US919884A - Manufacture of lubricating and anticorrosive oils. - Google Patents
Manufacture of lubricating and anticorrosive oils. Download PDFInfo
- Publication number
- US919884A US919884A US29301805A US1905293018A US919884A US 919884 A US919884 A US 919884A US 29301805 A US29301805 A US 29301805A US 1905293018 A US1905293018 A US 1905293018A US 919884 A US919884 A US 919884A
- Authority
- US
- United States
- Prior art keywords
- oils
- alcohol
- lubricating
- manufacture
- oleates
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000003921 oil Substances 0.000 title description 13
- 230000001050 lubricating effect Effects 0.000 title description 4
- 238000004519 manufacturing process Methods 0.000 title description 3
- 235000019441 ethanol Nutrition 0.000 description 20
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 15
- 239000003513 alkali Substances 0.000 description 12
- 238000009835 boiling Methods 0.000 description 10
- 229930195733 hydrocarbon Natural products 0.000 description 8
- 150000002430 hydrocarbons Chemical class 0.000 description 8
- 239000000203 mixture Substances 0.000 description 7
- 150000001298 alcohols Chemical class 0.000 description 6
- 238000000034 method Methods 0.000 description 5
- 239000002253 acid Substances 0.000 description 4
- 239000004215 Carbon black (E152) Substances 0.000 description 3
- 239000000314 lubricant Substances 0.000 description 3
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 2
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 2
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 2
- 239000005642 Oleic acid Substances 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 239000002480 mineral oil Substances 0.000 description 2
- 101100489581 Caenorhabditis elegans par-5 gene Proteins 0.000 description 1
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 230000001066 destructive effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- VKYKSIONXSXAKP-UHFFFAOYSA-N hexamethylenetetramine Chemical compound C1N(C2)CN3CN1CN2C3 VKYKSIONXSXAKP-UHFFFAOYSA-N 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 235000015927 pasta Nutrition 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- IVDFJHOHABJVEH-UHFFFAOYSA-N pinacol Chemical compound CC(C)(O)C(C)(C)O IVDFJHOHABJVEH-UHFFFAOYSA-N 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 229940099259 vaseline Drugs 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M101/00—Lubricating compositions characterised by the base-material being a mineral or fatty oil
- C10M101/02—Petroleum fractions
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M129/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen
- C10M129/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen having a carbon chain of less than 30 atoms
- C10M129/04—Hydroxy compounds
- C10M129/06—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/129—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of thirty or more carbon atoms
Definitions
- This invention relates to the manufacture of lubricating and anti'corrosi've oils, cape cially of such oils, which are ada ted to solve or to remove the residues 0 nitric gunpowders from the bore offire'arms.
- the invention consists 1n mixing alkali 2 0 oleates with hydrocarbons and alcohol or alcohols which have a high boiling point.
- 1* first add to I the alkaliolea'tes, beforemixing them with y H able of formin an emulsiornfan alcohol or acohols havin a h 1 boiling point and whichQcan be heate to'tie' boilin point without, v..dec(imposition.
- I have ound that glycerin, which is sometimes considered to be an' alcohol', and ethyl alcohol cannot-be satisfactorily employed'in carrying out my recess but' I can use'of the aliphatic series'a mono acid. (monatomic) alcohols from ropyl alcohol u ward and of the-di v acid diatomic) classt e inacone. Phenyl paraflin alcoholsmay; a
- the newcompounds obtained are capable of dissolving or removing the destructive residues which remain in the bores of firearms when fired with nitric powders.
- the lubricants composed according to myinvention combine with the said residues, which in conseuence are removed more speedil and t oroughly1 than it was hitherto possible by mere mec anical action by means of'other The arms are therefore preserved in a more erfect state than formerly.
- the 'gh-boiling alcohols above referred to do not combine with the alkalies themselves; nevertheless the combination which is necessary for the present purpose can be effected forinstance by first'combinin the oleic acid with the alkalies and then a ding the high-boiling alcohol, or by first embodying the latter into the oleic acid, then adding the alkalies and finally incorporating the resultin mixture with the hydrocarbons and the li e, thus, producing. the'desired qualities.
