WO1990011182A1

WO1990011182A1 - A multilayer film and laminate for use in producing printed circuit boards

Info

Publication number: WO1990011182A1
Application number: PCT/US1990/001547
Authority: WO
Inventors: Stephen M. Imfeld; Randall S. Shipley
Original assignee: The Dow Chemical Company
Priority date: 1989-03-22
Filing date: 1990-03-22
Publication date: 1990-10-04
Also published as: CA2012670A1; JPH04506584A; DK0464144T3; DE69031216D1; EP0464144B1; US5057372A; JP3142554B2; ES2104603T3; CA2012670C; KR920700106A; DE69031216T2; ATE156420T1; EP0464144A4; KR0168034B1; EP0464144A1

Abstract

A laminate (10) of a layer of a cladding metal foil and a multilayer film having as one surface layer thereof a support layer (24)containing a thermoplastic resin able to withstand temperatures up to 200°C without softening and the other surface layer being an adhesive layer (26) containing a thermoplastic resin having a melting point ranging from 100°C to 200°C. Optionally, a tie layer (28) may be employed between the support layer (24) and the adhesive layer (26). The multilayer film is useful as a protective carrier sheet for a cladding metal foil (18) used in the production of printed circuit boards. The carrier sheet provides temporary, peelable surface protection for the cladding metal foil (18) preventing contamination and physical damage to the foil both before and during printed circuit board formation. Adhesion of the carrier sheet (20) to the cladding metal foil (18), measured using a 180 degree peel test is less than 0.4 lbs./inch-width and greater than 0.005 lbs./inch-width (0.18 to 0.002 kgs/2.54 cm width), and preferably less than 0.1 lbs./inch-width and greater than 0.01 lbs./inch-width and greater than 0.01 lbs./inch-width (0.05 to 0.005 kgs/2.54 cm width).

Description

A MULTILAYER FILM AND LAMINATE FOR USE IN PRODUCING PRINTED CIRCUIT BOARDS

The present invention relates to a multilayer film which may serve as a protective carrier sheet for metal foil and a metal foil bearing laminate having special utility in the production of printed circuit boards. More particularly, it relates to a multilayer film which is useful as a temporary, peelable protective carrier sheet for a cladding metal foil used in the production of printed circuit boards.

Various methods are known for producing metal clad laminates useful in the production of printed circuit boards. In the typical process, metal clad laminates are produced by impregnating a fibrous

substrate with a resin varnish, drying the substrate to prepare a prepreg, stacking one or more prepregs to a desired thickness, bonding a cladding metal foil on one or both sides of the prepreg stack with, optionally, an adhesive coating being applied on the surface of the metal foil, and finally curing the assemblage under heat and pressure in a molding press to laminate/mold it.

Examples of patents which discuss various aspects of this conventional process include U.S. Patent No.

4,302,501 directed to porous, heat resistant insulating substrates for use as prepregs in the production of printed circuit boards and U.S. Patent No. 4,410,388 directed to an aging process to avoid variations in performance of metal clad laminates in the production of printed circuit boards.

A recognized problem in the production of printed circuit boards is that the cladding metal foil may be subject to damage in the molding press. For that reason it has been suggested that a protective pad be used between the molding press and the metal foil layer. For example in U.S. Patent No. 4,690,845 there is disclosed a "stratiform" sheet useful in a flat press method of laminating printed circuit boards. The stratiform sheet has a thermoplastic layer, a polymer release layer on one side, a polymeric stabilizing layer having a melting point higher than the laminating temperature peak, and a melting point higher than the peak. The stratiform sheet is said to be characterized by substantial freedom from creases, trapped gases, and contaminants. The stratiform sheet is utilized in the method of laminating printed circuits in a flat press by providing a work piece comprising one or more circuit assemblies in need of lamination, providing the

stratiform sheets, and arranging each circuit assembly in a book with one of said stratiform sheets on each side of a circuit assembly with the release layers thereof facing the circuit assemblies in the press, then pressing the book for the press cycle time appropriate to the product and thickness of the book.

