US3961940A - Post-treatment of ilmenite ore subjected to selective chlorination treatment - Google Patents

Post-treatment of ilmenite ore subjected to selective chlorination treatment Download PDF

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US3961940A
US3961940A US05/524,340 US52434074A US3961940A US 3961940 A US3961940 A US 3961940A US 52434074 A US52434074 A US 52434074A US 3961940 A US3961940 A US 3961940A
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ore
magnetic
magnetic portion
flotation
process according
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Seitaro Fukushima
Ariyoshi Saito
Fukuzo Kaneko
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Mitsubishi Metal Corp
Mitsubishi Materials Corp
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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G23/00—Compounds of titanium
    • C01G23/04—Oxides; Hydroxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
    • B03D1/00—Flotation
    • B03D1/001—Flotation agents
    • B03D1/004—Organic compounds
    • B03D1/012—Organic compounds containing sulfur
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
    • B03D1/00—Flotation
    • B03D1/001—Flotation agents
    • B03D1/004—Organic compounds
    • B03D1/014—Organic compounds containing phosphorus
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B34/00—Obtaining refractory metals
    • C22B34/10—Obtaining titanium, zirconium or hafnium
    • C22B34/12—Obtaining titanium or titanium compounds from ores or scrap by metallurgical processing; preparation of titanium compounds from other titanium compounds see C01G23/00 - C01G23/08
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
    • B03D2201/00—Specified effects produced by the flotation agents
    • B03D2201/02—Collectors
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
    • B03D2203/00—Specified materials treated by the flotation agents; Specified applications
    • B03D2203/02—Ores
    • B03D2203/04—Non-sulfide ores
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C01P2002/72—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/80—Compositional purity
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00—Technologies related to metal processing
    • Y02P10/20—Recycling

