US5788755A - Method and equipment for producing foam bitumen - Google Patents

Method and equipment for producing foam bitumen Download PDF

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Publication number
US5788755A
US5788755A US08/693,065 US69306596A US5788755A US 5788755 A US5788755 A US 5788755A US 69306596 A US69306596 A US 69306596A US 5788755 A US5788755 A US 5788755A
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United States
Prior art keywords
bitumen
foaming
equipment
foam
pressure
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Expired - Lifetime
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US08/693,065
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English (en)
Inventor
Nestor Mikael Salminen
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CMI Terex Corp
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CMI Corp
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Assigned to CMI CORPORATION reassignment CMI CORPORATION ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: SALMINEN, NESTOR MIKAEL
Priority to US08/960,442 priority Critical patent/US5827360A/en
Application granted granted Critical
Publication of US5788755A publication Critical patent/US5788755A/en
Assigned to CREDIT SUISSE, AS COLLATERAL AGENT reassignment CREDIT SUISSE, AS COLLATERAL AGENT SECURITY AGREEMENT Assignors: A.S.V., INC., AMIDA INDUSTRIES, INC., CMI TEREX CORPORATION, GENIE INDUSTRIES, INC., TEREX ADVANCE MIXER, INC., TEREX CORPORATION, TEREX CRANES WILMINGTON, INC., TEREX USA, LLC (FORMERLY CEDARAPIDS, INC.), TEREX-TELELECT, INC.
Assigned to CREDIT SUISSE AG, CAYMAN ISLANDS BRANCH, AS COLLATERAL AGENT reassignment CREDIT SUISSE AG, CAYMAN ISLANDS BRANCH, AS COLLATERAL AGENT SECURITY AGREEMENT Assignors: A.S.V., INC., CMI TEREX CORPORATION, AN OKLAHOMA CORPORATION, GENIE INDUSTRIES, INC. A WASHINGTON CORPORATION, TEREX USA, LLC, A DELAWARE LIMITED LIABILITY COMPANY, TEREX-TELELECT, INC., A DELAWARE CORPORATION
Assigned to TEREX CORPORATION, TEREX ADVANCE MIXER, INC., A.S.V., INC., TEREX USA, LLC, TEREX CRANES WILMINGTON, INC., CMI TEREX CORPORATION, TEREX-TELELECT, INC., GENIE INDUSTRIES, INC., AMIDA INDUSTRIES, INC. reassignment TEREX CORPORATION RELEASE BY SECURED PARTY (SEE DOCUMENT FOR DETAILS). Assignors: CREDIT SUISSE AG, CAYMAN ISLANDS BRANCH, AS COLLATERAL AGENT
Assigned to CMI TEREX CORPORATION reassignment CMI TEREX CORPORATION CHANGE OF NAME (SEE DOCUMENT FOR DETAILS). Assignors: CMI CORPORATION
Assigned to TEREX CORPORATION, TEREX USA, LLC, CMI TEREX CORPORATION reassignment TEREX CORPORATION RELEASE OF SECURITY INTEREST Assignors: CREDIT SUISSE AG, CAYMAN ISLANDS BRANCH, AS COLLATERAL AGENT
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    • E—FIXED CONSTRUCTIONS
    • E01—CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
    • E01C—CONSTRUCTION OF, OR SURFACES FOR, ROADS, SPORTS GROUNDS, OR THE LIKE; MACHINES OR AUXILIARY TOOLS FOR CONSTRUCTION OR REPAIR
    • E01C19/00—Machines, tools or auxiliary devices for preparing or distributing paving materials, for working the placed materials, or for forming, consolidating, or finishing the paving
    • E01C19/45—Portable apparatus for preparing, or for preparing and applying to the road, compound liquid binders, e.g. emulsified bitumen, fluxed asphalt
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10C—WORKING-UP PITCH, ASPHALT, BITUMEN, TAR; PYROLIGNEOUS ACID
    • C10C3/00—Working-up pitch, asphalt, bitumen
    • E—FIXED CONSTRUCTIONS
    • E01—CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
    • E01C—CONSTRUCTION OF, OR SURFACES FOR, ROADS, SPORTS GROUNDS, OR THE LIKE; MACHINES OR AUXILIARY TOOLS FOR CONSTRUCTION OR REPAIR
    • E01C19/00—Machines, tools or auxiliary devices for preparing or distributing paving materials, for working the placed materials, or for forming, consolidating, or finishing the paving
    • E01C19/12—Machines, tools or auxiliary devices for preparing or distributing paving materials, for working the placed materials, or for forming, consolidating, or finishing the paving for distributing granular or liquid materials
    • E01C19/16—Machines, tools or auxiliary devices for preparing or distributing paving materials, for working the placed materials, or for forming, consolidating, or finishing the paving for distributing granular or liquid materials for applying or spreading liquid materials, e.g. bitumen slurries
    • E01C19/17—Application by spraying or throwing
    • E—FIXED CONSTRUCTIONS
    • E01—CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
    • E01C—CONSTRUCTION OF, OR SURFACES FOR, ROADS, SPORTS GROUNDS, OR THE LIKE; MACHINES OR AUXILIARY TOOLS FOR CONSTRUCTION OR REPAIR
    • E01C19/00—Machines, tools or auxiliary devices for preparing or distributing paving materials, for working the placed materials, or for forming, consolidating, or finishing the paving
    • E01C19/12—Machines, tools or auxiliary devices for preparing or distributing paving materials, for working the placed materials, or for forming, consolidating, or finishing the paving for distributing granular or liquid materials
    • E01C19/16—Machines, tools or auxiliary devices for preparing or distributing paving materials, for working the placed materials, or for forming, consolidating, or finishing the paving for distributing granular or liquid materials for applying or spreading liquid materials, e.g. bitumen slurries
    • E01C19/17—Application by spraying or throwing
    • E01C19/176—Spraying or throwing elements, e.g. nozzles; Arrangement thereof or supporting structures therefor, e.g. spray-bars