It is also know to use a poly-4-methylpentene-1 film as a releasable protective layer between a

stainless steel press and a copper cladding metal foil in the manufacture of copper clad laminates. See Japanese Patent No. 58/128846 dated August 1, 1983 in the name of Toshiba Chem. KK. See also Japanese Patent Nos. 47/070654 and 57/070653 dated May 1, 1982 in the name of Mitsubishi Gas Chem. Ind. (releasing film

comprising 4-methylpentene-1 homopolymer, copolymer or a mixture with other resins used in laminating prepregs) and Japanese Patent No. 56/111637 dated September 3, 1981 in the name of Hitachi Chemical KK (release film comprising 4-methylpentene-1 homopolymer, and copolymers with polyethylene, polypropylene, vinyl acetate, etc. used in laminated sheet manufacture).

A somewhat similar system is shown in U.S.

Patent No. 4,753,847 where there is disclosed a mold release sheet which can be used in the production of printed circuit boards. The mold release sheet

comprises a film of polyester, nylon or cellulose acetate treated for promoting resin adhesion and having a coating of a thin release layer of a cured release acrylated oligomer resin on at least one side of the film. In the molding operation, the mold release sheet may be selectively interleaved among the laminate-making layers and the press platens and caul plates. The stratiform sheet/mold release sheet systems of the Japanese patents and U.S. Patent Nos. 4,690,845 and 4,753»847 have a number of advantages. For example, at Col. 4, lines 45 to 60 of U.S. Patent No. 4,753,847 the following advantages are listed:

The release sheet structure:

(i) does not stick to the clad, the prepreg sheet, the kraft sheet nor the laminate surfaces; (ii) assists in preventing migration of

flowable material from one laminate component to another;

(iii) does not shrink;

(iv) is resistant to embrittlement;

(v) has good tensile strength;

(vi) has sufficient rigidity to assist in handling;

(vii) does not emit excessive odors;

(viii) minimizes the static electric charges, thus easing removal from the mold; and

(ix) has good hole-forming characteristics whether drilled or punched.

Despite these advantages, a problem remains. While the stratiform sheet/mold release sheet protects the cladding metal foil during the molding process, the cladding metal foil may be subject to damage while handling before, during, or after the molding process. Typically, the cladding metal foil is a thin foil such as a copper foil which must be kept intact and free from surface contamination. It would, therefore, be

desirable to protect/support the cladding metal foil particularly during handling before molding.

There is in the patent literature at least one reference to use of a transfer/support for a copper film to be used in producing printed circuit boards. Lifshin et al in U.S. Patent No. 4,455,181 discloses vapor depositing a film of zinc on a copper film on a silica coated aluminum carrier sheet, vapor depositing a silica film on the resulting zinc-copper foil, bonding the resulting body to a substrate (prepreg) and then

stripping the silica-coated aluminum carrier sheet from the copper-clad laminate. At col. 1, lines 22 to 35, it is disclosed that rather than an aluminum carrier sheet, the carrier sheet may be a "sheet material of other metals as well as of plastics, such as DuPont commercial products known as MYLAR and KAPTON and other organic polymeric materials of similar flexibility which will withstand the processing temperatures involved in this invention and have the strength at the temperature of deposition of the copper film and the characteristics of inertness and bondability to release agent coatings necessary for coating adherence as copper-clad laminate products are stripped from the carrier sheets."

It would clearly be desirable to use an organic polymeric material as the carrier sheet in view of the lower cost, easier handling, more flexible nature of such materials. However, a number of difficulties are encountered in that regard. Foil contamination due to resin additives exuding to the foil surface must be controlled. Excessive adhesion also results in polymer contamination of the foil. Likewise, adhesion of the backside of a polymeric carrier to the molding press during molding is also a problem. The polymeric carrier sheet must provide sufficient support for the cladding metal foil so that the high temperatures and molding pressures do not damage it. Finally, the carrier sheet must be easily strippable from the cladding metal foil (i.e. it must have a peel value of less than about 0.4 Ibs./inch-width). This is difficult to achieve with a polymer carrier because of polymer degradation during molding (which has been found to be increased due to the catalytic effect of the copper foil) and migration during molding of any adhesives used in conjunction with the polymeric carrier.

