WO1985003901A1 - The preparation of ultra high molecular weight polyethylene morphologies of totally fused particles with superior mechanical performance - Google Patents

The preparation of ultra high molecular weight polyethylene morphologies of totally fused particles with superior mechanical performance Download PDF

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Publication number
WO1985003901A1
WO1985003901A1 PCT/US1985/000344 US8500344W WO8503901A1 WO 1985003901 A1 WO1985003901 A1 WO 1985003901A1 US 8500344 W US8500344 W US 8500344W WO 8503901 A1 WO8503901 A1 WO 8503901A1
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WO
WIPO (PCT)
Prior art keywords
stock
memory
morphology
granular
ultra
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US1985/000344
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English (en)
French (fr)
Inventor
Anagnostis E. Zachariades
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to DE8585901692T priority Critical patent/DE3586117D1/de
Priority to AT85901692T priority patent/ATE76604T1/de
Publication of WO1985003901A1 publication Critical patent/WO1985003901A1/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C43/00—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
    • B29C43/003—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor characterised by the choice of material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C43/00—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
    • B29C43/32—Component parts, details or accessories; Auxiliary operations
    • B29C43/52—Heating or cooling
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C55/00—Shaping by stretching, e.g. drawing through a die; Apparatus therefor
    • B29C55/02—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets
    • B29C55/18—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets by squeezing between surfaces, e.g. rollers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C67/00—Shaping techniques not covered by groups B29C39/00 - B29C65/00, B29C70/00 or B29C73/00
    • B29C67/24—Shaping techniques not covered by groups B29C39/00 - B29C65/00, B29C70/00 or B29C73/00 characterised by the choice of material
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
    • A61F2210/00—Particular material properties of prostheses classified in groups A61F2/00 - A61F2/26 or A61F2/82 or A61F9/00 or A61F11/00 or subgroups thereof
    • A61F2210/0014—Particular material properties of prostheses classified in groups A61F2/00 - A61F2/26 or A61F2/82 or A61F9/00 or A61F11/00 or subgroups thereof using shape memory or superelastic materials, e.g. nitinol
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2023/00—Use of polyalkenes or derivatives thereof as moulding material
    • B29K2023/04—Polymers of ethylene
    • B29K2023/06—PE, i.e. polyethylene
    • B29K2023/0658—PE, i.e. polyethylene characterised by its molecular weight
    • B29K2023/0683—UHMWPE, i.e. ultra high molecular weight polyethylene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
    • B29K2105/25—Solid
    • B29K2105/251—Particles, powder or granules
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2995/00—Properties of moulding materials, reinforcements, fillers, preformed parts or moulds
    • B29K2995/0037—Other properties
    • B29K2995/0041—Crystalline
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2995/00—Properties of moulding materials, reinforcements, fillers, preformed parts or moulds
    • B29K2995/0037—Other properties
    • B29K2995/0045—Isotropic
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2995/00—Properties of moulding materials, reinforcements, fillers, preformed parts or moulds
    • B29K2995/0037—Other properties
    • B29K2995/0088—Molecular weight
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2031/00—Other particular articles
    • B29L2031/753—Medical equipment; Accessories therefor
    • B29L2031/7532—Artificial members, protheses
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S528/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S528/92—Polymers useful for replacing hard animal tissues, e.g. dentures, bones
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913—Rod, strand, filament or fiber

