WO1988007956A1 - Microbubble injection device for reducing the fluid frictional resistance against a vessel - Google Patents
Microbubble injection device for reducing the fluid frictional resistance against a vessel Download PDFInfo
- Publication number
- WO1988007956A1 WO1988007956A1 PCT/AU1988/000107 AU8800107W WO8807956A1 WO 1988007956 A1 WO1988007956 A1 WO 1988007956A1 AU 8800107 W AU8800107 W AU 8800107W WO 8807956 A1 WO8807956 A1 WO 8807956A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- strap
- board
- vessel
- duct
- injection device
- Prior art date
Links
- 238000002347 injection Methods 0.000 title claims abstract description 16
- 239000007924 injection Substances 0.000 title claims abstract description 16
- 239000012530 fluid Substances 0.000 title claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000011148 porous material Substances 0.000 claims abstract description 7
- 238000000034 method Methods 0.000 claims description 4
- 238000004891 communication Methods 0.000 claims description 3
- 238000004026 adhesive bonding Methods 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B63—SHIPS OR OTHER WATERBORNE VESSELS; RELATED EQUIPMENT
- B63B—SHIPS OR OTHER WATERBORNE VESSELS; EQUIPMENT FOR SHIPPING
- B63B1/00—Hydrodynamic or hydrostatic features of hulls or of hydrofoils
- B63B1/32—Other means for varying the inherent hydrodynamic characteristics of hulls
- B63B1/34—Other means for varying the inherent hydrodynamic characteristics of hulls by reducing surface friction
- B63B1/38—Other means for varying the inherent hydrodynamic characteristics of hulls by reducing surface friction using air bubbles or air layers gas filled volumes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B63—SHIPS OR OTHER WATERBORNE VESSELS; RELATED EQUIPMENT
- B63B—SHIPS OR OTHER WATERBORNE VESSELS; EQUIPMENT FOR SHIPPING
- B63B1/00—Hydrodynamic or hydrostatic features of hulls or of hydrofoils
- B63B1/32—Other means for varying the inherent hydrodynamic characteristics of hulls
- B63B1/34—Other means for varying the inherent hydrodynamic characteristics of hulls by reducing surface friction
- B63B1/38—Other means for varying the inherent hydrodynamic characteristics of hulls by reducing surface friction using air bubbles or air layers gas filled volumes
- B63B2001/387—Other means for varying the inherent hydrodynamic characteristics of hulls by reducing surface friction using air bubbles or air layers gas filled volumes using means for producing a film of air or air bubbles over at least a significant portion of the hull surface
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T70/00—Maritime or waterways transport
- Y02T70/10—Measures concerning design or construction of watercraft hulls
Definitions
- This invention relates to drag reduction and more particularly to a microbubble injection device for the purpose of reducing skin friction in a turbulent boundary layer by the injection of microbubbles of gas between a body of fluid and the surface, or skin, of an object immersed therein.
- the gas of interest is air, the liquid water and the object a waterborne vessel.
- a microbubble injection device which comprises a member attachable to, or incorporatable in, the external surface, or skin, of a waterborne vessel; the said member having a longitudinal duct extending therethrough, said duct being adapted to be in communication with a body of water, in which said member is immersed via a foraminous region provided on that part of the said member which is remote from said external surface, or skin, of the said vessel.
- the member should have an aerofoil-shaped transverse cross-section, while the pores of the foraminous region preferably have a diameter of less than about 100 microns.
- the pores of the foraminous region preferably have a diameter of less than about 100 microns.
- Figure 1 is a schematic drawing showing an -injection device according to the present inventions
- Figure 2 is a transverse cross-section through a typical device
- Figure 3 shows an alternative cross-sectional form
- Figure 4 illustrates an inventive device particularly applicable to surboards and sailboards
- Figure 5 shows a further embodiment
- Figure 1 shows schematically a typical microbubble injection device according to the present invention, the device comprising a member, generally referenced 1, in the form of a strap 2 of aerofoil-shaped cross-section and having a longitudinal duct 3 extending therethrough, best to be seen in Figures 2 and 3.
- Strap 2 as it is depicted in Figure 1, is affixed to the external surface or skin 4 of a waterborne vessel 5; strap 2 extends part-way round the vessel 5 from gunwhale to gunwhale and may be kept in contact with surface 4 by any suitable means such as by gluing, or by maintaining it under tension, or other like methods.
- Figure 2 is a transverse cross-section through the strap 2 showing a foraminous region 6 provided on the part of strap 2 which is remote from surface or skin 4.
- the pores of this foraminous wall region 6 ideally have a diameter of less than about 100 microns.
