mechanisch feste Verbindung der einzelnen Elemente des Systems. Dies wird ebenfalls von dem umspritzten Kunststoff übernommen.The present invention is intended primarily for entire systems of pipe sections. The individual parts are put together before being inserted into the molding space, it being possible to use corresponding connecting elements, such as T-pieces, branches or the like. The joints need 'only so closely to lie to each other that no flowing around Kunst¬ polymer melt -' n penetrates the cavities. The complete sealing of the entire system is achieved by overmoulding the inserted hollow body system after the melt has solidified. It also does not require a mechanically fixed connection between the individual elements of the system. This is also done by the overmolded plastic.
Für gerade oder leicht gebogene Rohrstücke wird vorzugs¬ weise Metall verwendet. Anschlußstutzen bzw. Verbindungs- elemente oder auch scharfe Umlenkungen können dagegen wiederum aus Kunststoff hergestellt sein. Hier soll dem erfinderischen Gedanken keine Grenze gesetzt sein.Metal is preferably used for straight or slightly curved pipe sections. On the other hand, connecting pieces or connecting elements or also sharp deflections can be made of plastic. There should be no limit to the inventive idea here.
In jedem Fall sollte aber das System mit den Hohlkörpern einen genügenden Abstand von der Formrauminnenwand einhal¬ ten, damit gewährleistet bleibt, daß tatsächlich jeder Hohlkörper mit Kunststoff umspritzt ist. Die Oberfläche der eingelegten Hohlkörper soll nicht durch die Außenhaut der Umspritzung dringen, da dies möglicherweise zu Dich- tungsproblemen führen könnte.
Die Fixierung der eingelegten Hohlkörper innerhalb des Spritzgieß-Werkzeugs erfolgt bevorzugt über bewegliche Werkzeug-Kerne, die in Anschlußöffnungen der Hohlkörper eingreifen. An der Umspritzung sind entsprechende Dicht- flächen um diese Anschlußöffnungen ausgebildet, an denen Nachbarbauteile zur Umspritzung hin abgedichtet werden.In any case, however, the system with the hollow bodies should be kept at a sufficient distance from the inner wall of the molding space, so that it is ensured that every hollow body is actually encapsulated with plastic. The surface of the inserted hollow body should not penetrate through the outer skin of the extrusion coating, since this could possibly lead to sealing problems. The inserted hollow bodies are preferably fixed within the injection molding tool by means of movable tool cores which engage in connection openings in the hollow bodies. Corresponding sealing surfaces are formed on the extrusion coating around these connection openings, on which neighboring components are sealed off for encapsulation.
Die Besonderheiten der vorliegenden Erfindung sind in folgendem zu suchen:The special features of the present invention can be found in the following:
- Ausformung von komplizierten Hohlräumen innerhalb von Spritzgieß-Formteilen durch Zusammenfügen von Teil-Hohl¬ körpern;- Formation of complicated cavities within injection molded parts by joining part hollow bodies;
- Festlegung der Hohlkörper innerhalb des Werkzeuges durch Werkzeugkerne an Anshclußöffnungen und Abdichtung der- Fixing the hollow body within the tool by means of tool cores at the connection openings and sealing the
Anschlußbauteile gegenüber der Umspritzung.
Connection components opposite the extrusion coating.
Claims
1. Verfahren zum Herstellen von konventionell nicht entform¬ baren rohrförmigen Hohlräumen, wie beispielsweise von U-Rohren, Rohren mit verschlossenen Enden, langen, dünnen Rohren ohne Entformungsschrägen, in Kunststoff-Spritzgie߬ formteilen, dadurch gekennzeichnet, daß vorgeformte Hohl¬ körper zu den gewünschten Hohlräumen zusammengefügt, in einen Formraum für das Kunststoff-Formteil eingelegt und danach der Kunststoff in den Formraum eingebracht, insbe- sondere eingespritzt wird.1. A method for producing conventionally non-demoldable tubular cavities, such as U-tubes, tubes with closed ends, long, thin tubes without draft angles, in plastic injection molded parts, characterized in that preformed hollow bodies to the the desired cavities are joined, placed in a molding space for the plastic molding and then the plastic is introduced into the molding space, in particular is injected.
2. Verfahren nach Anspruch 1, dadurch gekennzeichnet, daß als Hohlkörper für rohrför ige Hohlräume Rohrstücke verwendet werden.2. The method according to claim 1, characterized in that pieces of pipe are used as a hollow body for tubular cavities.
3. Verfahren nach Anspruch 1 oder 2, dadurch gekennzeichnet, daß die Hohlkörper vor dem Einlegen in den Formraum zu einem gewünschten System, beispielsweise durch T-Stücke, Abzweigungen od. dgl. verbunden werden.3. The method according to claim 1 or 2, characterized in that the hollow body or before the insertion into the mold space to a desired system, for example by T-pieces, branches. Like. Are connected.