Definitions

  • This invention relates to a novel type of ultra-
  • the nominal weight-average molecular weight is several 27 million, usually from three to six million.
  • the polymer 19 400,000, has an extremely high molecular weight— ypically 0 2 to 6 million—and is intractable.
  • the polymer is 1 supplied as fine powder and is processed into various 2 profiles using " compression molding and ram extrusion
  • Radio-frequency heating of such polymers can * occur by incorporating in the polymer agents such as 6 Frequon (a trademark of the Phillips Chemical Co.) which ' are sensitive to radio frequency.
  • 6 Frequon a trademark of the Phillips Chemical Co.
  • This invention provides the complete fusion of 5 powder particles of ultra-high molecular weight poly- 6 ethylene in an hitherto unexplored temperature range, 7 resulting in a homogeneously melt crystallized morphology 8 with no grain memory of the powder particles and the 9 preparation of an anisotropic morphology with significant- 0 y enhanced modulus and superior elastic response perform- 1 ance by solid state deformation techniques.
  • the present invention provides a homogeneously 3 melt-crystallized morphology of ultra-high molecular poly- 4 ethylene obtained by complete fusion of the powder 5 particles of the raw material in a temperature range in 6 which the powder particles fuse completely and have no 7 memory of their granular structure prior to melting and 8 during the inadequate melting which is practiced in 9 currently used processes.
  • the mechanical performance of 0 such homogeneous melt crystallized morphologies of ultra- 1 high molecular weight polyethylene are superior to the 2 properties of commercially available products of ultra- 3 h gh molecular weight polyethylene.
  • This invention provides also the preparation of an 5 anisotropic morphology of ultra-high molecular weight 6 polyethylene with significantly enhanced modulus and 7 superior elastic response performance by the solid state 1 deformation techniques of drawing and extrusion through an
  • the prepara- ° tion of the anisotropic morphology of ultra-high olec- ular-weight polyethylene comprises the steps of (1) pre- paring initially a uniform semicrystalline morphology by * * compression-molding an ultra-high molecular-weight poly- " ethylene melt in a temperature range in which the melt has 1 no memory of the granular nature of the original powder, 2 and (2) solid-state deforming the so-produced uniformly 3 melt-crystallized morphology by conventional drawing or by 4 extruding it through an extrusion rolling die at a 5 temperature preferably near but below its crystalline 6 melting point and at a deformation ratio of 5-8.
  • the 7 deformation ratio is determined by the displacement of 8 printed markers or fiducial marks on the surface of the drawn or extruded specimen or the cross-sectional areas of the samples before and after drawing or extrusion.
  • Fig. 1 is a graph showing the stress-elongation behavior at ambient temperature of two compression-molded specimens of ultra-high molecular weight polyethylene, one molded at 180°C and the other according to the present invention, at 320OC.
  • Fig. 2 is a similar graph contrasting the stress- strain behavior of three specimens of five-times-drawn ultra-high molecular weight polyethylene obtained by s&lid-state deforming of compression molded specimens at 180OC, .and 210°C, and, according to the present - invention, at 320°C.
  • • ⁇ Fig. 3 is a similar drawing, showing the stress-
  • FIG. 4 is a diagrammatic cross-sectional view of a flexor tendon and related parts, employing the principles 0 of this invention, indicating the tendon-bone and the 1 muscle-tendon functions and the body of the tendon which was truncated to insert and suture the artificial tendon of ultra-high molecular weight polyethylene of this invention.
  • An ultra-high-molecular-weight polyethylene melt in which the powder particles fuse completely and lose memory of their granular structure in the original powder stock, is achieved by heating the powder stock or partially fused, melt-crystallized morphology having granular memory — in the absence of oxygen to avoid degradation, e.g., under nitrogen — in a temperature - range above 220°C. and below 340OC. the latter being the temperature at which excessive decomposition occurs under nitrogen.
  • the five-times-drawn morphologies from specimens - compression molded at 320°C. have a Young modulus of 5-6 GPa,and in cyclic load tests under 40-45 MPa for testing U to 1 hour they deform practically elastically (see Fig. 3). on the contrary, as also shown in Fig. 3, the five- times-drawn morphologies from specimens compression molded at 180°C have a low Young modulus (0.7-0.8 GPa) and in cyclic load tests under the same conditions undergo a maximum residual elongation greater than 3%.
  • Artificial tendons made according to the present invention exhibit very satisfactory anastomosis after an observation period of six weeks, and they replicate the properties of the natural tendons. For example, they have been found to replicate the properties of the tendon (Flexor Hollucis * longus) of a dog weighing approximately 70 pounds, as demonstrated by the complete mobility of the 3 0 g during the six-week testing period.
  • a lateral view of a flexor tendon indicating the tendon-bone and the musculo-tendon junctions and the body of the tendon which was truncated to insert and suture the artificial tendon of ultra-high molecular weight polyethylene is shown in Fig. 4.
  • the present invention also includes within its scope the use of the isotropic (the initially homogeneous melt-crystallized morphology, prepared from either a raw powder stock or a partially fused me ' lt-crystallized stock - with granular memory, prior to drawing or extrusion) and anisotropic ultra-high-molecular-weight polyethylene morphologies in other biomedical applications, e.g., ligament prostheses in which a high elastic recovery and a small percent strain under high load requirements are necessary.
  • isotropic the initially homogeneous melt-crystallized morphology, prepared from either a raw powder stock or a partially fused me ' lt-crystallized stock - with granular memory, prior to drawing or extrusion
  • anisotropic ultra-high-molecular-weight polyethylene morphologies in other biomedical applications, e.g., ligament prostheses in which a high elastic recovery and a small percent strain under high load requirements are necessary.
  • the homogeneity of the morphologies in this invention versus the partially fused * morphologies used to date is important in eliminating the fatigue failure observed with orthopedic prostheses which are.fab icated from partially fused morphologies and also in the fabrication of orthopedic prostheses with abrasion resistance uses such as joints and intervertebral disks.
  • Other applications on which the homogeneity of the morphologies in this invention is important, is in the fabrication of industrial parts with abrasion resistance uses such as bearings, sprockets, gaskets, ball valve seats, conveyor belt parts and other industrial parts currently made from metal.

