WO1988008408A1 - Systeme et procede d'extraction de cyanure a partir d'une solution finale - Google Patents

Systeme et procede d'extraction de cyanure a partir d'une solution finale Download PDF

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Publication number
WO1988008408A1
WO1988008408A1 PCT/AU1988/000119 AU8800119W WO8808408A1 WO 1988008408 A1 WO1988008408 A1 WO 1988008408A1 AU 8800119 W AU8800119 W AU 8800119W WO 8808408 A1 WO8808408 A1 WO 8808408A1
Authority
WO
WIPO (PCT)
Prior art keywords
liquid
air
aeration
stage
columns
Prior art date
Application number
PCT/AU1988/000119
Other languages
English (en)
Inventor
Kevin John Lobb
Original Assignee
Golconda Engineering And Mining Services Pty. Ltd.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Golconda Engineering And Mining Services Pty. Ltd. filed Critical Golconda Engineering And Mining Services Pty. Ltd.
Publication of WO1988008408A1 publication Critical patent/WO1988008408A1/fr

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/20—Treatment of water, waste water, or sewage by degassing, i.e. liberation of dissolved gases
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D21/00—Separation of suspended solid particles from liquids by sedimentation
    • B01D21/01—Separation of suspended solid particles from liquids by sedimentation using flocculating agents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D21/00—Separation of suspended solid particles from liquids by sedimentation
    • B01D21/24—Feed or discharge mechanisms for settling tanks
    • B01D21/2488—Feed or discharge mechanisms for settling tanks bringing about a partial recirculation of the liquid, e.g. for introducing chemical aids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D21/00—Separation of suspended solid particles from liquids by sedimentation
    • B01D21/30—Control equipment
    • B01D21/305—Control of chemical properties of a component, e.g. control of pH
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2221/00—Applications of separation devices
    • B01D2221/04—Separation devices for treating liquids from earth drilling, mining
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00—Nature of the contaminant
    • C02F2101/10—Inorganic compounds
    • C02F2101/16—Nitrogen compounds, e.g. ammonia
    • C02F2101/18—Cyanides
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/10—Nature of the water, waste water, sewage or sludge to be treated from quarries or from mining activities
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/22—Nature of the water, waste water, sewage or sludge to be treated from the processing of animals, e.g. poultry, fish, or parts thereof
    • C02F2103/24—Nature of the water, waste water, sewage or sludge to be treated from the processing of animals, e.g. poultry, fish, or parts thereof from tanneries

