US4008080A - Copper free dental gold alloys - Google Patents

Copper free dental gold alloys Download PDF

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Publication number
US4008080A
US4008080A US05/628,766 US62876675A US4008080A US 4008080 A US4008080 A US 4008080A US 62876675 A US62876675 A US 62876675A US 4008080 A US4008080 A US 4008080A
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US
United States
Prior art keywords
gold
alloy
consisting essentially
alloys
palladium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US05/628,766
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English (en)
Inventor
Ewald Wagner
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Evonik Operations GmbH
Original Assignee
Deutsche Gold und Silber Scheideanstalt
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Filing date
Publication date
Application filed by Deutsche Gold und Silber Scheideanstalt filed Critical Deutsche Gold und Silber Scheideanstalt
Application granted granted Critical
Publication of US4008080A publication Critical patent/US4008080A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C5/00Alloys based on noble metals
    • C22C5/02Alloys based on gold
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K6/00Preparations for dentistry
    • A61K6/80Preparations for artificial teeth, for filling teeth or for capping teeth
    • A61K6/84Preparations for artificial teeth, for filling teeth or for capping teeth comprising metals or alloys
    • A61K6/844Noble metals

Definitions

  • the invention is directed to a copper free dental gold alloy based on silver-gold-palladium containing a relatively low gold content.
  • dental alloys can be discolored in the mouth if local elements are formed which are traced back to differential aeration.
  • differential aeration cells can form.
  • the alloy components which are less noble than oxygen, as for example copper, can be dissolved there as ions. They wander to the cathodic region and then are deposited. Frequently, the thin precipitate is scarcely seen. Under the action of food and air it can change into plainly visible oxide and/or sulfide films. Also in telescopic work, the danger of coloration is present, since the primary part is always more poorly aerated than the secondary crown. The deciding role in this discoloration must be reduced to the copper of the alloy.
  • alloys which consisted of 25 to 40% silver, 40 to 60% gold, 5 to 20% palladium, 0.05 to 0.5% iridium, 0 to 6% indium, 0 to 6% tin and 0 to 2% zinc with the proviso that the normal non-noble metals must total at least 2%.
  • alloys that consisted of 28 to 35% silver, 50 to 58% gold, 5 to 10% palladium, 0.05 to 0.15% iridium, 2 to 5% indium, 0 to 3% tin and 0 to 1% zinc wherein the non-noble metal content is at least 4%.
  • the dental alloys of the invention contain significantly less gold than the previously known copper free dental gold alloys and the expensive platinum is eliminated without the mechanical and chemical corrosion resistant properties falling out of the FDI specifications.
  • the sum of the content of gold, palladium and iridium expressed in atomic percent is slightly over 50%, except in alloys 2, 3, 4 and 13 in which the sum is below 50%. Despite this relatively low content of gold, palladium and iridium, the alloys are corrosion resistant.
  • the alloys are arranged in the FDI Specification No. 7 as Type I (soft), II (medium), III (hard) and IV (extra hard). Especially approved are alloys 3 (Type I), 5 and 6 (Type II), 7 and 10 (Type III), 13 and 14 (Type IV).
  • compositions can consist essentially of or consists of the stated materials.

Landscapes

  • Health & Medical Sciences (AREA)
  • Oral & Maxillofacial Surgery (AREA)
  • Chemical & Material Sciences (AREA)
  • Veterinary Medicine (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Epidemiology (AREA)
  • Plastic & Reconstructive Surgery (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Dental Preparations (AREA)
US05/628,766 1974-11-13 1975-11-04 Copper free dental gold alloys Expired - Lifetime US4008080A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE2453799A DE2453799C3 (de) 1974-11-13 1974-11-13 Kupferfreie Dentalgoldlegierungen
DT2453799 1974-11-13

Publications (1)

Publication Number Publication Date
US4008080A true US4008080A (en) 1977-02-15

Family

ID=5930717

Family Applications (1)

Application Number Title Priority Date Filing Date
US05/628,766 Expired - Lifetime US4008080A (en) 1974-11-13 1975-11-04 Copper free dental gold alloys

Country Status (6)

Country Link
US (1) US4008080A (pt)
JP (1) JPS5172921A (pt)
BR (1) BR7507328A (pt)
CH (1) CH597353A5 (pt)
DE (1) DE2453799C3 (pt)
FR (1) FR2291282A1 (pt)

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4255191A (en) * 1979-03-02 1981-03-10 Degussa Aktiengesellschaft Gold-silver alloys with good tarnish resistance for the dental art
US4266973A (en) * 1979-12-14 1981-05-12 The J. M. Ney Company Tarnish-resistant gold color alloy and dental restorations employing same
US4319877A (en) * 1979-10-10 1982-03-16 Boyajian Benjamin K Palladium-based dental alloy containing indium and tin
US4539176A (en) * 1984-05-04 1985-09-03 Pennwalt Corporation Low gold dental alloys
US5217685A (en) * 1991-10-03 1993-06-08 The Wilkinson Company Abutment base alloy for jawbone mounted dental implants
US5453290A (en) * 1990-09-10 1995-09-26 Elephant Edelmetaal B.V. Dental procelain, a method of producing a dental restoration, a dental alloy
US5695714A (en) * 1993-07-23 1997-12-09 Degussa Aktiengesellschaft Gold-palladium alloys for dental materials
US20070026249A1 (en) * 2005-07-29 2007-02-01 Roland Strietzel Veneerable silver alloy for producing ceramic-veneered dental restorations
US20080138842A1 (en) * 2006-12-11 2008-06-12 Hans Boehringer Indirect lateral flow sandwich assay
KR101181491B1 (ko) 2010-06-25 2012-09-11 (주)탑플러스 치과 보철물용 합금 조성물 및 치과 보철물의 제조방법
EP2818567A1 (de) 2013-06-27 2014-12-31 C. Hafner GmbH + Co. KG Weißgold-Legierung, insbesondere zur Verwendung für ein Steinguss-Verfahren
DE102013010700A1 (de) * 2013-06-27 2014-12-31 C. Hafner Gmbh + Co. Kg Weißgold-Legierung, insbesondere zur Verwendung für ein Steinguss-Verfahren

