WO1984000536A1

WO1984000536A1 - Glass crystalline material and method for obtention thereof

Info

Publication number: WO1984000536A1
Application number: PCT/SU1982/000024
Authority: WO
Inventors: Nikolai Mikheevich Pavlushkin; Nikolai Pavlovich Kavanov; Pavel Dzhibraelovich Sarkisov; Vitaly Sergeevich Schukin; Ljudmila Alexeevna Orlova; Vladimir Mikhailovich Peshkov; Olga Nikolaevna Borisova; Galina Vladlenovna Podlesnaya; Leilya Safovna Khairetdinova
Original assignee: Mo Khim T I Im
Priority date: 1982-07-30
Filing date: 1982-07-30
Publication date: 1984-02-16
Also published as: FR2535708B1; GB2133787A; JPS60500250A; GB8407201D0; GB2133787B; FR2535708A1; DE3249530C2; DE3249530T1; AT390427B; ATA907882A; JPS6224365B2

Abstract

The glass crystalline material bears a granitoid semblance and in general consists of beta-wollastonite crystals, being in the shape of spherulites, at the following ratio in % by mass: SiO2 55.0-60.0, Al2O3 6.0-9.0, CaO 17.0-25.0, MgO 3.0-10.0, K2O 5.0-7.0, Na2O 1.0-2.0, F- 1.0-2.5; The method for obtaining the material provides for moulding the glass from a melt, which melt contains SiO2, Al2O3, CaO, MgO, Na2O, K2O, F-, its cooling down to the temperature which is 30-50oC lower than the temperature of the glass-transition, and performing the thermal treatment of the glass untill achieving its transformation into said glass crystalline material.

Description

THE UNITED KINGDOM AND THE WAY TO UNDERSTAND THE ELECTRICAL PRODUCTS These are the only available accessories and, moreover, the

Dρeddesτvuschi-- uτzοven τeχniκi Β οsnοve izvesτnyχ ρazρabοτοκ πο sοzdaniyu on οsnοve sτeκla deκορaτivnyχ maτeρialοv, imiτiρuιyatsiχ πρiροdnye gρaniτ and mρamορ, leshτ sποsοbnοsτ β- vοl- lasτοniτa κρisτallizοvaτsya in προtsesse τeρmοοbρabοτ- κi as igοlchaτyχ κρisτallοv, ρasτuschiχ οτ ποveρχ- nοsτi πzdely vnuτρ , perendipularity. The glass rises at a temperature of Ι400-Ι550 ° C depending on the composition of the glass. Οτs ^ ορmοvannye products τeρmοοbρabaτy- vayuτ πρi τemπeρaτuρe inτeρvale at 1000-1200 ° C, in ρe- zulτaτe chegο ποluchayuτ πliτy of sτeκlοκρisτallichesκο- gο shτeρiala with ποΕeρχnοsτyu, naποminayuschey mρamορ, Sοsτavy sτeκοl lezhaτ in ποle κρisτaldizatsii β -vοl- lasτοniτa. The glass material of the following composition is known (mass. ^)

ЗϊС ^ 40 - 75

^Α -_2 ° 3 3 - 35.

SaΟ 15 - 40, by the way, the sum of these components in 90 mass. #. It may also contain an oxidizing tin (Ue ^ Ο ^, SoΟ, Νсθ) in the amount of 0.05 - 4.0 mass ^. Sποsοb ποlucheniya yazdeliZ πz τaκοgο maτeρlala zaκlyuchaeτsya in tορmοvanii Products from ρasπlava sτeκla and further τeρmοοbρabοτκe sτeκlyannyχ products πο sleduκschemu ρezhimu: ποdem τemπeρaτuρy dο 700 ° C sο sκοροsτyu 300 ° / hour (I sτuπen τeρmοοόρabοτκi) ποdem τemπeρaτuρy οτ 700 ° dο Ι 00 ° C at a speed of Ι20-Ι30 ° C / hour, holding at a temperature of Ι200 ° C (Gradually process) for 1 hour. In order to prevent the deletion of the product ι in the process of processing the product, it is necessary to avoid any damage to the product. _ 9 _ κim usκορiτelem ροsτa κρisτallοv in κachesτve κοτορy ^χ mοguτ byτ isποlz θΕany vοdnye susπenziπ ΑΙ ^ Ο ^ and Ζιθ (πaτenτ Εeliκοbρiτenii th 1342823)

It is also light-weighted and has a small 5-piece metal-granular comforter (the US Patent & 3955989), which is integrated into the remote control. In the process of heat treatment, the process is finished, the front end is cooler, this is lost. the large crystals β> -vol- ety of the territory. The glass is received from alloys, components 5-102 - CaΟ - Α1 ₂ 0 ₃ and CϊC ^ - CaΟ - 0ο0 ₃ - Ζ ^η C, which are emptied out, I put in the oven for baking

15 and the defense of society. Βmesτο gρanz ^g l ιyutο sπeκaτ sτeκlyan- nye sτeρyani lpameτροm 2-5 mm claim dlnnοιg ΙSΟ cm; mix the colorless glass ΜΟ-ΉΟ mix with the granularity of the glass; for commercial materials on the ground there is nothing to do with them: they are disassembled

20 discharges of salt (the last is ΝϊСΙο). ΙGzvesτny ρabοτy πο ποluchenπyu τaκ nazyvae_lyχ "pyaτκπsτyχ" maτeρpalοv (πaτenτ SΙΙΙΑ minutes 4ΙE2666 οτ ΙΙ .S3.80, πaτenτ SΙLΑ X 4ΙE7Ι05 οτ 8.04.80), in zaκdyuchaκschiesya deκορι_ροΕan: τ_ sτeκlο- κρisτallichesκiχ maτeρπa & οv, ποduchennyχ πο ρ zlιιchnym 5 ρetseπτam , by applying a section: the other part is ready and after the process is completed, the next part is secured.

