US936389A - Method of treating metal. - Google Patents

Method of treating metal. Download PDF

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US936389A
US936389A US44953108A US1908449531A US936389A US 936389 A US936389 A US 936389A US 44953108 A US44953108 A US 44953108A US 1908449531 A US1908449531 A US 1908449531A US 936389 A US936389 A US 936389A
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metal
article
depressions
projections
passes
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US44953108A
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Frank L O Wadsworth
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    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/14—Removing excess of molten coatings; Controlling or regulating the coating thickness
    • C23C2/22—Removing excess of molten coatings; Controlling or regulating the coating thickness by rubbing, e.g. using knives, e.g. rubbing solids
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/12—All metal or with adjacent metals
    • Y10T428/12014—All metal or with adjacent metals having metal particles
    • Y10T428/12028—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, etc.]
    • Y10T428/12063—Nonparticulate metal component
    • Y10T428/1209—Plural particulate metal components
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/12—All metal or with adjacent metals
    • Y10T428/12389—All metal or with adjacent metals having variation in thickness

Definitions

  • the invention described herein relates to certain improvements in the art of forming a dense protective coating or skin of substantial thickness on the surface of metal articles.
  • This skin or coating is produced by increasing the superficial area of the metal by forming projections on or depressions in the surfaces of the .metal preferably during the shaping of the metal, chilling the surfaces of the projections or depressions and finally forcing the chilled walls of the projections or depressions into a common plane, or in other words decreasing the superficial area of the article. due, it is thought to a structural or physical change in the molecules and not in any ma-' terial degree to any chemical change.
  • This invention has for its object the production of both a'physical and a chemical change in thecharacter of the metal forming the skin, bycombining or alloying with such metal, a material or materials, which will so change or modify the metal composing the skin as to impart improved resistant qualities to the surface without detrimentally affecting the physical change produced by the mechanical treatment of the metal.
  • FIG. 1 is a seetional elevation of a form of apparatus adapted to the practice of my invention
  • Fig. 2 is a similar view illustrating a modification of the apparatus
  • Fig. 3 is an elevation of the rolls shown in Fig. 1, and illustrating a construction of the roll-surfaces for V the mechanical treatment of the metal Fig.
  • FIG. 4 is a diagrammatic view illustrating a step in my improved method
  • Fig. 5 is a similar view illustrating the rolling down of the kneaded projecting portions of the metal The skin thus produced is' to a uniform plane, and the action resulting therefrom.
  • the surfaces of the article to be treated are subjected, preferably during the reduction of the metal to the desired shape, to the action of projection or depression forming surfaces, and during such operation, the material such as carbon, vanadium, nickel, ,zinc, etc., which is to be incorporated or alloyed with the surface metal, is applied to the surface or surfaces of the article in a finely divided or pulverulent condition.
  • the material such as carbon, vanadium, nickel, ,zinc, etc., which is to be incorporated or alloyed with the surface metal, is applied to the surface or surfaces of the article in a finely divided or pulverulent condition.
  • the finely divided material will be forced 1nto and thoroughly mixed with the metal and being in a finely divided condition will quickly and readily combine or alloy thercwith.
  • the invention described herein can be conveniently carried out, while reducing the metal by rolling between rolls having passes shaped to produce the article desired. It will be understood that although the invention is shown and described as carried out in a three high mill having the passes shaped to form sheet bars or skelps that. other forms or construction of mills may be employed and the passes shaped to produce the article desired. As shown the reducing surfaces which when in contact with the metal move in the same direction as the metal, are constructed to form projections on or depressions inthe surface of the metal.
  • the metal should be subjected to the projection or depression forming surfaces in a plurality of passes, both for the reason that suflicient chilling of the surfaces of the projections and depressions can be effected by the roll-surfaces and for the reason thatamore effectual and thorough incorporation of the combining or alloying materialcan be effected, when a plurality of the passes having marked or patterned surfaces are employed, it is preferred that the marks or patterns on successively operating roll surfaces should be varied so that the material to be combined or alloyed can be more thoroughly kneaded into the metal.
  • the material to be combined or alloyed with the metal may be applied to the surterial from the box onto the article.
  • the finely divided material may be placed in a box 3, suitably supported above or both above and below the position of the article when moving into 'a pass in the rolls.
  • the forward ends of thebox is closed by a roller 4: suitably mounted so as to be rotated in any manner as by contact with the article being rolled.
  • the surface of the roller is slightly roughened so as to carry the Tm;-
  • e material is pushed forward into contact with the roller by a piston 5 or any other suitable means and the amount of material carried out by the rollers is .regulated by gates 6.
  • the roller should press with some considerable force against the article so as to embed the material in the surface of the article or cause it to adhere thereto until workedin by the rolls; This requisite pressure can be obtained by a spring 7 or other suitable means.
  • rovide a bridge or feed blocka interposed between the feed roll and the lower roll which serves to catch any material not adhering to the under surface and return it to said under surface through the action of the corrugated or marked face of the lower roll.
  • pulverulent material is carried by a roller 8 into a nozzle 9 where it is caught by a stream of fluid flowing from the pipe 10 (which is connected to a suitable source of fluid under pressure,) and forced through the end of the nozzle and between the roll and the article.
  • Another form of apparatus consists of adrum 11 into which the material is forced from one end by a screw 12 on the shaft 13. As the screw shaft is rotated the material is drawn in and distributed alongthe drum in front of openings 14 connecting with the nozzle 15.
  • the material reaches these openings, it is forced through into the nozzle by fluid introduced under pressure into the drum through the hollow shaft 13.
  • fluid introduced under pressure into the drum through the hollow shaft 13.
  • suificient material to produce the desired effect can not be applied in the first marking or patterning pass, successive applications of the same or of different materials can be applied in any or all of the passes as desired.
  • the kneadin of the metal due to the successive actions 0 the marking or patterning surfaces, especially if the marks or patterns on such successive surfaces are varied, will effectually work the of the material with the metal, theplate bar or other shape is sent through one or more smoothing passes, and in these passes. the projections or depressions formed by the marked or patterned rolls are compressed to a smooth surface. In these final passes the area of the patterned or marked surface is reduced as shown in Figs. 4 and 5, and by reason of this reduction the composite material of the surface skin is subjected to compression, resultin in a 'very substantial densification oft e particles of this skin,
  • the method of treating metal which consists in applying a combining or alloy- 1 ing material in a finely divided condition to the surface of highly heated metal, and incorporating such material with the metal by forming projections on or depressions in the metal after the application of the metal and eliminating the projections or depressions so formed by pressure applied in a direction substantially normal to such surface.
  • the method of treating metal which consists in applying a combining or alloying material in a finely divided condition to the surface of highly heated metal, and incorporating such material with the metal by forming projections on or depressions in the metal after the application of the metal, chilling the surfaces of the projections or depressions and restoring the surface of the metal to a uniform plane by pressure applied in a direction substantially normal to.
  • the method herein described which consists in applying a combining or alloying material in a finely dividedstate to the surface of highly heated metal and then incorporating such material with the metal by the successiye formation of differently shaped projections or depressions whereby the material and the surface metal are kneaded together and rolling down said depressions and projections to form a surface of less area, thereby subjecting the material 10 on the surface to compression in a direction substantially parallel with said surface.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Metal Rolling (AREA)