Definitions

  • the present invention relates to a process for post-treating an ilmenite ore subjected to a selective chlorination treatment wherein the ilmenite ore resulting from the chlorination furnace is separated from the unreacted ore (including the unreacted ore and partially reacted ore), solid carbonaceous materials and other impurities contained therein thereby to obtain an artificial rutile with a TiO 2 content of at least 95 % as a final product.
  • titanium oxide common titaniferous iron ores having a wide range of compositions of titanium dioxide (hereinafter referred to as titanium oxide), and ferrous and ferric oxide.
  • a selective chlorination process for ilmenite ore is well known as a process for upgrading the ilmenite wherein the ilmenite ore is mixed with coke or other solid carbonaceous materials to form a mixture which is treated with chlorine gas to preferentially chlorinate the iron oxide contained in the ore, and titanium oxide is concentrated into the residue.
  • the reaction control of this selective chlorination process depends on the preferential reaction between the iron oxide contained in the ilmenite ore and chlorine.
  • the selective chlorination merely includes utilization of the relative difference in reactivity of chlorine with the iron oxide and the titanium oxide. As the chlorination reaction proceeds and the residual iron oxide reaches a certain limit value, chlorine begins to react with the titanium oxide, while the unreacted iron oxide remains intact.
  • the chlorination furnace is operated in such a manner that the unreacted iron oxide exceeding the limit level is allowed to remain thereby to prevent the formation of titanium tetrachloride. Therefore, the ore discharging from the chlorination furnace contains the unreacted ore corresponding to the unreacted iron oxide or the partially reacted ore, and excessive solid carbonaceous materials which were not used for the chlorination reaction is discharged together therewith from the furnace.
  • the mixed ore is too low in titanium value to use as a product. That is, in order to provide an artificial rutile having a TiO 2 content of at least 95%, separation of the unreacted ore and excessive solid carbonaceous material from the substantially completed reacted ore must be carried out.
  • Japanese Laid-Open Publication No. 2657/71 a process for post-treating ilmenite ore removed from a chlorination furnace is disclosed which comprises carrying out the separation of the unreacted ore by magnetic separation.
  • Japanese Laid-Open Publication No. 4319/73 discloses a treating process including a combination of a magnetic separation process and a tabling process for separating coke and silica.
  • Japanese Laid-Open Publication No. 33906/72 proposes separation of silica and alumina by subjecting the titanium concentrate resulting from the chlorination furnace to an electrostatic separator and separation of excessive coke by floatation or an electrostatic separation.
  • the coke has a wide range of a particle size due to its consumption attendant on the chlorination reaction and a portion thereof always exhibits the same physical behavior as the ore when being subjected to a tabling or electrostatic separation, a complete separation thereof is impossible.
  • the separation of coke by flotation ordinarily involves the use of a collector of hydrocarbon type such as kerosene. Since the coke subjected to the chlorination reaction has adsorbed various materials in the course of the treatment and the quantity of the materials absorbed varies with the reaction conditions, it is necessary to determine each flotation condition according to the influence of the adsorbing action of the coke, which is not necessarily easy, and the separation is thus unsatisfactory.
  • the process of the present invention is characterized in that an ilmenite ore which has undergone a selective chlorination treatment and been taken from the chlorination furnace (hereinafter sometimes referred to as "chlorinated ilmenite ore" or “chlorinated ore”) is subjected to a magnetic separation in a high magnetic field.
  • chlorinated ilmenite ore or "chlorinated ore”
  • an excessive solid carbonaceous material concentrated into the non-magnetic portion resulting from the magnetic separation of the ilmenite ore is subjected to flotation with the use of a frothing agent and a collector for a sulfide ore, and gangue materials partially liberated from the ilmenite in the selective chlorination treatment is washed with water or suspended in water in the flotation to separate the carbonaceous material and the gangue respectively.
  • the present invention provides a process for separating by the magnetic separation the unreacted ore as a magnetic portion from the substantially completely created ore, both constituting the chlorinated ore which has undergone the selective chlorination treatment, by utilizing the difference in magnetic susceptability between hematite or pseudobrookite of paramagnetism remaining in the unreacted ore and rutile constituting most part of the substantially completely reacted ore in a high magnetic field.
  • the non-magnetic portion consisting primarily of the completely reacted ore resulting from the magnetic separation is subjected to flotation with the use of a collector for sulfide ore, for example, zanthates or Aerofloat (commercial name, dithiophosphate type), and an excessive solid carbonaceous material contained in the non-magnetic portion is floated to separate it.
  • a collector for sulfide ore for example, zanthates or Aerofloat (commercial name, dithiophosphate type)
  • Aerofloat commercial name, dithiophosphate type
  • the magnetic field is preferably not less than 15,000 gauss and particularly preferably not less than 20,000 gauss.
  • FIGS. 1-5) show X-ray diffraction patterns respectively, of the original ilmenite ore (1), its oxidizing roasted ore (2), and the portions resulting from the magnetic separation after the chlorination process, that is, the magnetic portion (3), the middling portion (4) and the non-magnetic portion (5).
  • the raw ore is passed through an oxidizing atmosphere at a temperature of 900° to 950°C to oxidize the ferrous oxide contained in the ore to ferric oxide, after which the oxidized ore is introduced into a fluidized-bed type chlorination furnace together with a solid carbonaceous material, such as calcined petroleum coke (hereinafter referred to as coke), in a quantity of 6 to 8% by weight based on the ore.
  • coke calcined petroleum coke
  • the ore which has undergone the selective chlorination treatment is continuously removed through a side wall of the furnace and supplied into a water cooled hopper wherein it is rapidly cooled.
  • the formation of titanium tetrachloride may be suppressed by so adjusting the quantity of the iron remaining in the recovered ore that it is in the range of 2 to 3 % in terms of Fe.
  • the ore in the hopper is weighted and supplied to a dressing plant wherein it is passed through a magnetic separator having a magnetic field of at least 15,000 gauss and particularly preferably at least 20,000 gauss to separate the unreacted ore.
  • the slight difference in magnetic susceptability in a high magnetic field between the paramagnetic material of hematite or pseudobrookite remaining in the unreacted ore and the completely reacted ore represented by rutile is utilized.
  • the unreacted ore having a high content of iron value is freely dropped through the magnetic separator, the passage of the unreacted ore is distorted in the direction of a magnetic pole, while the reacted ore falls vertically, so that they are separated from each other. It has been verified by X-ray diffraction analysis that the iron remaining in the unreacted ore separated as the magnetic material corresponds to hematite or pseudobrookite. This hematite or pseudobrookite has been present per se in the original ore or produced in the oxidizing roasting for pre-treating the raw ore.
