WO1985000590A1 - Making hot pressed silicon nitride by use of low density reaction bonded body - Google Patents
Making hot pressed silicon nitride by use of low density reaction bonded body Download PDFInfo
- Publication number
- WO1985000590A1 WO1985000590A1 PCT/US1983/001111 US8301111W WO8500590A1 WO 1985000590 A1 WO1985000590 A1 WO 1985000590A1 US 8301111 W US8301111 W US 8301111W WO 8500590 A1 WO8500590 A1 WO 8500590A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- plates
- cavity
- dimension
- wall
- hot pressing
- Prior art date
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Classifications
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/515—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics
- C04B35/58—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on borides, nitrides, i.e. nitrides, oxynitrides, carbonitrides or oxycarbonitrides or silicides
- C04B35/584—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on borides, nitrides, i.e. nitrides, oxynitrides, carbonitrides or oxycarbonitrides or silicides based on silicon nitride
- C04B35/593—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on borides, nitrides, i.e. nitrides, oxynitrides, carbonitrides or oxycarbonitrides or silicides based on silicon nitride obtained by pressure sintering
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/64—Burning or sintering processes
- C04B35/645—Pressure sintering
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/64—Burning or sintering processes
- C04B35/645—Pressure sintering
- C04B35/6455—Hot isostatic pressing
Definitions
- This invention relates to the technology of hot pressing ceramics, particularly silicon nitride.
- This invention is directed to an improvement in the art of making hot pressed silicon nitride from silicon or silicon nitride powder as a starting material.
- silicon powder When starting with silicon powder, such powder is first subjected to a reactive nitriding gas to form a mixed phase polycrystalline silicon nitride rigid body, the body being then hot pressed.
- a reactive nitriding gas to form a mixed phase polycrystalline silicon nitride rigid body, the body being then hot pressed.
- agglomerate the powder materials (a) by cold compacting or forming into a powder preform as an early stage in the process before or without nitriding (see U.S. patent 3,839,540), (b) nitriding without compaction (see U.S. patent application Serial No. 448,889, commonly assigned to the assignee herein), and (c) by hot pressing without prior compaction or nitriding as the last stage in the process with S13N4.
- the preform or resulting cake presents a severe height to width ratio requiring an unusually long hot pressing stroke to obtain full densification of the material.
- the cake or preform can have a density of .9-2.5 gm/cm 3 and must be converted to a density of 3.25 gm/cm 3 or above.
- a long pressing stroke particularly under the high temperature and pressing conditions associated with hot pressing, induces significant side wall drag, a friction impediment at the interface between the sides of the cake or billet and the interior wall of the pressing cavity.
- the side wall drag in conjunction with the thermal and pressure gradients within the material, produces "material transport," leading to a dishing effect of the resulting pressed product which can be quite pronounced.
- the invention is a method of fully densifying a plurality of preformed ceramic plates by axial compression of the plates along a wall defining a cylindrical cavity.
- the series of preformed ceramic plates are stacked along the wall with the smallest dimension of the plates being aligned with the axis of the cavity, each plate having a ratio of the smallest dimension to largest dimension in the range of 1:3 to 1:40 and having the largest dimension less than the lateral dimension of the cavity, to leave an annular space between the plates and wall.
- a pseudo isostatic pressing medium is placed about the plates to fill the space when stacked in the cavity.
- the stacked series of plates are hot pressed with said pressing medium filling said space, the hot pressing being carried out with sufficient temperature and pressure to convert said plates into billets with substantially full density.
- Preforming of the plates can be accomplished in a number of ways, including the following: (1) compacting a mixture of S13N4 and densification additives under pressure, (2) preheating a mixture of Si3N 4 and densification additives in a forming crucible without pressure, (3) compacting a mixture of silicon metal powder and densification additives and then nitriding the mixture in a suitable forming dish, and (4) nitriding an uncompacted mixture of silicon metal powder and densification additives in a suitable forming dish.
- the pseudo isostatic pressing medium is selected from the group comprising boron nitride powder, flake graphite, a powder mixture of silicon nitride and boron nitride, ground borosilicate glass, and graphite foil.
- the annular space is preferably 1/8-1/64 inch taken along a radius of the cavity.
- the pseudo isostatic pressing medium can be placed about the billets by one of the following modes: casting, vibration, slurry coating, or implantation.
- the plates preferably have a density in the overall range of .8-2.4 gm/cm 3 .
