WO1982002647A1 - Pesticidal formulations - Google Patents
Pesticidal formulations Download PDFInfo
- Publication number
- WO1982002647A1 WO1982002647A1 PCT/GB1982/000031 GB8200031W WO8202647A1 WO 1982002647 A1 WO1982002647 A1 WO 1982002647A1 GB 8200031 W GB8200031 W GB 8200031W WO 8202647 A1 WO8202647 A1 WO 8202647A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- composition
- active compound
- water
- insecticide
- insecticidally active
- Prior art date
Links
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/34—Shaped forms, e.g. sheets, not provided for in any other sub-group of this main group
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
Definitions
- THIS INVENTION relates to insecticides, particularly pesticides for the treatment of animals.
- insects When dipping animals, such as cattle and sheep, the animals are dipped in an aqueous dip emulsion or suspension containing insecticides. As each animal passes through the dip, it removes a portion of the wash containing the insecticide. The amount removed by each animal varies generally between 0,05 gram and 7,5 grams.
- the insecticides used are generally organo-chlorine compounds, organo-phosphates, formamidines and pyrethroids. These insecticides are generally formulated as emulsifiable concentrates, wettable powders or suspension concentrates. These formulations are usually measured out in the field by the farmer and diluted with water before dipping or spraying.
- the invention concerns a suitable form of such insecticides, and which avoids handling by the farmer of highly toxic insecticides.
- the present invention provides a new composition of matter comprising a predetermined amount of a multiple unit dose of an insecticidally active compound in a package form, said package form being soluble in water.
- the insecticide conveniently may be a solid insecticide.
- a multiple unit dose is an amount of insecticide which is calculated to be used for treating a multiple number of animals.
- the package form may be a water-soluble sachet, tablet, capsule, or the like.
- Gelatin or polyvinyl alcohol may be used for forming a capsule or sachet.
- the insecticide may be present in the package as a finely milled dispersible powder (eg of a size below 10 ⁇ ), a wettable powder, or the like.
- Any suitable insecticide can be used, particularly a pyrethroid insecticide.
- An example is DELTAMETHRIN.
- Some of these pyrethroid insecticides are highly active and dipping or spraying at 0,0025% or less has been found to be sufficient for providing protection for many types of animals against external parasites, such as insects, ticks, flies, fleas, cattle mange mites, lice, sheep scab, goat mange, or the like.
- the composition may contain sufficient multiple dose for dipping from about 50 to 120 cattle, eg for dipping about 100 cattle of average size.
- the insecticide may also be mixed with a dispersing agent (for example the sodium salt of oxylignin, or a sodium naphthalene sulphonate/formaldehyde condensation product), a wetting agent and/or an anti-frothing agent.
- a dispersing agent for example the sodium salt of oxylignin, or a sodium naphthalene sulphonate/formaldehyde condensation product
- wetting agents are nonylphenol ethylene oxide/propylene oxide condensates and/or sodium diiscpropyl naphthalene sulphonate.
- a suitable anti-frothing agent is a silicone/water emulsion.
- the insecticide may make up from 10 to 90%, more usually about 30 to 60% of the composition.
- the dispersing agent can be present in amounts varying from less than that of the insecticide to more than that of the insecticide. Amounts of from 10 to 60% of dispersing agent have been found to be suitable.
- Anti-frothing agents may be present in amounts of up to 1%, and wetting agents in amounts of up to 7% by weight of the composition.
- the package form of the invention may be sold in any suitable size.
- the invention also provides a method of making up an animal dip, particularly a dip for cattle or sheep, which comprises dissolving or suspending the composition of matter, as provided by the invention, in a predetermined amount of water.
- Dispersing agent 47 7 % ('TAMOL NNO)
- Anti-frothing agent 0 , 12 % ('SILCOLAPSE 5000A')
- wetting agent (2) 0 , 90 % (Aerosol 'OS')
- the above mixture was milled with water to a very fine particle size (1-5 u) and dried. It was then packed into a watersoluble sachet.
- the sachets were made by heat-sealing together two layers of water-soluble pclyvinyl alcohol film. The sachets, when added to a dipping tank, dissolved rapidly and released the 47,7% Deltamethrin dispersible powder which dispersed easily to form a very stable suspension.
- Deltamethrin can be irritant to humans.
- the use of the capsule avoided handling of the insecticide by the user, such as a farmer:
Abstract
Insecticide compositions are in unit dose packages, the package being soluble or dispersible in water. Preferably the insecticidal active ingredient is a solid pyrethroïd, e.g. deltamethrin.
Description
Pesticidal Formulations.
THIS INVENTION relates to insecticides, particularly pesticides for the treatment of animals.