  • the ilmenite is separated into a magnetic portion consisting mainly of the unreacted ore and a non-magnetic portion consisting mainly of the reacted ore by the magnetic separation.
  • the magnetic portion is returned directly to the chlorination furnace for retreatment.
  • the non-magnetic portion contains, in addition to the reacted ore, excessive coke and ash due to the coke consumed in the chlorination reaction or the gangue materials contained in the original ore in a concentrated state.
  • a weak magnetic portion (middling) which is intermediate between the magnetic portion and the non-magnetic portion is separated with a certain range of distribution.
  • the middling portion is not removed in a single form but divided into the magnetic and non-magnetic portions by a separating plate positioned at a suitable position such that the middling portion is delivered to the non-magnetic portion at as high a ratio as possible within the permitted limit depending upon the desired content of TiO 2 in the artificial rutile as a product.
  • the proportion of the magnetic portion to be returned to the chlorination furnace is in the range of from 10 to 25 % of the ore to be supplied to the furnace and it may sometimes exceed this limit depending on the operational conditions of the chlorination furnace.
  • the coke transferred into the non-magnetic portion need not be separated in some cases, the coke is usually separated in order to up-grade the TiO 2 content, and the separated coke is recovered and, like the magnetic portion, is returned to the chlorination furnace for re-use. That is, when the non-magnetic portion is subjected to flotation with the use of a frothing agent such as methylisobutylcarbinol and a collector for sulfide ore such as xanthates or Aerofloat, the coke contained in the non-magnetic portion is floated and may be completely separated. Although the reason why such a collector compound generally used as a collector for sulfide ore in flotation provided the above-mentioned effect is not clear, it is conceivable that a small amount of sulfur compounds contained in the coke contributes to this effect.
  • xanthates representable by the general formula ##EQU1## or dithiophosphates representable by the general formula ##EQU2## ; wherein R is an alkyl group containing 2 to 5 carbon atoms and M is selected from sodium, potassium and allyl groups.
  • dithiophosphates is sodium diethyldithiophosphate known under the commercial name of ⁇ Aerofloat ⁇ .
  • the collector above-mentioned is used in a quantity per ton of the non-magnetic portion of from 10 to 500g, preferably from 100 to 200g.
  • the frothing agent to be used in the present invention is not specifically limited and, for example, the following compounds can be used without problem singly or in combination: methylisobutylcarbinol, pine oil and ethylene glycol.
  • the frothing agent is used in a quantity per ton of the non-magnetic portion of from 10 to 500g, preferably from 50 to 150g.
  • the artificial rutile is recovered as the flotation tailing, while the finely divided coke adhering to the surface of the ore or the ash separated from the coke and the gangue materials such as silica and alumina present as the impurities of the original ore are liberated as finely divided particles under the free state thereof from the ore by the abrasive action between the ores during the flotation operation.
  • the coke floats up and the gangue is suspended in water and separated as a slime.
  • the slime is filtered, and the filtrate, water, is repeatedly used, while the tailing, artificial rutile, is dried to give a product with a TiO 2 content of at least 95%.
  • the impurities including the gangue such as silica and alumina can be suspended in water and separated as a slime.
  • a better separation of the coke is effected by subjecting the flotation tailing to a scavenging operation.
  • a scavenging solution which contains 5 to 100g, preferably 20 to 50g, per ton of non-magnetic portion of an alkylamine derivative selected from alkylamine acetates and alkylamine hydrochlorides, each alkyl group containing 8 to 18 carbon atoms, and/or 10 to 500g, preferably 50 to 200g, per ton of non-magnetic portion of kerosene.
  • the use of an excess alkylamine derivative is not desirable since it is liable to cause a titanium value to float along with coke.
  • This scavenging operation is conducted in a vessel, preferably in a type of floating machine.
  • the separated magnetic portion can be returned directly to the chlorination furnace without being subjected to further pre-oxidizing roasting of the ore.
  • a portion of the gangue materials such as silica, alumina, and the like contained in the original ore is separated, while the same phenomenon is observed with chromium oxide considered to be present in combination with the iron oxide in the original ore. That is, when the iron oxide combined with the chromium oxide is removed, the chromium oxide is isolated in a single form and removed in the flotation process.
  • the present invention provides a process for post-treating an ilmenite subjected to a selective chlorination treatment wherein the unreacted ore, coke, coke ash, or the gangue materials partially liberated from the original ore contained in the ilmenite which has undergone the selective chlorination treatment are separated by a magnetic separation, flotation, or a combination of a water washing process and flotation to obtain an artificial rutile with a TiO 2 content of at least 95 % as a final product.
  • the process of the present invention is considered to have high utility for industrial purposes.
  • the accompanying drawings show X-ray diffraction patterns relating to the respective sample of (1) an original ilmenite ore, (2) an oxidizing-roasted ore, (3) a magnetic portion, (4) a middling portion and (5) a non-magnetic portion, the last three portions being obtained by processing the selective chlorination treated ore in the magnetic separator.
  • the samples are illustrated in FIGS. 1 to 5 of the drawings, respectively.
  • the X-ray diffraction patterns indicate that the remaining iron in the unreacted ore separated from the ilmenite which has undergone the selective chlorination treatment consists mainly of pseudobrookite.
  • the non-magnetic portion separated in the above magnetic separation process was introduced into a conditioning bath, and potassium amyl zanthate and methylisobutylcarbinol were added in quantities of 200 g/ton and 100 g/ton of the non-magnetic portion respectively, thereto.
  • the resulting mixture at a pulp concentration of 10 % was subjected to flotation by using an Agitayer type floating machine.
  • coke corresponding to about 3 % of the supplied ore was floated and recovered, and as a tailing, an artificial rutile with a TiO 2 content of 95 % was obtained in a yield of 82 % and in a net yield of TiO 2 of 89 %.
  • results of analysis of a slime separated from the tailing suspended in water are shown in Table 2.
  • Example 2 The same ilmenite ore removed from a chlorination furnace used in Example 1 was subjected to magnetic separation under the same conditions as in Example 1. 100kg of the non-magnetic portion separated by the above magnetic separation was mixed with potassium amyl xanthate and methylisobutylcarbinol in quantities of respectively 150g and 100g, per ton of the non-magnetic portion, and the resulting mixture adjusted at a pulp concentration of 10% was subjected to flotation by using an Agitayer type floating machine.
  • the tailing from the flotation was further subjected to a scavenging operation with the use of lourylamine hydrochloric acid salt and kerosene in quantities of 50g and 100g respectively, per ton of the non-magnetic portion, at a pulp concentration of 10% in another Agitayer type floating machine.