- the preformed plates are prepared by cold compacting a powder mixture of silicon nitride and pressing aids, each preform having a density, prior to hot pressing, of 1.6-1.8 gm/cm 3 .
- the preformed plates are stacked in groups of about five, each group separated from the other by a rigid, inert spacer (such as graphite) which has a lateral dimension snuggly fitting across the cylindrical cavity; the space is preferably filled with boron nitride powder.
- the billets are prepared by cold pressing Si metal and nitriding, preferably having a density of 2.0-2.3 gm/cc.
- the plates are separated by a parting agent such as BN or grafoil sheet and placed one on top of the other to a height that upon hot compression will occupy available effective hot pressing zone.
- No rigid spacers such as graphite are used.
- the billets are advantageously prepared by heating an uncompacted quantity of silicon and fluxing agents in a nitriding atmosphere to fully react the mixture and form a reaction bonded cake; the cakes
- O PI HO each have a density of 1.1-1.8 gm/cm 3 .
- the reaction bonded cakes are wrapped with several plys of graphite foil which are effective to fill said space.
- Figure 1 is a schematic cross sectional view of a hot pressing apparatus with a stacked series of preformed plates ready for hot pressing in accordance with the principles of this invention
- Figures 2 and 3 are views similar to Figure 1 for Q hot pressing in accordance with alternative modes.
- a mixture of powder silicon, S1O2 as an oxide film on the silicon powder, and at least one reactive oxygen carrying agent is prepared.
- the reactive oxygen carrying agent is defined herein to mean a powder 0 ingredient that is effective to form second phase crystallites, particularly oxynitrides and/or appropriate silicates, when reacted with the silicon under a heated nitrogen atmosphere or which develop during the hot pressing operation itself.
- the oxygen carrying agents can 5 function as a densification aid and can be advantageously selected from the group consisting of Y2°3- MgO, Ce0 2' Zr ⁇ 2, Hf ⁇ 2, as well as other rare earths.
- a uniform powder mixture is prepared with 2000 grams of 0 silicon (86.6 weight percent of the mixture), 278 grams of Y2O3 (12 weight percent of the mixture and 13.9 weight percent of the silicon), and 32 grams of AI2O3 (1.4 weight percent of the mixture and 1.6 weight percent of the silicon).
- the usable range for the oxygen carrying agents is .4-2.3 molar percent of the mixture, and .42-2.4 molar percent of the silicon.
- the normal permitted impurities and particle size is detailed further in copending U.S. application Serial No. 444,251, commonly assigned to the assignee herein, the disclosure of which is incorporated herein by reference.
- the mixture is comminuted and blended by being charged into an inert milling jar along with grinding media in the form of Burundum cylinders (85% AI2O3, 11% Si ⁇ 2 2% MgO, 1.2% CaO, .8% of the combination of Ti0 2 , Fe2 ⁇ 33, Na2 ⁇ and K2O) .
- the mixture is milled for a period of about 48 hours at 64 rpm and then separated from the media by use of a #10 mesh screen; this milling is carried out dry.
- the resulting milled mixture will have at least 50% by weight thereof with an average particle size of about 4 microns and 90% by weight having a particle size of less than 23 microns.
- the milled mixture is then poured onto a generally flat refractory dish or plate to be used as a carrier into the furnace.
- the dish may have a rim of sufficient height only to prevent the material from spilling over the edge of the plate.
- the diameter or lateral dimension of the plate should be sized so that it forms a preformed plate or cake (see Figure 1) having a diameter (16) which is less than the diameter (18) of the cylindrical cavity (14) to be later used for hot pressing. This difference is to allow for an annular space (15) about the preforms (21) which is filled by an isostatic pressing medium.
- the ratio of the smallest dimension (17) to the largest dimension (16) of each billet (21) to be formed should be in the range of 1:3 to 1:40. 5
- the powder mixture is distributed generally uniformly across the dish to have a thickness in the range of 1-2 inches.
- Other forms of carriers may be employed to transfer the powder in a desired configuration to the heating furnace. For example, refractory type furnace
- furniture in the form of cylinders or cubicles may be employed, or other polygons having a general cross-sectional configuration similar to that which is desired in the final product and similar to the cross-section of the hot pressing cylinder.
- the furnace
- the density of the loose, uncompacted powder on such carrier or furnace furniture can be in the range of .4-1.2 gm/cm 3 , preferably less than 1.0 gm/cm 3 .