Description

F. L. O. WADSWORTH.
METHOD OF TREATING METAL.
APPLICATION FILED AUG.20, 1908.
936,389, Patented Oct. 12, 1909.
2 SHEETS-SHEET 1.
NVENTOR MM FRANKLTOWADISWORTH. 5 pf 8f 5 (lbac wflmr,
F. L. O. WADSWORTH.
METHOD OF TREATING METAL.
APPLIGATION FILED AUG. 20, 1908.
Patented Oct. 12, 1909.
2 SHEETS-SHEET 2.
FIGS- A G H FRANK L. 0. WADSWEIEQEIIIC-JIR 27 awa t: Q5335,
WITNESSES:
dm fa lq/q -Am eA area.
Y FRANK L. O. WADSWORTH, OF SEVICKLEY, PENNSYLVANIA.
METHOD OF TREATING METAL.
Specification of Letters Patent.
Patented Oct. 12, 1909.
To all whom it may concern:
Be it known that I, FRANK L. O. WADs- WORTH, residing at Sewickley, in the county of Allegheny and Stateof Pennsylvania, a citizen of the United States, have invented or discovered certain new and useful Improvements in Methods of Treating Metal, of which improvement the following is a specification.
The invention described herein relates to certain improvements in the art of forming a dense protective coating or skin of substantial thickness on the surface of metal articles. This skin or coating is produced by increasing the superficial area of the metal by forming projections on or depressions in the surfaces of the .metal preferably during the shaping of the metal, chilling the surfaces of the projections or depressions and finally forcing the chilled walls of the projections or depressions into a common plane, or in other words decreasing the superficial area of the article. due, it is thought to a structural or physical change in the molecules and not in any ma-' terial degree to any chemical change.
This invention has for its object the production of both a'physical and a chemical change in thecharacter of the metal forming the skin, bycombining or alloying with such metal, a material or materials, which will so change or modify the metal composing the skin as to impart improved resistant qualities to the surface without detrimentally affecting the physical change produced by the mechanical treatment of the metal.
The invention is hereinafter more fully described and claimed.
In the accompanying drawings forming a part of this specification Figure 1 is a seetional elevation of a form of apparatus adapted to the practice of my invention; Fig. 2 is a similar view illustrating a modification of the apparatus; Fig. 3 is an elevation of the rolls shown in Fig. 1, and illustrating a construction of the roll-surfaces for V the mechanical treatment of the metal Fig.
4 is a diagrammatic view illustrating a step in my improved method, and Fig. 5 is a similar view illustrating the rolling down of the kneaded projecting portions of the metal The skin thus produced is' to a uniform plane, and the action resulting therefrom.
In the practice of my invention the surfaces of the article to be treated are subjected, preferably during the reduction of the metal to the desired shape, to the action of projection or depression forming surfaces, and during such operation, the material such as carbon, vanadium, nickel, ,zinc, etc., which is to be incorporated or alloyed with the surface metal, is applied to the surface or surfaces of the article in a finely divided or pulverulent condition. As the metal is quite soft and plastic at this time the finely divided material will be forced 1nto and thoroughly mixed with the metal and being in a finely divided condition will quickly and readily combine or alloy thercwith.
The invention described herein can be conveniently carried out, while reducing the metal by rolling between rolls having passes shaped to produce the article desired. It will be understood that although the invention is shown and described as carried out in a three high mill having the passes shaped to form sheet bars or skelps that. other forms or construction of mills may be employed and the passes shaped to produce the article desired. As shown the reducing surfaces which when in contact with the metal move in the same direction as the metal, are constructed to form projections on or depressions inthe surface of the metal. It is preferred that the metal should be subjected to the projection or depression forming surfaces in a plurality of passes, both for the reason that suflicient chilling of the surfaces of the projections and depressions can be effected by the roll-surfaces and for the reason thatamore effectual and thorough incorporation of the combining or alloying materialcan be effected, when a plurality of the passes having marked or patterned surfaces are employed, it is preferred that the marks or patterns on successively operating roll surfaces should be varied so that the material to be combined or alloyed can be more thoroughly kneaded into the metal.
The material to be combined or alloyed with the metal may be applied to the surterial from the box onto the article.
faces in any suitable manner. As for example the finely divided material may be placed in a box 3, suitably supported above or both above and below the position of the article when moving into 'a pass in the rolls. The forward ends of thebox is closed by a roller 4: suitably mounted so as to be rotated in any manner as by contact with the article being rolled. The surface of the roller is slightly roughened so as to carry the Tm;-
e material is pushed forward into contact with the roller by a piston 5 or any other suitable means and the amount of material carried out by the rollers is .regulated by gates 6. When applying the material to the under surfaces of an article the roller should press with some considerable force against the article so as to embed the material in the surface of the article or cause it to adhere thereto until workedin by the rolls; This requisite pressure can be obtained by a spring 7 or other suitable means. In this case it is also desirable to rovide a bridge or feed blocka interposed between the feed roll and the lower roll which serves to catch any material not adhering to the under surface and return it to said under surface through the action of the corrugated or marked face of the lower roll.