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US05/524,340 1973-11-20 1974-11-15 Post-treatment of ilmenite ore subjected to selective chlorination treatment Expired - Lifetime US3961940A (en)

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JP13046873A JPS5080298A (enrdf_load_html_response) 1973-11-20 1973-11-20
JA48-130468 1973-11-20

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Cited By (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4174274A (en) * 1978-01-12 1979-11-13 Uop Inc. Separation of rutile from ilmenite
US5348696A (en) * 1987-11-06 1994-09-20 Carbotek Inc. Integrated lunar materials manufacturing process
US6375923B1 (en) 1999-06-24 2002-04-23 Altair Nanomaterials Inc. Processing titaniferous ore to titanium dioxide pigment
US6440383B1 (en) 1999-06-24 2002-08-27 Altair Nanomaterials Inc. Processing aqueous titanium chloride solutions to ultrafine titanium dioxide
US6548039B1 (en) 1999-06-24 2003-04-15 Altair Nanomaterials Inc. Processing aqueous titanium solutions to titanium dioxide pigment
US20060127486A1 (en) * 2004-07-13 2006-06-15 Moerck Rudi E Ceramic structures for prevention of drug diversion
US20060292049A1 (en) * 2003-09-04 2006-12-28 Tetsuya Nagasaka Process for producing rutile
US20080008843A1 (en) * 2006-03-02 2008-01-10 Fred Ratel Method for Production of Metal Oxide Coatings
US20080020175A1 (en) * 2006-03-02 2008-01-24 Fred Ratel Nanostructured Indium-Doped Iron Oxide
US20080038482A1 (en) * 2006-03-02 2008-02-14 Fred Ratel Method for Low Temperature Production of Nano-Structured Iron Oxide Coatings
US20080045410A1 (en) * 2005-08-23 2008-02-21 Jan Prochazka HIGHLY PHOTOCATALYTIC PHOSPHORUS-DOPED ANATASE-TiO2 COMPOSITION AND RELATED MANUFACTURING METHODS
US20080254258A1 (en) * 2007-04-12 2008-10-16 Altairnano, Inc. Teflon® replacements and related production methods
CN100430127C (zh) * 2006-07-10 2008-11-05 东北大学 一种利用强磁场改性高钛渣制备光催化材料的方法
US20090148364A1 (en) * 2007-12-05 2009-06-11 Heiko Frahm Method for Increasing the Yield When Chlorinating Titaniferous Raw Materials
EP1666419A4 (en) * 2003-09-24 2009-07-15 Tohoku Techno Arch Co Ltd PROCESS FOR PRODUCING RUTIL
CN111495606A (zh) * 2020-05-26 2020-08-07 河南天鸿选矿科技有限公司 一种钛铁矿浮选捕收剂
CN115351053A (zh) * 2022-09-23 2022-11-18 攀钢集团攀枝花钢铁研究院有限公司 一种氯化尾渣的处理方法

