WO1989008486A1 - Toy with thermochromic material - Google Patents
Toy with thermochromic material Download PDFInfo
- Publication number
- WO1989008486A1 WO1989008486A1 PCT/US1989/000929 US8900929W WO8908486A1 WO 1989008486 A1 WO1989008486 A1 WO 1989008486A1 US 8900929 W US8900929 W US 8900929W WO 8908486 A1 WO8908486 A1 WO 8908486A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- color
- thermochromic
- temperature
- thermochromic material
- toy
- Prior art date
Links
- 239000000463 material Substances 0.000 title claims abstract description 148
- 239000003973 paint Substances 0.000 claims abstract description 86
- 230000006903 response to temperature Effects 0.000 claims abstract description 7
- 239000003086 colorant Substances 0.000 claims description 15
- 210000004905 finger nail Anatomy 0.000 claims description 13
- 210000001508 eye Anatomy 0.000 claims description 10
- 210000000720 eyelash Anatomy 0.000 claims description 9
- 210000004709 eyebrow Anatomy 0.000 claims description 8
- 210000003128 head Anatomy 0.000 claims description 8
- 239000004033 plastic Substances 0.000 claims description 8
- 239000012780 transparent material Substances 0.000 claims description 6
- 230000003796 beauty Effects 0.000 claims description 3
- 210000005069 ears Anatomy 0.000 claims description 3
- 238000007650 screen-printing Methods 0.000 claims description 2
- 239000000976 ink Substances 0.000 description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 13
- 239000007921 spray Substances 0.000 description 10
- 239000004593 Epoxy Substances 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- 229910052751 metal Inorganic materials 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 239000000835 fiber Substances 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 210000000088 lip Anatomy 0.000 description 3
- 210000003467 cheek Anatomy 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000007598 dipping method Methods 0.000 description 2
- 210000004209 hair Anatomy 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 230000002441 reversible effect Effects 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- LHYQAEFVHIZFLR-UHFFFAOYSA-L 4-(4-diazonio-3-methoxyphenyl)-2-methoxybenzenediazonium;dichloride Chemical compound [Cl-].[Cl-].C1=C([N+]#N)C(OC)=CC(C=2C=C(OC)C([N+]#N)=CC=2)=C1 LHYQAEFVHIZFLR-UHFFFAOYSA-L 0.000 description 1
- 241000905358 Actaea pachypoda Species 0.000 description 1
- WYLIRYQDDKDHLT-UHFFFAOYSA-N CC1=CC=CC=C1C.CC1=CC=CC=C1C Chemical compound CC1=CC=CC=C1C.CC1=CC=CC=C1C WYLIRYQDDKDHLT-UHFFFAOYSA-N 0.000 description 1
- 239000004986 Cholesteric liquid crystals (ChLC) Substances 0.000 description 1
- 241000083869 Polyommatus dorylas Species 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000002178 crystalline material Substances 0.000 description 1
- 210000003298 dental enamel Anatomy 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 239000002991 molded plastic Substances 0.000 description 1
- 238000007649 pad printing Methods 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- STZCRXQWRGQSJD-UHFFFAOYSA-M sodium;4-[[4-(dimethylamino)phenyl]diazenyl]benzenesulfonate Chemical compound [Na+].C1=CC(N(C)C)=CC=C1N=NC1=CC=C(S([O-])(=O)=O)C=C1 STZCRXQWRGQSJD-UHFFFAOYSA-M 0.000 description 1
- 238000007592 spray painting technique Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 210000004906 toe nail Anatomy 0.000 description 1
- YXZRCLVVNRLPTP-UHFFFAOYSA-J turquoise blue Chemical compound [Na+].[Na+].[Na+].[Na+].[Cu+2].NC1=NC(Cl)=NC(NC=2C=C(NS(=O)(=O)C3=CC=4C(=C5NC=4NC=4[N-]C(=C6C=CC(=CC6=4)S([O-])(=O)=O)NC=4NC(=C6C=C(C=CC6=4)S([O-])(=O)=O)NC=4[N-]C(=C6C=CC(=CC6=4)S([O-])(=O)=O)N5)C=C3)C(=CC=2)S([O-])(=O)=O)=N1 YXZRCLVVNRLPTP-UHFFFAOYSA-J 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A63—SPORTS; GAMES; AMUSEMENTS
- A63H—TOYS, e.g. TOPS, DOLLS, HOOPS OR BUILDING BLOCKS
- A63H33/00—Other toys
- A63H33/22—Optical, colour, or shadow toys
-
- A—HUMAN NECESSITIES
- A63—SPORTS; GAMES; AMUSEMENTS
- A63F—CARD, BOARD, OR ROULETTE GAMES; INDOOR GAMES USING SMALL MOVING PLAYING BODIES; VIDEO GAMES; GAMES NOT OTHERWISE PROVIDED FOR
- A63F2250/00—Miscellaneous game characteristics
- A63F2250/10—Miscellaneous game characteristics with measuring devices
- A63F2250/1026—Miscellaneous game characteristics with measuring devices for temperature
- A63F2250/1031—Miscellaneous game characteristics with measuring devices for temperature using colour indicators
Definitions
- thermochromic or light-sensitive materials embedded or mixed in plastic
- plastic printed on paper or plastic
- impregnated in fibers used for clothing, doll hair, plush figures, or the like For example, U.S. Patent Nos. 4,560,604 issued to Shimizu et al., on December 24, 1985 (coating fibers used for stuffed toys with thermochromic material); 4,134,853 issued to Ehrlich et al. on January 16, 1979 (photochromic composition combined with moldable materials for forming toys); and 3,980,300 issued to Hornsby, Jr. on September 14, 1976 (layer of liquid crystalline material used for ball) which disclose the use of such materials in toys.