Definitions

  • the invention relates to a method for producing foam bitumen or the like by mixing liquid, such as water, and bitumen.
  • the equipment according to the method can be used in mobile stabilizing machines or in fixed mixing plants.
  • the equipment according to the invention comprises a foaming reactor, means for spreading foam bitumen and pipes related thereto, and valves required for adjustment.
  • foam bitumen in asphalt work is prior art. Even though foam bitumen has been commonly used, the method has quite often caused difficulties and problematic situations in practice.
  • the foaming principle in the earlier methods has been to add the foaming agent, in general water, to the substance to the foamed, generally bitumen, under pressure, whereupon the pressure is higher than the saturation pressure of steam at the temperature of a hot bituminous binder, and to let the mixture swell under a pressure lower than said saturation pressure of steam.
  • Finnish Patent 872,911 discloses this type of method and equipment.
  • the method according to this reference also employs an additional substance to improve the properties of the foam bitumen.
  • Finnish Published Specification 57,807 also discloses a method for producing foam bitumen by using water and bitumen as starting materials.
  • the solutions according to the patent are not, however, very well applicable to practice, and for example the static mixers of water and bitumen disclosed in the patent may clog easily, or they do not produce homogeneous foam bitumen.
  • a so-called reticulate structure is formed in the foaming equipment used in the foaming procedure in the beginning of the reaction.
  • the reticulate structure is formed in such a way that at the foaming temperature of the hot bituminous binder under a high pressure, energy is transferred from the substance to be foamed to the foaming agent only in the surface layer.
  • the small amount of the foaming agent and the high pressure also have a negative effect on this, thus accelerating the formation of the reticulate structure.
  • the reticulate structure simply consists of a net of molecules developing on the surface of the substance to be foamed according to natural laws, the molecule net trying to prevent other changes once it has itself become saturated.
  • the foamed hot bituminous binder bursts out of the equipment under a low pressure, the reticulate structure on the surface of the binder is broken, and if the equipment comprises one or two input lines, the reticulate bitumen which has lost its activity is immediately released in the area of the nozzles near the input line, and this shows in the finished processed material as a dark reticulate area.
  • the temperature of the substance to be foamed is over 180° C., and foaming water is used over 10% of the substance to be foamed, or if the foaming agent is warmed to a temperature of e.g. 80° C. and is fed with a high pressure to the foaming equipment, very quick foaming and strong formation of steam may occur, whereupon the entire equipment may be destroyed in an explosion-like eruption. The situation may naturally cause a danger for those working near the asphalt machine. Therefore, known methods of producing foam bitumen have required infinitely accurate and careful work.
  • the most important advantage of the method and equipment according to the invention is that they provide a more effective overall method for realizing the flow conduits and spraying of the foamed hot bituminous binder than what the methods and equipments known and used so far have provided.
  • hot bituminous binder circulates in the equipment during the entire working process, whereby the effectiveness of the equipment is maintained and the operating temperature does not fall under any circumstances.
  • the devices following the foaming reactor are planned to be as simple as possible, and furthermore, they are insulated in order to decrease thermal problems. Elbows in the pipeline, contractions and possible cold surfaces have been eliminated to avoid the problems caused by clogging.