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Casting Or Compression Moulding Of Plastics Or The Like (AREA)
  • Materials For Medical Uses (AREA)
  • Prostheses (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
PCT/US1985/000344 1984-03-06 1985-03-05 The preparation of ultra high molecular weight polyethylene morphologies of totally fused particles with superior mechanical performance Ceased WO1985003901A1 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
DE8585901692T DE3586117D1 (de) 1984-03-06 1985-03-05 Herstellung von polyethylenmorphologien total verschmolzener teilchen ultrahohen molekulargewichts und mit ausgezeichneter mechanischer leistung.
AT85901692T ATE76604T1 (de) 1984-03-06 1985-03-05 Herstellung von polyethylenmorphologien total verschmolzener teilchen ultrahohen molekulargewichts und mit ausgezeichneter mechanischer leistung.

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US58679684A 1984-03-06 1984-03-06
US586,796 1984-03-06
US667,020 1984-11-01
US06/667,020 US4587163A (en) 1984-03-06 1984-11-01 Preparation of ultra high molecular weight polyethylene morphologies of totally fused particles with superior mechanical performance

Publications (1)

Publication Number Publication Date
WO1985003901A1 true WO1985003901A1 (en) 1985-09-12

Family

ID=27079813

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US1985/000344 Ceased WO1985003901A1 (en) 1984-03-06 1985-03-05 The preparation of ultra high molecular weight polyethylene morphologies of totally fused particles with superior mechanical performance

Country Status (6)

Country Link
US (1) US4587163A (https=)
EP (1) EP0177552B1 (https=)
AT (1) ATE76604T1 (https=)
AU (1) AU4067085A (https=)
DE (1) DE3586117D1 (https=)
WO (1) WO1985003901A1 (https=)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0223252A3 (en) * 1985-11-21 1987-12-09 Nippon Petrochemicals Co., Ltd. Method for preparing molded articles of ultra-high molecular weight polyethylene
EP0341033A3 (en) * 1988-05-04 1990-12-12 United Kingdom Atomic Energy Authority An extrusion process and apparatus therefor
WO1997029895A1 (en) * 1996-02-16 1997-08-21 New York Society For The Ruptured And Crippled Maintaining The Hospital For Special Surgery Process for producing ultra-high molecular weight low modulus polyethylene shaped articles