- the inventive microbubble injection device operates in the following manner: when vessel 5 is in motion, the movement of water over the aerofoil shape hydro-dynamically generates a low pressure area adjacent the foraminous region 6. When sufficient speed has been attained, the pressure drop is such as to cause air to enter strap 2 through the open ends 7, located above the waterline', flow through duct 3 and out through the pores of foraminous region 6.
- the combination of small pore size - less than 100 microns - and the velocity of the water over the foraminous region results in microbubbles of air entering the turbulent boundary layer to thereby cause a reduction in skin friction drag on the hull surface aft of the device.
- vessels of some considerable size may well be provided with a plurality of inventive straps 2, spaced at approximately two metre intervals along the hull.
- the location of the device or devices can be varied to conform with the position on the hull of different kinds of friction, such as skin friction and form friction. In the case of planing hulls, the or each device would be aft of the so-called "stagnation point".
- Figure 3 shows an alternative transverse cross-sectional form in which duct 3 is bounded on both sides by walls of the strap 2.
- Figures 2 and 3 show straps having therein foraminous regions 6, it is also envisaged that the strap's entire outside wall could well be porous.
- the device may be in communication with atmosphere via ducting within the vessel.
- the member- 1 may be ' incorporated into the structure of the vessel.
- Figure'4 illustrates a device in accordance with Jkhe invention which is particularly applicable to surfboards and sailboards.
- the strap 2 continues
- an inventive strap is attachable to a vessel hull, or a board, in a number of ways such as by gluing, etc.
- Figure 5 there is shown an embodiment suitable for fitment to, say, a sailboard having a keel, or a centre-board, retractable or otherwise.
- a sailboard 9 having a centreboard 10-, is provided with _a divided porous strap 11, each half being held at its immersed end by being anchored in co-acting grooves 12 in the fabric of the board.
- the • ⁇ ?p.per end of each half-strap 11 being held in place by the tension exerted by fasteners 13 on the upper surface of the board; fasteners 13 may well be conventional, over-centre action.toggle s eners.
- Figure 6 depicts yet another embodiment wherein a board, again referenced 8, has a length of inventive strap 2 affixed only to the underside of the board; ends 14 of this strap are- closed-off.
- atmospheric air - is caused to enter the duct within the strap through a bore 15 in board 8.
- the mouth of bore 15 is advantageously provided with a simple, foot-operated flap valve 16, preferably made of rubber.
- a bore-and-valv combination is operable to control microbubble injection an is usable by a rider to give controlled speed increase decrease as and when required or desired.
- microbubble injection device is applicable to virtually all kinds o watercraft from large oceangoing vessels, all pleasur craft, trimarans, catamarans, planing-hull craft, hydrofoils, and the like down to sailboards and surfboards. It is envisaged that the greatest commercial advantage will be gained by the provision of the inventive, foraminous, aerofoil-shaped straps in a range of lengths and sizes fo attachment to, or incorporation in, the external surface, or skin, of a waterborne vessel.
Landscapes
- Physics & Mathematics (AREA)
- Fluid Mechanics (AREA)
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Mechanical Engineering (AREA)
- Ocean & Marine Engineering (AREA)
- Toys (AREA)
Abstract
A microbubble injection device in the form of a strap (2) which is fixed about the beam of a waterborne vessel (4). The strap (2) has an aerofoil-shaped cross-section and has a duct (3) running through it. The outer wall of the strap (2) is largely foraminous (6); atmospheric air flowing through the duct and out through the pores of the outer wall reduces skin friction in the turbulent boundary layer by injection of microbubbles of air between the vessel and the water.
Description
MICRO-BUBBLE INJECTION DEVICE FOR REDUCING THE FLUID FRICTIONAL RESISTANCE AGAINST A VESSEL Technical Field
This invention relates to drag reduction and more particularly to a microbubble injection device for the purpose of reducing skin friction in a turbulent boundary layer by the injection of microbubbles of gas between a body of fluid and the surface, or skin, of an object immersed therein. Generally, the gas of interest is air, the liquid water and the object a waterborne vessel. BACKGROUND ART
As early as about 1800 a patent was granted for the engendering of a layer of air between a ship's hull and its water boundary layer, for the purpose of reducing skin friction. In 1973, some experimental work was reported by
McCormick and Bhattacharyya involving microbubbles of hydrogen, and more recently the effects of microbubbles upon a turbulent boundary layer have been studied in the Soviet
Union. Instead of using an electrolytic method for the generation of the hydrogen microbubbles, air was forced through a porous surface; simple flat plate geometry was employed and measurements were made downstream of the porous region. Results indicated that local skin friction might well be reduced by upwards of 50%; however, no way was ever postulated to actually produce engineering - particularly marine engineering - benefits from the discovery.
