US799542A - Process of cementing iron or steel. - Google Patents

Process of cementing iron or steel. Download PDF

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US799542A
US799542A US23278704A US1904232787A US799542A US 799542 A US799542 A US 799542A US 23278704 A US23278704 A US 23278704A US 1904232787 A US1904232787 A US 1904232787A US 799542 A US799542 A US 799542A
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iron
steel
cementing
carbonaceous material
plates
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US23278704A
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Charles C Davis
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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C8/00Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C8/06Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases
    • C23C8/08Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases only one element being applied
    • C23C8/24Nitriding
    • C23C8/26Nitriding of ferrous surfaces

Definitions

  • My invention relates to an improved method .of cementing or supercarburizing steel or iron articles, especially adapted for producing a decrementally-hardened surface, such as re.
  • the article under treatment is preferably maintained at a nascent cherry heat in contact with suitable carbonaceous material, and a direct electric current is passed through the carbonaceous material and article to cause rapid absorption of the carbon by the latter without raising the temperature in such circuit.
  • a direct electric current is passed through the carbonaceous material and article to cause rapid absorption of the carbon by the latter without raising the temperature in such circuit.
  • Figure 1 is a vertical sectional view taken on theline 1 1 of Fig. 2,'illustrating more or less diagrammatically one arrangementfor carrying outmy invention
  • Fig. 2 is a plan View of the parts shown in Fig. 1.
  • 1 indicates a steel truck or other suitable carrier supporting two armor-plates 2 and 3, together with an interposed electrode, such as an iron plate 4:.
  • a layer of suitable carbonaceous material 5 is packed between the plate 4: and the adjacent faces of the armor-plates 2 and 3.
  • Such carbonaceous material may consist of graphite, coal, or coke, which may be mixed with sand, silica, barium carbonate, or other suitable material for adjusting the electrical resistance of the layer.
  • a wall 6 of fire-brick or other heat-non-conducting material is shown surrounding the several elements for effectively preventing entrance of air to the faces of the plates under treatment.
  • the plate 4 is provided with suitable means, such as a lug 7, for connecting it to the positive pole of a source of electrical energy, and the armorplates 2 and 3 are provided with similar means 8 and 9 for convenient connection to the negative pole of said electrical supply.
  • the operation of my invention is as follows:
  • the armor-plates 2 and 3 are placed in a furnace with suitable carbonaceous material 5 packed between them and a common interposed positive electrode l, means, such as-a fire-brick wall 6, being employed to prevent access of air to the carbonaceous material.
  • the parts thus assembled are raised to and maintained at a temperature of approximately 800 centigrade to 850 centigrade.
  • a direct electric current of suitable strength and character is then passed from the common positive electrode ithrough the carbonaceous material and armor-plates to cause a rearrangementof the atoms of said plates and expedite the absorption of carbon thereby without pro- 1 ducing an appreciable increase of temperature by the resistance of said circuit.
  • This operation is continued until the desired degree of cementation is produced, after which the plates are slowly cooled in the usual manner to prevent strains and distortion.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Furnace Details (AREA)