- GB 2,066,089A issued to Rickson on July , 1981 describes the use of temperature-sensitive cholesteric liquid crystal material for changing the color of the eyes of a doll.
- U.S. Patent No. 3,382,607 issued to Ryan et al. on May 14, 1968 discloses a figure toy having synthetic hair fibers impregnated with an indicator dye which changes color in response to contact with liquids of different pH concentrations.
- Thermochromic materials are disclosed in U.S. Patent Nos. 4,567,019 issued to Lawton on January 28, 1986; 4,421,560 issued to Kito et al. on December 20, 1983; and 4,028,118 issued to Nakasuji et al. on June 7, 1977.
- Heat-sensitive recording materials are described in U.S. Patent Nos. 4,611,072 issued to Nachbar et al.; 4,462,616 issued to Shanton on July 31, 1984; and 4,444,819 issued to Maruta et al.
- a reversible heat sensitive recording composition is disclosed in U.S. Patent No. 4,720,301 issued to Kito et al. on January 19, 1988.
- thermochromic material which changes color as the temperature of the toy varies.
- thermochromic material It is another object of this invention to provide a toy vehicle which is spray painted with paint containing thermochromic material.
- thermochromic material to produce a variety of patterns, designs, numbers, letters or other indicia which change color as the temperature of the vehicle varies.
- thermochromic material It is still another object of this invention to provide a toy vehicle having portions thereof colored with inks and other portions thereof painted with paint containing thermochromic material.
- thermochromic material which changes color as the temperature of the doll varies.
- thermochromic material which changes color as the temperature of the doll varies.
- a child may apply cold water to the doll's cheeks darkening the color of the cheeks so that the doll appears to be blushing.
- the cheeks may be returned to their original color by applying hot water to the cheeks.
- the color of the other portions of the doll painted with paint containing thermochromic material such as the doll's eyes, eyelashes, fingernails, etc. may also be changed by applying hot or cold water to these painted portions of the doll.
- FIG. 1 is a perspective view of an embodiment of the present invention as a toy vehicle having a portion thereof painted with paint containing thermochromic material;
- FIGS. 2 through 4 are perspective views of other embodiments of the toy vehicle of the present invention having different portions thereof painted with paint containing thermochromic material to provide a variety of patterns, designs, numbers, letters or other indicia;
- FIG. 5 is a perspective view of another embodiment of the toy vehicle of the present invenion having different portions thereof painted with different paints containing different colored thermochromic materials;
- FIG. 6 is a perspective view of another embodiment of the toy vehicle of the present invention having portions thereof colored with inks and other portions thereof painted with paint containing thermochromic material;
- FIG. 7 is a front elevational view of another embodiment of the present invention as a toy doll having different portions thereof painted with paint containing thermochromic material.
- a toy vehicle 10 of the present invention having a body 12 is disclosed.
- the body 12 is painted with paint containing thermochromic material at portions thereof to provide a pattern or stripes 14 as illustrated.
- the body 12 may be painted with thermochromic material at different portions thereof to provide a variety of designs 16, letters 18, numbers 20 or other indicia (not shown) as illustrated in FIGS. 2 through 4.