Families Citing this family (46)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6190705A (ja) * 1984-10-09 1986-05-08 Terumo Corp 中空糸膜の製造方法
FR2578780B1 (fr) * 1985-03-12 1987-08-14 Commissariat Energie Atomique Piece en polyolefine de haut poids moleculaire, notamment pour prothese articulaire, et son procede de fabrication par forgeage en matrice fermee
US4731084A (en) * 1986-03-14 1988-03-15 Richards Medical Company Prosthetic ligament
US5049347A (en) * 1988-11-22 1991-09-17 The University Of Pittsburgh Method for producing doubly oriented polymers
ATE70004T1 (de) * 1986-10-24 1991-12-15 Kraftanlagen Ag Verfahren und vorrichtung zur herstellung von platten, bahnen, plattenaehnlichen formteilen oder profilen aus kunststoffen.
GB2207436B (en) * 1987-07-24 1991-07-24 Nat Research And Dev Corp The Solid phase deformation process
FR2624028B1 (fr) * 1987-12-04 1992-09-11 Rossignol Sa Procede pour ameliorer les proprietes de glissement d'une semelle de ski en polyethylene haute densite en poudre, et de tres haut poids moleculaire
US5478906A (en) * 1988-12-02 1995-12-26 E. I. Du Pont De Nemours And Company Ultrahigh molecular weight linear polyethylene and articles thereof
US5030402A (en) * 1989-03-17 1991-07-09 Zachariades Anagnostis E Process for producing a new class of ultra-high-molecular-weight polyethylene orthopaedic prostheses with enhanced mechanical properties
US5037928A (en) * 1989-10-24 1991-08-06 E. I. Du Pont De Nemours And Company Process of manufacturing ultrahigh molecular weight linear polyethylene shaped articles
US5204045A (en) * 1990-06-15 1993-04-20 Symplastics Limited Process for extruding polymer shapes with smooth, unbroken surface
US5210130A (en) * 1990-08-07 1993-05-11 E. I. Du Pont De Nemours And Company Homogeneous, high modulus ultrahigh molecular weight polyethylene composites and processes for the preparation thereof
US5352732A (en) * 1990-08-07 1994-10-04 E. I. Du Pont De Nemours And Company Homogeneous, high modulus ultrahigh molecular weight polyethylene composites and processes for the preparation thereof
EP0499917B1 (en) * 1991-02-21 1994-08-24 Synthes AG, Chur High-strength, high-modulus, compound-filament or compound-film implant and method for producing it
CA2114101A1 (en) * 1991-07-26 1993-02-18 Edward George Howard Jr Homogeneous high modulus ultrahigh molecular weight polyethylene composites and processes for the preparation thereof
AT397207B (de) * 1991-09-26 1994-02-25 Isosport Verbundbauteile Verfahren zur herstellung eines bandförmigen skibelagsmaterials aus ultrahochmolekularem polyethylen und skibelag
DE4210351A1 (de) * 1992-03-30 1993-10-07 Hoechst Ag Verfahren zum Pelletieren von ultrahochmolekularem Polyethylen
US5466530A (en) * 1993-01-21 1995-11-14 England; Garry L. Biocompatible components fabricated from a substantially consolidated stock of material
US5830396A (en) * 1993-01-21 1998-11-03 Biomet, Inc. Method for processing thermoplastics, thermosets and elastomers
US5414049A (en) * 1993-06-01 1995-05-09 Howmedica Inc. Non-oxidizing polymeric medical implant
USRE44762E1 (en) 1994-09-21 2014-02-11 Bmg Incorporated Ultra high molecular weight polyethylene molded article for artificial joints and method of preparing the same
CA2166450C (en) * 1995-01-20 2008-03-25 Ronald Salovey Chemically crosslinked ultrahigh molecular weight polyethylene for artificial human joints
GB9522477D0 (en) * 1995-11-02 1996-01-03 Howmedica Method of improving the wear quality of ultra-high molecular weight polyethylene
US8865788B2 (en) * 1996-02-13 2014-10-21 The General Hospital Corporation Radiation and melt treated ultra high molecular weight polyethylene prosthetic devices
US8563623B2 (en) * 1996-02-13 2013-10-22 The General Hospital Corporation Radiation melt treated ultra high molecular weight polyethylene prosthetic devices
CA2260241C (en) * 1996-07-09 2010-09-14 The Orthopaedic Hospital Crosslinking of polyethylene for low wear using radiation and thermal treatments
NL1005294C2 (nl) 1997-02-17 1998-08-18 Univ Eindhoven Tech Werkwijze voor het verwerken van polyetheen met een zeer hoog molecuulgewicht (UHMWPE) van ten minste 400.000 door verwarmen onder verhoogde druk en daarna afkoelen, aldus verkregen UHMWPE en een biomedische toepassing hiervan.
CA2370208C (en) * 1999-04-21 2008-09-09 Howmedica Osteonics Corp. Selectively cross-linked polyethylene orthopedic devices
US6121413A (en) * 1999-04-30 2000-09-19 Burstein; Albert H. Heat treatment of ultra high molecular weight polyethylene
US6395799B1 (en) 2000-02-21 2002-05-28 Smith & Nephew, Inc. Electromagnetic and mechanical wave energy treatments of UHMWPE
EP1463457A4 (en) * 2002-01-04 2006-12-20 Massachusetts Gen Hospital RETICULATED POLYETHYLENE WITH A HIGH MODULE AND REDUCED CONCENTRATION IN RESIDUAL FREE RADICALS DEVELOPED UNDER THE FUSION POINT
JP4384496B2 (ja) * 2002-01-29 2009-12-16 プラス オーソペディクス アーゲー 超高分子ポリエチレンの焼結方法
CA2429930C (en) 2002-06-06 2008-10-14 Howmedica Osteonics Corp. Sequentially cross-linked polyethylene
US7547405B2 (en) 2004-10-07 2009-06-16 Biomet Manufacturing Corp. Solid state deformation processing of crosslinked high molecular weight polymeric materials
US7462318B2 (en) * 2004-10-07 2008-12-09 Biomet Manufacturing Corp. Crosslinked polymeric material with enhanced strength and process for manufacturing
US8262976B2 (en) 2004-10-07 2012-09-11 Biomet Manufacturing Corp. Solid state deformation processing of crosslinked high molecular weight polymeric materials
US7344672B2 (en) 2004-10-07 2008-03-18 Biomet Manufacturing Corp. Solid state deformation processing of crosslinked high molecular weight polymeric materials
US7538379B1 (en) * 2005-06-15 2009-05-26 Actel Corporation Non-volatile two-transistor programmable logic cell and array layout
US8871131B2 (en) * 2006-10-30 2014-10-28 Smith And Nephew Orthopaedics Ag Processes comprising crosslinking polyethylene or using crosslinked polyethylene
US8641959B2 (en) 2007-07-27 2014-02-04 Biomet Manufacturing, Llc Antioxidant doping of crosslinked polymers to form non-eluting bearing components
US8133436B2 (en) 2008-08-05 2012-03-13 Howmedica Osteonics Corp. Polyethylene cross-linked with an anthocyanin
CA2741296A1 (en) * 2008-10-23 2010-04-29 Polteco Inc. Abrasion resistant cords and ropes
US8883302B2 (en) * 2008-10-23 2014-11-11 Polteco, Inc. Abrasion resistant cords and ropes
EP2518208A3 (en) 2011-04-27 2015-02-11 Polteco Inc. Abrasion resistant cords and ropes
CN104884530B (zh) 2012-12-13 2018-08-14 瑞来斯实业公司 易加工的超高分子量聚乙烯及其制备方法
US9586370B2 (en) 2013-08-15 2017-03-07 Biomet Manufacturing, Llc Method for making ultra high molecular weight polyethylene