- the density will be described in detail below.
- 2Q be a function of the particle size and particle size distribution of the silicon powder.
- the density will be about .75 gm/cm 3 .
- the loose mixture is then heated in a suitable nitriding atmosphere to produce a silicon nitride comprising preform.
- the furnace is preferably evacuated
- the furnace is then filled with a gaseous mixture consisting of 97% by weight nitrogen, 3% hydrogen, at a pressure of about 2.7 psig.
- a gaseous mixture consisting of 97% by weight nitrogen, 3% hydrogen, at a pressure of about 2.7 psig.
- the nitriding sequence is carried out for a period of about 72 hours, and in all cases no longer than
- the nitrided preformed plate will preferably have a density of 1.1-1.8 gm/cm 3 and have silicon nitride (at least 60% by weight of which is in the preferred alpha phase), along with 3-15% silicon yttrium oxynitrides. 2. Stacking
- 35 plates preferably are coated with a thin parting agent
- OMPI such as boron nitride or grafoil, neither of which acts as a rigid spacer.
- the number of plates can preferably be 10-12 in ..he stacking being without intervening spacers.
- the apparatus is of a construction that has a graphite cylinder 11 defining the interior side wall 14 and graphite plungers 12 and 13, at least one of which is moved axially to provide a pressing force 23.
- the preformed plates can have a density of .8-2.0 gm/cm 3 , preferably 1.1-1.8 gm/cm 3 for the reaction bonded body of S13N4, and a ratio of the smallest dimension 17 to the largest dimension 16 in the range of 1:3 to 1:40.
- the largest dimension must be less than the lateral dimension
- the space preferably has a dimension of 1/8-1/64 inch along a radius
- the annular space 15 is filled with a pseudo isostatic pressing medium preferably selected from the group consisting of boron nitride powder, flake graphite, a powder mixture of silicon nitride and boron nitride
- the isostatic media must have a compression ratio higher than that experienced by the preformed plates so as not to interfere with the densification process thereof.
- the stacked preformed plates, with the isostatic pressing medium in place, are then hot pressed to produce silicon nitride comprising billets of required dimension 5 and density.
- the heating and pressing is carried out preferably in increments:
- 10 may be increased up to 2000 or 3000 psi if desired to predensify the nitrided plates.
- the resulting object will consist essentially of beta silicon nitride and 2.9-14.4% by weight silicon oxynit ides and a small amount of silicate glass, presumably an aluminum containing silicate. 5_ Alternate Modes
- the preferred mode may simply be varied by cold compacting the silicon metal mixture by use of compacting foces of above 1500 psi to form a low density preformed plate (density of about 1.4 gm/cm 3 ).
- the preforms are then processed as in the preferred mode by nitriding and
- the plates are coated with boron nitride as a separation means.
- the pseudo isostatic pressing medium is preferably selected to be a powder mixture of 50% silicon nitride and 50% boron nitride. The media is filled into the space 15. Again, no rigid spacers between plates or groups of plates is needed.
- the preforms may also be made by mixing silicon nitride powder with densification aids, cold compacting or preheating the mixture into a plate having the required thickness (38) to width (39) ratio in the range of 1:3 to 1:40. If compacted, the pressure of about 1500 psi is employed to provide a density of 1.6-1.8 gm/cm 3 in such plates. If preheated, a temperature of about 2200-4500°F for about 4-40 hours in an inert atmosphere is utilized.
- the billets may be stacked in groups of five (group 22 having members 24-28 and group 23 having members 29-33), separated longitudinally by full size rigid graphite spacers 34 (having a diameter 50), and separated laterally from wall 14 by the annular spaces 35 and 36.
- the spaces have a radial dimension 37 of 1/8-1/16 inch and are filled with boron nitride powder.
- Both pistons 13 and 12 are moved to impart biaxial compression to the stacked billets while employing the heating sequence of the preferred embodiment, except that the temperature is raised to 1750°C. If more than 10 plates are desired to be hot pressed simultaneously, they should be arranged within the cavity in groups which decrease in numbers, the more remote they are from the minimum zone of movement 24.
- a group of plates 43 is placed on a rigid graphite member 44 and contains five billets; the group is in the zone of minimum movement.
- Group of plates 42 contains three billets, and groups 41 and 40, respectively, contain two and one billet, and are located more remote from the minimum zone of movement. These groups are separated by increasingly thicker rigid
- the spacers have a diameter effective to snuggly fit the interior of the cylindrical wall 50.