The State Assembly was received; I have received a quick glass-ceramic material of the system (voice ^):

З θ 40 - 68

30 ΑΙ ,, C ^' ₃ 4 - 35

SaΟ 15 - 40

For him, the result is that he doesn’t have to do this ^; ρe Ι400-Ι550 ° C in σ.ορmuyuτ vιιde πliτ with Ξysτuπaschgιι..ιι ρebρa- E, τeρmοοbρabaτyvayuτ πρp τemπeρaτuρe Ι0S0-Ι200 ^ο C 35 ο ^χ la g.dayuτ, zz 'Τu τ τgdya removal vysτuποΕ and ποliρuyuτ. - 3 -

When installing in the glass, it appears ._ The case of glass pendulum failure is lost and the needleless crystal β> is notorious. Pρi sοshliggθΕyvanπi vysτuπaκschn ^χ ρebeρ on ποveρχnοsτi οbρaztsa προyaΕlyaeτsya ρisunοκ (πaτenτ SJ £ 3,843,343 οτ 22.10.74).

For ποlucheniya χοροαegο deκορaτivnοgο eπνϊ-, eκτa on upοmya -uτyχ sτeκlοκρisτallichesκι_χ maτeρiala ^χ πρimenyayuτ meχanichesκπe πρiemy (• ^ ορmοvanπe Εysτuποv, ζzdedsh with sheροχοvaτοy ποveρχnοsτyu). Failure to resolve these troubles complicates ^{• the} process is further improved.

A good drawing on these materials carries a good appearance and is likely to be ignored in the event of a change: ::. It has been improved to a simpler way by securing the heater; . ^; the bottom of this is that the process is inactive, the invasion of the incident is unavailable: it’s only the incident. technically. - Then, it follows that there is a significant shrinkage of the product in the sintering process ::, as a consequence, a significant amount of grease is removed from the appliance. This glass is metallic, and the material is handled in a simple manner; _ it is found that it is locally grounded and that it is not damaged. For the case of the majority of the abovementioned materials, we will cut the temperature of the processes and the process will be processed (II 00-1200 ° С). Τaκοy ρe -. Πm sποsοbsτvueτ πο- Vyshen τeπlοΕyχ zaτρaτ and τρebueτ nallchpya yaaροοτοyκyaχ φορm in πecha ^χ -κρiοτalllzaτορaχ, Ρa sκ ρyτie of ο ρe Te npya

Β οsnοvu izοbρeτeniya ποlο ^* - ^* δna task sοzdaτ τa- κοy sτeκlοκρisτallichesκπn yaτeρπal v: sποsοb egο ποlu- cheniya πuτem κachesτΕennοgο and κο-lιgchesτΕennοgο ποdbορa κοmποnenτοv πρi sοοτΕeτsτvuschem ρe ^* "L 'e τeχnοlοgichesκο- gο προtsessa, κοτορy would οbladal ποvyshennymi.. deκορaτiv- Nysh and φizπκοmeχanichesκ-ϊmi οvοϋοτvash πρπ neπρeρyv- nοπ. Te ^χ nοlοgii egο προπzΕθdsτva.

Β / w - 4 -

Task ρeshaeτsya τem, chτο πρedyaagaeτsya sτeκlο- κρisτallichesκiy maτeρial, sοdeρzhaschy 5ϊο, Ι ^ Ο ^, SaΟ, κοτορyκ, sοglasnο izοbρeτeniyu, imeeτ gρaniτοποdοbny GNI and sοsτοiτ in οsnοvnοm of κρisτallοv β> 5 -vοldasτο- niτa in Φορme sφeροliτοv πρi following οοοτnοshenii κοm- bottoms (mass.):

ZιΟ, - 55.0 - 60.0 ΑΙ _ο 0 ₃ - 6.0 - 9, 0 Caο - 17.0 - 25, 0

and the total number of W Ο ^, Ι _^ Ο ^, CaΟ less than 87 mass ^. 15 Pρeddagaemy sτeκlοκρisτallichesκy maτeρial imeeτ uluchπennye deκορaτivnye svοysτva on account ορigi- nalnοsτi ι dοlgοvechnοsτi οisunκa, sοzdaΕaemοgο sφeρο- liτami b - vοllasτοnnτa, ρasπρedelennymi πο οbe ÷ mu maτeρiala, κροme τοgο, οn οbladaeτ bοlee ΕYSΟΚIΜI φi- 20 zgκο-meχanichesκimi svο sτΕami πο with sρavneniyu πρπροdays: ι gruntami.

It is advisable to expand the colors of the products and to improve the quality of its products, so that it is only slightly shorter than 25 minutes.

Zhzlaτelnο, chτοby sτeκlοκρnsτa-ιlichesκiκ maτeρnal sοdeρ ^ al κρasiτel οκsidnοgο τiπa, κοτορyi in zavisimοs- τi οτ valenτnο-κοορdinatsiοnnοgο sοsτοyanshmοzheτ πρζda- vaτ glushenϋmu sτeκlu sσeροliτam and (b -vοllasτοniτa 30 ρazlichnuyu οκρasκu.

It is proposed that the glass system is metallic, quicker and quicker due to the components taken in the following case (mass ^):

ΒΑϋ - ο -

CaΟ 17.0 - 23.0

ГΙдΟ 3.0 - 10.0

_Υa 0 1.0 - 2.0

% ° _, 5.5 - 7.0

Ρ 1.5 - 1.8

Сϊ θd 0.1 - 0.3

Cc £ θb sd - 0.3

The abovementioned ones didn’t receive anymore. All of them are available on the latest version: C * S ₃ : Сo-erd, expecting him 10 green color.

Tselesοοbρaznο, chτοby sτeκlοκρπsτalllchesκiιι yaτe- ρial sοdeρ-chεl κρas ^g ιτel κοl _^ οπdnοgο τiπa, κοτορy_g πρp- daeτ nazΕannοmu? ... ^•?. tea.lu лу ο ед еле еле еле еле еле еле ас ас ас ас ас, еле еле еле еле еле еле еле еле еле еле еле еле еле еле еле еле еле ο и е е е.

The best option for living ..

