WO1982000648A1 - Porous polymer membrane and method of making it - Google Patents
Porous polymer membrane and method of making it Download PDFInfo
- Publication number
- WO1982000648A1 WO1982000648A1 PCT/SU1980/000144 SU8000144W WO8200648A1 WO 1982000648 A1 WO1982000648 A1 WO 1982000648A1 SU 8000144 W SU8000144 W SU 8000144W WO 8200648 A1 WO8200648 A1 WO 8200648A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- poli
- ρсτ
- membrane
- water
- group
- Prior art date
Links
- 238000004519 manufacturing process Methods 0.000 title abstract description 7
- 229920005597 polymer membrane Polymers 0.000 title abstract 2
- 239000012528 membrane Substances 0.000 claims abstract description 39
- VEUMBMHMMCOFAG-UHFFFAOYSA-N 2,3-dihydrooxadiazole Chemical compound N1NC=CO1 VEUMBMHMMCOFAG-UHFFFAOYSA-N 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 6
- VAYGXNSJCAHWJZ-UHFFFAOYSA-N dimethyl sulfate Chemical compound COS(=O)(=O)OC VAYGXNSJCAHWJZ-UHFFFAOYSA-N 0.000 claims description 3
- 239000002904 solvent Substances 0.000 claims description 2
- ADLSWZDEMJETGK-UHFFFAOYSA-N I.I.I.I.I.I.I.I.I.I.I Chemical compound I.I.I.I.I.I.I.I.I.I.I ADLSWZDEMJETGK-UHFFFAOYSA-N 0.000 claims 5
- LGXVIGDEPROXKC-UHFFFAOYSA-N 1,1-dichloroethene Chemical class ClC(Cl)=C LGXVIGDEPROXKC-UHFFFAOYSA-N 0.000 claims 1
- GNOIPBMMFNIUFM-UHFFFAOYSA-N hexamethylphosphoric triamide Chemical compound CN(C)P(=O)(N(C)C)N(C)C GNOIPBMMFNIUFM-UHFFFAOYSA-N 0.000 claims 1
- 239000002245 particle Substances 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 32
- 238000005345 coagulation Methods 0.000 abstract description 2
- 230000015271 coagulation Effects 0.000 abstract description 2
- KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 abstract 2
- 239000003960 organic solvent Substances 0.000 abstract 2
- FKASFBLJDCHBNZ-UHFFFAOYSA-N 1,3,4-oxadiazole Chemical compound C1=NN=CO1 FKASFBLJDCHBNZ-UHFFFAOYSA-N 0.000 abstract 1
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 abstract 1
- 238000000926 separation method Methods 0.000 abstract 1
- 239000010865 sewage Substances 0.000 abstract 1
- 230000001954 sterilising effect Effects 0.000 abstract 1
- 238000004659 sterilization and disinfection Methods 0.000 abstract 1
- 239000000203 mixture Substances 0.000 description 12
- 0 CC(CCC1)C[C@@]1C(OC)=**=CC(CC1)CCC1C(C1CCCCC1)C1CC=C(C)CC1 Chemical compound CC(CCC1)C[C@@]1C(OC)=**=CC(CC1)CCC1C(C1CCCCC1)C1CC=C(C)CC1 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- 102000001554 Hemoglobins Human genes 0.000 description 3
- 108010054147 Hemoglobins Proteins 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- -1 hexamethylphosphate Chemical compound 0.000 description 3
- DLFVBJFMPXGRIB-UHFFFAOYSA-N Acetamide Chemical compound CC(N)=O DLFVBJFMPXGRIB-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical group C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 2
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 150000003254 radicals Chemical class 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 239000002351 wastewater Substances 0.000 description 2
- 108010087702 Penicillinase Proteins 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 229920002301 cellulose acetate Polymers 0.000 description 1
- HRYZWHHZPQKTII-UHFFFAOYSA-N chloroethane Chemical compound CCCl HRYZWHHZPQKTII-UHFFFAOYSA-N 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 239000000645 desinfectant Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- OUZWUKMCLIBBOG-UHFFFAOYSA-N ethoxzolamide Chemical compound CCOC1=CC=C2N=C(S(N)(=O)=O)SC2=C1 OUZWUKMCLIBBOG-UHFFFAOYSA-N 0.000 description 1
- 229950005098 ethoxzolamide Drugs 0.000 description 1
- 229960003750 ethyl chloride Drugs 0.000 description 1
