US4487740A - Procedure and equipment for injecting gas into liquids - Google Patents

Procedure and equipment for injecting gas into liquids Download PDF

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Publication number
US4487740A
US4487740A US05/947,671 US94767178A US4487740A US 4487740 A US4487740 A US 4487740A US 94767178 A US94767178 A US 94767178A US 4487740 A US4487740 A US 4487740A
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US
United States
Prior art keywords
gas
nozzles
bubble column
group
conduit
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
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US05/947,671
Inventor
Max Stiefel
Erich Wolfbeiss
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ABB Reaktor GmbH
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Babcock Brown Boveri Reaktor GmbH
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Assigned to BABCOCK-BROWN BOVERI REAKTOR GMBH, reassignment BABCOCK-BROWN BOVERI REAKTOR GMBH, ASSIGNMENT OF ASSIGNORS INTEREST. Assignors: STIEFEL, MAX, WOLFBEIB, ERICH
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    • G—PHYSICS
    • G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
    • G21C—NUCLEAR REACTORS
    • G21C15/00—Cooling arrangements within the pressure vessel containing the core; Selection of specific coolants
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
    • B01F23/20—Mixing gases with liquids
    • B01F23/23—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids
    • B01F23/232—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids using flow-mixing means for introducing the gases, e.g. baffles
    • B01F23/2322—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids using flow-mixing means for introducing the gases, e.g. baffles using columns, e.g. multi-staged columns
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E30/00—Energy generation of nuclear origin
    • Y02E30/30—Nuclear fission reactors

Definitions

  • This invention is directed to a procedure for injecting gas into liquids, and, more particularly to the injection of hydrogen into the primary coolant of pressurized water nuclear power plants.
  • the makeup tank is used to equalize primary coolant volume changes, and contains both the primary coolant and a hydrogen-gas blanket.
  • the problem is solved in that the liquid flows through a bubble column, only the gas volume necessary for reaching the required gas content is injected into the bubble column above the liquid inlet, and the gas and liquid are mixed prior to leaving the bubble column.
  • the device used for implementing this procedure has a bubble column that contains several motionless mixers.
  • the gas feed line is equipped with a gas pump, and the pipe section of the two-conduit gas injection line arranged inside the bubble column is equipped with nozzles.
  • the nozzles moreover, can be flushed with the aid of a bypass flow of the liquid to be gassed.
  • An advantage of this feature is that the bypass flow conduits are connected with the pipe sections that support the nozzles.
  • a ventilation line is also attached at the bubble column in order to prevent gas bubble formation in the primary coolant.
  • Analyses measuring devices are installed in the liquid line upstream and downstream of the bubble column.
  • the gas volume injected through the gas pump depends upon the pre-existing hydrogen concentration of the liquid to be injected with gas, and the head of the liquid flow.
  • the isolation valves of the bypass flow conduits can be manipulated to enable the nozzles to be covered with gas and rinse water on alternate sides.
  • conduit 14 the primary coolant to be injected with gas flows into a pressurized water reactor system (not shown) in the direction of arrow 19, and after the adjustment of the volume flow control valve 10, flows into bubble column 6 at liquid inlet 20.
  • gas proportioning or dosage equipment e.g. gas dosage pump 1
  • the hydrogen gas in conduit 2 is channeled into the bubble column 6 and is injected above liquid inlet 20 via the double gas injection conduits 2a or 2b, and nozzles 5 or 5a.
  • the mode of operation for implementing the flushing process enables the nozzles 5, 5a to be flushed alternately, or to be used for gas injection.
  • isolation valves 3 and 11a are closed and isolation valves 11 and 3a are open.
  • isolation valves 3a and 11 are closed and isolation valves 11a and 3 are open.
  • Check valves 4a, 12a, 4 and 12 prevent gas or flushing liquid from returning.
  • An analysis measuring device 8 is installed in bypass conduit 13, which measures the hydrogen gas concentration of the liquid to be injected with gas so that exact gas dosing can be accomplished through the gas dosage pump 1 as a function of gas content and liquid volume in conduit 14.
  • Nitrogen moreover, can be used as a gas blanket for the makeup tank, in order to avoid the danger of a combustible gas explosion.
  • An additional advantage of the invention is the fact that the hydrogen concentration of the reinjected primary coolant can be kept within a specified range during load change processes.