Accordingly, the need exists for an improved polymeric protective carrier sheet for cladding metal foil and for a cladding metal foil having a carrier sheet releasably laminated thereto which has special utility in the production of printed circuit boards.

The need is met by the present invention which provides a multilayer thermoplastic film adapted for use as a temporary, peelable protective carrier sheet for cladding metal foil and a laminate of the carrier sheet and cladding metal foil which may be used in the

production of printed circuit boards.

The multilayer film may be a coextruded or laminated film having as one surface layer thereof a support layer containing an extrudable thermoplastic resin able to withstand temperatures up to 200°C without softening such as polymethylpentene (PMP), polyester (PBT or PET), polyamide, polycarbonate or copolymers of the foregoing materials. Preferably the support layer contains 80 to 100 percent polymethylpentene or

polymethylpentene copolymer having a melting point of 220°C to 240°C.

The other surface layer of the multilayer film is an adhesive layer containing at least one extrudable thermoplastic resin having a melting point ranging from 100°C to 200°C. The term adhesive in this context depicts a layer which is capable of releasably bonding to a cladding metal foil. Thus the thermoplastic resin may be a polyolefin resin such as polyethylene,

polypropylene, copolymers of propylene/ethylene,

copolymers of ethylene with alpha olefins, or copolymers of propylene/ethylene. This layer may also contain up to 70 percent of a higher melting thermoplastic such as polymethylpentene or copolymers of polymethylpentene.

Optionally, a tie layer may be employed between the support layer and the adhesive layer. The tie layer may contain any polymeric material which improves the interply adhesion of the multilayer film yet does not interfere with the bond between the film's adhesive layer and the cladding metal foil. The tie layer may be composed of either a thermosetting laminating adhesive polymer such as polyethylene terephthalate (PET) with a toluene diisocyanate (TDI) catalyst or any of the thermoplastic resins utilized in either surface layer or blends thereof. In a preferred example, the tie layer contains a blend of the support layer and adhesive layer resins.

With a two-layer coextruded film, i.e. support layer and adhesive layer, the support layer

advantageously comprises 5 to 95 percent, and preferably 75 to 85 percent, by weight of the multilayer film and the adhesive layer advantageously comprises 5 to 95 percent, and preferably 15 to 25 percent, by weight of the multilayer film. With a three-layer coextruded film, i.e. support layer, thermoplastic tie layer, and adhesive layer, the support layer advantageously

comprises 5 to 90 percent, and preferably 10 to 20 percent, by weight of the multilayer film, the tie layer advantageously comprises 5 to 90 percent, and preferably 60 to 80 percent, by weight of the multilayer film, and the adhesive layer advantageously comprises 5 to 90 percent, and preferably 10 to 20 percent, by weight of the multilayer film.

With a three-layer laminated film, i.e. support layer, thermosetting resin tie layer, and adhesive layer, the support layer advantageously comprises 25 to 70 percent, and preferably 50 to 60 percent, by weight of the multilayer film, the tie layer may be 2 to 10 percent, and preferably 3 to 7 percent, by weight of the multilayer film, and the adhesive layer advantageously comprises 25 to 70 percent, and preferably 35 to 45 percent, by weight of the multilayer film.

The multilayer film, preferably, as mentioned, serves as a protective carrier sheet for a cladding metal foil such as copper foil. The carrier sheet may be applied to the cladding metal foil at any point following foil fabrication. By softening or melting the adhesive layer of the carrier sheet and then bringing it into contact with the metal foil, a controlled

releasable bond can be formed. Adhesion of the carrier sheet to the cladding metal foil, measured using a 180 degree peel test is less than 0.4 pounds/inch-width and greater than 0.005 pounds/inch-width (0.18 to 0.002 kgs./2.45 cm width), and preferably less than 0.1 pounds/inch-width and greater than 0.01 pounds/inch- width (0.05 to 0.005 kgs/2.54 cm width).

When the resulting film/foil laminate is placed in a heated platen press for lamination/molding to the prepreg in forming a printed circuit board, the heat resistant support layer of the carrier sheet supports the sheet and provides release from either the press plates or additional printed circuit board laminates present. Prior to printing the electrical circuit on the resulting printed circuit board, the carrier sheet can be easily removed, leaving a clean foil surface to be printed.

