US949444A - Art of case-hardening or cementing. - Google Patents

Art of case-hardening or cementing. Download PDF

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Publication number
US949444A
US949444A US49626909A US1909496269A US949444A US 949444 A US949444 A US 949444A US 49626909 A US49626909 A US 49626909A US 1909496269 A US1909496269 A US 1909496269A US 949444 A US949444 A US 949444A
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cementing
hardening
art
coking
case
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US49626909A
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Hugh Rodman
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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C8/00Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C8/60Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using solids, e.g. powders, pastes
    • C23C8/62Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using solids, e.g. powders, pastes only one element being applied
    • C23C8/64Carburising
    • C23C8/66Carburising of ferrous surfaces

Definitions

  • This invention relates to the art of casehardening or cementing and more particularly to materials for use in same art.
  • I mean such material, not necessarily carbonaceous material, as will when added to an inactive carbonaceous substance, render such carbonaceous substance active, as a I have found that by mixing with these shrinkable materials certain proportions of a setting or coking material I can obtain cementing material practically free from shrinkage. For instance, peat with ten per cent. of slaked lime has cementing properties but will shrink in use about seventy-five per cent. By mixing peat,
  • cementing material satisfactory both in carbonizing efficiency and in supporting power.
  • the cementing material thus obtained does not remain granular nor pulverulent during use as a case-hardening or cementing material as does charcoal and bone dust, but instead there is a more or less marked adhesion of particles throughout the mass caused by the fritting together of the coking and shrinkable constituents and it is this adhesion (which is controllable by varying the/ratio of coking to shrinkable material) which explains the good supporting qualities of the mixture.
  • a cementing compound containing coking material and shrinkable carbonaceous matter 1.

Description

' slakcd lime and bituminous coking coal in ing materials so far as regards .their ability rials, either alone or in combination with an carbonizing agent.
nnrran srrrrns rarnnr QJFFKCE,
HUGH RODMAN, 0F PITTSBURG, PENNSYLVANIA.
ART OF GASE-HARDENING OR CEMENTING.
No Drawing.
To all whom it may concern:
Be it known that I, HUGH RODMAN, a citizen or the United States, and a resident of Pittsburg, in the county of Allegheny and State of Pennsylvania, have made a new and useful Invention in the Art of Case-Hardening or Cementing, of which the following is a specification.
This invention relates to the art of casehardening or cementing and more particularly to materials for use in same art.
Certain vegetable and mineral matters used alone or in admixture with various energizing substances are excellent cementto surrender carbon to heated iron, but are practically useless in service because of excessive shrinkage underheat treatment. As examplesmf such materials, I may mention saw-dustand various low forms of coal, such as peat and lignite. All of these mateenergizing substance, such as lime or sodaash, as described by me in a co-pending application for patent Serial No. 496,271, filed on or about May 15, 1909, have active cementing properties, but when heated change so greatly in volume and supporting power as to' render ,them wholly impracticable as dry packing material. By energizing substance, I mean such material, not necessarily carbonaceous material, as will when added to an inactive carbonaceous substance, render such carbonaceous substance active, as a I have found that by mixing with these shrinkable materials certain proportions of a setting or coking material I can obtain cementing material practically free from shrinkage. For instance, peat with ten per cent. of slaked lime has cementing properties but will shrink in use about seventy-five per cent. By mixing peat,
proportions 50, 10 and 50 by weight, I can produce cementing material which is satisfactory in all respects. Again, saw-dust with seventy-five per cent. of soda-ash has active cementing properties but shrinks so under-heat treatment as to render its use impracticable, but by mixing therewith seventy-five parts by weight of coking coal I have produced cementing material having active cementing properties and good supporting qualities. I have found that by Specification of Letters Patent. Patented Feb. 15, 1 910. Application filed May 15, 1909. Serial No. 496,269. I I
adding heavy hydrocarbons such as asphaltum or materials containing heavy hydrocarbons, such as crude petroleum, to various cementing materials, unfit in themselves because of their shrinking or settling qualities, I have obtained cementing material satisfactory both in carbonizing efficiency and in supporting power. The cementing material thus obtained does not remain granular nor pulverulent during use as a case-hardening or cementing material as does charcoal and bone dust, but instead there is a more or less marked adhesion of particles throughout the mass caused by the fritting together of the coking and shrinkable constituents and it is this adhesion (which is controllable by varying the/ratio of coking to shrinkable material) which explains the good supporting qualities of the mixture. I am not certain that the individual particles of shrinkable material do not shrink as much when mixed with coking material as they do alone, but the mixed mass-as a whole retains substantially its original volume and has sufficient supporting power to render it practicable as acementing material. Moreover, the coking constituent of the material I find does not coke to such an extent as to be objectionable.
The mixtures given are by way of example only, as various coking and shrinkable ma terials may be combined and used either with or without energizin substances and the ratio of coking to shrinkable material may be varied to produce cementing material of definite rigidity and strength when heated, depending upon the character of the work and the methods'to be followed in the use of the cementing material.
In using the cementing material, when it is desired to empty the contents of the heated pots directly'into the quenching bath, the mixture will be proportioned so that just sufficient. strength and rigidity will be obtained to support the metal parts to be treated, and when the metal parts to be treated are allowed to cool slowly in the carbonizing pots, a mixture which will producg material of greater rigidity may be use Having thus described my invention, what I claim is:
1. A cementing compound containing coking material and shrinkable carbonaceous matter.
2. A cementing compound containing coksubscribed my name this 12th day of May,
ing cgel, peat and lime. 1 1909. g
3. cementing compound containing 00 ing coal, peat 51nd soda ash. HUGH 5 4; A cementing compound containing cok- Witnesses:
ingcoal, peat, lime and soda ash. C. W. MOGHEE,
In testimony whereof, I have hereunto GEO. C. WALKER.
US49626909A 1909-05-15 1909-05-15 Art of case-hardening or cementing. Expired - Lifetime US949444A (en)

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