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  • Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • High Energy & Nuclear Physics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Plasma & Fusion (AREA)
  • General Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Monitoring And Testing Of Nuclear Reactors (AREA)
  • Accessories For Mixers (AREA)
  • Measuring Volume Flow (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Geophysics And Detection Of Objects (AREA)
  • Preventing Corrosion Or Incrustation Of Metals (AREA)

Abstract

A method and apparatus is shown for establishing a predetermined concentration of gas in the reactor core coolant for a pressurized water nuclear power system. Gas is added to core coolant water in a bubble column. The gas-water mixture flows through static mixers in the column to produce the desired gas concentration in the water.

Description

TECHNICAL FIELD
This invention is directed to a procedure for injecting gas into liquids, and, more particularly to the injection of hydrogen into the primary coolant of pressurized water nuclear power plants.
BACKGROUND ART
For example, it is not uncommon in nuclear power plants, to inject hydrogen gas into primary coolant water by spraying the primary coolant into an hydrogen atmosphere, e.g. into the hydrogen gas blanket of the makeup tank, or by bubbling hydrogen gas in the water phase of the makeup tank. The makeup tank among other things, is used to equalize primary coolant volume changes, and contains both the primary coolant and a hydrogen-gas blanket.
These known procedures have the disadvantage that due to the large hydrogen volume in the makeup tank, a release of relatively large hydrogen volumes into the space surrounding the makeup tanks is possible, and therefore the occurrence of combustible gas explosions must be taken into account. Further, the gas/water concentration can not be precisely controlled.
There is a need, therefore, to find a procedure through which a predetermined gas concentration can be reached in the liquid under consideration and through which the potential release of dangerous volumes of explosive gas can be minimized.
SUMMARY OF THE INVENTION
The problem is solved in that the liquid flows through a bubble column, only the gas volume necessary for reaching the required gas content is injected into the bubble column above the liquid inlet, and the gas and liquid are mixed prior to leaving the bubble column.
The device used for implementing this procedure has a bubble column that contains several motionless mixers. The gas feed line is equipped with a gas pump, and the pipe section of the two-conduit gas injection line arranged inside the bubble column is equipped with nozzles.
The nozzles, moreover, can be flushed with the aid of a bypass flow of the liquid to be gassed. An advantage of this feature is that the bypass flow conduits are connected with the pipe sections that support the nozzles.
A ventilation line is also attached at the bubble column in order to prevent gas bubble formation in the primary coolant. Analyses measuring devices are installed in the liquid line upstream and downstream of the bubble column.
The gas volume injected through the gas pump depends upon the pre-existing hydrogen concentration of the liquid to be injected with gas, and the head of the liquid flow.
In accordance with a specific embodiment of the invention, the isolation valves of the bypass flow conduits can be manipulated to enable the nozzles to be covered with gas and rinse water on alternate sides.
BRIEF DESCRIPTION OF THE DRAWING
The method and apparatus for implementing the invention are shown in a schematic drawing.
DESCRIPTION OF THE PREFERRED EMBODIMENTS
In conduit 14 the primary coolant to be injected with gas flows into a pressurized water reactor system (not shown) in the direction of arrow 19, and after the adjustment of the volume flow control valve 10, flows into bubble column 6 at liquid inlet 20. With the aid of gas proportioning or dosage equipment, e.g. gas dosage pump 1, the hydrogen gas in conduit 2 is channeled into the bubble column 6 and is injected above liquid inlet 20 via the double gas injection conduits 2a or 2b, and nozzles 5 or 5a.
Hydrogen gas and primary coolant are now intensively mixed when liquid flows through motionless mixer 7. After the liquid has flowed through the mixer 7, the primary coolant which has been provided with the desired hydrogen content, discharges from the bubble column 6 through conduit 15. Automatic ventilation through the conduit 16, float valve 17 and isolation valve 18 ensures that no gas bubbles remain in the primary coolant. Bypass conduit 13 in which coolant flows in the direction of arrow 21, which comprises a certain portion of the primary coolant that to be injected with gas flows, branches off from the conduit 14.
The mode of operation for implementing the flushing process enables the nozzles 5, 5a to be flushed alternately, or to be used for gas injection. For the case "flush nozzle 5", isolation valves 3 and 11a are closed and isolation valves 11 and 3a are open. For the case "flush nozzle 5a" isolation valves 3a and 11 are closed and isolation valves 11a and 3 are open. Check valves 4a, 12a, 4 and 12 prevent gas or flushing liquid from returning.
An analysis measuring device 8 is installed in bypass conduit 13, which measures the hydrogen gas concentration of the liquid to be injected with gas so that exact gas dosing can be accomplished through the gas dosage pump 1 as a function of gas content and liquid volume in conduit 14.
It should also be noted that the entire gassing and flushing process takes place automatically.
Gassing in accordance with the principles of the invention now is possible in a simplified and advantageous manner. Nitrogen, moreover, can be used as a gas blanket for the makeup tank, in order to avoid the danger of a combustible gas explosion.
An additional advantage of the invention is the fact that the hydrogen concentration of the reinjected primary coolant can be kept within a specified range during load change processes.