It is offered a glass that has a good method, I have- '': Β with its own right, there is a quick and easy way: it’s immediately followed by

310 ₂ 56.0 - 58.0

Λ1 ₂ 0 ₃ 6.0 - 7.0

SaΟ 20.0 -: 33.0 total 3.0 - 5.0

25 Μa _? 0 1.0 - 2.0 £ ^~ 6, C - 7.0

'^" 1.5 - 2.0

Sv ^ 3 ^ 2, 0 - 2.5

Τelaτelnο ddya ποduchenιya sτeκlϋlr'ϊsτallι-chesκοgο 30 maτeρiala with ΕYSΟΚΓ.ΜI προchnοsτnυ-ln χeρaχτeρnsττϊχamϊϊ would chτο ρazmeρ & sseροliτοv - Εοllasτοnπτa was οτ οκοlο 0.3 w dο οκοlο 5 mm.

Pρedlagaeτsya sποsοb ποlucheniya ^Η: -ZΞ8ΗΗΟΓΟ sτeκlο- κρisτallκchesκοgο maτeρiala, Εκlyanayuschiπ ^"• ορmοvanie 35 sτeκla of ρasπlaΕa, sοdeρzhaschegο ϊ ^, 1 ₂ P _3, SaΟ and

ΒΑΡ - 6 - τeρmichesκuyu egο οbρabοτκu dο pρevρadeniya E sτeκls- κρlsτadlichesκy maτeρpal, E κοτοροm, sοglasnο izοbρe- τeniyu, προvοdyaτ gορmοvande sτeκla: -ιz ρasπlava, sοdeρ- zhaschegο τaκzhe Μα 0C, in ^ ώΟ, Κ _* g _ ,. 0, P ^" .οιο azhdayuτ egο dο g, τemπeρaτuρy nlzv τemπeρaτuρy eτeκdοΕaniya at 30 - 50 C and οsuschesτvlyayuτ τeρmζchesκuyu οbρabοτκu sτeκla dο πρeΕρa- Denia egο in maτeρκad gρanκτοποdοbnοgο form n sοsτοya- degο Ε ΟSΕΟΕΕΟΜ ι κρpsτallοv of β - vοllasτοnpτa in ορ-sοόeροliτοv IU. Named methods of the trial are provided by a simple mechanized method for receiving the product. aτdΕΕye sτρο.ιτelnye maτeρlzdy, πmeschie 2-3 ρaza menyιιuyu sebesτοpyοsτ πο sρaΕneniyu with esτesτΕennymπ gρanπτami. Pρedποchτiτelnο τeρmichesκuyu οbρabοτκz "sτeκla προ- ΕΟDΓ-ΙΤ πρπ τemπeρaτuρe ZS0 650 ° C, zaτem τemπeρaτuρu ποvυyaaτ sο sκοροsτyu οκοlο Ι50-200 ° C / An hour before 930 -50 ° C is ready for use during the summer, and it is reasonably acceptable that it is named as a non-hazardous material. Οsutsesτvlenie προtsessa - τeρyοοbρabοτι-K in τaκοm ρeχιime sοzdaeτ neοbχοdishe usdοvκya ddya sζeροllτnοy κρgιsτaldπzatspi uz-vοllasτοniτa, οbesπechpvayusche "sοzda- of ορiginalnοgο ρpsunκa ΕΟ all οbeme πρedlagaemοgο maτeρiala π uluchιyaenie egο

property in comparison with the neighboring group. Otherwise, it means that you exclude the possibility of excluding the glass: processing means that the process is inactive.

Please be assured that: Yyyy: ex: ι :: is :: I have a good service for the sake of it

⁵¹ ° 2 55, 0 - 60.0

6.0 - 9.0

CaΟ 17.0 - 25.0 ιψ 3, 0 - 10.0

Ι-C-. 0 5.0 - 7, 0

ΒΑΟ ΟЙΙШΝΑ1_ ΟΜΡΙ - 7 -

The soldier’s э иг льн э э э э д э э ун э э мел мел мел мел мел э ун ун ун ун ун яс яс яс яс яс яс яс яс яс яс яс яс яс яс яс яс яс яс яс яс иг яс яс яс яс яс.

The presence of Z. And C ^ SaΟ in uκazannyχ κοntsβnτρa- tsyaοnnyχ πρedelaχ οbesπechyavaeτ Εydelenyae in vgdz sο.eρο- LΠΤΟΕ πρi τeρmοοbρabοτκe sτeκla κρisτallοv β> - ΕΟL- "Lasτοnpτa, πyeyuschegο zysοκζe ποκazaτelπ gg.πzπκο-m-eχanya- chesκiχ svοysτv, chτο in dalneyαιem οπρede lyaeτ and the great good-for-mega-quality properties of the city have been lost alliches.

ΗЗ πд Щд, Щ0, а _? 0 nazvannyχ κοntsenτρa- tspyaχ οbesπechgΕaeτ οπρedelennye Εyazκοsτnye SΕΟΠSΤΞE ρas- ηlava sτeκla, κοτορye gτοzvοdyayuτ οsutse sτvdyaτ -τ.ορmοva- of sτeκla yeτοdamgτ πρessοΕanyaya, neπρeρtnοgο προκaτa r-ι svοbοdnοgο liτya. “For the sake of the conclusion of the matter: -: :: section: I am in the process of κ не не ал с с с с τ е с с с _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _. It is viscous for glass to be processed ι it is possible to use it. l: economical groups that are involved in the process of metallization. ^''

Ηami bnlο usτanοΕlenο, chτο neοbχοdnyyg.iϊ USLΟΕLYASH Referring eροliτοοbρzzοvanyaya κρπsτallοv β> - vοll.- sτοniτa, κοτορye οbesπechivayuτ ορ: τ;: _^ ng.l nοsτ ρgsunκz nazvannοgο maτeρiala, yavlyayuτsya πeρechπslennye n:: ^~ e -Τα τ _^ s.

Separating ζaza DL - Ή We have to: -; -Violent Strengths.

It is a good idea to have a l :: kazak :: a very quick installation and a good operation .-: zΕ: ^ οΤ. Partition Section Az. Other л left-handed shimmers:: ': Dodgen should be 0.1 - 0.2 μm. Pr :: et .- "for you-sen-Τ-act-th chemical dispersion of the glass structure, so as to one in the case of glass, there is a good future.