- the roportion of high-boiling alcohols and al ali oleates 'varies from 15 to 30 per cent., accordin to the quality, density or viscosity of the hy rocarbon to be improved.
- the hydrocarbon which is to be employed contains alcohol which would be decomposed when subjected to a high temperature, such alcohol may be removed and replaced wholly or to any desired extent b alcohol of the proper character. If 0 y a transito efiect istobe reduced the high boiling a cohol may be ad ed to the finished. product preferably under pressure of from about 1 kg. per sq. cm. to 4 k per sq. 'cm.
Description
45 the .oils to. be made ca STA E 'iA OF CE.
wltuntiixtav ua; orooLoeNE, eEaMANY-. I, w nnuzsnrea'rmenm an'rrconaosrvn ons.
" Specification of Letters Patent.
- Pastas April .27 100,9.
' .Applioa tion .fllednecember 22, $1905. 8eria1;No..2 93,016.
' .To all whom it 'mu/y comer rt:
'Be it known that 'I," Fnmnmon- WILHELM KLEVER, vmanufactu'rer, a subject of the Iierman Emperor, residing at: 6: Branden burgerstrasse, Cologne-on-the-Rhine, v Germany, have inventedcerta'in newand useful Improvements in and Relating to the Manufacture of Lubricating and Anticorrosive Oils; and I do herebydeclare the following- 10 to be a full, clear, and exact description of the invention, such as will enable others skilled in the art to which it appertains to make and use the same. 1
This invention relates to the manufacture of lubricating and anti'corrosi've oils, cape cially of such oils, which are ada ted to solve or to remove the residues 0 nitric gunpowders from the bore offire'arms.
The invention consists 1n mixing alkali 2 0 oleates with hydrocarbons and alcohol or alcohols which have a high boiling point. Processes are known for renderlng hydrocarbons, paraflin oils, mineral oils or 'vaseline oils, capable of =forming' emulsions, which processes consist in adding alkali oleates to the said hydrocarbons or the like which are insoluble in water when employedalone. The less alkali oleates areadded to the hydrocarbons and the like, the more the lubricating and anticorrosive qualities of the mixture obtained are increased. The' usefulness of the said oils was hitherto impaired by the fact j that the storage of such oils as well as variations of temperature some 5 times caused separation of the oils and the alkali oleates, the density of the several components not'being the same, and thereby those qualities by which theyv are rendered capable of form' emulsions were; de-
4 stroyed. This draw ack is obviated by my invention which will'be'. fully described in the following'specification.
In carrying out my process, 1* first add to I the alkaliolea'tes, beforemixing them with y H able of formin an emulsiornfan alcohol or acohols havin a h 1 boiling point and whichQcan be heate to'tie' boilin point without, v..dec(imposition. I have ound that glycerin, which is sometimes considered to be an' alcohol', and ethyl alcohol cannot-be satisfactorily employed'in carrying out my recess but' I can use'of the aliphatic series'a mono acid. (monatomic) alcohols from ropyl alcohol u ward and of the-di v acid diatomic) classt e inacone. Phenyl paraflin alcoholsmay; a
- oils.
so be employed.
Preferably-I em loy pinacone, omanthylor hepty -alcoho, 'caprylor octy'laloohol and buty'lalcohol. Or, I mix the h drocar'bonsand the like with the alkali o eates and then add the said alcohol or alcohols to the resulting mixture." By the admixture of high boilin alcohols the quantityof alkali oleates adde to the'minera'l oil ma be reduced to such extent that the alkah oleates together with the-alcohol, amount to about 15% of the mineral oil. Furthermore the newcompounds obtained are capable of dissolving or removing the destructive residues which remain in the bores of firearms when fired with nitric powders. The lubricants composed according to myinvention combine with the said residues, which in conseuence are removed more speedil and t oroughly1 than it was hitherto possible by mere mec anical action by means of'other The arms are therefore preserved in a more erfect state than formerly.