Definitions

  • the present invention relates to a method and a system for treating by aeration a liquid containing a component to separate the component from the liquid.
  • the present invention relates to a method and a system for treating by aeration a liquid containing cyanide to separate cyanide from the liquid.
  • An object of the present invention is to alleviate the problem described in the preceding paragraph and to provide a more efficient and cost effective method and system for treating by aeration a liquid containing a component to separate the component from the liquid.
  • a method of separating by aeration a component from a liquid containing the component comprising, in a first stage, passing the liquid counter-current to a stream of air to entrain a portion the component in the air thereby to separate the portion. from the liquid, subsequently dividing the liquid into a plurality of divided portions, and, in a second stage, passing each divided portion counter-current to a stream of air so as to entrain a further portion of the component in the air thereby to separate the further portion from the liquid.
  • the component comprises cyanide.
  • a method of separating by aeration cyanide from liquid containing cyanide comprising: (a) adjusting the pH of the liquid to be in the acidic range to cause the formation of free hydrogen cyanide gas in the liquid; (b) passing the liquid through an array of aeration columns arranged in stages so that the liquid flowing from one aeration column in a first stage is divided into two or more streams which are introduced into separate aeration columns in a successive second stage; and (c) passing air through the aeration columns counter-current to the liquid to entrain the free hydrogen cyanide gas, thereby to separate cyanide from the liquid.
  • a system for separating a component from a liquid containing the component comprising:
  • (b) means to direct air through the aeration columns counter-current to the liquid to entrain the component in the air, thereby to separate the component from the liquid.
  • the system when the system is used to separate cyanide from a liquid, in accordance with the invention the system comprises a means to adjust the pH of the liquid to be in the acidic range to cause the formation of free hydrogen cyanide gas in the liquid prior to the introduction of the liquid into the aeration columns.
  • column is understood herein to mean any container or the like, such as an open ended tube which is adapted to receive liquid therein.
  • aeration is understood herein to mean a process in which a liquid is exposed to the action of air or any other aeration gas.
  • Figure 1 is a schematic block diagram of a tailings treatment process in its entirety
  • Figure 2 is a detailed schematic drawing showing the particular arrangement of the aeration columns and caustic circulation tanks used in the process;
  • Figure 3 is a block diagram showing the principal of passing air through the aeration columns in a serial manner without changing the volume of air relative to each aeration column;
  • Figure 4 Is a detailed schematic diagram showing the manner in which air passes through a single pair of separation and absorption aeration columns counter-current with the liquor and caustic solution.
  • the specific embodiment concerns a system and process for -treating tailings from an extraction plant for the recovery of gold or other minerals.
  • cyanide is dissolved in water and the resultant solution is used to leach gold from deposits of ore. In the leaching process, some of the cyanide remains in the tailings or the residue from the plant.
  • the purpose of the system and process described herein is to treat the tailings so as to remove sufficient of the cyanide to enable the tailings to be disposed of in an environmentally satisfactory condition.
  • the system and process initially comprises forming a tails liquor from the tailings dump which is decanted by known means 1 and pumped to a mixing chamber 2.
  • Acid stored in a bulk acid storage tank 3 is pumped by an acidification dosing pump to the chamber for admixture with the tails liquor so as to adjust to the pH of the liquor into the acid range thereby to cause the formation of free hydrogen cyanide gas which is retained in the liquor.
  • the liquor is pumped into a sand-floc contact tank 4.
  • Coagulant, flocculant and make-up sand from respective storage tanks 5, 6 and 7 are added to the sand-floc contact tank 4.
  • the mixture is agitated and flows by gravity to a constant density tank 8.
  • the underflow from the constant density tank 8 is pumped to a cyclone 9.
  • the cyclone underflow is returned to the sand-floc contact tank 4 for re-use.
  • the cyclone overflow is directed to a settling pond 10 from which liquor is drawn off and returned to the sand-floc contact tank 4 and the liquid is transferred to pondage.
  • the liquor from the constant density tank 8 flows by gravity through sand filters 12 and then is pumped to a column 13a.
  • the column 13a is a preliminary aeration column for the separation of cyanide from the liquor.
  • the liquor is sprayed into the column 13a and flows downwardly therethrough counter-current to a stream of air directed upwardly through the column 13a.
  • the stream of air is drawn from the constant density tank 8 and has the effect of entraining a portion of the free hydrogen cyanide gas in the liquor.
  • the air is drawn from the top of column 13a and is directe'd through an absorption column 13b for absorption of the hydrogen cyanide gas into a caustic solution.
  • the liquor, with a reduced cyanide concentration, which collects at the bottom of the column 13a is pumped to an array of aeration columns, generally identified by the numeral 14, to remove a further• portion of the cyanide in the liquor.
