UST102909I4 - Intermediates and process for insecticidal biphenylmethyl esters - Google Patents

Intermediates and process for insecticidal biphenylmethyl esters Download PDF

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Publication number
UST102909I4
UST102909I4 US06/415,004 US41500482A UST102909I4 US T102909 I4 UST102909 I4 US T102909I4 US 41500482 A US41500482 A US 41500482A US T102909 I4 UST102909 I4 US T102909I4
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United States
Prior art keywords
iii
insecticidal
intermediates
biphenylmethyl
esters
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Pending
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US06/415,004
Inventor
Philip A. Cruickshank
Anthony J. Martinez
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Priority to US06/415,004 priority Critical patent/UST102909I4/en
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Publication of UST102909I4 publication Critical patent/UST102909I4/en
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Classifications

    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N53/00Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof

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  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Compounds of formulae II, III and IV: ##STR1## are useful intermediates for preparation of an insecticidal compound of formula (I) ##STR2## in which Ra and Rb are independently hydrogen, halogen, or alkyl. The intermediate II is prepared by reacting 3,3-dimethyl-4-pentenoic acid, a salt thereof, a lower alkyl ester or an acid chloride thereof with a compound of the formula ##STR3## in which X is hydroxy or a good leaving group. Intermediate III is prepared by reacting II with 1,1,1-trichloro-2,2,2-trifluoroethane in the presence of a solvent and catalyst. Intermediate III is then dehydrohalogenated in the presence of base to remove 2 moles of halogen halide per mole of III in one or two steps to produce I.
US06/415,004 1981-07-24 1982-09-07 Intermediates and process for insecticidal biphenylmethyl esters Pending UST102909I4 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US06/415,004 UST102909I4 (en) 1981-07-24 1982-09-07 Intermediates and process for insecticidal biphenylmethyl esters

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US28648981A 1981-07-24 1981-07-24
US06/415,004 UST102909I4 (en) 1981-07-24 1982-09-07 Intermediates and process for insecticidal biphenylmethyl esters

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
US28648981A Continuation 1981-07-24 1981-07-24

Publications (1)

Publication Number Publication Date
UST102909I4 true UST102909I4 (en) 1983-04-05

Family

ID=26963858

Family Applications (1)

Application Number Title Priority Date Filing Date
US06/415,004 Pending UST102909I4 (en) 1981-07-24 1982-09-07 Intermediates and process for insecticidal biphenylmethyl esters

Country Status (1)

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US (1) UST102909I4 (en)

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