When dipping animals, such as cattle and sheep, the animals are dipped in an aqueous dip emulsion or suspension containing insecticides. As each animal passes through the dip, it removes a portion of the wash containing the insecticide. The amount removed by each animal varies generally between 0,05 gram and 7,5 grams. The insecticides used are generally organo-chlorine compounds, organo-phosphates, formamidines and pyrethroids. These insecticides are generally formulated as emulsifiable concentrates, wettable powders or suspension concentrates. These formulations are usually measured out in the field by the farmer and diluted with water before dipping or spraying.
The invention concerns a suitable form of such insecticides, and which avoids handling by the farmer of highly toxic insecticides.
The present invention provides a new composition of matter comprising a predetermined amount of a multiple unit dose of an insecticidally active compound in a package form,
said package form being soluble in water. The insecticide conveniently may be a solid insecticide. A multiple unit dose is an amount of insecticide which is calculated to be used for treating a multiple number of animals.
The package form may be a water-soluble sachet, tablet, capsule, or the like. Gelatin or polyvinyl alcohol may be used for forming a capsule or sachet. The insecticide may be present in the package as a finely milled dispersible powder (eg of a size below 10 μ), a wettable powder, or the like.
Any suitable insecticide can be used, particularly a pyrethroid insecticide. An example is DELTAMETHRIN. Some of these pyrethroid insecticides are highly active and dipping or spraying at 0,0025% or less has been found to be sufficient for providing protection for many types of animals against external parasites, such as insects, ticks, flies, fleas, cattle mange mites, lice, sheep scab, goat mange, or the like. The composition may contain sufficient multiple dose for dipping from about 50 to 120 cattle, eg for dipping about 100 cattle of average size.
The insecticide may also be mixed with a dispersing agent (for example the sodium salt of oxylignin, or a sodium naphthalene sulphonate/formaldehyde condensation product), a wetting agent and/or an anti-frothing agent. Examples of wetting agents are nonylphenol ethylene oxide/propylene oxide condensates and/or sodium diiscpropyl naphthalene sulphonate. A suitable anti-frothing agent is a silicone/water emulsion.
The insecticide may make up from 10 to 90%, more usually about 30 to 60% of the composition. The dispersing agent can be present in amounts varying from less than that of the insecticide to more than that of the insecticide. Amounts of from 10 to 60% of dispersing agent have been found to be suitable.
Anti-frothing agents may be present in amounts of up to 1%, and wetting agents in amounts of up to 7% by weight of the composition.
The package form of the invention may be sold in any suitable size.
The invention also provides a method of making up an animal dip, particularly a dip for cattle or sheep, which comprises dissolving or suspending the composition of matter, as provided by the invention, in a predetermined amount of water.
The invention is illustrated in non-limiting manner by reference to the following Examples:
EXAMPLE 1
The following composition was made , up :
Deltamethrin Technical 47 , 7%
Dispersing agent 47 , 7 % ('TAMOL NNO)
Anti-frothing agent 0 , 12 % ('SILCOLAPSE 5000A')
Wetting agent (1) 3 , 58 %
('SYNPERONIC NPE 1800')
Wetting agent (2) 0 , 90 % (Aerosol 'OS')
The above mixture was milled with water to a very fine particle size (1-5 u) and dried. It was then packed into a watersoluble sachet. The sachets were made by heat-sealing together two layers of water-soluble pclyvinyl alcohol film. The sachets, when added to a dipping tank, dissolved rapidly and released the 47,7% Deltamethrin dispersible powder which dispersed easily to form a very stable suspension.
Deltamethrin can be irritant to humans. The use of the capsule avoided handling of the insecticide by the user, such as a farmer:
EXAMPLE 2
Method of filling and replenishing cattle-dicoing tanks.
15 000 litres of clean water were pumped into an empty dipping tank. 750 grams of 47,7% Deltamethrin dispersible powder packed in 7 × 100 gram sachets and 1 × 50 grams sachets, were added to the water to give a dilution of 0,0025% active ingredient. The sachets dissolved rapidly and released the insecticide. 400 Cattle were dipped. The following week, water was added until the water level reached the 15 000 litres mark. 4 × 12 grams (ie 12 g per 100 head) sachets of the 47,7% Deltamethrin were added to the dipping tank and the animals were again dipped. The following week, the same procedure was followed. After 16 weeks, the dipwash 'behaviour' was still satisfactory. The weekly dipwash concentration was found to vary between 0,0025 to 0,003% Deltamethrin. No adverse
reaction was experienced by the farmer when using this product during the entire period. Tick control was excellent.
Claims
1. A new composition of matter comprising a predetermined amount of a multiple unit dose of an insecticidally active compound in package form, said package form being soluble in water.