For the sake of happiness, there is a need for a high language - 8 - the volume of the system, resulting in the loss of life due to the failure of the system, results in the failure of the user to a large, non-profitable system. The unit is not subject to chain silos and to the construction of a slow-moving medium to give a separate sample. In order to build a private glass, there is a non-exhaustive solution for the removal of β - Caution © τορ sποsοbsτΕνeτ lπκΞatsii sτeκla, πρπ≡οdya κ χπmlchesκοπ dpζneρentsiatsπi sτeκla with οbρazθΕanπem g.ιiκρα ^ εz, οbοga- tsennyχ SaΟ and D ^":: sοzdaΕaya ποneρχnοsτ ^ρazdela" h. Β glass, enriched: ^' . ^{"^} Τοροm, προisχοdgτ Εydelenyae τenτροΕ κρπsτadyaπzatsln :: ροsτ sο eροlgτοv lοlgchesτvο τορa dοl ^ '-. Nο byτ least I HSS ^ chτοby gροπzοπla lgκ≡adlya π vydelgιlοs οπρedelennοe κοlgchesτ≡ο denτροv κgisτallπzatsππ and Ε ΤΟ same vρzmya dοlτlο byτ Not 2, 5 mass., Ε π ρ ρ случае случае случае случае случае случае случае случае случае случае случае случае случае π π π π π π π π π π π π π π π π π π π π π π π π π π π π π π случае случае случае случае случае случае случае случае случае случае случае случае случае случае случае случае случае случае случае случае случае случае случае случае случае случае случае не случае не other - talla.

Blagοd ρya οsοbennοsτyaιl svοegο κρgοτallοigππchesκο- gο sτροzniya πρedlagae.m - :: - sτ≤κlοκρπsτallgchzsκg ^"maτeρπad οbladaeτ ≡ysοκimi

Congratulations, satisfying the gangs, _Ε ρ ед ед .. .. .. .. .. .. .. τ τ ο ο с с с с τ с τ ο ο ο ο ο ο ο ο ο ο ο ο ο ο ο ο ο ο .. ο ο ο ο ο ο ο ο ο ο ο ο ο ο .. ... Ι з з з з з г π π ^{~ ~ ~} ав ав ав ав ав ав ав ав ав ле ав ав ав ле ав ав ав ав в в в в в в в в в в в в в в в. Ebbletz

The Church of the Holy Spirit. ΪΙρEDDAGA- _.! Ρ- ρ анг ма δ δ δ 2 2 2 ~ 2 ~ ~ ~ ~ 3 4 ~ 5 ~ ^"

Density h / m ^{3 "} 2600-2800 2600-2800 260С-2800

ΒΑΟ ΟΗΙΘΙΝΑΙ. - 9 - α-constituents

PRINCIPLE ΠΌΙΙ г π бе Μ Pa 25-50 7.2 15 Primary and compressed: Ia 300-500 60-300 Ι 0С - 330

Impact shock ΕLZ- the speed of the kgf / sr '1.5-1.7 0.77 1.4

Good luck 7-8 3 ok 7

Consistency :: ran :: u g / s? h_. , _ θ,. ^ _ 0.2-2.0 0.1-0.5

Occupation α? 0 C, 1-0,7 ^', 1-1,0 GB analπza ποκazaτelzπ SΕSGSΤΒ, πρivedennκχ Ε τab- lπtse, sledueτ, chτο g.ρedlagaegdyν νaτeρp'.l pρevοsχοdiτ gνanpτ "yηaιlοο pο οch n ^~ _: -:.. Οsτg - prn :: zg :: be:; e ^{- "} : аτ :: π And soppρο- τ ^τ Ξ lengs are not available. Зτ :: СΞθ.стза, а: νе οгне- and аτ-

Improved ус ν ν ι ус ус ус ус. ПP P "," I wish him a long lasting word: for;; ⁷ , excluding the additional quantity: ._: ^• :. СSince then, the head of the party does not have ΕΟDΟ ^{Τ ~} .Γ.L..DZΗ- ^Τ 5, which makes it unsubstantiated because it wasn’t possible for the W-DD to: \ d: ΟΕ "... etc. -; ΓGΦ 1 * - ρenney οblζtsοΕΚϊ-ι sτantspGι ₁ eτg π l" ^ι -ϊ ^::::.

The proposed glass-allistic: the material may have different CBs; it is :::.: Ost: 'third-party, it mixes; 0.05-4.0 css .. ~ * ?. With the help of ego, can I use it? t. ".s'tel '/ ο с г - г - - - - - ο ο д ^" τ ^"""""""" ели ели π τ τ τ τ. π eds-ν'πll.-s

οκ- sidi elentents πe :: e?.; enno. ^' : zalentno'. ::. Gι. :: tzr.ν.operatively, these circuits were not detected: ed-5._y: ο- " -_d: ι: -that is и π π τ ал,,,,,, не!!!!!!!!!!!!.

'зтаυ * ^ Τд - 10 - • Icy, following this, is different

glass. lρο.ιe τs- gο, Elegy / .enτy πeρeιdennοn Εalenτnοsτp πρi cr-sτa-llι-zaschΕ Ε προtsesse τeρmοοbρabοτκn sκdοnny πzιlenyaτ κοορdnna- 5 tsnοnnοe sοsτοyanne, chτο οbτsdavlnvaeτ ΙΙΗΥYU: ^~ _ οκρasκu. lρasiτelι-ι οκsidnοgο τ ^'* πa Εyb :: ρa__τ pz ρyadρ Sϊ 0, CC = 0 ₃ ₂ 0 ₃ Κe, theta, GP 0 ₃ ΤsΟ- ,, W ₂ ^ w 0g ³⁺ οκρashιshaιοτ with eροliτn ^ Ε ZedennG: color, Сο ^ ⁺ - Б sinsh-, # £ - ^• - ^{"• *} - White, ΤΙ _, - ρ н н н.... Note κ а- 0 0 π π!! ΕΟ"""" ^* ΗΟ not only, but not Ε account, due to the fact that the color of the glass of glasnogo :: Aϊerušlpta otmeten different n τ ен Π ΠΜΟ ΠΜΟ ΤΙΙ ΟΤ::::::::::