Claims (5)

The embodiments of the invention in which as exclusive property or privilege is claimed are defined as follows:
1. A device for injecting a gas into a stream of reactor coolant for a pressurized water nuclear power plant comprising:
a bubble column, the stream of reactor coolant being directed up therethrough;
motionless mixer means positioned within said bubble column for mixing the stream of reactor coolant;
a gas pump;
gas conduit means for establishing fluid communication between said gas pump and said bubble column below said motionless mixer means;
a plurality of nozzles on said gas conduit means establishing fluid communication between said gas conduit means and the stream of reactor coolant within said bubble column;
gas analysis measuring apparatus for measuring the gas concentration in the reactor coolant liquid.
2. A device as in claim 1 further comprising:
by-pass flow conduit means for establishing fluid communication between the coolant prior to entry into said bubble column and said plurality of nozzles to enable a portion of the stream of reactor coolant to bypass a portion of said bubble column and flush a portion of said plurality of nozzles;
valve means for selectively isolating said plurality of nozzles from said gas injection conduit means and said by-pass flow conduit means.
3. A device as in claim 2 wherein:
said plurality of nozzles include a first group of nozzles and a second group of nozzles;
said gas conduit means includes a first gas conduit and a second gas conduit establishing fluid communication between said first group of nozzles and said second group of nozzles respectively;
said by-pass flow conduit means including a first by-pass flow conduit and a second by-pass flow conduit providing fluid communication between the coolant prior to entry into said bubble column and said first group of nozzles and said second group of nozzles respectively;
said valve means being capable of selectively isolating said first group of nozzles and said second group of nozzles from said gas pump while by-pass flow is directed therethrough, while said second group of nozzles and said first group of nozzles respectively remain in fluid communication with said gas pump to provide flushing without interrupting the gas injection.
4. A device according to claim 1 further comprising:
a vent conduit to eliminate gas bubbles from the reactor coolant liquid in said bubble column above said motionless mixer means; and, vent valve means for isolating said vent conduit and precluding backflow through said vent conduit into said bubble column.
5. A method for injecting gas into a reactor coolant for a pressurized water nuclear power plants comprising the steps of passing the coolant up through a bubble column that has a liquid inlet, injecting only the gas quantity needed for reaching a predetermined gas concentration in the coolant into the bubble column above the liquid inlet and mixing the gas and the coolant prior to leaving the bubble column.
US05/947,671 1977-10-27 1978-10-02 Procedure and equipment for injecting gas into liquids Expired - Lifetime US4487740A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE2748159 1977-10-27
DE2748159A DE2748159C2 (en) 1977-10-27 1977-10-27 Device for gassing the primary coolant of a water-cooled nuclear reactor plant

Publications (1)

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US4487740A true US4487740A (en) 1984-12-11

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US05/947,671 Expired - Lifetime US4487740A (en) 1977-10-27 1978-10-02 Procedure and equipment for injecting gas into liquids

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Country Link
US (1) US4487740A (en)
EP (1) EP0001903B1 (en)
JP (1) JPS5923398B2 (en)
AT (1) AT364045B (en)
CA (1) CA1131887A (en)
CH (1) CH635521A5 (en)
DE (1) DE2748159C2 (en)
ES (1) ES474579A1 (en)
IL (1) IL55769A (en)
IT (1) IT1104225B (en)
SE (1) SE429696B (en)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2948297C2 (en) * 1978-06-27 1985-01-17 Kraftwerk Union AG, 4330 Mülheim Nuclear reactor with a liquid coolant
DE2828153C3 (en) * 1978-06-27 1984-07-26 Kraftwerk Union AG, 4330 Mülheim Nuclear reactor with a liquid coolant
US4749505A (en) * 1985-07-08 1988-06-07 Exxon Chemical Patents Inc. Olefin polymer viscosity index improver additive useful in oil compositions
RU2254626C2 (en) * 2003-08-21 2005-06-20 Государственное унитарное предприятие Опытное конструкторское бюро машиностроения им. Африкантова И.И. Steam pressurizer
CN109342492B (en) * 2018-11-23 2021-09-10 哈尔滨工程大学 Experimental device and experimental method for researching bubble rupture behavior characteristics of aerosol-containing liquid pool surface