Accordingly, this invention provides an improved temporary, peelable protective carrier sheet for a cladding metal foil and a resulting film/foil laminate which can be used in the production of printed circuit boards. Other advantages of the invention will become apparent from the following detailed description, the accompanying drawings and the appended claims.

Fig. 1 is an enlarged cross-sectional view through one embodiment of the multilayer film making up the carrier sheet of the present invention.

Fig. 2 is an enlarged cross-sectional view through another embodiment of the multilayer film making up the carrier sheet of the present invention. Fig. 3 is an enlarged cross-sectional view of the one embodiment of the laminate of the present invention, namely the carrier sheet of Fig. 2 having a cladding metal foil laminated thereto. Fig. 4 is an enlarged cross-sectional view of another embodiment of the laminate of the present invention, namely the carrier sheet of Fig. 1 having a cladding metal foil laminated thereto. Fig. 5 is a schematic view of the

laminating/molding operation for producing printed circuit boards using the laminate of the present invention. Referring first to Fig. 5, there is

schematically shown a molding assembly for producing printed circuit boards using film/foil laminate 10 of the present invention. Thus, a cladding metal foil layer 18 (in this case copper foil), supported by the protective carrier sheet 20, is laminated/molded to prepreg 22 which may be a reinforced epoxy resin. This molding process occurs between release layers 16 and 16' which may be composed of either rigid metal plates or plastic films which can withstand temperatures up to 200°C without softening. Multiples of this assembly may be placed between upper platen.12 and lower platen 14 such that several metal foil layers 18 are

laminated/molded to several prepregs 22 in one process step.

Typically the lamination/molding cycle for producing the printed circuit board involves the

following steps:

1) load press cold (ambient);

2) increase pressure to 300 psi; temperature set to 360°F; 3) hold for 20 minutes;

4) increase pressure to 600 psi;

5) hold for 90 minutes;

6) decrease temperature set point to ambient;

7) hold for 50 minutes;

8) decrease pressure; and 9) unlead press.

Following this process, carrier sheet 20 can be easily removed from cladding metal foil 18 and the circuit board subjected to further processing. Using a 180 degree peel test, adhesion between carrier sheet 20 of the present invention and cladding metal foil layer 18 is less than 0.4 Ibs./inch-width and greater than 0.005 Ibs./inch-width (0.18 to 0.002 kgs/2.54 cm width), and preferably less than 0.1 Ibs./inch-width and greater than 0.01 Ibs./inch-width (0.05 to 0.005 kgs/2.45 cm. width). This is because of the unique multilayer film comprising the carrier sheet of the present invention.

In one embodiment, carrier sheet 20 consists of a multilayer film of two extruded layers as shown in Fig. 1. As shown there, support layer 24 comprises 5 to 95 percent, and preferably 75 to 85 percent, by weight of the multilayer film. Support layer 24 contains an extrudable thermoplastic resin able to withstand

temperatures up to 200°C without softening such as polymethylpentene (PMP), polyester (PBT or PET),

polyamide, polycarbonate or copolymers of the foregoing materials. Preferably the support layer contains 80 to 100 percent polymethylpentene or polymethylpentene copolymer having a melting point of 200 to 240°C. The remaining components of support layer 24, if any, may be recycle materials and compatibilizers such as

polyethylene, polypropylene, or copolymers or

propylene/ethylene.

Adjoining support layer 24 is adhesive layer 26 which comprises 5 to 95 percent, and preferably 15 to 25 percent, by weight of the multilayer film. The term adhesive in this context depicts a layer which is capable of releasably bonding to a cladding metal foil. Adhesive layer 26 contains at least one extrudable thermoplastic resin having a melting point ranging form about 100 to 200°C. Thus, the thermoplastic resin may be a polyolefin resin such as polyethylene,

polypropylene, copolymers of propylene/ethylene,

copolymers of ethylene with alpha olefins, or copolymers of ethylene or propylene with a polar comonomer.

Preferably the adhesive layer contains 30 to 100 percent polyethylene, polypropylene, or copolymers of

propylene/ethylene. This layer may also contain up to 70 percent of a higher melting thermoplastic such as polymethylpentene or copolymers of polymethylpentene.

