US4666710A - Anti-perspirant compositions - Google Patents
Anti-perspirant compositions Download PDFInfo
- Publication number
- US4666710A US4666710A US06/121,174 US12117480A US4666710A US 4666710 A US4666710 A US 4666710A US 12117480 A US12117480 A US 12117480A US 4666710 A US4666710 A US 4666710A
- Authority
- US
- United States
- Prior art keywords
- weight
- perspirant
- compositions
- aluminium
- ethanol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 50
- 239000003213 antiperspirant Substances 0.000 title claims abstract description 27
- 230000001166 anti-perspirative effect Effects 0.000 title claims abstract description 15
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 30
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 21
- 239000000194 fatty acid Substances 0.000 claims abstract description 21
- 229930195729 fatty acid Natural products 0.000 claims abstract description 21
- 150000004665 fatty acids Chemical class 0.000 claims abstract description 21
- 239000004411 aluminium Substances 0.000 claims description 9
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 9
- 229910052782 aluminium Inorganic materials 0.000 claims description 9
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 5
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 claims description 5
- 239000002562 thickening agent Substances 0.000 claims description 5
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 claims description 4
- 150000003754 zirconium Chemical class 0.000 claims description 4
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 claims description 3
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 claims description 3
- 239000002304 perfume Substances 0.000 claims description 3
- ADGFKRMKSIAMAI-UHFFFAOYSA-L oxygen(2-);zirconium(4+);chloride;hydroxide Chemical compound [OH-].[O-2].[Cl-].[Zr+4] ADGFKRMKSIAMAI-UHFFFAOYSA-L 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 3
- AOHAPDDBNAPPIN-UHFFFAOYSA-N 3-Methoxy-4,5-methylenedioxybenzoic acid Chemical compound COC1=CC(C(O)=O)=CC2=C1OCO2 AOHAPDDBNAPPIN-UHFFFAOYSA-N 0.000 claims 2
- GZQCBOPXKHXJPF-UHFFFAOYSA-G aluminum;zirconium(4+);heptachloride;hydrate Chemical compound O.[Al+3].[Cl-].[Cl-].[Cl-].[Cl-].[Cl-].[Cl-].[Cl-].[Zr+4] GZQCBOPXKHXJPF-UHFFFAOYSA-G 0.000 claims 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 claims 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims 1
- -1 aluminium chlorhydrate Chemical compound 0.000 abstract description 12
- 235000021360 Myristic acid Nutrition 0.000 abstract description 7
- TWJNQYPJQDRXPH-UHFFFAOYSA-N 2-cyanobenzohydrazide Chemical compound NNC(=O)C1=CC=CC=C1C#N TWJNQYPJQDRXPH-UHFFFAOYSA-N 0.000 abstract description 6
- TUNFSRHWOTWDNC-UHFFFAOYSA-N Myristic acid Natural products CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 abstract description 6
- 230000009467 reduction Effects 0.000 abstract description 6
- 150000004668 long chain fatty acids Chemical class 0.000 abstract 1
- 238000003756 stirring Methods 0.000 description 5
- 239000007864 aqueous solution Substances 0.000 description 4
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 229940075894 denatured ethanol Drugs 0.000 description 3
- 239000001863 hydroxypropyl cellulose Substances 0.000 description 3
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 description 3
- 238000012216 screening Methods 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- 210000004243 sweat Anatomy 0.000 description 3
- 241001340526 Chrysoclista linneella Species 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 235000021314 Palmitic acid Nutrition 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000000443 aerosol Substances 0.000 description 1
- 150000001398 aluminium Chemical class 0.000 description 1
- 210000001099 axilla Anatomy 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 150000002943 palmitic acids Chemical class 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q15/00—Anti-perspirants or body deodorants
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/26—Aluminium; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/28—Zirconium; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
- A61K8/361—Carboxylic acids having more than seven carbon atoms in an unbroken chain; Salts or anhydrides thereof
Definitions
- This invention relates to anti-perspirant compositions.
- a desirable property of anti-perspirant compositions is that they should dry quickly after application to the skin.
- the inclusion of a volatile solvent in the composition may often achieve this effect, the solvent evaporating quickly after application to leave a dry deposit of the active anti-perspirant material on the skin.
- Ethanol has often been used for this purpose, since it is readily available and relatively non-toxic.
- the use of high concentrations of ethanol can seriously reduce the efficacy of certain anti-perspirant compositions. This is particularly marked in the case of compositions containing an astringent anti-perspirant such as aluminium chlorhydrate.
