US7855299B2 - Preparation method of porous organic inorganic hybrid materials - Google Patents
Preparation method of porous organic inorganic hybrid materials Download PDFInfo
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- US7855299B2 US7855299B2 US12/278,556 US27855607A US7855299B2 US 7855299 B2 US7855299 B2 US 7855299B2 US 27855607 A US27855607 A US 27855607A US 7855299 B2 US7855299 B2 US 7855299B2
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- C07F11/005—Compounds containing elements of Groups 6 or 16 of the Periodic Table compounds without a metal-carbon linkage
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- C07—ORGANIC CHEMISTRY
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- B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
- B01J20/223—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material containing metals, e.g. organo-metallic compounds, coordination complexes
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- B82B3/00—Manufacture or treatment of nanostructures by manipulation of individual atoms or molecules, or limited collections of atoms or molecules as discrete units
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- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
- B01J31/2208—Oxygen, e.g. acetylacetonates
- B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
- B01J31/223—At least two oxygen atoms present in one at least bidentate or bridging ligand
- B01J31/2239—Bridging ligands, e.g. OAc in Cr2(OAc)4, Pt4(OAc)8 or dicarboxylate ligands
Definitions
- FIG. 2 represents the scanning electron microscopes of chromium terephthalate, obtained in Example 3.
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Abstract
Description
amide (—CONH2), sulfonic acid (—SO3H), sulfonate (—SO3 −), methanedithionic acid (—CS2H), methanedithionate (—CS2 −), pyridine, pyrazine, etc. Multidentates, having multiple coordinating sites, such as bidentates and tridentates are suitable for preparing stable porous hybrid inorganic-organic materials. Any organicmolecules can be used irrespective of the charges such as cationic, anionic and neutral compounds as long as they have coordination sites. For example, neutral molecules such as bipyridine and pyrazine and anionic molecules such as terephthalate, naphthalenedicarboxylate, benzenetricarboxylate, glutarate and succinate can be used.
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