Description

No- 799,542. PATENTED SEPT. 12, 1905.
G. G. DAVIS.
PROCESS OF CEMENTING IRON 0R STEEL.
APPLICATION FILED NOV.15, 1904.
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CHARLES C. DAVIS, OF GERMANTOIVN, PENNSYLVANIA.
PROCESS OF CEIVIENTING IRON OR STEEL.
Specification of Letters Patent.
Patented Sept. 12, 1905.
I Application filed November 15, 1904. Serial No. 232,787-
To all whom it may concern.-
Be it known that I, CHARLES C. DAvIs, a citizen of the United States, residing at Germantown, in the county of Philadelphia and State of Pennsylvania, have invented certain new and useful Improvements in Processes of Cementing Iron or Steel, of which the following .is a specification.
My invention relates to an improved method .of cementing or supercarburizing steel or iron articles, especially adapted for producing a decrementally-hardened surface, such as re.
veniently obtained by establishing an electric arc between a carbon electrode and the surface under treatment or by passing a sufiiciently heavy electric current through a layer of granular carbonaceous material in contact with the article under treatment to generate an intense heat by the resistance of such carbonaceous layer. This proposed use of an electric current for the purpose of producing intense local heating of the surface during the cementation process causes burning and deterioration of portions of the surface under treatment and has proven impracticable.
In the operation of my invention the article under treatment is preferably maintained at a nascent cherry heat in contact with suitable carbonaceous material, and a direct electric current is passed through the carbonaceous material and article to cause rapid absorption of the carbon by the latter without raising the temperature in such circuit. The advantageous action of the electric current in the practice of my invention seems to reside primarily in producing a beneficial rearrangement of the atoms of the iron or steel article under treatment and also in producing a more uniformly graduated penetration of the carbon in the said articles, thereby expediting the absorption of carbon and producing a uniform decremental hardening of the entire surface under treatment.
In the accompanying drawings, forming a part of this application, and in which similar reference-numerals indicate corresponding parts in both views, Figure 1 is a vertical sectional view taken on theline 1 1 of Fig. 2,'illustrating more or less diagrammatically one arrangementfor carrying outmy invention; and Fig. 2 is a plan View of the parts shown in Fig. 1.
Referring to the drawings, 1 indicates a steel truck or other suitable carrier supporting two armor-plates 2 and 3, together with an interposed electrode, such as an iron plate 4:. A layer of suitable carbonaceous material 5 is packed between the plate 4: and the adjacent faces of the armor-plates 2 and 3. Such carbonaceous material may consist of graphite, coal, or coke, which may be mixed with sand, silica, barium carbonate, or other suitable material for adjusting the electrical resistance of the layer. A wall 6 of fire-brick or other heat-non-conducting material is shown surrounding the several elements for effectively preventing entrance of air to the faces of the plates under treatment. The plate 4 is provided with suitable means, such as a lug 7, for connecting it to the positive pole of a source of electrical energy, and the armorplates 2 and 3 are provided with similar means 8 and 9 for convenient connection to the negative pole of said electrical supply.
The operation of my invention is as follows: The armor-plates 2 and 3 are placed in a furnace with suitable carbonaceous material 5 packed between them and a common interposed positive electrode l, means, such as-a fire-brick wall 6, being employed to prevent access of air to the carbonaceous material. The parts thus assembled are raised to and maintained at a temperature of approximately 800 centigrade to 850 centigrade. A direct electric current of suitable strength and character is then passed from the common positive electrode ithrough the carbonaceous material and armor-plates to cause a rearrangementof the atoms of said plates and expedite the absorption of carbon thereby without pro- 1 ducing an appreciable increase of temperature by the resistance of said circuit. This operation is continued until the desired degree of cementation is produced, after which the plates are slowly cooled in the usual manner to prevent strains and distortion.
I have illustrated and described a single means for carrying out my invention; but obviously it is applicable in other manners.
ITO
Having thus described my invention, what I claim, and desire to secure by Letters Patcm, is-
- 1. The herein-described process of cementing or carburizing steel or iron, which consists in maintaining the article at a nascentcherry heat in contact with carbonaceous ma terial, and simultaneously passing a direct electric current of suitable strength and character through said carbonaceous material and article to cause a rearrangement of the atoms of said article, substantially as described.
2. The herein-described process of cementing or carburizing steel or iron, which consists in maintaining the article at a temperature of approximately 800 centigrade to 850 centigrade in contact with carbonaceous material, and simultaneously passing a direct electric current of suitable strength and character through said carbonaceous material and article to expedite the absorption of carbon by the latter, substantially as described.
3. The herein-described process of cementing or carburizing steel or iron, which consists in maintaining the article at a temperature of approximately 800 centigrade to 850 centigrade in contact with carbonaceous material, simultaneously passing a direct electric current of suitable strength and character through said carbonaceous material and article to expedite the absorption of carbon by the latter, and excluding the parts under treatment from access of the atmosphere, substantially as described.
4. The herein-described process of cementing or carburizing armor-plates, which consists in packing carbonaceous material between two armor-plates and a common positive electrode interposed therebetween, maintaining the parts so arranged at a temperature approximately 800 centigrade to 850 centitive electrode interposed therebetween, main-v taining the parts so arranged at a temperature approximately 800 centigrade to 850 centigrade, simultaneously passing from such com- -mon electrode through the carbonaceous material and plates a direct electric current of suitable strength and character to expedite the absorption of carbon by the latter, and excluding the opposing faces of said plates from access of the atmosphere,- substantially as described.
In testimony whereof I affix my signature in presence of two witnesses.
CHARLES C. DAVIS. Witnesses:
E. B. PEAoo'oK, H. BERENS.
US23278704A 1904-11-15 1904-11-15 Process of cementing iron or steel. Expired - Lifetime US799542A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2913642A (en) * 1953-05-28 1959-11-17 Rca Corp Method and apparatus for making semi-conductor devices
US3096221A (en) * 1959-09-15 1963-07-02 To A Kako Kabushiki Kaisha Method of quick nitrification in which fluidized particles are employed
US3099589A (en) * 1959-09-15 1963-07-30 To A Kako Kabushiki Kaisha Method of cementation in which fluidized carbon powder particles are employed

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2913642A (en) * 1953-05-28 1959-11-17 Rca Corp Method and apparatus for making semi-conductor devices
US3096221A (en) * 1959-09-15 1963-07-02 To A Kako Kabushiki Kaisha Method of quick nitrification in which fluidized particles are employed
US3099589A (en) * 1959-09-15 1963-07-30 To A Kako Kabushiki Kaisha Method of cementation in which fluidized carbon powder particles are employed

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