- this invention provides an aqueous anti-perspirant composition
- an aqueous anti-perspirant composition comprising from 2 to 30% by weight of an astringent aluminium or zirconium salt as anti-perspirant agent, from 30 to 80% by weight of ethanol, and from 0.1 to 6% by weight of one or more C 14-18 fatty acids.
- Anti-perspirant agents suitable for use with the composition include aluminium basic chloride, bromide or iodide, zirconyl hydroxychloride, and astringent aluminium/zirconium complexes such as aluminium zirconium chlorohydrates.
- aluminium basic chloride means a compound having the approximate empirical formula Al 2 (OH).sub.(6-x) Cl x , where x is a number from 1 to 5.
- x is a number from 1 to 5.
- bromide and iodide have analogous formulae.
- compositions of the invention contain from 0.5 to 4%, or more preferably 1.0 to 3% by weight of one or more C 14-18 fatty acids.
- Suitable fatty acids include myristic, palmitic, stearic and iso-stearic acids, and mixtures thereof.
- the most highly preferred fatty acids are myristic and palmitic acids.
- compositions of the invention will normally contain from 5 to 20% by weight of anti-perspirant agent.
- the preferred anti-perspirant agent for use in the compositions of the invention is an aluminium basic chloride wherein the atomic ratio of aluminium to chloride is from 1.9:1 to 2.1:1. This material is generally known as aluminium chlorhydrate.
- compositions may contain further ingredients if desired, such as perfume, which will be present at conventional levels, such as 0.5 to 1% by weight.
- compositions of the invention are more effective anti-perspirants than analogous compositions without fatty acids.
- compositions will generally be adapted for application from a roll-ball or spray applicator.
- Metal containers such as those used for aerosol compositions, are generally unsuitable for use with the present compositions since they may be subject to corrosion. Glass or plastic containers are therefore preferred.
- compositions adapted for application from a roll-ball applicator will generally be thickened, for example, by the addition of conventional thickening agents, such as hydroxypropyl cellulose, or other thickening agents well known to those skilled in the art of formulating cosmetic compositions.
- thickening agent such as hydroxypropyl cellulose, or other thickening agents well known to those skilled in the art of formulating cosmetic compositions.
- hydroxypropyl cellulose When hydroxypropyl cellulose is used as thickening agent, it will generally be present in the composition in an amount from 0.1 to 2% by weight, more usually 0.1 to 1% or 0.3 to 0.8% by weight.
- compositions may also be adapted for application from spray applicators, such as pump-sprays or squeeze-bottles.
- compositions of the invention may be prepared as follows:
- the myristic acid was dissolved in the ethanol with stirring, and then the aluminium chlorhydrate solution was added, and the mixture was stirred thoroughly.
- the myristic acid was dissolved with stirring in the ethanol, followed by Klucel H, and then the aluminium chlorhydrate solution was added. The mixture was thoroughly stirred, to produce a composition suitable for application to the skin from a roll-ball applicator.
- Example 2 Using the method described in Example 1, three compositions having the above constitution were prepared.
- the fatty acids used were myristic, palmitic and isostearic acids.
- compositions and a corresponding composition containing no fatty acid were tested on 20 subjects using the back screening method descrived in J. Soc. Cosmet. Chem. 29, 413-422 (1978).
- compositions analogous to those in Examples 1 and 3 but having Crosterene S4310, a mixture of fatty acids, C 16 and C 18 acids predominating (Croda Chemicals Ltd.) was prepared and tested on 8 subjects using the back screening test, together with a corresponding composition containing no fatty acid.
- the compositions produced mean sweat reductions of 46% and 17%, respectively.
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Inorganic Chemistry (AREA)
- Chemical & Material Sciences (AREA)
- Emergency Medicine (AREA)
- Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Cosmetics (AREA)
- Medicinal Preparation (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
An anti-perspirant composition includes 30% by weight of an anti-perspirant agent, aluminium chlorhydrate, 68.5% by weight of ethanol and 1.5% by weight of a long chain fatty acid, myristic acid.
The presence of the fatty acid counteracts the reduction in efficacy caused by the high concentration of ethanol.
Description
This invention relates to anti-perspirant compositions.
A desirable property of anti-perspirant compositions is that they should dry quickly after application to the skin. The inclusion of a volatile solvent in the composition may often achieve this effect, the solvent evaporating quickly after application to leave a dry deposit of the active anti-perspirant material on the skin. Ethanol has often been used for this purpose, since it is readily available and relatively non-toxic. However, the use of high concentrations of ethanol can seriously reduce the efficacy of certain anti-perspirant compositions. This is particularly marked in the case of compositions containing an astringent anti-perspirant such as aluminium chlorhydrate.