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2637807C3 (de) * 1976-08-21 1981-11-19 W.C. Heraeus Gmbh, 6450 Hanau Verwendung einer Gold-Legierung für Schwachstrom-Kontakte
ATE49703T1 (de) * 1985-12-07 1990-02-15 Degussa Dental-goldlegierungen.
DE3641164A1 (de) * 1985-12-07 1987-06-11 Degussa Verwendung von goldlegierungen in der dentaltechnik
DE3819904C1 (pt) * 1988-06-11 1989-11-02 Degussa Ag, 6000 Frankfurt, De
US5635131A (en) * 1994-05-27 1997-06-03 Hoover & Strong, Inc. Palladium white gold alloy ring settings and method of making same

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB683004A (en) * 1949-12-14 1952-11-19 Degussa Highly acid-resistant objects
US3667936A (en) * 1969-03-21 1972-06-06 Aurium Research Corp Dental alloy
DE2139331A1 (de) * 1971-08-06 1973-02-15 Degussa Kupferfreie dental-goldlegierungen
US3767391A (en) * 1969-05-19 1973-10-23 Pennwalt Corp Tarnish resistant alloy
US3819366A (en) * 1969-03-21 1974-06-25 Aurium Res Corp Dental alloy

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB683004A (en) * 1949-12-14 1952-11-19 Degussa Highly acid-resistant objects
US3667936A (en) * 1969-03-21 1972-06-06 Aurium Research Corp Dental alloy
US3819366A (en) * 1969-03-21 1974-06-25 Aurium Res Corp Dental alloy
US3767391A (en) * 1969-05-19 1973-10-23 Pennwalt Corp Tarnish resistant alloy
DE2139331A1 (de) * 1971-08-06 1973-02-15 Degussa Kupferfreie dental-goldlegierungen

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4255191A (en) * 1979-03-02 1981-03-10 Degussa Aktiengesellschaft Gold-silver alloys with good tarnish resistance for the dental art
US4319877A (en) * 1979-10-10 1982-03-16 Boyajian Benjamin K Palladium-based dental alloy containing indium and tin
US4266973A (en) * 1979-12-14 1981-05-12 The J. M. Ney Company Tarnish-resistant gold color alloy and dental restorations employing same
US4539176A (en) * 1984-05-04 1985-09-03 Pennwalt Corporation Low gold dental alloys
US5453290A (en) * 1990-09-10 1995-09-26 Elephant Edelmetaal B.V. Dental procelain, a method of producing a dental restoration, a dental alloy
US5217685A (en) * 1991-10-03 1993-06-08 The Wilkinson Company Abutment base alloy for jawbone mounted dental implants
US5695714A (en) * 1993-07-23 1997-12-09 Degussa Aktiengesellschaft Gold-palladium alloys for dental materials
US20070026249A1 (en) * 2005-07-29 2007-02-01 Roland Strietzel Veneerable silver alloy for producing ceramic-veneered dental restorations
EP1770179A1 (de) 2005-07-29 2007-04-04 BEGO Bremer Goldschlägerei Wilh. Herbst GmbH & Co. KG Aufbrennfähige Silber-Legierung zur Herstellung keramisch verblendeter Dentalrestaurationen
US20080138842A1 (en) * 2006-12-11 2008-06-12 Hans Boehringer Indirect lateral flow sandwich assay
KR101181491B1 (ko) 2010-06-25 2012-09-11 (주)탑플러스 치과 보철물용 합금 조성물 및 치과 보철물의 제조방법
EP2818567A1 (de) 2013-06-27 2014-12-31 C. Hafner GmbH + Co. KG Weißgold-Legierung, insbesondere zur Verwendung für ein Steinguss-Verfahren
DE102013010700A1 (de) * 2013-06-27 2014-12-31 C. Hafner Gmbh + Co. Kg Weißgold-Legierung, insbesondere zur Verwendung für ein Steinguss-Verfahren
DE102013010700B4 (de) * 2013-06-27 2016-12-08 C. Hafner Gmbh + Co. Kg Weißgold-Legierung, insbesondere zur Verwendung für ein Steinguss-Verfahren

Also Published As

Publication number Publication date
FR2291282B1 (pt) 1977-12-16
JPS5172921A (pt) 1976-06-24
FR2291282A1 (fr) 1976-06-11
BR7507328A (pt) 1976-08-10
DE2453799B2 (de) 1978-11-30
DE2453799A1 (de) 1976-05-26
DE2453799C3 (de) 1979-08-02
CH597353A5 (pt) 1978-03-31

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