Another embodiment of carrier sheet 20 consists of three coextruded layers as shown in Fig. 2 where like numerals have been used. As in the first embodiment, there is a support layer 24 and an adhesive layer 26, but in this embodiment, those layers comprise 5 to 90 percent, and preferably 10 to 20 percent, by weight of the multilayer film. Tie layer 28 makes up the rest, broadly in the range of 5 to 90 percent, but preferably 60 to 80 percent, by weight of the multilayer film making up carrier sheet 20.

Tie layer 28 is employed to improve the interply adhesion between support layer 24 and adhesive layer 26. Tie layer 28 in this example may contain any extrudable thermoplastic resin which performs this function yet does not interfere with the bond between the film's adhesive layer 26 and cladding metal foil. The tie layer may be composed of any of the

thermoplastic resins utilized in either support layer 24, adhesive layer 26, or blends thereof. Preferred in this embodiment, the tie layer contains a blend of polymethylpentene and the polyolefin resin employed in adhesive layer 26.

A third embodiment of carrier sheet 20 consists of three layers assembled using a lamination process. This multilayer film is also shown in Fig. 2 where like numerals have again been used. In this embodiment, support layer 24 comprise 25 to 70 percent, and

preferably support layer 24 is a self supported film composed of polyethylene terephthalate (PET) resin.

Adhesive layer 26 comprises 25 to 70 percent, and preferably 35 to 45 percent, by weight of the multilayer film. Adhesive layer 26 is also a self supported film and is composed of the same polyolefin resins described in the first embodiment.

Tie layer 28 may be 2 to 10 percent, and preferably 3 to 7 percent, by weight of the multilayer film and is employed to improve the interply adhesion between support layer 24 and adhesive layer 26. Tie layer 28 in this example may contain any laminating adhesive which performs this function yet does not interfere with the bond between the film's adhesive layer 26 and cladding metal foil. Preferred in this embodiment, tie layer 28 is composed of a thermosetting laminating adhesive polymer such as PET with a toluene diisocyanate (TDI) catalyst.

Example 1

The multilayer film illustrated in Fig. 1 and, subsequently, the laminate illustrated in Fig. 4 were prepared as follows:

Step A. A two-layer coextruded multilayer film was produced on both blown film and cast film pilot plant equipment. The following conditions were used to produce the blown film version:

Multilayer Film Formulation - (Film Gauge - 2.0 mils (0.05 mm))

Support Layer 24 (75%) :

Polymethylpentene Copolymer - 100%

Adhesive Layer 26 (25?) :

Polymethylpentene Copolymer - 60%

Propylene/Ethylene Copolymer - 39.9%

(20 to 25% ethylene)

Phosphite Stabilizer - 0.05%

Phenolic Stabilizer - 0.05%

Layer

Extruder Conditions: Support 24 Adhesive 26

Zone Temperature Range (C) 246-288 232-252

Melt Temperature Range (C) 257-274 243-252

Die Conditions:

Average Temperature (C) - 272

Die Gap (inches) - 0.040 (1 mm)

Draw Down Ratio - 12:1

Die Diameter (inches) - 6 (15 cm)

Blow up Ratio - 1.7:1

Step B. The two-layer multilayer film formed in Step A was used as a protective carrier sheet 20 for a cladding metal foil layer 18. A roll of 2.0-mil (0.05 mm) film was thermally laminated to a roll of 1.5-mil (0.04 mm) copper foil using a laminator having a heated metal bottom roll and a non-heated rubber top roll. The hot roll temperature was 235°C and nip pressure was 85 psi (5.95 kgs./cm²). Each we was preheated using 160°C preheat rolls. The result is a laminate 10 as shown in Fig. 4.

