Classifications

• • A—HUMAN NECESSITIES
  • A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
  • A47L—DOMESTIC WASHING OR CLEANING; SUCTION CLEANERS IN GENERAL
  • A47L25/00—Domestic cleaning devices not provided for in other groups of this subclass 
  • A47L25/005—Domestic cleaning devices not provided for in other groups of this subclass  using adhesive or tacky surfaces to remove dirt, e.g. lint removers
• • A—HUMAN NECESSITIES
  • A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
  • A47L—DOMESTIC WASHING OR CLEANING; SUCTION CLEANERS IN GENERAL
  • A47L13/00—Implements for cleaning floors, carpets, furniture, walls, or wall coverings
  • A47L13/10—Scrubbing; Scouring; Cleaning; Polishing
  • A47L13/16—Cloths; Pads; Sponges
• • A—HUMAN NECESSITIES
  • A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
  • A47L—DOMESTIC WASHING OR CLEANING; SUCTION CLEANERS IN GENERAL
  • A47L13/00—Implements for cleaning floors, carpets, furniture, walls, or wall coverings
  • A47L13/10—Scrubbing; Scouring; Cleaning; Polishing
  • A47L13/16—Cloths; Pads; Sponges
  • A47L13/18—Gloves; Glove-like cloths
• • C09J7/0207—
• • C—CHEMISTRY; METALLURGY
  • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
  • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
  • C09J7/00—Adhesives in the form of films or foils
  • C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
  • C09J7/35—Heat-activated
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
  • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
  • Y10T428/00—Stock material or miscellaneous articles
  • Y10T428/28—Web or sheet containing structurally defined element or component and having an adhesive outermost layer
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
  • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
  • Y10T428/00—Stock material or miscellaneous articles
  • Y10T428/28—Web or sheet containing structurally defined element or component and having an adhesive outermost layer
  • Y10T428/2813—Heat or solvent activated or sealable