  • the bituminous binder is almost identical to the original bitumen and it bursts out of the nozzles in the form of a heavy liquid.
  • FIG. 1 shows schematically the method for producing foam bitumen.
  • FIG. 2 shows schematically a longitudinal section of a foaming reactor.
  • FIG. 3 shows a flow graph of a continuous mixing plant using foam bitumen.
  • reference numeral 1 denotes a spray bar for foam bitumen.
  • the spray bar 1 has two conduits, bitumen flowing in conduit 2 and foam bitumen flowing in conduit 3.
  • the distribution of the foam bitumen is performed through control valves 4 via nozzles 5.
  • the foam bitumen is supplied to the spray bar 1 via pipes 6, and the amount of the foam bitumen is adjusted by means of valves 7.
  • a distribution manifold 8 distributes the foam bitumen to the pipes 6.
  • the foam bitumen is supplied to the distribution manifold 8 by means of a pipe 9.
  • the bitumen to be processed is supplied to a foaming reactor 17 via the conduit 2 of the spray bar 1 by means of a pipe 10.
  • hot bitumen can be circulated from the conduit 3 of the spray bar 1 via a conduit 11 back to the bitumen tank, and the line is closed by means of a valve 12.
  • the control valves 4 are controlled by means of a mechanical or electrical guide 13, which receives a control impulse from the valve control system 14.
  • a system 15 controls the feeding of the foam bitumen to the spray bar 1 by adjusting the valves 7.
  • Water is led to the foaming reactor 17 through a water inlet 16.
  • FIG. 2 shows the foaming reactor 17, where reference numeral 18 denotes a water nozzle.
  • Numeral 19 denotes an actuator, which moves a cone 21 situated at the end of a vector bar 20, the cone choking an orifice 23 at the end of a collar 22.
  • the hot bitumen is led, via a pipe fitting 25, tangentially to a cylinder formed by a cylinder 24, whereby a whirling motion is created in the bitumen which presses into the inner part of the foaming reactor via the orifice 23 in the collar part 22 of the cylinder 24.
  • a jet of water coming from the nozzle 18 is directed to a conical whirling jet of bitumen 27, where pressure has fallen due to the increasing flow rate.
  • a mixer 28 consists of a round bar to which mixing blades 29 are attached.
  • mixers 28 The purpose of these mixers 28 is to further homogenize and improve the foam bitumen.
  • the foam bitumen leaves the foaming reactor 17 via an orifice 31 to a pipe fitting 30, which is placed tangentially in relation to the foaming reactor 17.
  • the entire foaming reactor is insulated with an insulating material 32 to improve the energy efficiency.
  • reference numeral 1 denotes the spray bar for foam bitumen
  • reference numeral 17 denotes the foaming reactors
  • reference numeral 33 denotes the continuous asphalt mixer.
  • Numeral 35 denotes the 3-way valves of the water and bitumen lines.
  • Reference numeral 36 denotes the water outlet, and numeral 37 the water inlet.
  • reference numeral 38 denotes the bitumen inlet, and numeral 39 the bitumen outlet.
  • the heated bitumen is led from the bitumen tank to the spray bar 1 via the conduit 2, and from there via the pipe 10 of the conduit to the foaming reactor 17, from where the bitumen is taken via the pipe 9 to the distribution manifold 8, and from there via the pipes 6 to the spray bar 1 to the conduit 3, from where it is returned, via the conduit 11 at the end of the conduit, back to the bitumen tank to be heated.
  • the circulation is continued until the temperature of the equipment is high enough. After this, the flow of the bitumen back to the feeding tank is closed with the valve 12, and the production of the foam bitumen is started by feeding water into the foaming reactor 17.
  • the water is supplied to the foaming reactor 17 by means of the pipe 16, and the nozzle 18 forms a jet of water 26, which is fed into the jet of bitumen 27.
  • the hot bitumen is supplied to the foaming reactor 17 through the pipe fitting 25 connected tangentially to the cylinder 24, so that a strong whirling motion can be created in the bitumen.