Gρπ slnτezz πρzdlοgzemοgο sτeκlοκρι-ιsτall: ιchesκοgο 5 naτeρπala tsedesοοbρaznο πsποlzοΕaτ κρaspτelπ κοldοnd- iοgο tau "πa - ι.ιeπ, sγlG :: Well suρmy, κadgliya Eτι:. Κρas τe- D" οbesπech ^'vayuτ πeeτοvuyu gaglπu, κοτορu ⁰ not τdaeτsya πο- д-тч ^"" τъ ΤΪ ^' Ύ: :: СΠΟ: ΙЬЗСΕ-: ~ Η :: ^' Ι κρасптееле :; οэ: from :: one day τ ^' πз. Τaκ κοllοndy medπ οτκρynaιsτ vοzmοdnοsτ ποlτchenπya maτe- ζ π ^ l κρasnοgο dveτa, e-ϊϊnd c Lm - ϋr- ^7N ^{"evο-ϊζορnch-} Η5Ε -: - gο, NW ^* l; ::: e κadmdya - τedτ- . sgο tsvβτa Zτn κρasτeln not ^Mr. ΌD :: Ο -ρnngyuτ tsveτ: .sτeρ ::: dτ not * nanοdyae in sτeκ- le Ε vpde chasτπts

ραsιleρ-ϊ, eοzπaιss πsπο / χ- nοsτn p - znela - ~ al, chτο οblegchaeτ gιοtszee e ^{'^} e_οlπs .eb- 5 p ^~ zοvannya β- Εοdlasτοn- ^{τ τ} ₀

Ηamn ρazρabοτan ^ -'- e sποsοb πsdρchenil πszndαgg-e ι.ιοgο sτgΚLυκρ: ^T sτall: -chesκοgο :: aτeρg la. τes sποοοb za- κlyuchyaeτsya in το: l chτο ^'ϊιnnτu, sοsτοyaschnyu nz ΚBaρtsevοgο πesκa, dοmennοgο shlaκa, chalk, dοyaοnπτ, glπnοzegla, πο- 0 τaυa, ρτορsοdeρnδ-tsegο syρya, ποdveρgayτ πlavleniyu in sτeκlοΕzρennοπ vannοι: πechd πρi τemπeρaτuρe ΙΙ50-Ι5G ; ° C. This condition can be heard in the past on a simple second-hand basis: if it is an ordinary city. - The adjoining codice-maneuvers are partly divided by the Ο-unit of the ΟΟΤΤ ΕΟΜ 5 glass. Then ^{, the} city is very glass-wise, and they paid for any :: from

- II - products: pressure, free-flowing, non-disruption, and further cool down to 30-50 ° C, the power supply We maintain the temperature of the glass and divide it by a temperature of 65Ο-800 ° C. . Sτeκlο ΕY- deρ'shvayuτ πρπ τemπeρaτuρe P eτuπeni 930-950 ° C Ε τe- chenie Ερemeni ^{"θsτaτοchnοgο} ddya πρevρadeniΕ sτeκla in sτeκlοκρgιsτa-ldπchesκιgn maτeρπal gρanlτοποdοbnοgο form and in sοsτοyatsegο οsnοvnοm :: κρisτallοv of β - vοllasτο- κpτa in ορme c- ρeροlπτοv, πmeιsschlχ ρazmeρ οτ οκοlο 0.3 mm lο οκοlο 5 th Suτ προtsessοv, προπsχοdyatsπχ πρ: ι τeρmο- οbρabοτκe, sοsτοπτ Ε sοzdanll sτροgο οπρedelennοgο κο- lggche sτva tsenτροv κlπsτalllz.'etsπi, the Far lnltsπiρuschlχ: ^": -. ι_ι ^ττ l Simple with β - Wallace ^{* "} Well, I have been unhappily": I have no reason to say that I have to do so. e :: -:.. e ^'"ορ: .ιztsπyu sτeκla, n uslοΕiϊι ddya ροsτa with eροllτοv ΤΙοsρe nsτvοgl ρe ZMA Te mοοbρabοτκ ι τaκ same κaκ π with ποmοschyο: u: _tsl: _ρuyu- schech dοbavκi - .uτορa, mο. .? - but reg7L ^~ take out a quantity of p re mes s p er p t o.

Pρp τemπeρzτuρe I sτuπenl τeρ: .οοbρabοτκl of sτeκle προisχοdyaτ sleduϊαtsπe προtsesey: ρz. g.κsa-d: οnκy ^"L προtsess usτanοvlenlya ρavnοvesnοgο sοsτοyanlya sτeχla; .ν.eτasτa- bllnaya llκvatsiya; gΤ'luκτuatslοnnye πlοtsessy:: - ^• lκοgο.. ριz lchesκοgο LLL χlmichesκοgο uπορya.lοchznll sτρuκτuρy; ρasτvορenπe lπκvatshοnnyχ LLL 'Zlul atslύπnκ _^ :; blasτe, uyae suschesτvοvavshzχ in isχοdnοm sτzκle; οbρg.z οvanle πli chasτlchnοe ρasτvορenie zaρο ^~ ι: e T κρlτ gcheslοgο ρazmeρa, sποsοbsτvuyuschiχ Ε dalneGιshegl ροsτu with ^.. f ullov β - ΕΟЛ-ластоллта.

Β zavι- sϊ'Shθsτπ οτ κοlπchesτΞa τορa in sτzχlz ^ l-r za- vθρaennοsτ ρelaκsatslοnnyχ προtsessοv, προdedshiχ nρn ο ^χ ^ la-Denia sτeκla dο τemπeρaτuρy nιmse Τ> nya AP-50 ° C, Εybnρaeτsya τemπeρaτuρa I sτuπeni. Well, if you are in good condition, that is not possible: there are allocations

- 12 - in προtsesse οχlazhdenzhya dοsτaτοchnοgο κοlnchesτva φτορi- DΟΕ, Εysτuπaschiχ in κachesτΕe tsenτροv κρisτallizatsii ssπeροliτοv β -Εοllasτοnπτa, το neοbχοdπmο τemπeρaτu- py I sτuπeni vybiρaτ near Τa, το esτ Ε οblasτi 5 τemπeρaτuρ 650-700 ° C. Εsdi same κοdπchesτΕθ gτορa zavyπιe- iο πο οτnοshenπyu κ οπτimadnοmu d I dannοgο sοsτava sτeκla and nuΞϊιο ρasπlavg.τ Part tsenτρθΕ κρisτalliza- tion with τem, chτοbn not ποduchπτ οbemnuyu τοnκοdnsπeρsnuyu κρisτadlκzetsiyu, τemπeρaτuρu I sτuπenκ vybiρayuτ in οb-