  • the aeration columns in the array 14 are arranged in stages so that the liquid ' flowing from one aeration column in a first stage is divided into two streams which are introduced into two separate aeration columns in a successive second stage.
  • the aeration columns in the array 14 are also arranged to receive therethrough air in counter-current flow to the flow of liquor, thereby to entrain free hydrogen cyanide gas in the air.
  • the array 14 of aeration columns is described in more detail hereinafter.
  • the liquor is passed downwardly through the aeration column 15 counter-current to an upward flow of air drawn from the atmosphere.
  • the liquor from the columns 16 is suitable for disposal. Such disposal may be by direct transfer to a tailings impoundment system or via a pH correction stage 17 where a suitable reagent such as lime or caustic soda is added to raise the pH of the liquor to a level suitable for discharge into the environment.
  • the array 14 of aeration columns is now described in more detail with reference to Figures 2 and 4.
  • the array comprises a plurality of pairs of aeration columns 14a, 14b, ... c' 1 ' which are arranged in three stages.
  • the first stage comprises the pair of-aeration columns 14a
  • the second stage comprises the pairs of aeration columns 14b, 14b'
  • the third stage comprises the pairs of aeration columns 14c, 14c', 14c' ' and 14c* * ' .
  • 14c' ' ' comprises, an aeration column 25 for use in connection with the separation of free hydrogen cyanide gas fror ⁇ liquor by means of a counter-current flow of air, and an aeration column 26 for use in connection with the absorption of hydrogen cyanide gas from the air into a stream of caustic solution.
  • the separation column 25 and absorption column 26 in each pair are separated by an intermediate air duct 29 which maintains liquor in separation column 25 and caustic solution in absorption column 26 whilst allowing air flow 27 to pass serially through both columns from an inlet air port 28 disposed in the separation column 25 to an outlet air port 30 disposed in the absorption column 26. In this manner air is passed serially through the columns 25, 26 in each pair.
  • the liquor is introduced in a spray through an inlet liquor port 31 disposed near the top of each separation column 25 and flows downwardly and is discharged through an outlet liquor port 33 near the base of each separation column 25.
  • Each separation column 25 contains a bed of packing material 32 suspended therein to promote dispersion of the downward flow of liquor and upward flow of air thereby to enhance aeration of the liquor and, as a consequence, to enhance entrainment of the free hydrogen cyanide gas in the air.
  • the caustic solution is introduced in a spray through a caustic inlet port 34 disposed near the top of each absorption column 26 and flows downwardly and is discharged through a caustic outlet port 36 disposed near the base of each absorption column 26.
  • each absorption column 26 contains a bed of packing material 35 suspended therein to promote dispersion of the downward flow of caustic solution and upward flow of air thereby to enhance aeration of the caustic solution and, as a consequence, to enhance absorption of the hydrogen cyanide gas in the caustic solution.
  • the pairs of aeration columns 14a, 14b, ... 14c 1 * ' are interconnected to allow selective circulation of the liquor and the caustic solution.
  • Figure 2 shows the physical arrangement of the pairs of aeration columns and the circulation system for liquor and caustic solution
  • Figure 3 shows the conceptual disposition of the separation columns 25 in each pair of aeration columns at the various stages.
  • the liquor is introduced into the first stage of the array 14 which comprises the pair of aeration columns 14a.
  • the liquor is introduced into the separation column 25 thereof at the inlet liquor port 31 and flows downwardly to the base of the separation column 25.
  • the liquor discharged from the outlet port 33 is circulated by a liquor pump 37 to the second stage of the array 14 which comprises the pairs of aeration columns 14b and 14b'.
  • the stream of liquor is split equally so that half of the original volume is introduced through inlet port 31 into the separation column 25 of the pair of aeration columns 14b and the other half is introduced through the inlet port 31 into the separation column 25 of the pair of aeration columns 14b* .
  • the liquor After flowing through the second stage the liquor is discharged from the outlet ports 33 of respective separation columns 25 and is collectively circulated by a second stage pump 38 to the third stage of the array 14 which comprises the pairs of aeration columns 14c, 14c', 14c' 1 and 14c' ''.
  • the recollected liquor is split equally Into four streams such that a quarter of the original volume is introduced into the separation column.25 of the pair of aeration columns 14c and so on up to the pair of aeration columns 14c'' 1 .
  • the liquor After discharge from the third stage the liquor is combined In a single pipeline 38 and is transferred to the final aeration stage 15 and thence to the columns 16 prior to eventual discharge as shown in Figure 1 of the drawings;
  • the caustic solution is pumped from a bulk caustic storage tank 19 via a pipe line 39 and initially is discharged into a caustic circulation tank 20a intended to supply the third stage of the array 14 of aeration columns, i.e. converse to the supply of liquor which is fed initially to the first stage of the array 14 as described in the preceding paragraph.
  • Water from a water storage tank 23 is also pumped into the third stage caustic circulation tank 20a via a pipe line 22.