Definitions

• the present invention relates to an article for cleaning hard surfaces comprising an adhesive.
• the adhesive is able to quickly trap and retain dust, lint, hairs, sand, food crumbs, grass and the like.
• said adhesive is able to retain those particles and hairs which are normally not captured by usual articles not comprising an adhesive and which need to be collected with a vacuum cleaner or a broom. This is achieved by carefully selecting the chemical composition and rheological characteristics of the adhesive.
• Hard surface cleaning articles comprising an adhesive to retain particles and hairs are known in the art.
• PCT patent application WO 01/62132 by The Procter & Gamble Company describes cleaning sheets comprising an additive that enhances the pick up and retention of particulate material from surfaces, while minimizing the amount of residue left on the surface being cleaned.
• Adhesives are mentioned among the additives which can be used.
• the mentioned application also describes a cleaning implement comprising a mop head having a resilient bottom surface, a portion of which preferably has a substantially smooth curved profile or crown which engages a removable cleaning sheet.
• the application also describes how the adhesive can be applied to the cleaning sheet only in selected zones, in order to avoid excessive tackiness and preserve the ability of the cleaning sheet to smoothly glide across surfaces
• Patent application WO 03/075735 by 3M Company describes a wipe for capturing ordinary dust or dirt and heavier particles such as sand that includes a wiping member having discrete valleys and peaks, and wherein an adhesive is provided in the valleys and not on the peaks.
• the adhesive can contact a surface sufficiently to pick up sand and other heavy particles, but not to so great a degree that the coefficient of friction between the wipe and the surface is unduly high, which can make wiping difficult.
• U.S. Pat. No. 6,550,092 from S. C. Johnson describes a cleaning sheet including a fabric layer with a plurality of cavities secured to a flexible backing layer so as to define an outer fabric surface with a plurality of cavities therein.
• the cavities can include a tacky bottom surface capable of enhancing the retention of dust and other particles. Cleaning implements and methods of cleaning surfaces using the cleaning sheet are also described.
• the hard surface cleaning articles described in the prior art can be further improved, especially as concerns their efficiency in capturing and retaining particles and hairs.
• hard surface cleaning articles comprising generic adhesives. We have surprisingly found that by selecting a specific range of adhesive materials having peculiar Theological properties, hard surface cleaning articles can be obtained having an improved efficiency of particles/hairs pickup. This translates in a much easier handling of the article, in a faster cleaning action and also in more effective cleaning, including the ability of collecting bigger particles.
• the present invention relates to a method of cleaning a hard surface which comprises contacting said surface with an article comprising an adhesive as described above.
• a further embodiment of the present invention relates to the use of an article comprising an adhesive as described above, for cleaning a hard surface in order to remove more effectively big particles and hairs.
• G′ describing the elastic behavior of the material
• G′′ which describes the viscous behavior of the adhesive material.
• G′ and G′′ are measured in Pascal (Pa) and all values must specify the temperature (° C.) and the frequency (rad/s) at which it has been measured since both G′ and G′′ can change significantly with these two parameters.
• the viscous behavior of the adhesive can be interpreted to represent an indication of the ability of the adhesive to quickly attach and securely adhere.
• the elastic behavior can be interpreted as an indication of the “hardness” of the adhesive. Its value is also critical for good initial attachment. Their combination is believed to be an indicator of the required force upon removal.
• the ratio between viscous and elastic and modulus is considered to be an indication of which fraction of the removal energy will be dissipated within the adhesive and which fraction is available to trigger the actual removal.
• the dynamic behavior of the elastic modulus at different frequencies representative of the conditions in which the adhesive respectively adheres/embeds dirt particles and retains them, is of key importance.
• the ratio between the viscous modulus and the elastic modulus is important as well in order to further optimize the adhesive selection.
• An adhesive to be used in the present invention has an elastic modulus G′ 25 at a temperature of 25° C. and a viscous modulus G′′ 25 at a temperature of 25° C. of wherein each of these values is measured at a specified frequency in rad/s.
• the adhesive further has a dynamic elastic behavior expressed in terms of elastic modulus percent increase ⁇ G′ 25 which is defined in this case as the percent increase of G′ 25 from a frequency of 0.1 rad/s to a frequency of 100 rad/s:
• G 25 ′ G 25 ′ ⁇ ( 100 ⁇ rad ⁇ / ⁇ s ) - G 25 ′ ⁇ ( 0.1 ⁇ ⁇ rad ⁇ / ⁇ s ) G 25 ′ ⁇ ( 0.1 ⁇ ⁇ rad ⁇ / ⁇ s ) ⁇ 100
• the adhesive also has a “crossover frequency” which is defined as the frequency in rad/s at which the value of G′ 25 is equal to G′′ 25 .
• the adhesive to be used in the present invention satisfies the following conditions.
• the adhesive to be used in the present invention also has a crossover frequency below 1000 rad/s, preferably below 700 rad/s most preferably below 500 rad/s.
• the adhesives of the present invention are in the form of hot melt adhesives.
• the adhesives will also preferably satisfy conditions such as sufficient cohesiveness (to prevent residue of adhesive on the treated surfaces) which are critical for commercial use of such adhesives and apparent to those skilled in the art.
• hard surface cleaning articles comprising an adhesive as described above have an improved efficacy in trapping large particles and hairs.
• adhesives work by two main mechanisms, i.e. 1) energetic interactions between the surface of the adhesive and the surface of the particle/substrate to be adhered (adherend) and 2) mechanical grafting or embedding by the adhesive of the particle/substrate to be adhered (adherend).
• both mechanisms the effectiveness of the adhesion achieves a maximum.
• the adhesive is sufficiently soft—i.e. that it's absolute value of G′ is sufficiently low—at the typical frequencies at which the bond formation occurs, e.g. between 0.01 and 1 rad/s.
• this can be interpreted as meaning that a high fraction of the energy applied for the debonding is dissipated within the adhesive (so it is not effective in causing the debonding) while this fact causes macroscopically the recording of a very high level of adhesive force.
• compositions are expressed in wt % unless otherwise stated.
• formulation criteria can be used in addition.
• most compositions useful as adhesive have a substantially gel-like structure and are preferably gels.
• Gels are materials wherein a three dimensional network caused by physical or chemical links formed between the molecules. Gels commonly comprise a relatively large amount (30-80 wt %) of low molecular weight components like plasticizers and tackifiers which are often liquid at room temperature and an amount of a macromolecular or polymeric component which is generally less than 50% in weight of the gel.