  • the jet of bitumen bursts inside the foaming reactor via the orifice 23, which is adjusted by means of the cone 21 at the end of the vector bar 20, and the adjustment is performed by the action of the actuator 19.
  • the resultant foam bitumen is supplied via the pipe 9 to the distribution manifold 8, where the valves 7 distribute the foam bitumen under pressure to the spray bar 1.
  • the purpose of the valves 7, especially when mobile gear is used and the equipment is in an inclined position, is to distribute the amount or the pressurized foam bitumen in the right proportion to the spray bar 1.
  • the control system 15 controls, via the actuators 13, the valves 7 in relation to the inclination of the asphalt machine.
  • the valves 4 of the spray bar 1 are adjusted by means of the actuators 13 and the control system 14 in such a way, that the pipeline and the conduit 3 have an adequate pressure, so that no steam will be formed, and the actual foaming will take place only after the nozzles 5.
  • the control system 14 is used to close the valve 12 to stop the foam bitumen from entering the bitumen tank.
  • the mixing plant Since it is preferable in a fixed mixing plant to mix foam bitumen separately into coarse ballast and fine material, the mixing plant must be provided with two foaming reactors.
  • the foaming reactor and the devices connected thereto operate during the entire procedure at an operating temperature, and the hot bituminous binder to be foamed is within the temperature range of 145° to 165° C.
  • the foaming reactor operates in such a way that the hot bituminous binder needed for the foaming enters the reactor under the pressure of 4 bars, and during the reaction meets the foaming agent under the absolute pressure of 0.8 bars.
  • the foaming reactor is adjusted according to the amount of the bitumen to be foamed, and the pressure and flow rate of the foaming agent, taking into consideration the width of the lane, the layer thickness of the material, the rate of the procedure, and the increase percentage of the foam bitumen.
  • the information may be transferred either automatically or manually as a vector value to the foaming reactor, by means of which the size of the orifice 23 is controlled.
  • the same absolute pressure and flow rate always prevail at the moment of reaction, and the foaming occurs in such a way that no phenomenon of reticulate structure occurs, i.e. the resultant foamed product is one and the same homogenous substance, and the processed material always results in a product fulfilling the norms.
  • the foaming reactor which acts in a state according to the vector field diagram, always produces a completely foamed bituminous binder in the temperature range of 145° to 165° C.
  • the foaming reactor can be used with a good result also in the lower temperature range of 125° to 145° C., but the operating efficacy within that temperature range is low, and the stabilizing rate is uneconomically low.
  • the equipment is provided with the above-described valves 7 of the valve system by means of which an entity regulating the flow of the foam bitumen either manually or automatically is achieved.
  • costs are reduced considerably. The extent of the reductions is illustrated for example by the fact that the investment costs can be amortized during the first year of operation.
  • the method and especially the equipment according to the invention for producing foam bitumen can naturally be realized in a different manner than in the embodiment according to the application.
  • the flow graphs can be realized in a manner different from what is described in the application.
  • the equipment constructions themselves may also differ from the arrangements according to the application.
  • the foaming reactor and especially the mixer and the ejector contained in it may be realized in a different manner than what is described in the application.
  • the distribution manifolds and the control valves may also be realized in a different way without deviating from the inventive idea according to the application.