DISCLOSURE OF INVENTION
It is therefore an object of the present invention to overcome the above and other disadvantages by the provision of a microbubble injection device which comprises a member attachable to, or incorporatable in, the external surface, or skin, of a waterborne vessel; the said member having a longitudinal duct extending therethrough, said duct being adapted to be in communication with a body of water, in which said member is immersed via a foraminous region provided on that part of the said member which is
remote from said external surface, or skin, of the said vessel.
Ideally, the member should have an aerofoil-shaped transverse cross-section, while the pores of the foraminous region preferably have a diameter of less than about 100 microns. Throughout the drawings like integers are referred to by the same numeral. BRIEF DESCRIPTION OF DRAWINGS
In order that the reader may gain a better understanding of the present invention, hereinafter will be described some preferred embodiments thereof, by way of example only and with reference to the accompanying drawings in which:-
Figure 1 is a schematic drawing showing an -injection device according to the present inventions;
Figure 2 is a transverse cross-section through a typical device;
Figure 3 shows an alternative cross-sectional form; Figure 4 illustrates an inventive device particularly applicable to surboards and sailboards;
Figure 5 shows a further embodiment; and
-Figure 6 depicts yet' another embodiment. MODES OF CARRYING OUT THE INVENTION;-
Figure 1 shows schematically a typical microbubble injection device according to the present invention, the device comprising a member, generally referenced 1, in the form of a strap 2 of aerofoil-shaped cross-section and having a longitudinal duct 3 extending therethrough, best to be seen in Figures 2 and 3. Strap 2, as it is depicted in Figure 1, is affixed to the external surface or skin 4 of a waterborne vessel 5; strap 2 extends part-way round the vessel 5 from gunwhale to gunwhale and may be kept in contact with surface 4 by any suitable means such as by gluing, or by maintaining it under tension, or
other like methods.
Figure 2 is a transverse cross-section through the strap 2 showing a foraminous region 6 provided on the part of strap 2 which is remote from surface or skin 4. The pores of this foraminous wall region 6 ideally have a diameter of less than about 100 microns.
The inventive microbubble injection device operates in the following manner: when vessel 5 is in motion, the movement of water over the aerofoil shape hydro-dynamically generates a low pressure area adjacent the foraminous region 6. When sufficient speed has been attained, the pressure drop is such as to cause air to enter strap 2 through the open ends 7, located above the waterline', flow through duct 3 and out through the pores of foraminous region 6. The combination of small pore size - less than 100 microns - and the velocity of the water over the foraminous region results in microbubbles of air entering the turbulent boundary layer to thereby cause a reduction in skin friction drag on the hull surface aft of the device.
As this drag reduction effect persists only for a distance of about two metres downstream of the injection point, vessels of some considerable size may well be provided with a plurality of inventive straps 2, spaced at approximately two metre intervals along the hull. The location of the device or devices can be varied to conform with the position on the hull of different kinds of friction, such as skin friction and form friction. In the case of planing hulls, the or each device would be aft of the so-called "stagnation point".
Figure 3 shows an alternative transverse cross-sectional form in which duct 3 is bounded on both sides by walls of the strap 2.
While Figures 2 and 3 show straps having therein foraminous regions 6, it is also envisaged that the strap's entire outside wall could well be porous. In another
(- variation the device may be in communication with atmosphere via ducting within the vessel. There again, the member- 1 may be' incorporated into the structure of the vessel. r- "^Figure'4 illustrates a device in accordance with Jkhe invention which is particularly applicable to surfboards and sailboards. In this embodiment, the strap 2 continues
-'..abross the top of a board 8. Air enters strap 2 through its foraminous. region 6 located on the top of the board and then travels through the duct 3 to exit through the foraminous region 6 located"beneath t\ e board. Because of the very fine pore size the strap is far more permeable to air than it is to water, thus, even when water washes over the top of the board, only a very small quantity will enter the strap 2. This water will eventually find its way out beneath the _board*.-and similarly any water . ntering the strap when board 8 is not- moving will also -be ejected once movement commences.
While it has been stated that an inventive strap is attachable to a vessel hull, or a board, in a number of ways such as by gluing, etc., in Figure 5 there is shown an embodiment suitable for fitment to, say, a sailboard having a keel, or a centre-board, retractable or otherwise.