The laminate formed in Step B can then be applied to an epoxy dielectric material using a heated press process as illustrated by Fig. 5. Following this process, carrier sheet 20 can be easily removed from cladding metal foil layer 18 and the circuit board subjected to further processing. Using a 180 degree peel test, adhesion between carrier sheet 20 and

cladding material foil 18 was found to be less than 0.1 Ibs./inch-width and greater than 0.01 Ibs./inch-width (0.05 to 0.005 kgs./2.54 cm width). Example 2

The multilayer film illustrated in Fig. 2 and, subsequently, the laminate illustrated in Fig. 3 were prepared as follows:

Step A. A three-layer coextruded multilayer film was produced on both blown film and cast film pilot plant equipment. The following conditions were used to produce the blown film version:

Multilayer Film Formulation - (Film Gauge - 2.0 mils (0.05 mm))

Support Layer 24 (15%):

Polymethylpentene Copolymer - 100% Tie Layer 28 (60%):

Polymethylpentene Copolymer - 60%

Propylene/Ethylene copolymer - 39.9%

(20 to 25% ethylene)

Phosphite Stabilizer - 0.05%

Phenolic Stabilizer - 0.05%

Adhesive Layer 26 (25%):

Propylene/Ethylene copolymer - 99.75%

(20 to 25% ethylene)

Phosphite Stabilizer - 0.125%

Phenolic Stabilizer - 0.125%

Layer

Extruder Conditions: Support Tie Adhesive

24 Layer 28 26

Zone Temperature Range (C) 246-288 232-252 190-216 Melt Temperature Range (C) 257-274 243-252 210-216

Die Conditions:

Average Temperature (C) - 272

Die Gap (inch) - 0.040 (1.0 mm)

Draw Down Ratio - 12:1

Die Diameter (inch) - 6 (15 cm)

Blow up Ratio - 1.7:1

Step B. The three layer multilayer film formed in Step A was used as a protective carrier sheet 20 for a cladding metal foil layer 18. A roll of 2.0-mil (0.05 mm) film was thermally laminated to a roll of 1.5-mil (0.04 mm) copper foil using a laminator having a heated metal bottom roll and a non-heated rubber top roll. The hot roll temperature was 216°C and nip pressure was 85 psi (5.95 kgs/cm2). The copper foil web was preheated using 143°C preheat roll. The result is a laminate 10 as shown in Fig. 3. The laminate formed in Step B can then be applied to an epoxy dielectric material using a heated press process as illustrated by Fig. 5. Following this process, carrier sheet 20 can be easily removed from cladding metal foil layer 18 and the circuit board subjected to further processing. Using a 180 degree peel test, adhesion between carrier sheet 20 and cladding metal foil 18 was found to be less than 0.1 Ibs./inch-width and greater than 0.01 Ibs./inch-width (0.5 to 0.005 kgs/2.54 cm width).

Example 3

Step A. Adhesive layer 26, formed as a monolayer film, was produced on blown film pilot plant equipment under the following conditions:

Monolayer Film Formulation:

(Film Gauge - 1.5 mils (0.04 mm) )

Propylene/Ethylene copolymer - 99.7%

(20 to 25% ethylene)

Phosphite Stabilizer - 0.15%

Phenolic Stabilizer - 0.15%

Extruder Conditions:

Zone Temperature Range (C) 190 to 213

Melt Temperature (C) 207 to 213

Die Conditions:

Average Temperature (C) - 400

Die Gap (inch) - 0.040 (1.0 mm)

Draw Down Ratio - 13:1

Die Diameter (inch) - 8 (20 cms)

Blow up Ratio - 2: 1 Corona Treat Level (Dynes) - >40

Step B. The corona treated film formed in Step A was adhesively laminated to a corona treated 1.0 mil (0.025 mm) polyester (PET) film support layer 24 using a tie layer 28 of a thermosetting polyethylene

terephthalate (PET) adhesive containing a toluene diisocyanate (TDI) catalyst. The result was a

multilayer film as shown in Fig. 2.

Step C. The multilayer film formed in Step B was used as a protective carrier sheet 20 for a cladding metal foil layer 18. A roll of 2.5-mil (0.06 mm) film was thermally laminated to a roll of 1.5-mil (0.04 mm) copper foil using a laminator having a heated metal bottom roll and a non-heated rubber top roll. The hot roll temperature was 216°C and nip pressure was 85 psi (5.95 kgs/cm2). The copper foil web was preheated using 143°C preheat roll. The result is a laminate 10 as shown in Fig. 3. The laminate formed in Step C can then be applied to an epoxy dielectric material using a heated press process as illustrated by Fig. 5. Following this process, carrier sheet 20 can be easily removed from cladding metal foil layer 18 and the circuit board subjected to further processing. Using a 180 degree peel test, adhesion between carrier sheet 20 and cladding metal foil 18 was found to be less than 0.1

Ibs./inch-width and greater than 0.01 Ibs./inch-width

(0.05 to 0.005 kgs/2.54 cm width).