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  • Engineering & Computer Science (AREA)
  • Civil Engineering (AREA)
  • Structural Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Architecture (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Road Paving Machines (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
US08/693,065 1994-02-18 1995-02-15 Method and equipment for producing foam bitumen Expired - Lifetime US5788755A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US08/960,442 US5827360A (en) 1996-10-09 1997-10-22 Method and equipment for producing foam bitumen

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FI940784 1994-02-18
FI940784A FI94884C (fi) 1994-02-18 1994-02-18 Menetelmä ja laite vaahtobitumin valmistamiseksi
PCT/FI1995/000070 WO1995022661A1 (en) 1994-02-18 1995-02-15 Method and equipment for producing foam bitumen

Related Child Applications (1)

Application Number Title Priority Date Filing Date
US08/960,442 Division US5827360A (en) 1996-10-09 1997-10-22 Method and equipment for producing foam bitumen

Publications (1)

Publication Number Publication Date
US5788755A true US5788755A (en) 1998-08-04

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US08/693,065 Expired - Lifetime US5788755A (en) 1994-02-18 1995-02-15 Method and equipment for producing foam bitumen

Country Status (7)

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US (1) US5788755A (no)
EP (1) EP0745163A1 (no)
AU (1) AU1708395A (no)
DE (1) DE745163T1 (no)
FI (1) FI94884C (no)
NO (1) NO306960B1 (no)
WO (1) WO1995022661A1 (no)

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6149342A (en) * 1999-03-25 2000-11-21 Cmi Corporation Anti-bridging mechanism
FR2849874A1 (fr) * 2003-01-14 2004-07-16 Famatec Dispositif d'injection d'une rampe d'elaboration et d'epandage d'un liant
US20070060676A1 (en) * 2005-09-12 2007-03-15 Mathy Construction Bituminous paving composition and process for bituminous paving
US20070191514A1 (en) * 2005-09-12 2007-08-16 Reinke Gerald H Bituminous paving composition and process for bituminous paving
US20080110744A1 (en) * 2004-06-30 2008-05-15 Jean-Marc Girard Method for the Preparation of a Gas or Mixture of Gases Containing Molecular Fluorine
US20090068348A1 (en) * 2007-09-07 2009-03-12 Reinke Gerald H Warm asphalt binder compositions containing lubricating agents
US20090207684A1 (en) * 2008-02-18 2009-08-20 Terex Corporation Warm mix asphalt production system and method
US20100055304A1 (en) * 2008-08-05 2010-03-04 Alm Holding Co. Process for cold-in-place recycling using foamed asphalt and lubrication additive
US20100229757A1 (en) * 2006-08-23 2010-09-16 De Veenvoort B.V. Stable bitumen foam and its preparation and use
US20100319577A1 (en) * 2007-11-14 2010-12-23 Akzo Nobel N.V. Asphalt modifiers for "warm mix" applications including adhesion promoter
US7902277B2 (en) 2008-02-22 2011-03-08 Alm Holding Co. Processing bituminous mixtures for paving at reduced temperatures
US8404037B2 (en) 2007-07-26 2013-03-26 Akzo Nobel N.V. Adhesion and cohesion modifiers for asphalt
ES2516566A1 (es) * 2013-04-29 2014-10-30 Universidad De Huelva Procedimiento de espumación-modificación conjunta de betunes para su uso en pavimentación