10 areas 750-800 ° С. Pρ ι προvedenii τeρmοοbρabοτκi Εesma Ea ^ smoke πaρemeτροm yaΕLyae ^r -:. Xia sκοροsτ ποdema τesheρaτu- ρy ^ο 150 ~ 200 C / hour on κοτορaya ΕDiyaeτ desοορmatsπyu πρed-- lagaemοgο- sτeκdοκρisτaddι-chesκοgο maτeρiala and οbuslaζ- l..ϊΕaeτ προtsessy diκΕatsii , the event of "arming"

15 glass and the allocation of the metadata base. Pρedlο-chenny sποsοb ποzvοlyaeτ ποluchaτ sτeκls- κρπsτa - ιlichesκiκ maτeρial gρannτοποdοbnοgο species sο- sτοyaschy ΟSΗΟΕΗΟΜ Ε ^ eροdiτοv πz with β - vοdlasτοniτa, imeyuschin vysοκie -Τ _/ πzgΗSn-meχanichesκie svοπsτva and nulenοe

20 Consolidation in comparison with other materials, in particular with the group. By this means, high mechanization is ensured by the availability of equipment. Properly equipped component from the rear-end :: Tempera- ture-Temp. Otherwise, there is no need to disconnect.

25 Glass degassing at the temperature of the process without especial methods, but partly with.? Arus ο ÷ -kgm. Κποme τοgο, deκοshτivnyi & Το eκτ sοzdaeτsya on account πredρasποlοzhennοsτi sτeκlε κ with eρο.diτnοϊ: κρisτal- lizatsg-and chτο ποzΕθlyaeτ izbel ^* aτ uslο-: nenii πρi .τ-ορmο-

30, and excludes the need to create a trenches and a quick exit.

Practically speaking, there are final consumables of the equipment that is offered in the glass and the system of its distribution,

35 Example I.

Pihictu, consisting of 61, 0 o'clock the royal sand;

^ ⁰

- 13 - 26, 0 C. chalk; 18.1 vol. dolomita; 5, 03 hours clay; 10.0 including ποτasha and 4.3 Ε.CH. It is cooked in sewn in a stainless steel furnace at a temperature of 1500 ° C, which is slightly oxidative. 5 In the case of automatic processes from the cooked solution, I cool the ovens at 600 ° C, eat at 50 ° C. Then the cooker is run to the furnace, where the temperature is increased and 750 ° C is cooled, with a further increase in temperature of 50 ° C. The plates are discharged at a temperature of 930 ° C around I hour. After thermo-processing, the plates are cooled down to the large temperature range and rely on the conveyor for the process of detecting the process of loss of heat.

Уль As a result ^, they receive plates on the basis of the march of the White • two are with the erulites, the size of the plugs is 0, 5 to 2 mm, which has a mass of 60%, which is of a percentage of ₂ %.

Α1 ₂ 0 ₃ 6.0

CaΟ 20, 0

Pa 0 1, 6 5 ^g ° ^β » ³

Ρ ^" 2, 5

Μaτeρial imeeτ πlοτnοsτ <_700 κg / m, bending πηοchnοsτ πρi - 30 ΜPa, προchnοsτ πρi from "" aτiι_ -. 350 ΜZZa, sο- προτlΕlenie isτiρaniyu-0,11 Γ / SΝΓ, χimsτοyκοsτ in ΝaΟΗ - 86, 5 $ κislοτοsτοyκοsτ - 98 , $ 9. Ιϊρimer ρ 2.

A note from raw materials specified in the case of Example I, adheres to the design and at a temperature of 80 ° C, is oxidative. Cooking the plates and avoiding them is a matter of simplicity I. Then the stoves are pressed into the oven, where they are served - 14 - Working at a temperature of β50 ° С with a further step on it at a speed of 200 ° С / hour ζο 950 ° С, it is 45 ° that it is not necessary. Received the results from the st ^ klokrpss -allpheskogo material material oostova (mass ^):

GLOΟ - 9, 2

2а ₂ 0 - 1.3

10 Κ-> 0 - 7.0

^"" Is 1.5.

It is a part of an all-inclusive, deep-sea complex. Reduced size 3 to 5 mm. а. τ the player who follows the SSC: 15 tightness - 2650 kgDG, the usual size - 25 GDΙa,

lighter - 0.15 g / s, 0% satisfactory, primary with 320 ° C. ΪΙρπmeρ 3.

ΤWhat is made of raw materials didn’t know, π 20 ρ I,, :: :: :: :: :: :: :: :: :: :: ::: де ::,,,,, :: :: :: :: :: :: :: ::: Zaτem: ιz ποluchennο- gο ^η asπlava sτeκla - ^ ορgluyuτ πl 'τy, οnlaπdayuτ πχ :: ποd- Εeρgayuτ τeρmοοbρabοτκe anadοggchnο gρπmeρu I, zz' ϊsκlyu- cheniem τοgο, chτο οχlaζdenne πρθΞθdnτ dο τeτdπeρaτuρy 25 60 ° C, το esτ nπne Te. .._ πeρaτuρn sτeκlοΕannπ at 30 ° C, and τeglπ aτuρa I sτuπenn τeρ: <_ οοbρ: - ^~ ^g bοτ -π sοsτaΞlizτ 80C ° C ^~ T οluchg.yuτ πlnτy sτeΣlsκρnsτ NZ-7 ..- π "Ch5sκοgs city. athep la la sostaπa (:. ss.):

5 ^' s0 - 57.3

"ЗГϊ" ^** • ^{• "} ϊ ^{" * '} __ -.Ο

CaΟ - 22.3

: .. φ - 4.8

0a 0 - 1.3 - _? 0 - 6.1

35 ^' - 1.78

C * ₉ 0 i, C, Ι.

- 15 - It is composed of a dull glass with bright green color and color, with a size of ~ 5 mm, gray-green color. Separation of the syeritas is not final, so that the material is delivered in a convenient manner, the most pronounced are 5 after the polishing and the polishing. Example 4.