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4055862A (en) * 1976-01-23 1977-11-01 Zimmer Usa, Inc. Human body implant of graphitic carbon fiber reinforced ultra-high molecular weight polyethylene
US4116892A (en) * 1975-03-31 1978-09-26 Biax-Fiberfilm Corporation Process for stretching incremental portions of an orientable thermoplastic substrate and product thereof
US4164531A (en) * 1975-01-13 1979-08-14 Mitsui Petrochemical Industries, Ltd. Injection molding of ultra high molecular weight polyethylene
US4489033A (en) * 1981-04-14 1984-12-18 Mitsui Petrochemical Industries Process for injection compression molding

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4246390A (en) * 1980-04-21 1981-01-20 American Hoechst Corporation Molding powder of ultra-high molecular weight polyethylene and process for its preparation
ZA813915B (en) * 1980-06-25 1982-06-30 Hoechst Co American Injection molding and extrusion of ultra-high molecular weight polyethylene

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4164531A (en) * 1975-01-13 1979-08-14 Mitsui Petrochemical Industries, Ltd. Injection molding of ultra high molecular weight polyethylene
US4116892A (en) * 1975-03-31 1978-09-26 Biax-Fiberfilm Corporation Process for stretching incremental portions of an orientable thermoplastic substrate and product thereof
US4055862A (en) * 1976-01-23 1977-11-01 Zimmer Usa, Inc. Human body implant of graphitic carbon fiber reinforced ultra-high molecular weight polyethylene
US4489033A (en) * 1981-04-14 1984-12-18 Mitsui Petrochemical Industries Process for injection compression molding

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of EP0177552A4 *

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0223252A3 (en) * 1985-11-21 1987-12-09 Nippon Petrochemicals Co., Ltd. Method for preparing molded articles of ultra-high molecular weight polyethylene
EP0341033A3 (en) * 1988-05-04 1990-12-12 United Kingdom Atomic Energy Authority An extrusion process and apparatus therefor
WO1997029895A1 (en) * 1996-02-16 1997-08-21 New York Society For The Ruptured And Crippled Maintaining The Hospital For Special Surgery Process for producing ultra-high molecular weight low modulus polyethylene shaped articles
US5721334A (en) * 1996-02-16 1998-02-24 Newyork Society For The Ruptured And Crippled Maintaining The Hospital For Special Surgery Process for producing ultra-high molecular weight low modulus polyethylene shaped articles via controlled pressure and temperature and compositions and articles produced therefrom

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ATE76604T1 (de) 1992-06-15
EP0177552A4 (en) 1987-11-30
US4587163A (en) 1986-05-06
US4587163B1 (https=) 1990-04-03
EP0177552A1 (en) 1986-04-16
DE3586117D1 (de) 1992-07-02
EP0177552B1 (en) 1992-05-27
AU4067085A (en) 1985-09-24

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