- the space 15 is filled by plys of graphite foil.
- One of the great advantages of the inventive method is the ability to reuse the graphite hot pressing apparatus elements, uncontaminated by chemical reactions as a result of hot pressing.
- the apparatus has been used 20 times or more following this method without special reconditioning.
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Ceramic Products (AREA)
- Laminated Bodies (AREA)
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE8383902611T DE3377984D1 (en) | 1983-07-19 | 1983-07-19 | Making hot pressed silicon nitride by use of low density reaction bonded body |
EP19830902611 EP0150178B1 (de) | 1983-07-19 | 1983-07-19 | Herstellung von heissgepresstem siliciumnitrid aus einem reaktionsgebundenen körper niedriger dichte |
PCT/US1983/001111 WO1985000590A1 (en) | 1983-07-19 | 1983-07-19 | Making hot pressed silicon nitride by use of low density reaction bonded body |
BR8307737A BR8307737A (pt) | 1983-07-19 | 1983-07-19 | Preparacao de nitreto de silicio prensado a quente usando-se corpo de baixa densidade aglutinado por reacao |
AU18298/83A AU563498B2 (en) | 1983-07-19 | 1983-07-19 | Making hot pressed silicon nitride by use of low density reaction bonded body |
JP50267683A JPS60501850A (ja) | 1983-07-19 | 1983-07-19 | 低密度反応接着体の使用によるホツトプレスした窒化ケイ素の製造 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/US1983/001111 WO1985000590A1 (en) | 1983-07-19 | 1983-07-19 | Making hot pressed silicon nitride by use of low density reaction bonded body |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1985000590A1 true WO1985000590A1 (en) | 1985-02-14 |
Family
ID=22175368
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US1983/001111 WO1985000590A1 (en) | 1983-07-19 | 1983-07-19 | Making hot pressed silicon nitride by use of low density reaction bonded body |
Country Status (6)
Country | Link |
---|---|
EP (1) | EP0150178B1 (de) |
JP (1) | JPS60501850A (de) |
AU (1) | AU563498B2 (de) |
BR (1) | BR8307737A (de) |
DE (1) | DE3377984D1 (de) |
WO (1) | WO1985000590A1 (de) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2227713A (en) * | 1988-12-15 | 1990-08-08 | Murata Manufacturing Co | Manufacturing ceramic laminated compact |
US5091212A (en) * | 1988-12-19 | 1992-02-25 | Murata Manufacturing Co., Ltd. | Method and apparatus for forming electrode on electronic component |
EP0492284A1 (de) * | 1990-12-21 | 1992-07-01 | W.R. Grace & Co.-Conn. | Verwendung von permeablen Materialien zur Verbesserung des Heisspressprozesses |
EP0591907A2 (de) * | 1992-10-09 | 1994-04-13 | Mtu Motoren- Und Turbinen-Union MàNchen Gmbh | Verfahren zur Herstellung von Blech- oder Keramikplatten |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19622074A1 (de) * | 1996-05-31 | 1997-12-04 | Kratz Josef Gmbh | Verfahren und Vorrichtung zur Vermessung von UV-Strahlung in Bräunungsgeräten |
Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3116137A (en) * | 1958-07-01 | 1963-12-31 | Avco Mfg Corp | Hot pressed material and method of producing the same |
US3311522A (en) * | 1963-02-25 | 1967-03-28 | Eastman Kodak Co | Process for bonding crystalline components and composite article produced thereby |
US3535132A (en) * | 1967-12-15 | 1970-10-20 | Atomic Energy Commission | Titanium carbide molten metal barrier and method of production |
US3589880A (en) * | 1966-11-22 | 1971-06-29 | Eastman Kodak Co | Plurality optical element pressing process |
US3887411A (en) * | 1973-12-20 | 1975-06-03 | Ford Motor Co | Making a triple density article of silicon nitride |
US4087500A (en) * | 1973-12-20 | 1978-05-02 | Ford Motor Company | Method of making a duo density silicon nitride article |
US4215088A (en) * | 1978-10-31 | 1980-07-29 | The United States Of America As Represented By The United States Department Of Energy | Method for fabricating boron carbide articles |