It is an object of the present invention to provide aqueous anti-perspirant compositions which contain relatively high levels of ethanol to promote quick drying after application to the skin, and which have good levels of anti-perspirant efficacy.
We have discovered that the reduction in efficacy caused by the presence of high concentrations of ethanol may be counteracted by the addition of certain fatty acids.
The addition of, inter alia, fatty acids to anti-perspirant compositions containing "Rehydrol" (a complex of aluminium chlorhydrate and propylene glycol) has been suggested. This is to counteract gelling of the compositions, which can occur with "Rehydrol". Gelling is not normally a problem with aqueous aluminium chlorhydrate compositions, so there has been no suggestion that the addition of fatty acids to aqueous aluminium chlorhydrate compositions would have any beneficial effects.
Accordingly, this invention provides an aqueous anti-perspirant composition comprising from 2 to 30% by weight of an astringent aluminium or zirconium salt as anti-perspirant agent, from 30 to 80% by weight of ethanol, and from 0.1 to 6% by weight of one or more C14-18 fatty acids.
Anti-perspirant agents suitable for use with the composition include aluminium basic chloride, bromide or iodide, zirconyl hydroxychloride, and astringent aluminium/zirconium complexes such as aluminium zirconium chlorohydrates.
When used herein, "aluminium basic chloride" means a compound having the approximate empirical formula Al2 (OH).sub.(6-x) Clx, where x is a number from 1 to 5. The corresponding bromide and iodide have analogous formulae.
Preferably, the compositions of the invention contain from 0.5 to 4%, or more preferably 1.0 to 3% by weight of one or more C14-18 fatty acids.
Suitable fatty acids include myristic, palmitic, stearic and iso-stearic acids, and mixtures thereof. The most highly preferred fatty acids are myristic and palmitic acids.
The compositions of the invention will normally contain from 5 to 20% by weight of anti-perspirant agent.
The preferred anti-perspirant agent for use in the compositions of the invention is an aluminium basic chloride wherein the atomic ratio of aluminium to chloride is from 1.9:1 to 2.1:1. This material is generally known as aluminium chlorhydrate.
The compositions may contain further ingredients if desired, such as perfume, which will be present at conventional levels, such as 0.5 to 1% by weight.
The compositions of the invention are more effective anti-perspirants than analogous compositions without fatty acids.
The compositions will generally be adapted for application from a roll-ball or spray applicator. Metal containers, such as those used for aerosol compositions, are generally unsuitable for use with the present compositions since they may be subject to corrosion. Glass or plastic containers are therefore preferred.
Compositions adapted for application from a roll-ball applicator will generally be thickened, for example, by the addition of conventional thickening agents, such as hydroxypropyl cellulose, or other thickening agents well known to those skilled in the art of formulating cosmetic compositions. When hydroxypropyl cellulose is used as thickening agent, it will generally be present in the composition in an amount from 0.1 to 2% by weight, more usually 0.1 to 1% or 0.3 to 0.8% by weight.
The compositions may also be adapted for application from spray applicators, such as pump-sprays or squeeze-bottles.
The compositions of the invention may be prepared as follows:
Dissolve the fatty acid(s) in the alcohol with stirring, and then add the thickener (if required) and stir until dissolved. Finally, add an aqueous solution of the anti-perspirant agent and stir thoroughly. Perfume may be added to the composition before adding the anti-perspirant agent.
The following Examples illustrate the invention:
______________________________________
% by weight
______________________________________
Myristic acid 1.5
Denatured ethanol 68.5
Aluminium chlorhydrate
30.0
(50% aqueous solution)
______________________________________
The myristic acid was dissolved in the ethanol with stirring, and then the aluminium chlorhydrate solution was added, and the mixture was stirred thoroughly.
In the axilla screening test described in J. Soc. Cosmet. Chem. 29, 413-422 (1978), this composition produced a 43% sweat reduction compared with a 32% reduction for a corresponding composition containing no myristic acid and with 70% ethanol. (Significantly different at 0.02% level in Wilcoxon Matched Pairs Test).
______________________________________
% by weight
______________________________________
Myristic Acid 1.5
Denatured ethanol 67.84
Klucel H* 0.66
Aluminium chlorhydrate
30.00
(50% aqueous solution)
______________________________________
*Klucel H is hydroxypropyl cellulose (Hercules Powder Co.).