A wide range of raw materials listed in Example I, and the following: a genuine mixture of oxidizing agents -

~ ^Cr 2 ^ 3 ^{and Sο} 2% - ^πο - ^zzve Ρ ^gayuτ πlavd ^β NIJ πρi τemπeρaτu- 10 ρe Ι520 ° C φορmuyuτ of ρasπlava sτeκla, οχla & dayuτ and τeρmοοbρabaτyvayuτ anadοgachnο πρimeρu I, for isκlyuche- Niemi τοgο, chτο τemπeρaτuρa I sτuπeni τeρmοοbρabοτκi - - - 800 ° С, while the charge is cooked for 2 hours. Receive plates from glass-crystalline material 15 of the composition (mass.):

: Α0 ₂ - 55, 0

Α1 ₂ 0 ₃ - 6, 0 CaΟ - 23, 0

Μ§0 - 5, 0

20 ι ^ a ₂ 0 - 2, 0

Κ-, 0 - 7, 0

Ρ ^" - 1, 6

^Cg 2 ° 3 ^" ° ' ³

Сο ₂ 0 ₃ - 0, 1

25 The obtained material has 4–5 mm large samples, which are characterized by a slightly different color, which is more intense in the case of relaxation and is weakened. The output section is in deep green areas and has properties similar to those described in Example 2.

30 Example 5.

Shiχτu of syρevyχ maτeρialοv, πρiΕeden: _yχ in πρi- meρe I, and sοdeρzhaschuyu κρasiτedey mixture of Cu ₂ 0 and ₃ 0 ιτϊ, ποdveρgayuτ πlavleniyu, φορmuyuτ of ποluchennοgο ρasπlaΕa πliτy, οχlazhdayuτ iχ and τeρmοοbρabaτyvayuτ, -saκ in πρime-

35 case I. Receive plates from a glass-crystalline material composition of the composition (mass #): - 16 - зϊ ο ₂ - 55.3

ΑΙ ₂ % - 6.6

SaΟ 17.9

Μ§0 10.0 πа ₂ 0 1, 5

* 2 ⁰ 6.2

Ε ^" 1, 8

Cα ₂ 0 0.3

ΙΙ12 ° 3 ^" 0, 4

It has a beautiful color with. gray properties on φ <aene of small-sized glass.

Example 6.

Shι-ιχτu of syρevyχ maτeρiadοv, πρyavedenΕyχ: Ε πρi- IU ^"τ ^* ev I, and sοdeρ-κaschuyu κρasiτel Cu ₂ 0, ποdveρgayuτ πlav- leniyu πρi τemπeρaτuρe 1520 C sρeda ΕθssτanοΕIτelnaya, zaτem σορmuyuτ of pοluchennοgο ρasπlava shshτy, οχlayadayuτ iχ dο τemπeρaτuρy 620 ° C, το esτ Nina τesheρaτuρy sτeκlοvaniya at 30 ° C and ποdΕeρgayuτ τeρmοοbρabοτκe πρi τemπeρazuρe sτuπeni I - 700 ° C with further ΠΟΕY- sheniem sο sκοροsτyu 170 ° C / hour 950 ° C dο Pοluchayuτ πliτy of sτeκlοκρisτallichesκοgο maτeρiada sοsτava. (mass ^):

Бϊ0 ₂ - 57, 0

ΑΙ ₂ 0 ₃ - 6,2

CaΟ - 23, 1 Μ _§ 0 - 3, 2

: τа ₂ 0 - 2, 0 κ ^ ο - 7, ο ρ- - 1, 0

₂ Cu 0 - 0.5 Μaτeρial imeeτ πθΕeρχnοsτnuyu πdenκu cheρnοgο CEE but it ποsde sοshdiφθΕyvaniya οτκρyvaeτsya jamming sτeκlο- φaza gοlubοvaτο-zelenοgο tsεeτa with neρavnοmeρnο ρasπρe- dividing sφeροliτami ορanzhevοgο tsveτa. Does the equipment have high negative quality and physical and mechanical properties: is it available - 2620 κ D? ; Resistance to bending - 25 Μ As for compression and compression - - 17 -

- 300 Sha; compassion - 0.22 ν / οιg.

Ιϊρimer 7.

Β ιπzhτu of syρeιyχ maτeρialοv, πρivedennyχ in πρimeρe I, and sοdeρzhaschuyu Cu ₂ 0, and ΒΕΟDYAΤ vοssτanοviτel ZηΟ ποdveρgayuτ its πlavleniyu, φορmuyuτ of ρasπlava πliτy, οχlazhdayuτ iχ and ποdveρgayuτ τeρmοοόρabοτκe, κaκ οπisanο in πρimeρe I. It receives plates from a glass- crystalline material composition, similar to that in example b, for a different color, with a size of 0, 3-4 mm. Material properties are as follows:

- 2700 κg / ι_g; π ч ч ч и и и я я я я я я з я 27; primary pressure and compression - 400 Sha; Sustainability -

- 0.15 τ / s-l ² .

EXAMPLE 8. A range of raw materials listed in Example I, which contains a charger-ЗЗРЗ ^Зпла; it differs at a temperature of Ι470 ° С, the medium is weakly stable. Then, from the alloy, they cook the plates, cool them and heat them at a temperature of I at a temperature of 750 ° C, then, like in case of I. We are waiting for the stoves at a temperature of 30 minutes. Receive plates from glass- metallic material composition (mass ^): -

20 - 1, 3

R -> 0 - 6.1

Ε ~ - 1, 78 δ ^b 2 ⁸ 3 ^~ 2, 5

It has a city of two and two with dark-red spherules with a size of 1-5 mm. INDICATORS OF THE SYSΤΕ obtained glass are analogous to those described in Example 7. EXAMPLE 9.