US4357286A (en) * | 1980-11-05 | 1982-11-02 | United Technologies Corporation | Method of making a graphite-glass composite laser mirror |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1364451A (en) * | 1970-11-05 | 1974-08-21 | Secr Defence | Hot pressing silicon nitride |
CA954262A (en) * | 1971-04-20 | 1974-09-10 | Frederick F. Lange | Method of compacting shaped powdered objects |
BE794199A (fr) * | 1972-01-19 | 1973-05-16 | Lucas Industries Ltd | Procede pour produire des composants en nitrure de silicium moules a chaud |
JPS5276206A (en) * | 1975-12-22 | 1977-06-27 | Fujitsu Ltd | Hot press process |
JPS5622678A (en) * | 1979-07-28 | 1981-03-03 | Ngk Spark Plug Co | Manufacture of high tenacity silicon nitride sintered body |
WO1984001370A1 (en) * | 1982-09-30 | 1984-04-12 | Ford Motor Co | Method of fabricating hot pressed silicon nitride billets |
-
1983
- 1983-07-19 BR BR8307737A patent/BR8307737A/pt unknown
- 1983-07-19 DE DE8383902611T patent/DE3377984D1/de not_active Expired
- 1983-07-19 EP EP19830902611 patent/EP0150178B1/de not_active Expired
- 1983-07-19 JP JP50267683A patent/JPS60501850A/ja active Pending
- 1983-07-19 WO PCT/US1983/001111 patent/WO1985000590A1/en active IP Right Grant
- 1983-07-19 AU AU18298/83A patent/AU563498B2/en not_active Ceased
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3116137A (en) * | 1958-07-01 | 1963-12-31 | Avco Mfg Corp | Hot pressed material and method of producing the same |
US3311522A (en) * | 1963-02-25 | 1967-03-28 | Eastman Kodak Co | Process for bonding crystalline components and composite article produced thereby |
US3589880A (en) * | 1966-11-22 | 1971-06-29 | Eastman Kodak Co | Plurality optical element pressing process |
US3535132A (en) * | 1967-12-15 | 1970-10-20 | Atomic Energy Commission | Titanium carbide molten metal barrier and method of production |
US3887411A (en) * | 1973-12-20 | 1975-06-03 | Ford Motor Co | Making a triple density article of silicon nitride |
US4087500A (en) * | 1973-12-20 | 1978-05-02 | Ford Motor Company | Method of making a duo density silicon nitride article |
US4215088A (en) * | 1978-10-31 | 1980-07-29 | The United States Of America As Represented By The United States Department Of Energy | Method for fabricating boron carbide articles |
US4357286A (en) * | 1980-11-05 | 1982-11-02 | United Technologies Corporation | Method of making a graphite-glass composite laser mirror |
Non-Patent Citations (2)
Title |
---|
Ceramic Bulletin, issued 01 June 1979, BECHER et al, Solid-State Bonding Of Si3N4, see pages 582, 583 and 586 * |
See also references of EP0150178A4 * |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2227713A (en) * | 1988-12-15 | 1990-08-08 | Murata Manufacturing Co | Manufacturing ceramic laminated compact |
GB2227713B (en) * | 1988-12-15 | 1993-01-27 | Murata Manufacturing Co | Method of manufacturing ceramic laminated compact |
US5091212A (en) * | 1988-12-19 | 1992-02-25 | Murata Manufacturing Co., Ltd. | Method and apparatus for forming electrode on electronic component |
EP0492284A1 (de) * | 1990-12-21 | 1992-07-01 | W.R. Grace & Co.-Conn. | Verwendung von permeablen Materialien zur Verbesserung des Heisspressprozesses |
EP0591907A2 (de) * | 1992-10-09 | 1994-04-13 | Mtu Motoren- Und Turbinen-Union MàNchen Gmbh | Verfahren zur Herstellung von Blech- oder Keramikplatten |
EP0591907A3 (en) * | 1992-10-09 | 1995-12-13 | Mtu Muenchen Gmbh | Process for preparing metal sheets or ceramic plates |
Also Published As
Publication number | Publication date |
---|---|
AU563498B2 (en) | 1987-07-09 |
EP0150178B1 (de) | 1988-09-14 |
DE3377984D1 (en) | 1988-10-20 |
BR8307737A (pt) | 1985-06-04 |
AU1829883A (en) | 1985-03-04 |
EP0150178A4 (de) | 1986-03-18 |
EP0150178A1 (de) | 1985-08-07 |
JPS60501850A (ja) | 1985-10-31 |
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