2. A composition as claimed in Claim 1, in the form of a sachet.
3. A composition as claimed in Claim 1, in the form of a capsule.
4. A composition as claimed in Claim 1, in the form of a tablet.
5. A composition as claimed in any of the preceding claims, wherein the insecticidally active compound is a pyrethro insecticide.
6. A composition as claimed in Claim 5, wherein the insecticidally active compound is deltamethrin.
7. A composition as claimed in any of the preceding claims, wherein the composition contains sufficient insecticidally active compound for dipping from 50 to 120 cattle.
8. A composition as claimed in any of the preceding claims, wherein the insecticidally active compound is mixed with one or more dispersing agents and/or anti-frothing agents and/or wetting agents.
9. A new composition of matter, substantially as described.
10. A method of making up an animal dip, which comprisesdissolving or suspending a composition of matter as claimed in any of the preceding claims, in a predetermined amount of water.
11. A method as claimed in Claim 10, substantially as described.
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
BR8206159A BR8206159A (en) | 1981-02-09 | 1982-02-08 | PESTICIDE FORMULATIONS |
AU80832/82A AU8083282A (en) | 1981-02-09 | 1982-02-08 | Air supply device for internal combustion engine |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
ZA81/848810209 | 1981-02-09 | ||
ZA81848 | 1981-02-09 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1982002647A1 true WO1982002647A1 (en) | 1982-08-19 |
Family
ID=25575194
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/GB1982/000031 WO1982002647A1 (en) | 1981-02-09 | 1982-02-08 | Pesticidal formulations |
Country Status (6)
Country | Link |
---|---|
EP (1) | EP0070852A1 (en) |
JP (1) | JPS58500024A (en) |
AU (1) | AU8083282A (en) |
BR (1) | BR8206159A (en) |
WO (1) | WO1982002647A1 (en) |
ZW (1) | ZW1682A1 (en) |
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2221159A (en) * | 1988-06-15 | 1990-01-31 | May & Baker Ltd | Package releasing its contents on contact with water |
EP0387165A1 (en) * | 1989-03-07 | 1990-09-12 | Rhone-Poulenc Agrochimie | Herbicidal combinations |
GB2230445A (en) * | 1989-02-17 | 1990-10-24 | May & Baker Ltd | Package releasing its contents on contact with water |
WO1992017385A1 (en) * | 1991-04-02 | 1992-10-15 | David Lucas Miles | Insecticidal composition and insecticidal units |
EP0544602A1 (en) * | 1991-11-21 | 1993-06-02 | Rhone-Poulenc Agrochimie | Container systems for agricultural compositions |
FR2684968A1 (en) * | 1991-11-21 | 1993-06-18 | Rhone Poulenc Agrochimie | Containerisation system for agricultural compositions |
US5341932A (en) * | 1991-06-14 | 1994-08-30 | Rhone-Poulenc Ag Company | Aqueous formulations |
FR2718610A1 (en) * | 1994-04-14 | 1995-10-20 | Roussel Uclaf | New pesticide formulations and their preparation process. |
WO2001011964A1 (en) * | 1999-08-12 | 2001-02-22 | Eli Lilly And Company | Ectoparasiticidal aqueous suspension formulations of spinosyns |
US6927210B1 (en) | 1999-08-12 | 2005-08-09 | Eli Lilly And Company | Ectoparasiticidal aqueous suspension formulations of spinosyns |
US7772194B2 (en) | 2001-09-17 | 2010-08-10 | Eli Lilly And Company | Pesticidal formulations |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0248505A (en) * | 1988-08-10 | 1990-02-19 | Tosa Guriinzu Kk | Agricultural chemical packed in paper bag |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB191113504A (en) * | 1911-06-06 | 1912-06-06 | Robert Berk | Improvements relating to Manures, Fertilisers, Insecticides and the like. |
FR1263098A (en) * | 1960-07-25 | 1961-06-05 | Water soluble casing, for packaging detergents, insecticides, bath salts and other strong aroma materials | |
GB922317A (en) * | 1958-05-05 | 1963-03-27 | Associated Fumigators Ltd | Improvements in or relating to means for packaging pesticides |
US3556765A (en) * | 1967-08-08 | 1971-01-19 | Encap Products Co | Liquid soluble packet |
US3877928A (en) * | 1967-08-08 | 1975-04-15 | Walter A Houston | Liquid soluble packet |
-
1982