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DE29702162U1 (de) * 1997-02-08 1998-06-10 Wirtgen GmbH, 53578 Windhagen Vorrichtung zum Bearbeiten von Fahrbahnen, sowie Vorrichtung zum Erzeugen von Schaumbitumen
NO311140B1 (no) * 2000-02-25 2001-10-15 Kolo Veidekke As Prosess og system for produksjon av en lunken skumblandingsasfalt, samt anvendelse av denne
FR2853918B1 (fr) 2003-04-18 2005-06-24 Htp Est Procede et dispositif de mise en oeuvre a chaud d'un enrobe bitumineux
US7114843B2 (en) 2003-07-21 2006-10-03 Htp Est Method of manufacturing a bituminous coated aggregate mix
CA2704982C (en) 2008-02-06 2012-12-11 Icl Performance Products Lp Polyphosphate modifier for warm asphalt applications
DE102010013982A1 (de) 2010-04-06 2011-10-06 Bomag Gmbh Vorrichtung zum Erzeugen von Schaumbitumen und Verfahren zu deren Wartung
EP2385079A1 (en) 2010-04-13 2011-11-09 Sekisui Alveo AG Bitumen polyolefin foam and its production
CN104313977A (zh) * 2014-10-21 2015-01-28 中山市拓维电子科技有限公司 一种沥青混合装置
AT518507B1 (de) * 2016-03-23 2018-05-15 Dipl Ing Fh Dipl Ing Ronald J Hoffer Quasistatische Druckkompensation und Korrektur des Wiegeverfahrens in diskontinuierlich arbeitenden Asphaltmischanlagen
CN108166353B (zh) * 2017-12-20 2020-03-03 中联重科股份有限公司 洒油装置及洒油系统
CN108914748A (zh) * 2018-07-26 2018-11-30 江苏增光复合材料科技有限公司 一种道面施工用薄浆封层工艺
CN111074729A (zh) * 2019-12-25 2020-04-28 重庆市智翔铺道技术工程有限公司 一种双组分等体积比路面材料的一体化智能施工车
CN111361082B (zh) * 2020-05-11 2022-03-04 辽宁金铠厦科技有限公司 一种制造聚氨酯发泡颗粒用自动更换喷枪装置
CN114508023A (zh) * 2022-03-15 2022-05-17 河南北筑沥青发泡科技有限公司 一种防衰变泡沫沥青发生装置

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US2917395A (en) * 1957-06-24 1959-12-15 Iowa State College Res Found Method for combining a bituminous binder with an aggregate material
EP0127933A1 (en) * 1983-04-28 1984-12-12 Burt Boulton Holdings Plc Apparatus and method for spraying a mixture of a binder and a volatile liquid
US4592507A (en) * 1983-10-05 1986-06-03 Benedict Charles R Apparatus and method for producing and uniformly applying foamed bituminous binders to road surfaces
WO1987002694A1 (en) * 1985-11-04 1987-05-07 Nodest Vei A/S Method and apparatus for foaming of bitumen
US4692350A (en) * 1984-12-12 1987-09-08 Mobil Oil Corporation Asphalt coating method
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US2917395A (en) * 1957-06-24 1959-12-15 Iowa State College Res Found Method for combining a bituminous binder with an aggregate material
EP0127933A1 (en) * 1983-04-28 1984-12-12 Burt Boulton Holdings Plc Apparatus and method for spraying a mixture of a binder and a volatile liquid
US4592507A (en) * 1983-10-05 1986-06-03 Benedict Charles R Apparatus and method for producing and uniformly applying foamed bituminous binders to road surfaces
US4692350A (en) * 1984-12-12 1987-09-08 Mobil Oil Corporation Asphalt coating method
WO1987002694A1 (en) * 1985-11-04 1987-05-07 Nodest Vei A/S Method and apparatus for foaming of bitumen
FI872911A (fi) * 1985-11-04 1987-07-01 Nodest Vei As Menetelmä kuuman nestemäisen bitumin vaahdottamiseksi
US4832747A (en) * 1987-03-16 1989-05-23 Exxon Chemical Patents Inc. Bitumen emulsions