- the entire body 12 may be painted with paint containing thermochromic material if desired (not shown) . It is important to point out that any portion or all of the body 12 may be painted with paint containing thermochromic material to provide any desirable design, pattern, number, letter or indicia.
- FIG. 5 shows another embodiment of the toy vehicle 10.
- the body 12 of the vehicle 10 has different portions 22 through 28 . thereof painted with different paints containing different colored thermochromic materials so that each portion has a different colored thermochromic material.
- some of the portions 22 through 28 may have the same colored thermochromic material *
- the thermochromic materials of one or some of the portions 22 through 28 may change color at different temperatures.
- thermochromic material will change color as the temperature of the body 12 changes
- a child may vary the appearance or color of the toy vehicle i0 by raising or lowering the temperature of the body 12. This may be accomplished by 'immmersing the toy vehicle, 10 in heated or cold water, or using heated or cold air, ice, heated pens, heated brushes, light bulbs, heat blankets, etc. to change the temperature of the body 12.
- the heat of a child's hands may also be used to change the temperature of the body 12 and, thus, change the color of the thermochromic material.
- thermochromic material changes color from a darker color to a lighter color as the temperature of the material is increased.
- thermochromic material which becomes clear or transparent as the temperature of the material or body 12 is heated to a certain temperature level revealing an underlying coat of paint (or color) which does not contain thermochromic material.
- thermochromic material which changes from a brown color to a lighter color as the temperature increases.
- the body 12 of the toy vehicle 10 is preferably spray painted with a paint containing thermochromic material.
- the toy vehicle 10 may be painted with a paint containing thermochromic material by dipping the vehicle in the paint, using a brush to paint- " the vehicle, or using any other technique.
- the word "painted” as used herein is intended to include any means of coating the body 12 of the toy vehicle 10 with a paint containing thermochromic material.
- the word “paint” as used herein is intended to include any material containing thermochromic material that is coated to the body 12 of the toy vehicle 10.
- thermochromic material is painted onto the body 12
- the color of the toy vehicle 10 is brighter than that of a vehicle made out of molded plastic material containing thermochromic material.
- a toy metal vehicle spray painted with thermochromic material will retain its color longer, or stay warm or cold longer, than a vehicle made out of molded thermochromic plastic material.
- FIG. 6 shows another embodiment of the toy vehicle 10.
- the body 12 is painted with paint containing thermochromic material and has portions 29 and 31 thereof painted, printed, inked or otherwise colored, without using thermochromic paint, to present different particular colors.
- transferred pad printing is used with screen printing inks such as Fast Dry Enamel inks sold by Sinclair and Valentine, Screen Ink Division, North Kansas City, Missouri, to color portions 29 and 31.
- screen printing inks such as Fast Dry Enamel inks sold by Sinclair and Valentine, Screen Ink Division, North Kansas City, Missouri
- any suitable type of ink, paint or material may be used to color portions 29 and 31 which does not change color in response to temperature variations.
- the ink used for portions 31 is substantially the same color as the thermochromic material contained in the paint used to paint body 12.
- the ink used for portions 29 is a different color than the thermochromic material.
- the colors of the thermochromic material and inks are selected so that the color of portions 31 matches that of body 12 before the temperature of body 12 is changed and is different than that of body 12 after the temperature is changed. For example, if portions 31 and body 12 are colored or painted with a light-colored ink o'r paint whose colors match and portions 29 are colored with a darker-colored ink, then the color of the thermochromic material of the paint used for body 12 will darken if the temperature of body 12 is lowered, such as by dipping the vehicle 10 in cold water, while the colors of the inks used for portions 29 and 31 remain the same.
- the Chromic Epoxy Spray Paint has nine base colors: yellow, gold orange, vermilion, pink, fast blue, turquoise blue, green, brown and black.
- Matsui Shikiso Chemical Co., Ltd. has developed a method of spray painting the Chromic Epoxy Spray Paint onto a toy vehicle by spraying a first coat of the thermochromic paint onto the vehicle followed by heat treatment at 140 degrees C. for 5 minutes, and then spraying a second coat of the thermochromic paint followed by heat treatment at 140 degrees C. for 20 minutes.
- any number of coats (including only one coat) of thermochromic paint may be used and the heat treatment can be varied or eliminated if desired.
- thermochromic paint may be used instead of the above-mentioned Chromic Epoxy Spray Paint and any color paint or thermochromic material may be used. Also, the temperature ranges during which the thermochromic materials change color can be selected as desired.