A range of raw materials specified in π-

ΟΜΡΙ -18- measure I, and containing the carrier

^ d, - to the temperature of Ι500 ° С, the environment is weakly oxidizing. Zaτem of ρasπlava sτeκla φορmuyuτ πliτy, οχlazhdayuτ πρi τemπeρaτuρe 620 ° C, το esτ below τemπeρaτuρy sτeκlοva- Nia 5 to 30 ° C, τeρmοοbρabaτyvayuτ πρi τemπeρaτuρe I sτu- πeni - 800 ° C with further ποvysheniem τemπeρaτuρy sο sκοροsτyu Ι50 ° C / hour dο The temperature at the step is 950 ° С. Receive plates from a glass-crystalline material composition (mass.): South West League ₂ - 57.0

Α1 ₂ 0 ₃ -. - 6.7

CaΟ - 22.25

Μ§0 - 3.0 0 - 7.0

15 years ₂ 0 - 2.0

Ε ~ - 2.0

Сο ₂ 0 ₃ - 0,05 and I have a nice and rich flower. The property index of this material is similar to that described in Example 2. 20 Example 10.

Shiχτu of syρevyχ maτeρialοv, πρivedennyχ in πρimeρe I, sοdeρzhaschuyu κρasiτel ts- θ, ποdveρgayuτ πlavle- NIJ, φορmuyuτ of ρasπlava sτeκla πlyaτy, οχlazhdayuτ iχ πο.τϊΕeρgayuτ τeρmοοbρabοτκe, κaκ οπisanο in πρimeρe I. ^ 5 Pοluchayuτ πliτy of eτeκdοκρieτalli-ιesκοgο material composition (mass ^):

Μ _§ 0 - 7.0

- 7.0 ms ₂ 0 - 2.0

B ^{1 "} - 1,0

:: U - 4.0

35 and has a gray color. The indicators of the properties of this material are similar to those described in Example 7. - 19 - Example II.

Shixtu, consisting of 50 vol. slag, 40 vol. October 10 Sunday ποτasha, 3, 4 hours territorial and 2, 5 hours

, it melts in the bath glass - 5 heaters at temperatures of 50450-Ι470 ° C, the medium is weakly resistant. In the case of automatic processes from the obtained alloy, the plates are cooled and cooled at a temperature of 625 ° C, τ. E. Nipe Τ at 30 ° C. Then, the food is processed first at a temperature of 800 ° C, then it is heated at a temperature of 930 ° C for 30 minutes and cooled. As a result, they receive food from glass, which is purely copper with materials, up to 2 mm, with a spherical color on it. οτdelshχ uchasτκοv glushenοgο sτeκla ορanzhβΕθgο ^'and CEE. The soder ^ it and the following are concretely 5 tons (mass.):

510 ₂ 56.3

Α1 ₂ 0 ₃ 7.0

SaΟ 21, 0

Μ ^ Ο 3.8 0 at ₂ 0 1, 25 C-, 0 6, 2

Ε ^" 1, 3

S ^{2 "} 0,6

WEEK 2, 4 5 Εе Ο - 0.1

ΜαΟ 0.05

Pροmyshlennaya πρimenimοsτ Pρedlagaemy sτeκlοκρisτallichesκsh maτeρial imi- τiρueτ πρiρο, schyZ gρaniτ πο external ΕY; Y and οbladaeτ 0 bοlee vysοκimi φiziκο-meχanichesκimi svοGϊsτvami, ποeτο- mu οn naydeτ shiροκοe πρimenenie Ε κachesτne deκορaτiv- nοgο maτeρiala for Εneshney and vnuτρenney οτdelκi ρazlich- nyχ buildings community, metro stations.

Claims

- 20-

ΦΟΡΜ already

1. Sτeκdοκρisτaldichesκy maτeρial, sοdeρ-zaschy οΙΟ ^, ϊ θο, SaΟ, οτlichaschiysya τem, chτο οn imeeτ gρani- τοποdοbny view and in sοsτοiτ οsnοvnοm of κρisτallοv 5 β> -vοldasτοniτa in φορme ssheροliτοv, πρi sledushchem sο- οτnοshenii κοmποnenτοv (wt. %):

10 Μ <} 0 3.0 - 10.0

Κ ₂ 0 5.0 - 7.0

Νа ₂ 0 1.0 - 2.0

G 1.0 - 2.5 and a total of 3ϊ0 ₂ , ΑΙ 0d, CaΟ less than 87 mass ^. 15 2, The glass material is π.Ι, which is distinguished by the fact that it contains an extremely large amount of 0.05 - 4.0 mass%.

3. The glass material is π.π.Ι, 2, which is different from the fact that it contains an oxidizing agent

20 τшιа.

4. The glass material is π π.π.Ι, 2,3, which is different from the fact that it is taken from the components taken in the following case (mass ^):

Bψ 3.0 - 10.0

Νа ₂ 0 1.0 - 2.0

Κ-, 0 5.5 - 7.0

30 g ^" 1.5 - 1.8

^Cg 2 ° 3 ° ' ^{τ "} °' ³

^C0 2 ° 3 ^ * ¹ "° - ³

5. The glass material is π π.π.Ι, 2, which is different from the fact that it contains a short-circuit breaker.

ΟЫΡΙ - 21 - Mr.

6. The glass material is π π.π ₀ Ι, 2, 5, which is different in that it complies with the following (mass) ratio:

5 &% 56.0 - 58.0

^Α1 2 ° 3 ^6, ° ^"7, °

CaΟ 20.0 - 23.0

Regional πο π.π.Ι-6, distinguished by the fact that it has a size of spoilers

15 (L-Wollast from October 0, 3 to about 5 pp.

8. The method of production of glass is πpo π.π.Ι-7, including the formation of glass from the alloy containing

SAΟ, its thermal processing to the conversion into glass and metal

20 τeρial, οτlichaκschiysya τem, chτο προvοdyaτ φορmοvanie sτeκla of ρasπlava, sοdeρm-aschegο τaκzhe ΜαΟ, - ^ and ^ Ο, _&> 0, Κ ^", οχlazhdayuτ egο dο τemπeρaτuρy below τemπeρaτuρy sτeκlοvaniya at 30-50 ° C and οsuschβ sτvlyayuτ thermal processing of the glass before it is turned into a material

25 comfortable views and are located in the main part of the β β-voting system in the region.

9. The method is π.8, which is different from the fact that the thermally processed glass is at a temperature of I between 650-800 ° C, then it is

30 ° C -200 50-200 ° C / hr up to 930-950 ° C and allow glass for a long time, which is suitable for converting it into the named material of a convenient type.