- 1982-01-25 ZW ZW16/82A patent/ZW1682A1/en unknown
- 1982-02-08 JP JP57500506A patent/JPS58500024A/en active Pending
- 1982-02-08 EP EP82900377A patent/EP0070852A1/en not_active Withdrawn
- 1982-02-08 AU AU80832/82A patent/AU8083282A/en not_active Abandoned
- 1982-02-08 WO PCT/GB1982/000031 patent/WO1982002647A1/en not_active Application Discontinuation
- 1982-02-08 BR BR8206159A patent/BR8206159A/en unknown
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB191113504A (en) * | 1911-06-06 | 1912-06-06 | Robert Berk | Improvements relating to Manures, Fertilisers, Insecticides and the like. |
GB922317A (en) * | 1958-05-05 | 1963-03-27 | Associated Fumigators Ltd | Improvements in or relating to means for packaging pesticides |
FR1263098A (en) * | 1960-07-25 | 1961-06-05 | Water soluble casing, for packaging detergents, insecticides, bath salts and other strong aroma materials | |
US3556765A (en) * | 1967-08-08 | 1971-01-19 | Encap Products Co | Liquid soluble packet |
US3877928A (en) * | 1967-08-08 | 1975-04-15 | Walter A Houston | Liquid soluble packet |
Cited By (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2221159A (en) * | 1988-06-15 | 1990-01-31 | May & Baker Ltd | Package releasing its contents on contact with water |
GB2222083A (en) * | 1988-06-15 | 1990-02-28 | May & Baker Ltd | Package releasing its contents on contact with water |
GB2222083B (en) * | 1988-06-15 | 1993-01-06 | May & Baker Ltd | Package releasing its contents on contact with water |
GB2221159B (en) * | 1988-06-15 | 1993-02-24 | May & Baker Ltd | Package releasing its contents on contact with water |
GB2230445A (en) * | 1989-02-17 | 1990-10-24 | May & Baker Ltd | Package releasing its contents on contact with water |
GB2230445B (en) * | 1989-02-17 | 1993-10-27 | May & Baker Ltd | Package releasing its contents on contact with water |
EP0387165A1 (en) * | 1989-03-07 | 1990-09-12 | Rhone-Poulenc Agrochimie | Herbicidal combinations |
FR2644036A1 (en) * | 1989-03-07 | 1990-09-14 | Rhone Poulenc Agrochimie | HERBICIDE COMBINATION OF A WATER-SOLUBLE POLYMERIC PACKAGE AND AN N-PHOSPHONOMETHYLGLYCIN-CONTAINING HERBICIDE |
WO1992017385A1 (en) * | 1991-04-02 | 1992-10-15 | David Lucas Miles | Insecticidal composition and insecticidal units |
US5341932A (en) * | 1991-06-14 | 1994-08-30 | Rhone-Poulenc Ag Company | Aqueous formulations |
FR2686320A1 (en) * | 1991-11-21 | 1993-07-23 | Rhone Poulenc Agrochimie | CIPO - Patent - 2496090 Canadian Intellectual Property Office Symbol of the Government of Canada CA 2476092 EFFERVESCENCE AGROCHEMICAL COMPOSITION IN POWDERING CONDITION IN A WATER - SOLUBLE OR WATER - DISPERSIBLE BAG. |
FR2684968A1 (en) * | 1991-11-21 | 1993-06-18 | Rhone Poulenc Agrochimie | Containerisation system for agricultural compositions |
EP0544602A1 (en) * | 1991-11-21 | 1993-06-02 | Rhone-Poulenc Agrochimie | Container systems for agricultural compositions |
TR27227A (en) * | 1991-11-21 | 1994-12-20 | Rhone Poulenc Agrochimie | Container placement system for agricultural preparations |
FR2718610A1 (en) * | 1994-04-14 | 1995-10-20 | Roussel Uclaf | New pesticide formulations and their preparation process. |
WO1995028082A1 (en) * | 1994-04-14 | 1995-10-26 | Hoechst Schering Agrevo S.A. | Novel pesticide compositions and method of preparation |
WO2001011964A1 (en) * | 1999-08-12 | 2001-02-22 | Eli Lilly And Company | Ectoparasiticidal aqueous suspension formulations of spinosyns |
US6927210B1 (en) | 1999-08-12 | 2005-08-09 | Eli Lilly And Company | Ectoparasiticidal aqueous suspension formulations of spinosyns |
CN1306867C (en) * | 1999-08-12 | 2007-03-28 | 伊莱利利公司 | Ectoparasiticidal aqueous suspension formulations of Spinosyn |
US7772194B2 (en) | 2001-09-17 | 2010-08-10 | Eli Lilly And Company | Pesticidal formulations |
US8048861B2 (en) | 2001-09-17 | 2011-11-01 | Eli Lilly And Company | Pesticidal formulations |
Also Published As
Publication number | Publication date |
---|---|
EP0070852A1 (en) | 1983-02-09 |
JPS58500024A (en) | 1983-01-06 |
BR8206159A (en) | 1983-01-11 |
ZW1682A1 (en) | 1983-08-31 |
AU8083282A (en) | 1982-08-26 |
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