In Fig.2-the pulverulent material is carried by a roller 8 into a nozzle 9 where it is caught by a stream of fluid flowing from the pipe 10 (which is connected to a suitable source of fluid under pressure,) and forced through the end of the nozzle and between the roll and the article. Another form of apparatus consists of adrum 11 into which the material is forced from one end by a screw 12 on the shaft 13. As the screw shaft is rotated the material is drawn in and distributed alongthe drum in front of openings 14 connecting with the nozzle 15. As
the material reaches these openings, it is forced through into the nozzle by fluid introduced under pressure into the drum through the hollow shaft 13. In this form of application is secured not only a uniform feed of the material to the initial surfaces simultaneously with the entrance of the same into the roll pass but there is also secured a cooling action of the surfaces by the action of the fluid. If suificient material to produce the desired effect can not be applied in the first marking or patterning pass, successive applications of the same or of different materials can be applied in any or all of the passes as desired. As will be readily understood the kneadin of the metal due to the successive actions 0 the marking or patterning surfaces, especially if the marks or patterns on such successive surfaces are varied, will effectually work the of the material with the metal, theplate bar or other shape is sent through one or more smoothing passes, and in these passes. the projections or depressions formed by the marked or patterned rolls are compressed to a smooth surface. In these final passes the area of the patterned or marked surface is reduced as shown in Figs. 4 and 5, and by reason of this reduction the composite material of the surface skin is subjected to compression, resultin in a 'very substantial densification oft e particles of this skin,
with a consequent increase in its resistance Y to corrosion and abrasion. By reason of the described treatment, a very complete and effective amalgamation or alloying of the original surface metal and of thepowdered or finely divided material applied thereto is obtained, and an article is produced having an exterior surface possessing new and valuable characteristics, due in part to the nature of'the new combination of materials, and in part to the mechanical treatment to which said surface has been subjected during such combination.
I claim herein as my invention:
1. The method of treating metal, which consists in applying a combining or alloy- 1 ing material in a finely divided condition to the surface of highly heated metal, and incorporating such material with the metal by forming projections on or depressions in the metal after the application of the metal and eliminating the projections or depressions so formed by pressure applied in a direction substantially normal to such surface.
2. The method of treating metal, which consists in applying a combining or alloying material in a finely divided condition to the surface of highly heated metal, and incorporating such material with the metal by forming projections on or depressions in the metal after the application of the metal, chilling the surfaces of the projections or depressions and restoring the surface of the metal to a uniform plane by pressure applied in a direction substantially normal to.
such surface. a
3. The method herein described which- -consists in applying a combining 0r alloying material in a finely divided state to the surface of highly heated metal and then incorporating such material with the metal by the successive formation of diflerently.
4. The method herein described which consists in applying a combining or alloying material in a finely dividedstate to the surface of highly heated metal and then incorporating such material with the metal by the successiye formation of differently shaped projections or depressions whereby the material and the surface metal are kneaded together and rolling down said depressions and projections to form a surface of less area, thereby subjecting the material 10 on the surface to compression in a direction substantially parallel with said surface.
In testimony whereof, I have hereunto set my hand.
FRANK L. O. WADSWORTH. Witnesses:
CHARLES BARNETT, FRIEDA E. WOLFF.
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Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2446892A (en) * 1943-10-23 1948-08-10 Sk Wellman Co Method of shaping bimetallic articles
US2446891A (en) * 1944-01-29 1948-08-10 Sk Wellman Co Method of bending bimetallic articles
US2877738A (en) * 1954-03-01 1959-03-17 Heck Friedrich Apparatus for rolling metallic powder on a strip
US2914425A (en) * 1956-03-14 1959-11-24 Joseph C Mcguire Method for soldering normally nonsolderable articles
US3083407A (en) * 1959-06-08 1963-04-02 Copperweld Steel Co Powder cladding
US3087240A (en) * 1958-09-29 1963-04-30 Texas Instruments Inc Method of making ceramic-to-metal composite stock
US3109331A (en) * 1961-05-05 1963-11-05 Republic Steel Corp Method of texturing metal sheets
US3216059A (en) * 1961-09-29 1965-11-09 Voelskow Peter Apparatus for producing fiberboard sheets
US3807970A (en) * 1964-09-09 1974-04-30 C Greene Drill proof plate for safes
US4242150A (en) * 1979-05-25 1980-12-30 Maxwell Herris M Method of producing reinforcing bars with corrosion resistant coating
WO1982003575A1 (en) * 1981-04-16 1982-10-28 Philip O Badger Implantation of molybdenum disulfide into certain metallic surfaces by mechanical inclusion
US4528079A (en) * 1983-05-25 1985-07-09 Miracle Metals, Inc. Method of mitigating boundary friction and wear in metal surfaces in sliding contacts
US5316863A (en) * 1992-05-18 1994-05-31 Alcan International Limited Self-brazing aluminum laminated structure