  • the diluted caustic solution accumulated within the third stage circulation tank 20a is circulated by means of a third stage caustic recirculation pump 40 from the circulation tank 20a to each of the absorption columns -26 in the third stage of the array 14, i.e.
  • each of the absorption columns 26 of the third stage the caustic solution is sprayed from the top through the inlet liquor ports 34 and flows through the absorption columns 26 and subsequently is discharged through the outlet liquor ports 36.
  • Each of the outlet ports 36 of the absorption columns 26 of the third stage are connected to a common return pipe line 41 which discharges back into the third stage recirculation tank 20a, wherein excess caustic solution subsequently is fed • via pipe line 42 to a second stage circulation tank 20b.
  • the accumulated caustic solution in the second stage circulation tank 20b in turn is pumped via a second stage caustic recirculation pump 43 to each of the absorption columns 26 of the second stage, i.e. the absorption columns 26 in the pairs of aeration columns 14b and 14b'.
  • the caustic solution is sprayed into the absorption columns 26, through inlet ports 34 and flows downwardly and is discharged through the outlet ports 26 thereof.
  • the discharged caustic solution is fed to a common return pipe line 44 for return to the second stage circulation tank 20b, thus providing a closed loop circulation.
  • the excess caustic solution contained within the second stage caustic circulation tank 20b in turn is supplied to a first stage caustic circulation tank 20c via pipe line 45.
  • Caustic solution supplied to the first stage circulation tank 20c in turn is pumped via the first stage recirculation pump 46 to the absorption column 26 of the first stage; i.e. the absorption column 26 of the pair of aeration columns 14a.
  • the caustic solution as in the previous stages, flows downwardly and subsequently is discharged through the outlet port 36 for return via pipe line 47 to the first stage circulation tank 20c.
  • excess caustic solution in the first stage circulation tank 20c in turn is fed to a final caustic circulation tank 20d to be subsequently returned for use in the mineral recovery plant for leaching.
  • each stage of the array 14 of aeration columns receives therethrough substantially the same volume of liquor and that each pair of aeration columns 14a, 14b, ... 14c 1 * ' in each stage receives therethrough substantially the same volume of liquor and caustic solution.
  • Air is drawn serially through the pairs of aerator columns 14a, 14b, ... 14c' ' ' by fans 48a and 48b disposed respectively at the outlet air ports 30 of the pair of aeration columns 14c' and the pair of aeration columns 14c' ' ' .
  • the inlet air ports 28 of the pairs of aeration columns 14a, 14b are vented to the atmosphere so that air may be drawn from the inlet ports 28 to the outlet ports 30 in a serial fashion through the aeration columns.
  • the intermediate air ducts 29 between adjacent separation and absorption columns 25, 26 in each pair of aeration columns are arranged so as to create rising air streams counter-current to the downward flow of liquor and caustic solution in the aeration columns.
  • An important aspect of the embodiment of the invention as described herein is the circulation of liquor and air through the stages of the array 14 of aeration columns. This is best illustrated in Figure 3 where it can be seen that an initial volume of liquor is passed wholly through the first stage comprising the pair of aeration columns 14a and is subsequently divided into two half volumes which respectively pass through the second stage comprising the pairs of aeration columns 14b, 14b' .
  • the half volumes of cyanide liquor are subsequently divided again at the third stage comprising the pairs of aeration columns 14c, 14c', 14c' ', 14c- 1 ' so that quarter volumes of the original liquor volume are passed through each pair of aeration columns of the third stage. These quarter volumes are then recombined into a single supply pipe for eventual delivery to the final aeration stages as previously described.
  • a single volume of air is passed through the various columns serially so that each separation and absorption column 25, 26 is treated with the same volume of air. Therefore, the air to liquor ratio increases as the liquor passes through the pairs of aeration columns in successive stages without an increase in the amount of air required in the system. As a consequence, there is an improvement in the contact time for the liquor and air. and a consequential improvement in the separation of cyanide from the liquor.
  • the scope of the present invention is not limited to the particular embodiment herein described.
  • the invention is not limited to application to gold extraction processes and can be used elsewhere for the separation of cyanide from a liquid.
  • the invention is not restricted to the separation of cyanide from a liquid and relates to the separation of any dissolved gas from a liquid.
  • a stream of liquor flowing from a separation column in one stage is divided into two equal-volume portions for introduction into separation columns in the successive stage
  • the invention is not so limited and the stream of liquor could be divided into more than two portion ' s which may or may not be of equal volume.
  • the array 14 of aeration columns is arranged in three stages, it can readily be appreciated that any suitable number of stages could be used.
  • the air is passed through the pairs of aeration columns serially, it can readily be appreciated that any suitable air flow could be used.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Physical Water Treatments (AREA)
  • Treating Waste Gases (AREA)