- 125000004494 ethyl ester group Chemical group 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 231100001261 hazardous Toxicity 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000002483 medication Methods 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 229950009506 penicillinase Drugs 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000001356 surgical procedure Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/28—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof by elimination of a liquid phase from a macromolecular composition or article, e.g. drying of coagulum
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/06—Organic material
- B01D71/58—Other polymers having nitrogen in the main chain, with or without oxygen or carbon only
- B01D71/62—Polycondensates having nitrogen-containing heterocyclic rings in the main chain
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2379/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen with or without oxygen, or carbon only, not provided for in groups C08J2361/00 - C08J2377/00
- C08J2379/04—Polycondensates having nitrogen-containing heterocyclic rings in the main chain; Polyhydrazides; Polyamide acids or similar polyimide precursors
- C08J2379/06—Polyhydrazides; Polytriazoles; Polyamino-triazoles; Polyoxadiazoles
Definitions
- membranes based on basic cellulose acetate are characterized by a low stability of a lot of medications and may be a little worse than normal. 5, published in May 1975 / publishing house "Kimiya", Russia /; ⁇ . ⁇ . ⁇ ⁇ gsev, ⁇ .P.Dubyaga, ⁇ . ⁇ . ⁇ a ⁇ alevs ⁇ sh ⁇ "P ⁇ lu- chenie memb ⁇ an, s ⁇ y ⁇ i ⁇ ⁇ deys ⁇ viyu v ⁇ dny ⁇ s ⁇ ed in shi ⁇ m 20. In ⁇ e ⁇ vale ⁇ ", s ⁇ .77 /.
- a stable stable ⁇ ⁇ ⁇ ⁇ ⁇
- the agglomeration due to non-incidence of 5% of water In general, in particular, they receive membranes, which are only 5 " 10 ⁇ -you have a separate output from the circuit-C
- the 15 molar mass is 13,000 and 5 atm has a selectivity of 100 and a range of 4000 l / m. days.
- the indicated method is significantly cited in.
- the device is equipped with a membrane for the process of radiating membranes and, in particular, the continuous process, when the liquid is used
- the task posed was resolved by the creation of a public system. On the basis of the operational base, 1, 3, oxydiazole, it is recommended that the product is used in a manner that is free of charge, 3,4-phase,
- ⁇ . - a radical selected from a group consisting of
- ⁇ ' is a radical taken from a group consisting of ⁇
- membranes which include poli- ⁇ , 3,4-oxadiazole, corresponding to the present invention, are included in the present invention
- ⁇ As part of the business of distributors, the following can be used: -methyl-pyrrolidine, ⁇ / -dimethylphorm-dm, / ? - dimethylacetates, hexamethylphosphate, id, clean methylated, chloroethane, tetrachlomethane, dimethylamine, dimethyl sulfate, tetrahydride or mixed.
- the present invention makes it possible to significantly reduce the cost of membrane production.
- Poli--, 3-4-oxadiazole disinfectants in the Russian manufacturer do not cause damage to materials and feeds
- membranes for the manufacture of membranes it may be possible to use the usual- and other equipment and, in particular, to the extent that they are difficult to cook, they are much less cooked.
- the abovementioned membranes, as proposed by the invention may be obtained by the following method. It is sold in poli- ⁇ , 3,4-oxadiazole in the Russian market with a cost concentration of 12-16 wt. . Such a .filter is filtered and applied at a high thickness of 200-250 ⁇ m for a turning angle of, for example, on a moving steel tape, which is not in use.
- Example 3 The diaphragm is prepared for use with I, using a 10% non-volatile temperature in the consumer, which is inactive.
- EXAMPLE 4 The membrane is prepared for example I, using the third-party application. The results of the test of the membrane are given in table I.
- Example 6 The separator shown in Example 2. The results of the test of the membrane are shown in Table I. — Example 6.