• the adhesive compositions to be used in the present invention preferably comprise:
• the adhesives to be used in the present invention are gels based on a hydrophobic polymer, otherwise called “oil gels”.
• additives known in the art as preservatives, antioxidants, anti UV, pigments, mineral fillers, rheology modifiers etc. can also be comprised in quantities up to 10% by weight each.
• Articles according to the present invention are hard surface cleaning articles.
• hard surfaces are all common surfaces which are present inside or outside a house and which are not covered by fabrics, fibers or earth/grass and include floors, walls, doors, furniture, appliances and the like.
• Hard surfaces can be made with almost any material including resin, rubber, plastic, gres, marble, ceramics, porcelain, stone, metals (steel, aluminum), cement, bricks etc. More specifically the term hard surfaces, as defined in the present invention, include linoleum and resin surfaces and exclude carpet surfaces.
• the present invention relates to a hard surface cleaning article comprising an adhesive as described above.
• the article can be any known hard surface cleaning article, for example as those described in the prior art documents cited in the Background of Invention section of the present patent application.
• the adhesive can be applied onto a portion of the article or be incorporated as a removable cartridge or sheet.
• the articles of the present invention are disposable sheets like wipes or pads which can be used directly by hand or preferably affixed onto the head of a mop such as, for example, those described in FIGS. 1 and 2 of patent application WO01/62132 so that once the sheet has been used it can be disposed and substituted with a new one.
• the sheets can be attached to any type of implement which can aid wiping said sheet onto a surface including for example a cylindrical support which can be rolled onto a surface in order to clean it.
• Sheets according to the present invention can be made according to all known designs and construction for cleaning sheets such as but not limiting to those mentioned in the already cited patent applications WO01/62132 by Procter & Gamble, WO 03/075735 by 3M and U.S. Pat. No. 6,550,092 by S. C. Johnson. Accordingly sheets comprise as a substrate any natural or synthetic fibrous material in the form of a woven fabric or a knit fabric, a non woven fabric, a laminate of a fabric and a polymeric film and combinations thereof. Methods of making such substrate are also well know in the art and are not described in detail herein. Preferably said substrate is a non woven fabric.
• the adhesive comprised in the articles of the present invention does not directly contact the hard surface, or at least does not contact it to a large extent, otherwise the article could stick to the hard surface and prevent gliding. It is in fact preferred that the adhesive is present in a recessed area of the article so that particles and hairs which need to be removed can get in contact with the adhesive while the article is quickly passed onto the surface to be cleaned and be trapped into it.
• the adhesive may contact the particle or the hair for a fraction of second and only on a small portion of their surface, so it is crucial that the adhesive has the right “softness” features as described above in order to stick to the particle or hair and to trap it fast enough.
• said article can have any configuration wherein the adhesive has a limited contact or no contact at all with the surface to be cleaned.
• the articles of the present invention are sheets having a three dimensional structure comprising valleys and peaks wherein the adhesive in the valleys only.
• the articles of the present invention are multi layer sheets comprising a layer of adhesive sandwiched between to fabric layers wherein one of the fabric layers have holes.
• the article of the present invention are sheets wherein a layer of adhesive is covered by a very light fibrous layer which is resilient enough to avoid, when in use, contact of the adhesive with the surface to be treated and wherein the space between the fibers of said fibrous layer is large enough to allow particles and hairs to reach the adhesive and be trapped into that.
• the articles of the present invention are sheets having non uniform thickness, comprising at least two raised areas and a recessed area, wherein the adhesive is applied onto the recessed area so that when the sheets is placed onto an hard surface only the raised portions will contact said surface.
• the article of the present invention is a brush for removing particles such as breadcrumbs, comprising means to pick up particles from a hard surface and means to collect them to an inner compartment of said article where an adhesive as described above is applied (preferably in the form of a disposable sheet) so that it can capture and retain said particles.
• an adhesive as described above is applied (preferably in the form of a disposable sheet) so that it can capture and retain said particles.
• the adhesive is preferably in a removable cartridge or sheet which, when exhausted, can be disposed with the trapped particles.
• the articles of the present invention in all embodiments can also optionally comprise a cleaning lotion.
• a cleaning lotion e.g. a wax, a solvent or a water based solution.
• Cleaning lotions if present, preferably comprise a surfactant.
• the adhesives used in the present invention due to their rheological properties, are able to retain particles also in the presence of cleaning lotions which reduce the tackiness of the adhesive surface.
• An adhesive wipe according to the present invention was made using a commercially available spundbond polypropylene nonwoven web having a basis weight of 20 grams per square meter, available from Avgol Corporation of Holon, Israel.
• the adhesive was applied into recessed areas of the nonwoven by an embossing and adhesive printing process as described in our patent U.S. Pat. No. 6,881,471.
• the substrate was embossed between male and female rolls 15 and 16. The rolls were engaged between 1 to 1.5 mm (0.04 to 0.06 inches).
• the embossed substrate, maintaining contact and registration with the male roll 15 rotated toward the glue transfer nip.
• the adhesive transfer nip 17 was a second female role having a 0.13 mm (0.0005 inch) FEP release coating and an embossed pattern that is in register and had 0.4 mm (0.016 inch) engagement with the male pattern role.
• the adhesive was extruded onto the surface of the first adhesive application metering roll via a slot die 22.
• the application temperature for both the adhesive and the slot die was set at 130 C.
• the adhesive passed through metering rolls 22 and was transferred to the land areas of the adhesive transfer nip 17. Interaction between last metering roll 22 and embossing roll 17 was controlled to ensure adhesive application to the lands of the first embossing roll 17, without pressing the adhesive into the recesses or pockets between lands.
• the adhesive was applied on the second female roll at a basis weight of 2 grams per square meter. The combined adhesive/substrate was then pressed by a rubber covered niproll.
• the applied adhesive is a hot melt supplied by National Starch under the trade name Softgel 555-8819.
• the G′ at 0.1 rad/s and 25° C. of this adhesive material is 2700 Pa.