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US955004A (en) * 1909-07-31 1910-04-12 William O Singer Wrench.
US2937981A (en) * 1951-06-22 1960-05-24 Augustine O Allen Suppression of water decomposition
US3060726A (en) * 1957-02-07 1962-10-30 Westinghouse Electric Corp Hydrogen gauge
US3113913A (en) * 1963-12-10 Sealing and purging system for pressurized water reactor
US3286992A (en) * 1965-11-29 1966-11-22 Little Inc A Mixing device
US3353797A (en) * 1964-07-08 1967-11-21 Sonic Eng Corp Mixing system
US3450388A (en) * 1968-03-12 1969-06-17 Gen Motors Corp Mixer with flushing valve in the outlet
US3539509A (en) * 1967-06-08 1970-11-10 Siemens Ag Method for electromagnetic removal of iron-oxides from liquids
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UST955004I4 (en) 1976-04-05 1977-02-01 Westinghouse Electric Corporation Method for heat exchanger leak detection in a liquid metal cooled nuclear reactor
US4039289A (en) * 1971-02-08 1977-08-02 Chemsoil Corporation Sulphur-burning and gaseous products absorption system and components therefor
US4043864A (en) * 1971-12-22 1977-08-23 Kraftwerk Union Aktiengesellschaft Nuclear power plant having a pressurized-water reactor
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US3124518A (en) * 1964-03-10 Product
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US955004A (en) * 1909-07-31 1910-04-12 William O Singer Wrench.
US2937981A (en) * 1951-06-22 1960-05-24 Augustine O Allen Suppression of water decomposition
US3060726A (en) * 1957-02-07 1962-10-30 Westinghouse Electric Corp Hydrogen gauge
US3353797A (en) * 1964-07-08 1967-11-21 Sonic Eng Corp Mixing system
US3286992A (en) * 1965-11-29 1966-11-22 Little Inc A Mixing device
US3539509A (en) * 1967-06-08 1970-11-10 Siemens Ag Method for electromagnetic removal of iron-oxides from liquids
US3575294A (en) * 1967-11-27 1971-04-20 Nippon Rensui Kk Counterflow, moving bed type, ion exchange apparatus
US3450388A (en) * 1968-03-12 1969-06-17 Gen Motors Corp Mixer with flushing valve in the outlet
US3663725A (en) * 1970-04-23 1972-05-16 Gen Electric Corrosion inhibition
US4073683A (en) * 1970-05-19 1978-02-14 Westinghouse Electric Corporation Boron control system for a nuclear power plant
US4039289A (en) * 1971-02-08 1977-08-02 Chemsoil Corporation Sulphur-burning and gaseous products absorption system and components therefor
US3871842A (en) * 1971-07-05 1975-03-18 Licentia Gmbh Exhaust gas cleaning system for handling radioactive fission and activation gases
US4043864A (en) * 1971-12-22 1977-08-23 Kraftwerk Union Aktiengesellschaft Nuclear power plant having a pressurized-water reactor
US3964965A (en) * 1973-01-22 1976-06-22 Siemens Aktiengesellschaft Pressurized-water reactor coolant gas disposal system
US3976541A (en) * 1974-03-18 1976-08-24 Combustion Engineering, Inc. Secondary coolant purification system with demineralizer bypass
UST955004I4 (en) 1976-04-05 1977-02-01 Westinghouse Electric Corporation Method for heat exchanger leak detection in a liquid metal cooled nuclear reactor

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Also Published As

Publication number Publication date
SE7811046L (en) 1979-04-28
ES474579A1 (en) 1979-06-01
SE429696B (en) 1983-09-19
JPS55453A (en) 1980-01-05
CA1131887A (en) 1982-09-21
JPS5923398B2 (en) 1984-06-01
IT7809627A0 (en) 1978-10-26
DE2748159C2 (en) 1984-06-20
IL55769A (en) 1981-07-31
DE2748159A1 (en) 1979-05-03
AT364045B (en) 1981-09-25
IT1104225B (en) 1985-10-21
EP0001903B1 (en) 1981-10-21
CH635521A5 (en) 1983-04-15
ATA748878A (en) 1981-02-15
EP0001903A1 (en) 1979-05-16

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