- thermochromic material as used herein is intended to refer to any suitable material that changes color in response to temperature variations.
- the thermochromic paint used for this invention may be prepared using any of the thermochromic materials disclosed in U.S. Patent Nos. 4,028,118; 4,421,560; and 4,720,301.
- the thermochromic material used is mixed with a film forming resin, an appropriate solvent, and a stabilizer when required.
- FIG. 7 shows another embodiment of the present invention as a toy doll 30.
- the toy doll 30 has a head 32 with portions thereof painted with paint containing thermochromic material such as the doll's eyebrows 34, eyes 36, eyelashes 38, eyeshadow areas 40 above the eyes, lips 42, areas 44 at the doll's cheeks, heart- shaped beauty mark 46 on the doll's face, and heart-shaped earrings 48 on the doll's ears.
- Other portions of the doll 30 may be painted with paint containing thermochromic material such as the fingernails 50 or toenails (not shown) of the doll.
- any other portion on any part of the doll 30 may be painted with thermochromic paint such as any portion of the arms 52, torso 54, legs (not shown) , or other part of the doll.
- a child may play with the doll 30 by applying hot or cold water to the portions of the doll painted with paint containing thermochromic material, thereby changing the temperature of the thermochromic material and causing the color of the material to change.
- cold water may be applied to the doll's fingernails 50 so that the coior of the thermochromic material contained in the thermochromic paint at the fingernails darkens, allowing the child to pretend that the fingernails are being painted with fingernail polish.
- the child may then return the fingernails 50 to their original color by applying hot water to the fingernails causing the color of the thermochromic material to lighten.
- the colors of the thermochromic material contained in the thermochromic paint at the doll's eyebrows 34, eyes 36, eyelashes 38, eyeshadow areas 40, lips 42, cheek areas 44, mark 46, a r>d earrings 48 may be darkened by applying cold water to these areas of the doll so that a child can pretend that make up or jewelry is being put on the doll.
- the doll's cheek areas 44 may be darkened by applying cold water to - these areas so a child can pretend that make up is being applied to the doll's cheeks or the doll is blushing.
- the darkened colors of these areas may then be returned to their original lighter colors by applying hot water as explained above.
Landscapes
- Toys (AREA)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
BR898907112A BR8907112A (pt) | 1988-03-14 | 1989-03-08 | Brinquedo,veiculo de brinquedo e boneca |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US16761488A | 1988-03-14 | 1988-03-14 | |
US167,614 | 1988-03-14 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1989008486A1 true WO1989008486A1 (en) | 1989-09-21 |
Family
ID=22608071
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US1989/000929 WO1989008486A1 (en) | 1988-03-14 | 1989-03-08 | Toy with thermochromic material |
Country Status (8)
Country | Link |
---|---|
EP (1) | EP0406271A4 (enrdf_load_stackoverflow) |
AU (2) | AU3281089A (enrdf_load_stackoverflow) |
BR (1) | BR8907112A (enrdf_load_stackoverflow) |
CH (1) | CH678699A5 (enrdf_load_stackoverflow) |
DE (2) | DE8903160U1 (enrdf_load_stackoverflow) |
ES (1) | ES1009286Y (enrdf_load_stackoverflow) |
NL (1) | NL8900485A (enrdf_load_stackoverflow) |
WO (1) | WO1989008486A1 (enrdf_load_stackoverflow) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0473446A1 (en) * | 1990-08-31 | 1992-03-04 | The Pilot Ink Co., Ltd. | Electrothermal color-varying device and toy utilizing the same |
RU2130798C1 (ru) * | 1998-04-22 | 1999-05-27 | Ципенюк Дмитрий Юрьевич | Кукла |
US6736692B1 (en) | 2003-05-30 | 2004-05-18 | Mattel, Inc. | Hair styling doll head having color change hair crimper |