- Example 7 The membrane is prepared for use in Example 5, using a 20% industrial solution in the U-methylated form, which must be taken after application on a vaguly. The results of the test of the membrane are given in Table I. Example 7.
- ⁇ emb ⁇ anu g ⁇ vya ⁇ ⁇ ⁇ ime ⁇ u 7 is ⁇ lzuya ⁇ as ⁇ v ⁇ ⁇ lime ⁇ a in ⁇ -me ⁇ il ⁇ i ⁇ lid ⁇ ne, s ⁇ de ⁇ zhaschem 2 ⁇ ⁇ ⁇ c - ⁇ as ⁇ v ⁇ nan ⁇ sya ⁇ on chas ⁇ ichn ⁇ ⁇ g ⁇ uzhenny in v ⁇ du v ⁇ ascha ⁇ tsiy- camping s ⁇ aln ⁇ y ba ⁇ aban.
- Dieters are prepared for example I, using various types of poli-3, 3,4-oxadiazole products in the urban environment. The loss of viscosity and the resulting viscosity,
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP55502252A JPS57501237A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1980-08-22 | 1980-08-22 | |
DE19803050547 DE3050547A1 (de) | 1980-08-22 | 1980-08-22 | Porous polymer membrane and method of making it |
PCT/SU1980/000144 WO1982000648A1 (en) | 1980-08-22 | 1980-08-22 | Porous polymer membrane and method of making it |
GB8210910A GB2093460B (en) | 1980-08-22 | 1980-08-22 | Porous polymer membrane and method of making it |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/SU1980/000144 WO1982000648A1 (en) | 1980-08-22 | 1980-08-22 | Porous polymer membrane and method of making it |
WOSU80/00144800822 | 1980-08-22 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1982000648A1 true WO1982000648A1 (en) | 1982-03-04 |
Family
ID=21616656
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/SU1980/000144 WO1982000648A1 (en) | 1980-08-22 | 1980-08-22 | Porous polymer membrane and method of making it |
Country Status (4)
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5039418A (en) * | 1990-12-06 | 1991-08-13 | Exxon Research And Engineering Company | Membrane made from a multi-block polymer comprising an oxazolidone prepolymer chain extended with a compatible second prepolymer and its use in separations |
WO1994004253A2 (en) * | 1992-08-13 | 1994-03-03 | The Dow Chemical Company | Polyazole polymer-based membranes for fluid separation |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1252508A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1968-10-23 | 1971-11-03 | ||
SU520376A1 (ru) * | 1974-03-19 | 1976-07-05 | Волгоградский Политехнический Институт | Способ получени растворимых поли-1,3,4-оксадиазолов |
FR2295065A1 (fr) * | 1974-12-19 | 1976-07-16 | Furukawa Electric Co Ltd | Membrane de separation de solute |
SU556155A1 (ru) * | 1974-12-19 | 1977-04-30 | Предприятие П/Я М-5885 | Способ получени ароматических поли1,3,4-оксадиазолов |
-
1980
- 1980-08-22 JP JP55502252A patent/JPS57501237A/ja active Pending
- 1980-08-22 GB GB8210910A patent/GB2093460B/en not_active Expired
- 1980-08-22 DE DE19803050547 patent/DE3050547A1/de not_active Withdrawn
- 1980-08-22 WO PCT/SU1980/000144 patent/WO1982000648A1/en active Application Filing
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1252508A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1968-10-23 | 1971-11-03 | ||
SU520376A1 (ru) * | 1974-03-19 | 1976-07-05 | Волгоградский Политехнический Институт | Способ получени растворимых поли-1,3,4-оксадиазолов |
FR2295065A1 (fr) * | 1974-12-19 | 1976-07-16 | Furukawa Electric Co Ltd | Membrane de separation de solute |
SU556155A1 (ru) * | 1974-12-19 | 1977-04-30 | Предприятие П/Я М-5885 | Способ получени ароматических поли1,3,4-оксадиазолов |
Also Published As
Publication number | Publication date |
---|---|
DE3050547A1 (de) | 1982-09-23 |
JPS57501237A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1982-07-15 |
GB2093460B (en) | 1984-02-01 |
GB2093460A (en) | 1982-09-02 |
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