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2446892A (en) * 1943-10-23 1948-08-10 Sk Wellman Co Method of shaping bimetallic articles
US2446891A (en) * 1944-01-29 1948-08-10 Sk Wellman Co Method of bending bimetallic articles
US2877738A (en) * 1954-03-01 1959-03-17 Heck Friedrich Apparatus for rolling metallic powder on a strip
US2914425A (en) * 1956-03-14 1959-11-24 Joseph C Mcguire Method for soldering normally nonsolderable articles
US3087240A (en) * 1958-09-29 1963-04-30 Texas Instruments Inc Method of making ceramic-to-metal composite stock
US3083407A (en) * 1959-06-08 1963-04-02 Copperweld Steel Co Powder cladding
US3109331A (en) * 1961-05-05 1963-11-05 Republic Steel Corp Method of texturing metal sheets
US3216059A (en) * 1961-09-29 1965-11-09 Voelskow Peter Apparatus for producing fiberboard sheets
US3807970A (en) * 1964-09-09 1974-04-30 C Greene Drill proof plate for safes
US4242150A (en) * 1979-05-25 1980-12-30 Maxwell Herris M Method of producing reinforcing bars with corrosion resistant coating
WO1982003575A1 (en) * 1981-04-16 1982-10-28 Philip O Badger Implantation of molybdenum disulfide into certain metallic surfaces by mechanical inclusion
US4528079A (en) * 1983-05-25 1985-07-09 Miracle Metals, Inc. Method of mitigating boundary friction and wear in metal surfaces in sliding contacts
US5316863A (en) * 1992-05-18 1994-05-31 Alcan International Limited Self-brazing aluminum laminated structure

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