US8628373B2 (en) | 2010-08-26 | 2014-01-14 | Mattel, Inc. | Toy vehicle playset |
US8734200B2 (en) | 2009-04-24 | 2014-05-27 | Mattel, Inc. | Toy playset with a launcher and a material dispenser |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE29612669U1 (de) * | 1996-05-17 | 1996-11-07 | Schmalbach-Lubeca Ag, 38112 Braunschweig | Lebensmittelbehälter mit temperaturempfindlicher Markierung |
DE19707864A1 (de) * | 1997-02-27 | 1998-09-03 | Kloeckner Moeller Gmbh | Niederspannungs-Schaltgerät oder Niederspannungs-Schaltanlage |
DE102017210360A1 (de) * | 2017-06-21 | 2018-12-27 | Bayerische Motoren Werke Aktiengesellschaft | Verfahren zum Ermitteln einer Temperatur eines transparenten Mediums eines Fortbewegungsmittels und Fortbewegungsmittel |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4028118A (en) * | 1972-05-30 | 1977-06-07 | Pilot Ink Co., Ltd. | Thermochromic materials |
US4421560A (en) * | 1981-04-08 | 1983-12-20 | Pilot Ink Company Ltd. | Thermochromatic materials |
US4425161A (en) * | 1980-11-27 | 1984-01-10 | Yutaka Shibahashi | Thermochromic materials |
US4674985A (en) * | 1985-06-24 | 1987-06-23 | Hasbro Bradley, Inc. | Toy with encoded identification element |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2066089A (en) * | 1979-08-31 | 1981-07-08 | Rickson C D | Models |
-
1988
- 1988-10-21 ES ES8803099U patent/ES1009286Y/es not_active Expired - Lifetime
-
1989
- 1989-02-27 NL NL8900485A patent/NL8900485A/nl not_active Application Discontinuation
- 1989-03-08 BR BR898907112A patent/BR8907112A/pt not_active Application Discontinuation
- 1989-03-08 AU AU32810/89A patent/AU3281089A/en not_active Abandoned
- 1989-03-08 WO PCT/US1989/000929 patent/WO1989008486A1/en not_active Application Discontinuation
- 1989-03-08 EP EP19890903566 patent/EP0406271A4/en not_active Withdrawn
- 1989-03-14 DE DE8903160U patent/DE8903160U1/de not_active Expired - Lifetime
- 1989-03-14 DE DE19893908317 patent/DE3908317A1/de not_active Ceased
- 1989-03-14 CH CH94289A patent/CH678699A5/de not_active IP Right Cessation
-
1992
- 1992-07-31 AU AU20725/92A patent/AU2072592A/en not_active Abandoned
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4028118A (en) * | 1972-05-30 | 1977-06-07 | Pilot Ink Co., Ltd. | Thermochromic materials |
US4425161A (en) * | 1980-11-27 | 1984-01-10 | Yutaka Shibahashi | Thermochromic materials |
US4421560A (en) * | 1981-04-08 | 1983-12-20 | Pilot Ink Company Ltd. | Thermochromatic materials |
US4674985A (en) * | 1985-06-24 | 1987-06-23 | Hasbro Bradley, Inc. | Toy with encoded identification element |
Non-Patent Citations (2)
Title |
---|
Playthings Magazine, February 1985, page 329, see the entire page. * |
See also references of EP0406271A4 * |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0473446A1 (en) * | 1990-08-31 | 1992-03-04 | The Pilot Ink Co., Ltd. | Electrothermal color-varying device and toy utilizing the same |
US5316513A (en) * | 1990-08-31 | 1994-05-31 | The Pilot Ink Co., Ltd. | Electrothermal color-varying device and toy utilizing the same |
RU2130798C1 (ru) * | 1998-04-22 | 1999-05-27 | Ципенюк Дмитрий Юрьевич | Кукла |
WO1999054012A1 (en) * | 1998-04-22 | 1999-10-28 | Dmitry Jurievich Tsipenjuk | Doll |
US6736692B1 (en) | 2003-05-30 | 2004-05-18 | Mattel, Inc. | Hair styling doll head having color change hair crimper |
US8734200B2 (en) | 2009-04-24 | 2014-05-27 | Mattel, Inc. | Toy playset with a launcher and a material dispenser |
US8628373B2 (en) | 2010-08-26 | 2014-01-14 | Mattel, Inc. | Toy vehicle playset |
Also Published As
Publication number | Publication date |
---|---|
DE3908317A1 (de) | 1989-09-28 |
DE8903160U1 (de) | 1990-07-05 |
EP0406271A1 (en) | 1991-01-09 |
AU2072592A (en) | 1992-10-01 |
AU3281089A (en) | 1989-10-05 |
NL8900485A (nl) | 1989-10-02 |
BR8907112A (pt) | 1991-02-05 |
ES1009286U (es) | 1989-08-01 |
EP0406271A4 (en) | 1991-03-20 |
ES1009286Y (es) | 1991-02-01 |
CH678699A5 (enrdf_load_stackoverflow) | 1991-10-31 |
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