Landscapes

• Chemical & Material Sciences (AREA)
• Organic Chemistry (AREA)
• Cleaning Implements For Floors, Carpets, Furniture, Walls, And The Like (AREA)
• Adhesives Or Adhesive Processes (AREA)
• Detergent Compositions (AREA)
• Compositions Of Macromolecular Compounds (AREA)

Applications Claiming Priority (2)

Publications (2)

Family

ID=35311129

Family Applications (2)

Family Applications After (1)

Country Status (7)

Families Citing this family (2)

Citations (9)

Family Cites Families (12)

• 2005
  • 2005-08-05 EP EP05017142A patent/EP1749470A1/fr not_active Withdrawn
• 2006
  • 2006-06-27 EP EP06013182A patent/EP1749471B1/fr not_active Revoked
  • 2006-06-27 AT AT06013182T patent/ATE416666T1/de not_active IP Right Cessation
  • 2006-06-27 DE DE602006004117T patent/DE602006004117D1/de active Active
  • 2006-06-27 ES ES06013182T patent/ES2318619T3/es active Active
  • 2006-08-03 MX MX2008001787A patent/MX2008001787A/es unknown
  • 2006-08-03 US US11/498,370 patent/US9775490B2/en active Active
  • 2006-08-03 JP JP2008525171A patent/JP2009516530A/ja active Pending
  • 2006-08-04 US US11/499,051 patent/US20070032565A1/en not_active Abandoned

Patent Citations (10)

Non-Patent Citations (2)

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