The myristic acid was dissolved with stirring in the ethanol, followed by Klucel H, and then the aluminium chlorhydrate solution was added. The mixture was thoroughly stirred, to produce a composition suitable for application to the skin from a roll-ball applicator.
______________________________________
% by weight
______________________________________
Fatty Acid 1.5
Aluminium Chlorhydrate
30.0
(5O% aqueous solution)
Denatured ethanol 68.5
______________________________________
Using the method described in Example 1, three compositions having the above constitution were prepared. The fatty acids used were myristic, palmitic and isostearic acids.
These compositions and a corresponding composition containing no fatty acid were tested on 20 subjects using the back screening method descrived in J. Soc. Cosmet. Chem. 29, 413-422 (1978).
The results are shown below.
______________________________________ Fatty Acid Mean % Sweat Reduction ______________________________________ -- 34 Myristic 54 Palmitic 54 Isostearic 39 ______________________________________
A composition analogous to those in Examples 1 and 3 but having Crosterene S4310, a mixture of fatty acids, C16 and C18 acids predominating (Croda Chemicals Ltd.) was prepared and tested on 8 subjects using the back screening test, together with a corresponding composition containing no fatty acid. The compositions produced mean sweat reductions of 46% and 17%, respectively.
Claims (7)
1. An aqueous anti-perspirant composition, consisting essentially of from 2 to 30% by weight of an astringent aluminium or zirconium salt as anti-perspirant agent, from 30 to 80% by weight of ethanol, from 0.16 to 6% by weight of one or more C14-18 fatty acids, and water.
2. A composition according to claim 1, wherein the anti-perspirant agent comprises aluminium basic chloride, bromide, or iodide, zirconyl hydroxychloride, or an aluminium zirconium chlorohydrate.
3. A composition according to claim 1, wherein from 1.0 to 3% by weight of one or more C14-18 fatty acids is present.
4. A composition according to claim 1, wherein the fatty acid is myristic, palmitic, stearic, or iso-stearic acid, or a mixture of any thereof.
5. A composition according to claim 1, wherein from 5 20% by weight of said anti-perspirant agent is present.
6. An aqueous anti-perspirant composition, consisting essentially of from 2 to 30% by weight of an astringent aluminium or zirconium salt as anti-perspirant agent, from 30 to 80% by weight of ethanol, from 0.16 to 6% by weight of one or more C14-18 fatty acids, and water and a thickener.
7. An aqueous anti-perspirant composition consisting essentially of from 2 to 30% by weight of an astringent aluminium or zirconium salt as anti-perspirant agent, from 30 to 80% by weight of ethanol, from 0.16 to 6% by weight of one or more C14-18 fatty acids, and water and a perfume.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB7906281 | 1979-02-22 | ||
| GB7906281 | 1979-02-22 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US4666710A true US4666710A (en) | 1987-05-19 |
Family
ID=10503362
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US06/121,174 Expired - Lifetime US4666710A (en) | 1979-02-22 | 1980-02-13 | Anti-perspirant compositions |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US4666710A (en) |
| EP (1) | EP0016533B1 (en) |
| JP (1) | JPS55115817A (en) |
| AU (1) | AU534751B2 (en) |
| CA (1) | CA1127540A (en) |
| DE (1) | DE3070638D1 (en) |
| DK (1) | DK70780A (en) |
| GB (1) | GB2043445B (en) |
| IE (1) | IE49271B1 (en) |
| ZA (1) | ZA80882B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1995031961A1 (en) * | 1994-05-25 | 1995-11-30 | The Procter & Gamble Company | Gel stick compositions comprising optically enriched gellants |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3147136A (en) * | 1961-01-11 | 1964-09-01 | Owens Illinois Glass Co | Process for forming a grit-blasted and methyl methacrylate-epoxy resin coated glass surface |
| GB8518081D0 (en) * | 1985-07-17 | 1985-08-21 | Beecham Group Plc | Compositions |