Claims

1. A laminate for use in production of printed circuit boards comprising: a layer of a cladding metal foil and a carrier sheet comprising a multilayer film having as one surface thereof a support layer containing an extrudable thermoplastic resin able to withstand up to 200°C without softening and as the other surface thereof an adhesive layer containing at least one extrudable thermoplastic resin having a melting point range of from 100 to 200°C, the adhesive layer releasably bonding the carrier sheet to the cladding metal foil layer.

2. The laminate of Claim 1 wherein the cladding metal foil is copper foil.

3. The laminate of Claim 2 wherein the adhesive layer contains a polyolefin resin.

4. The laminate of Claim 3 wherein the support layer contains polymethylpentene, polyamide,

polycarbonate resins, and copolymers or a mixture thereof.

5. The laminate of Claim 3 wherein the support layer contains 80 to 100 percent polymethylpentene homopolymer or copolymer.

6. The laminate of Claim 5 wherein the multilayer film is coextruded, the support layer

comprises 75 to 85 percent by weight of the multilayer film and the adhesive layer comprises 15 to 25 percent by weight of the multilayer film.

7. The laminate of Claim 1 further including a tie layer between the support layer and the adhesive layer.

8. The laminate Claim 7 wherein the tie layer is a blend of the resin of the support layer and the resin of the adhesive layer.

9. The laminate of Claim 8 wherein the multilayer film is coextruded, the support layer

comprises 10 to 20 percent by weight of the multilayer film, the tie layer comprises 60 to 80 percent by weight of the multilayer film, and the adhesive layer comprises 10 to 20 percent by weight of the multilayer film.

10. A laminate for use in production of printed circuit boards comprising: a copper foil layer, and a carrier sheet comprising a multilayer film having as one surface thereof a support layer containing polyester resin and as the other surface thereof an adhesive layer containing polyolefin resin, the adhesive layer releasably bonding the copper foil layer to the carrier sheet.

11. The laminate of Claim 10 further including a tie layer between the support layer and the adhesive layer, the tie layer containing a thermosetting

polyethylene terephthalate resin.

12. The laminate of Claim 11 wherein the multilayer film is laminated, the support layer

comprises 50 to 60 percent by weight of the multilayer film, the tie layer comprises 3 to 7 percent by weight of the multilayer film, and the adhesive layer comprises 35 to 45 percent by weight of the multilayer film.

13. A multilayer film adapted for use as a temporary, peelable protective carrier sheet for

cladding metal foil used in the production of printed circuit boards, comprising: a support layer containing polymethylpentene resin, and an adhesive layer containing polyolefin resin adjoined to the polymethylpentene layer.

14. The multilayer film of Claim 13 wherein the support layer contains 80 to 100 percent of a

polymethylpentene or polymethylpentene copolymer having a melting point of 220 to 240°C.

15. The multilayer film of Claim 14 wherein the polyolefin resin is polyethylene, polypropylene, a copolymer of propylene/ethylene, a copolymer of ethylene with alpha olefins, or a copolymer of ethylene or propylene with a polar comonomer.

16. The multilayer film of Claim 15 wherein the support layer and the adhesive layer are coextruded.

17. The multilayer film of Claim 16 wherein the support layer comprises 75 to 85 percent by weight of the multilayer film and the adhesive layer comprises 15 to 25 percent by weight of the multilayer film.

18. The multilayer film of Claim 15 further including a tie layer between the support layer and the adhesive layer.

19. The multilayer film of Claim 18 wherein the tie layer is a blend of polymethylpentene resin and polyolefin resin.

20. The multilayer film of Claim 19 wherein the support layer comprises 10 to 20 percent by weight of the multilayer film, the tie layer comprises 60 to 80 percent by weight of the multilayer film and the adhesive layer comprises 10 to 20 percent by weight of the multilayer film.