In this embodiment a sailboard 9, having a centreboard 10-, is provided with _a divided porous strap 11, each half being held at its immersed end by being anchored in co-acting grooves 12 in the fabric of the board. The •ι?p.per end of each half-strap 11 being held in place by the tension exerted by fasteners 13 on the upper surface of the board; fasteners 13 may well be conventional, over-centre action.toggle s eners.
Figure 6 depicts yet another embodiment wherein a board, again referenced 8, has a length of inventive strap 2 affixed only to the underside of the board; ends 14 of this strap are- closed-off. In this embodiment, atmospheric air -is caused to enter the duct within the strap through a bore 15 in board 8. . Furthermore, the mouth of bore 15 is
advantageously provided with a simple, foot-operated flap valve 16, preferably made of rubber. Such a bore-and-valv combination is operable to control microbubble injection an is usable by a rider to give controlled speed increase decrease as and when required or desired. INDUSTRIAL APPLICABILITY
The microbubble injection device according to th present invention is applicable to virtually all kinds o watercraft from large oceangoing vessels, all pleasur craft, trimarans, catamarans, planing-hull craft, hydrofoils, and the like down to sailboards and surfboards. It is envisaged that the greatest commercial advantage will be gained by the provision of the inventive, foraminous, aerofoil-shaped straps in a range of lengths and sizes fo attachment to, or incorporation in, the external surface, or skin, of a waterborne vessel.
From the abovegoing, it will be readily appreciated by those skilled in the art that numerous variations and modifications may be made to the invention without departing from the spirit and scope thereof as set out in the following claims.
Claims
1. *. , A microbubble injection device comprising a member (1-i"attachable to, or incorporatable in, the external surface, ύ'or skin, (4) of a waterborne vessel (5); said member "(D having a longitudinal duct (3) extending therethrough, said duct (3) being adapted to be in communication with a body of water in which said member (1) is immersoib°le via a foraminous region (6) provided in that part -of said member (1) which is remote from said external -surface,- or skin-r- (4) of the said vessel (5).
2. The device as claimed in Claim 1, wherein said member (1)- is in the form of a strap (2) extending wholly or partly abeam of said vessel (5).
3*. " The device as claimed in Claim 1 or Claim 2, wherein said member (1) has an aerofoil-shaped transverse cross-section.
4. The device as claimed in Claim 1, wherein said foraminous region (6) pores have a diameter of less than 100 microns.
5. The device as claimed in Claim 2, wherein the free ends (7) of said strap (2) are open to atmospheric air, being disposed above said body of water.
6. The device as claimed in Claim 2, wherein said essel ϊv.3•a surfboard (8) and said strap (2) extends wholly abeam thereof, atmospheric air entering the foraminous region (6) of that portion of the strap (2) located at the }top of said board (8), flowing through said duct (3), and exiting through the forminous region (6) of that portion of said strap '(2) located beneath said board (8).
1. -The . evice as claimed in Claim 1 or Claim 2, wherein said vessel is a sailboard (9) and said member (1) is a divided strap (11) extending partly abeam of said board
'(9), each half of said divided strap (11) being anchored, at an immersed end thereof, in a groove (12) provided in the undersurface of -said board (9)-, one said groove (12) being positioned at each side of a centreboard (10) of said board
(9); the upper end of each half of said divide strap (11) being held in place on the upper surface of said board (9) by the tension exerted by a fastener (13) disposed thereon.
8. The device as claimed in Claim 1 or Claim 2 , wherein said vessel is a surfboard (8) and said strap (2) extends only across the underside of the board (8), said strap (2) having closed ends (14); atmospheric air entering said duct (3) through a communicating bore (15) in said board (8) and exiting through the foraminous region (6) of the strap (2) .
9. The device as claimed in Claim 7, wherein each said fastener (13) is an over-centre action toggle fastener.
10. The device as claimed in Claim 8, wherein a mouth of said bore (15) is provided with a rubber, foot-operated flap-valve (16) .
11. A method of reducing skin friction in a turbulent boundary layer existing between a body of fluid and the surface, or skin, of an object immersed therein; said method comprising injecting microbubbles of gas therebetween, using a microbubble injection device as claimed in Claim 1.