The 'gh-boiling alcohols above referred to do not combine with the alkalies themselves; nevertheless the combination which is necessary for the present purpose can be effected forinstance by first'combinin the oleic acid with the alkalies and then a ding the high-boiling alcohol, or by first embodying the latter into the oleic acid, then adding the alkalies and finally incorporating the resultin mixture with the hydrocarbons and the li e, thus, producing. the'desired qualities. The roportion of high-boiling alcohols and al ali oleates'varies from 15 to 30 per cent., accordin to the quality, density or viscosity of the hy rocarbon to be improved.
If the hydrocarbon which is to be employed contains alcohol which would be decomposed when subjected to a high temperature, such alcohol may be removed and replaced wholly or to any desired extent b alcohol of the proper character. If 0 y a transito efiect istobe reduced the high boiling a cohol may be ad ed to the finished. product preferably under pressure of from about 1 kg. per sq. cm. to 4 k per sq. 'cm.
and to an amount of not excee in 4%.
As the proportion of mineral o' .and mixture of high boiling alcohol and alkali oleates required to obtain the desired results will vary or depend upon the particular oil employed, it is necessary to determine such pro ortions by experiments. with solutions coo ed to a 'tem erature of from minus 10 to 20 C. With 0' s which under the conditions 5% of hi h boiling alcohol and alkalioleate's alkali oleates and alcoholwhich boils at a 7 without ecompositionof the components,"I high temperature"and can be heated to its first neutralize 100 kg. .of oleic' acid with o 5 point without decomposition. 5 alkali and afterward add thereto5O k'g of'a 2'.' he herein described process of manusuitable. high 7 boiling alcohol, for instance, facturing an anti corrosive lubricant, par- 5 am l-alcohol. To this mixture is then ticula'rly adapted for removing the residue of added 850 kg. of mineral oi l having for innitric powders from fire arms, which consists stance a specific gravity of 0.8800.910. in treating hydrocarbon under pressure with 10 The olelcacid hereinbefore. referred to can a mixture of alkalipleates and alcohol which baof either vegetable or animal origin and in boils at a high temperature and can be heated the'carrying out o? the invention may be reto-its boiling point without decomposition. placed by acids derived from fats or resins. In, testimony whereof I have signed'my Having thus described the invention what .name to this specification in the presence-of 1s, a
15 is claime W bs g W tn sse -1 1.= The hereinfdescribed process of manur I FRIEDRICH WILHELM KLEWER. 1
facturing an anti corrosive lubricant, par Witnesses; l j a ticu arl'yadapted for removing the residue of v 'WOL EMAR HAUP'I,
nitric powders from fire arms, which consists; HENRY-B ena I i just referred towill combine from 4 to in treating hydrocarbon with amiirture of 20
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US29301805A US919884A (en) | 1905-12-22 | 1905-12-22 | Manufacture of lubricating and anticorrosive oils. |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US29301805A US919884A (en) | 1905-12-22 | 1905-12-22 | Manufacture of lubricating and anticorrosive oils. |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US919884A true US919884A (en) | 1909-04-27 |
Family
ID=2988318
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US29301805A Expired - Lifetime US919884A (en) | 1905-12-22 | 1905-12-22 | Manufacture of lubricating and anticorrosive oils. |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US919884A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2701206A (en) * | 1952-02-12 | 1955-02-01 | Harry E Fales | Corrosion inhibiting composition |
| US6225271B1 (en) * | 1998-10-06 | 2001-05-01 | Hoffman & Wright Llc | Black powder gun barrel bore, cartridge, and parts cleaning solution |
-
1905
- 1905-12-22 US US29301805A patent/US919884A/en not_active Expired - Lifetime
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2701206A (en) * | 1952-02-12 | 1955-02-01 | Harry E Fales | Corrosion inhibiting composition |
| US6225271B1 (en) * | 1998-10-06 | 2001-05-01 | Hoffman & Wright Llc | Black powder gun barrel bore, cartridge, and parts cleaning solution |
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