4. Verfahren nach Anspruch 3, dadurch gekennzeichnet, daß die Verbindungselemente aus Kunststoff geformt werden.4. The method according to claim 3, characterized in that the connecting elements are molded from plastic.
5. Verfahren nach wenigstens einem der Ansprüche 1 bis 4, dadurch gekennzeichnet, daß mit den Hohlkörpern in jedem Fall ein. Abstand von Wänden des Formraumes einge¬ halten wird, wobei die Festlegung der Hohlkörper über Kerne erfolgt, die entsprechende Öffnungen bzw. Anschluß- Stücke zu benachbarten Hohlkörpern bilden. 5. The method according to at least one of claims 1 to 4, characterized in that with the hollow bodies in any case. The distance from the walls of the mold space is maintained, the hollow bodies being fixed by means of cores which form corresponding openings or connecting pieces to adjacent hollow bodies.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEP3938396.2 | 1989-11-18 | ||
DE19893938396 DE3938396A1 (en) | 1989-11-18 | 1989-11-18 | METHOD FOR PRODUCING CONVENTIONALLY NON-DEFORMABLE, TUBULAR CAVES IN PLASTIC INJECTION MOLDED PARTS |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1991007266A1 true WO1991007266A1 (en) | 1991-05-30 |
Family
ID=6393806
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/DE1990/000797 WO1991007266A1 (en) | 1989-11-18 | 1990-10-20 | Process for the production of conventionally non-deformable tubular cavities in injection-moulded plastics articles |
Country Status (2)
Country | Link |
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DE (1) | DE3938396A1 (en) |
WO (1) | WO1991007266A1 (en) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102005013719A1 (en) * | 2005-03-22 | 2006-09-28 | Pfefferle, Günter | Injection molded plastic component with metal insert for use in fluctuating temperatures and pressures has a pressure tight bond between insert and outer plastic |
DE102008057517A1 (en) * | 2008-11-15 | 2010-05-20 | Daimler Ag | Distributor pipe of fuel injection system of internal combustion engine for motor vehicle, comprises a tube-like main metal body having a hollow dome-like distributing metal sockets, which are connected with the interior of the main body |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1225004B (en) * | 1958-08-30 | 1966-09-15 | Ingbuero Gebrueder Holtschmidt | Block-shaped piping system for hydraulic systems and mold for its manufacture |
FR1565111A (en) * | 1967-10-02 | 1969-04-25 | ||
WO1982002020A1 (en) * | 1980-12-11 | 1982-06-24 | Feisel Armin | Method for making a distribution block for a liquid or gaseous medium |
US4743481A (en) * | 1986-11-26 | 1988-05-10 | Flex Technologies, Inc. | Molding process for articles having an irregular shaped internal passage |
EP0286973A2 (en) * | 1987-04-16 | 1988-10-19 | METZELER Automotive Profiles GmbH | Method of manufacturing rubber pipe junction and article manufactured thereby |
JPS6467316A (en) * | 1987-09-08 | 1989-03-14 | Taiho Kogyo Co Ltd | Hollow molded product |
-
1989
- 1989-11-18 DE DE19893938396 patent/DE3938396A1/en not_active Withdrawn
-
1990
- 1990-10-20 WO PCT/DE1990/000797 patent/WO1991007266A1/en unknown
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1225004B (en) * | 1958-08-30 | 1966-09-15 | Ingbuero Gebrueder Holtschmidt | Block-shaped piping system for hydraulic systems and mold for its manufacture |
FR1565111A (en) * | 1967-10-02 | 1969-04-25 | ||
WO1982002020A1 (en) * | 1980-12-11 | 1982-06-24 | Feisel Armin | Method for making a distribution block for a liquid or gaseous medium |
US4743481A (en) * | 1986-11-26 | 1988-05-10 | Flex Technologies, Inc. | Molding process for articles having an irregular shaped internal passage |
EP0286973A2 (en) * | 1987-04-16 | 1988-10-19 | METZELER Automotive Profiles GmbH | Method of manufacturing rubber pipe junction and article manufactured thereby |
JPS6467316A (en) * | 1987-09-08 | 1989-03-14 | Taiho Kogyo Co Ltd | Hollow molded product |
Non-Patent Citations (1)
Title |
---|
Patent Abstracts of Japan, Band 13, Nr. 265 (M-839)(3613) 19. Juni 1989; & JP-A-1 067 316 (TAIHO KOGYO) 14. M{rz 1989 * |
Also Published As
Publication number | Publication date |
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DE3938396A1 (en) | 1991-05-23 |
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