12. A waterborne vessel, whenever provided with a microbubble injection device as claimed in Claim 1 or Claim 2.
*-_>
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AUPI1492 | 1987-04-16 | ||
AU149287 | 1987-04-16 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1988007956A1 true WO1988007956A1 (en) | 1988-10-20 |
Family
ID=3692009
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/AU1988/000107 WO1988007956A1 (en) | 1987-04-16 | 1988-04-15 | Microbubble injection device for reducing the fluid frictional resistance against a vessel |
Country Status (1)
Country | Link |
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WO (1) | WO1988007956A1 (en) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0903287A3 (en) * | 1997-08-22 | 2002-01-30 | Ishikawajima-Harima Heavy Industries Co., Ltd. | Ship with reduced skin friction and gas jetting device for the same |
WO2003037702A1 (en) | 2001-11-02 | 2003-05-08 | Cnt Spolka Z O.O. | Superhydrophobic coating |
WO2005122676A2 (en) * | 2004-06-11 | 2005-12-29 | Universidad De Sevilla | Bubble-generating device for reducing friction on the hull of a boat |
JP2013052718A (en) * | 2011-09-01 | 2013-03-21 | Zuei-Ling Lin | Water flow resistance reducing apparatus |
JP2018094925A (en) * | 2012-03-03 | 2018-06-21 | バーデン−ビュルッテンベルク シュティフトゥング ゲーゲーエムベーハー | Gas-containing surface coating, arrangement, use |
US12000417B2 (en) | 2018-04-17 | 2024-06-04 | Baden-Württemberg Stiftung Ggmbh | Structured gas-containing surfaces |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1398246A (en) * | 1919-05-27 | 1921-11-29 | F G Trask | Apparatus for supplying air to the exterior of hulls of ships |
US1725452A (en) * | 1927-04-21 | 1929-08-20 | Jr William Harper | Means for increasing the speed of boats |
GB299727A (en) * | 1927-10-27 | 1929-08-22 | Johann Rudolf Klinger | Improvements in methods of and means for reducing the resistance to propulsion of ships, boats and the like |
GB425734A (en) * | 1934-01-04 | 1935-03-20 | Jules Pierre Victor Bragard | Application of compressed air in the navigation of ships |
US3690283A (en) * | 1970-10-07 | 1972-09-12 | Joseph Harbit Pool | Methods of and apparatus for reducing resistance to the hull of a vessel |
WO1986005758A1 (en) * | 1985-04-02 | 1986-10-09 | Roger Bolstad | Method and device for reducing the frictional resistance against an object. |
-
1988
- 1988-04-15 WO PCT/AU1988/000107 patent/WO1988007956A1/en unknown
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1398246A (en) * | 1919-05-27 | 1921-11-29 | F G Trask | Apparatus for supplying air to the exterior of hulls of ships |
US1725452A (en) * | 1927-04-21 | 1929-08-20 | Jr William Harper | Means for increasing the speed of boats |
GB299727A (en) * | 1927-10-27 | 1929-08-22 | Johann Rudolf Klinger | Improvements in methods of and means for reducing the resistance to propulsion of ships, boats and the like |
GB425734A (en) * | 1934-01-04 | 1935-03-20 | Jules Pierre Victor Bragard | Application of compressed air in the navigation of ships |
US3690283A (en) * | 1970-10-07 | 1972-09-12 | Joseph Harbit Pool | Methods of and apparatus for reducing resistance to the hull of a vessel |
WO1986005758A1 (en) * | 1985-04-02 | 1986-10-09 | Roger Bolstad | Method and device for reducing the frictional resistance against an object. |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0903287A3 (en) * | 1997-08-22 | 2002-01-30 | Ishikawajima-Harima Heavy Industries Co., Ltd. | Ship with reduced skin friction and gas jetting device for the same |
WO2003037702A1 (en) | 2001-11-02 | 2003-05-08 | Cnt Spolka Z O.O. | Superhydrophobic coating |
WO2005122676A2 (en) * | 2004-06-11 | 2005-12-29 | Universidad De Sevilla | Bubble-generating device for reducing friction on the hull of a boat |
WO2005122676A3 (en) * | 2004-06-11 | 2006-02-02 | Univ Sevilla | Bubble-generating device for reducing friction on the hull of a boat |
JP2013052718A (en) * | 2011-09-01 | 2013-03-21 | Zuei-Ling Lin | Water flow resistance reducing apparatus |
JP2018094925A (en) * | 2012-03-03 | 2018-06-21 | バーデン−ビュルッテンベルク シュティフトゥング ゲーゲーエムベーハー | Gas-containing surface coating, arrangement, use |
US10625833B2 (en) | 2012-03-03 | 2020-04-21 | Baden-Württemberg Stiftung Ggmbh | Gas-containing surface cover, arrangement, and use |
US11584490B2 (en) | 2012-03-03 | 2023-02-21 | Baden-Württemberg Stiftung Ggmbh | Gas-containing surface cover, arrangement, and use |
US12000417B2 (en) | 2018-04-17 | 2024-06-04 | Baden-Württemberg Stiftung Ggmbh | Structured gas-containing surfaces |
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