| DK483587D0 (en) * | 1987-09-15 | 1987-09-15 | Riemann & Co Aps Claus | ANTIPERSPIRANT PREPARATION |
| GB9604341D0 (en) * | 1996-02-29 | 1996-05-01 | Unilever Plc | Antiperspirant composition |
| JP6180995B2 (en) * | 2014-05-27 | 2017-08-16 | ライオン株式会社 | Antiperspirant composition |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB480379A (en) * | 1936-10-29 | 1938-02-22 | William Cabler Moore | A new and useful composition as a deodorant and for application to the human skin |
| GB1267959A (en) * | 1968-10-23 | 1972-03-22 | Armour Pharma | Method of making alcohol-soluble complexes of aluminum |
| GB1319437A (en) * | 1970-11-09 | 1973-06-06 | Armour Pharma | Basic aluminium bromide compositions |
| US4053581A (en) * | 1975-08-15 | 1977-10-11 | Lever Brothers Company | Antiperspirant solution containing a mixture of substantially volatile and substantially non-volatile siloxane liquids |
| US4152416A (en) * | 1976-09-17 | 1979-05-01 | Marra Dorothea C | Aerosol antiperspirant compositions delivering astringent salt with low mistiness and dustiness |
| US4174386A (en) * | 1975-03-03 | 1979-11-13 | Marra Dorothea C | Aerosol antiperspirant compositions with good adherence to the skin |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU484620B2 (en) * | 1973-10-26 | 1975-05-01 | Armour Pharmaceutical Company | Zinc and zirconium complexes of basic aluminum halides and methods of making same |
| JPS5470436A (en) * | 1977-11-15 | 1979-06-06 | Lion Dentifrice Co Ltd | Antiisweat agent |
-
1980
- 1980-02-11 AU AU55408/80A patent/AU534751B2/en not_active Ceased
- 1980-02-13 US US06/121,174 patent/US4666710A/en not_active Expired - Lifetime
- 1980-02-15 ZA ZA00800882A patent/ZA80882B/en unknown
- 1980-02-18 GB GB8005356A patent/GB2043445B/en not_active Expired
- 1980-02-18 EP EP80300457A patent/EP0016533B1/en not_active Expired
- 1980-02-18 DE DE8080300457T patent/DE3070638D1/en not_active Expired
- 1980-02-18 DK DK70780A patent/DK70780A/en not_active Application Discontinuation
- 1980-02-21 CA CA346,140A patent/CA1127540A/en not_active Expired
- 1980-02-21 IE IE344/80A patent/IE49271B1/en unknown
- 1980-02-22 JP JP2148180A patent/JPS55115817A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB480379A (en) * | 1936-10-29 | 1938-02-22 | William Cabler Moore | A new and useful composition as a deodorant and for application to the human skin |
| GB1267959A (en) * | 1968-10-23 | 1972-03-22 | Armour Pharma | Method of making alcohol-soluble complexes of aluminum |
| GB1319437A (en) * | 1970-11-09 | 1973-06-06 | Armour Pharma | Basic aluminium bromide compositions |
| US4174386A (en) * | 1975-03-03 | 1979-11-13 | Marra Dorothea C | Aerosol antiperspirant compositions with good adherence to the skin |
| US4053581A (en) * | 1975-08-15 | 1977-10-11 | Lever Brothers Company | Antiperspirant solution containing a mixture of substantially volatile and substantially non-volatile siloxane liquids |
| US4152416A (en) * | 1976-09-17 | 1979-05-01 | Marra Dorothea C | Aerosol antiperspirant compositions delivering astringent salt with low mistiness and dustiness |
Non-Patent Citations (1)
| Title |
|---|
| Ash et al., A Formulary of Cosmetic Preparations, 1977, pp. 7, 8, 9, 10 to 14, & 20 to 24. * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1995031961A1 (en) * | 1994-05-25 | 1995-11-30 | The Procter & Gamble Company | Gel stick compositions comprising optically enriched gellants |
| US5552136A (en) * | 1994-05-25 | 1996-09-03 | The Procter & Gamble Company | Gel stick compositions comprising optically enriched gellants |
Also Published As
| Publication number | Publication date |
|---|---|
| EP0016533A3 (en) | 1981-08-26 |
| IE49271B1 (en) | 1985-09-04 |
| GB2043445A (en) | 1980-10-08 |
| AU5540880A (en) | 1980-08-28 |
| EP0016533B1 (en) | 1985-05-15 |
| DK70780A (en) | 1980-08-23 |
| EP0016533A2 (en) | 1980-10-01 |
| AU534751B2 (en) | 1984-02-16 |
| CA1127540A (en) | 1982-07-13 |
| DE3070638D1 (en) | 1985-06-20 |
| IE800344L (en) | 1980-08-22 |
| GB2043445B (en) | 1983-08-17 |
| ZA80882B (en) | 1981-02-25 |
| JPS55115817A (en) | 1980-09-06 |
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