Cited By (42)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6149342A (en) * 1999-03-25 2000-11-21 Cmi Corporation Anti-bridging mechanism
FR2849874A1 (fr) * 2003-01-14 2004-07-16 Famatec Dispositif d'injection d'une rampe d'elaboration et d'epandage d'un liant
EP1439265A1 (fr) * 2003-01-14 2004-07-21 Famatec Dispositif d'injection d'une rampe d'élaboration et d'épandage d'un liant bitumineux
US20080110744A1 (en) * 2004-06-30 2008-05-15 Jean-Marc Girard Method for the Preparation of a Gas or Mixture of Gases Containing Molecular Fluorine
US20070060676A1 (en) * 2005-09-12 2007-03-15 Mathy Construction Bituminous paving composition and process for bituminous paving
US20070191514A1 (en) * 2005-09-12 2007-08-16 Reinke Gerald H Bituminous paving composition and process for bituminous paving
US8828135B2 (en) 2005-09-12 2014-09-09 Alm Holding Company Bituminous paving composition and process for bituminous paving
US20090304915A1 (en) * 2005-09-12 2009-12-10 Alm Holdings Co. Bituminous paving composition and process for bituminous paving
US8454741B2 (en) 2005-09-12 2013-06-04 Alm Holding Co. Bituminous paving composition and process for bituminous paving
US8454739B2 (en) 2005-09-12 2013-06-04 Alm Holding Co. Bituminous paving composition and process for bituminous paving
US8454740B2 (en) 2005-09-12 2013-06-04 Alm Holding Co. Bituminous paving composition and process for bituminous paving
US8206499B2 (en) * 2006-08-23 2012-06-26 De Veenvoort B.V. Stable bitumen foam and its preparation and use
US20100229757A1 (en) * 2006-08-23 2010-09-16 De Veenvoort B.V. Stable bitumen foam and its preparation and use
US8741052B2 (en) 2007-07-26 2014-06-03 Akzo Nobel N.V. Adhesion and cohesion modifiers for asphalt
US8404037B2 (en) 2007-07-26 2013-03-26 Akzo Nobel N.V. Adhesion and cohesion modifiers for asphalt
US8679245B2 (en) 2007-09-07 2014-03-25 A.L.M. Holding Company Warm mix asphalt binder compositions containing lubricating additives
US20110021673A1 (en) * 2007-09-07 2011-01-27 A.L.M. Holding Company Warm mix asphalt binder compositions containing lubricating additives
US7981466B2 (en) 2007-09-07 2011-07-19 A.L.M. Holding Company Warm mix asphalt binder compositions containing lubricating additives
US7981952B2 (en) 2007-09-07 2011-07-19 A.L.M. Holding Company Warm mix asphalt binder compositions containing lubricating additives
US20110214589A1 (en) * 2007-09-07 2011-09-08 A.L.M. Holding Company Warm mix asphalt binder compositions containing lubricating additives
US10214646B2 (en) 2007-09-07 2019-02-26 A.L.M. Holding Company Warm mix paving composition w/lubricating antistrip additive
US9394652B2 (en) 2007-09-07 2016-07-19 A.L.M. Holding Co. Warm mix asphalt binder compositions containing lubricating additives
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FI94884B (fi) 1995-07-31
NO963429L (no) 1996-10-16
EP0745163A1 (en) 1996-12-04
DE745163T1 (de) 1998-02-19
WO1995022661A1 (en) 1995-08-24
FI940784A0 (fi) 1994-02-18
AU1708395A (en) 1995-09-04
NO963429D0 (no) 1996-08-16
NO306960B1 (no) 2000-01-17

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