Abstract

La présente invention se rapporte à un procédé et à un système permettant de séparer par aération un composant, tel que du cyanure, à partir d'un liquide contenant ce composant. Ledit procédé consiste à faire passer le liquide à travers un réseau de colonnes d'aération disposées en paliers, de sorte que le liquide s'écoulant depuis une colonne d'aération dans un premier palier soit divisé en au moins deux courants qu'on introduit dans des colonnes d'aération séparées dans un second palier successif. Ledit procédé consiste également à faire passer de l'air à travers les colonnes d'aération à contre courant du liquide, afin d'entraîner dans l'air au moins une partie du composant, de façon à pouvoir séparer du liquide au moins cette partie.
PCT/AU1988/000119 1987-04-23 1988-04-22 Systeme et procede d'extraction de cyanure a partir d'une solution finale WO1988008408A1 (fr)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
AUPI1570 1987-04-23
AUPI157087 1987-04-23
AUPI378087 1987-08-17
AUPI3780 1987-08-17

Publications (1)

Publication Number Publication Date
WO1988008408A1 true WO1988008408A1 (fr) 1988-11-03

Family

ID=25643268

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/AU1988/000119 WO1988008408A1 (fr) 1987-04-23 1988-04-22 Systeme et procede d'extraction de cyanure a partir d'une solution finale

Country Status (5)

Country Link
EP (1) EP0355109A4 (fr)
CA (1) CA1331895C (fr)
MY (1) MY103266A (fr)
NZ (1) NZ224369A (fr)
WO (1) WO1988008408A1 (fr)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4994243A (en) * 1988-10-21 1991-02-19 Cyprus Minerals Company Cyanide regeneration process
US5078977A (en) * 1988-10-21 1992-01-07 Cyprus Minerals Company Cyanide recovery process
US5254153A (en) * 1988-10-21 1993-10-19 Cyprus Minerals Company Cyanide recycling process
DE19600774A1 (de) * 1996-01-11 1997-07-17 Biotecon Ges Fuer Biotechnologische Entwicklung & Consulting Mbh Cyanidentfernung aus Prozeßwasser

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1387289A (en) * 1918-03-21 1921-08-09 Merrill Co Cyaniding process
DE409259C (de) * 1924-05-31 1925-02-03 Atlas Werke Ag Verfahren zur Reinigung und Entgasung von Rohwasser unter Auskochung des Wassers
DE2156186A1 (de) * 1971-11-12 1973-05-17 Babcock & Wilcox Ag Sprueh-entgasungsanlage mit mischvorwaermung
AU2694577A (en) * 1976-07-14 1979-01-18 Brewing Patents Ltd Deoxygenated water

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1387289A (en) * 1918-03-21 1921-08-09 Merrill Co Cyaniding process
DE409259C (de) * 1924-05-31 1925-02-03 Atlas Werke Ag Verfahren zur Reinigung und Entgasung von Rohwasser unter Auskochung des Wassers
DE2156186A1 (de) * 1971-11-12 1973-05-17 Babcock & Wilcox Ag Sprueh-entgasungsanlage mit mischvorwaermung
AU2694577A (en) * 1976-07-14 1979-01-18 Brewing Patents Ltd Deoxygenated water

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
C.F. GURNHAM, "Principles of Industrial Waste Treatment", published 1955 by John Wiley and Sons (New York), see pages 243-244 *

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4994243A (en) * 1988-10-21 1991-02-19 Cyprus Minerals Company Cyanide regeneration process
US5078977A (en) * 1988-10-21 1992-01-07 Cyprus Minerals Company Cyanide recovery process
US5254153A (en) * 1988-10-21 1993-10-19 Cyprus Minerals Company Cyanide recycling process
DE19600774A1 (de) * 1996-01-11 1997-07-17 Biotecon Ges Fuer Biotechnologische Entwicklung & Consulting Mbh Cyanidentfernung aus Prozeßwasser

Also Published As

Publication number Publication date
MY103266A (en) 1993-05-29
NZ224369A (en) 1990-05-28
CA1331895C (fr) 1994-09-06
EP0355109A1 (fr) 1990-02-28
EP0355109A4 (fr) 1990-03-12

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