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2954278A (en) * 1956-10-31 1960-09-27 Gaskin Arthur John Production of rutile from ilmenite and related ores
US2982613A (en) * 1959-02-16 1961-05-02 Nat Lead Co Continuous titaniferous iron material digestion process utilizing concentrated sulfuric acid, a foaming agent and water
US3699206A (en) * 1970-03-23 1972-10-17 Dunn Inc Wendell E Process for beneficiation of titaniferous ores
US3784670A (en) * 1969-09-12 1974-01-08 Ishihara Mining & Chemical Co Titanium dixide concentrate and its manufacturing process

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5225366B2 (enrdf_load_html_response) * 1971-11-12 1977-07-07
JPS49123918A (enrdf_load_html_response) * 1973-03-16 1974-11-27

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2954278A (en) * 1956-10-31 1960-09-27 Gaskin Arthur John Production of rutile from ilmenite and related ores
US2982613A (en) * 1959-02-16 1961-05-02 Nat Lead Co Continuous titaniferous iron material digestion process utilizing concentrated sulfuric acid, a foaming agent and water
US3784670A (en) * 1969-09-12 1974-01-08 Ishihara Mining & Chemical Co Titanium dixide concentrate and its manufacturing process
US3699206A (en) * 1970-03-23 1972-10-17 Dunn Inc Wendell E Process for beneficiation of titaniferous ores

Cited By (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4174274A (en) * 1978-01-12 1979-11-13 Uop Inc. Separation of rutile from ilmenite
US5348696A (en) * 1987-11-06 1994-09-20 Carbotek Inc. Integrated lunar materials manufacturing process
US6375923B1 (en) 1999-06-24 2002-04-23 Altair Nanomaterials Inc. Processing titaniferous ore to titanium dioxide pigment
US6440383B1 (en) 1999-06-24 2002-08-27 Altair Nanomaterials Inc. Processing aqueous titanium chloride solutions to ultrafine titanium dioxide
US6548039B1 (en) 1999-06-24 2003-04-15 Altair Nanomaterials Inc. Processing aqueous titanium solutions to titanium dioxide pigment
US20060292049A1 (en) * 2003-09-04 2006-12-28 Tetsuya Nagasaka Process for producing rutile
EP1666419A4 (en) * 2003-09-24 2009-07-15 Tohoku Techno Arch Co Ltd PROCESS FOR PRODUCING RUTIL
US20060127486A1 (en) * 2004-07-13 2006-06-15 Moerck Rudi E Ceramic structures for prevention of drug diversion
US20080045410A1 (en) * 2005-08-23 2008-02-21 Jan Prochazka HIGHLY PHOTOCATALYTIC PHOSPHORUS-DOPED ANATASE-TiO2 COMPOSITION AND RELATED MANUFACTURING METHODS
US20080020175A1 (en) * 2006-03-02 2008-01-24 Fred Ratel Nanostructured Indium-Doped Iron Oxide
US20080044638A1 (en) * 2006-03-02 2008-02-21 Fred Ratel Nanostructured Metal Oxides
US20080038482A1 (en) * 2006-03-02 2008-02-14 Fred Ratel Method for Low Temperature Production of Nano-Structured Iron Oxide Coatings
US20080008843A1 (en) * 2006-03-02 2008-01-10 Fred Ratel Method for Production of Metal Oxide Coatings
CN100430127C (zh) * 2006-07-10 2008-11-05 东北大学 一种利用强磁场改性高钛渣制备光催化材料的方法
US20080254258A1 (en) * 2007-04-12 2008-10-16 Altairnano, Inc. Teflon® replacements and related production methods
US20090148364A1 (en) * 2007-12-05 2009-06-11 Heiko Frahm Method for Increasing the Yield When Chlorinating Titaniferous Raw Materials
CN111495606A (zh) * 2020-05-26 2020-08-07 河南天鸿选矿科技有限公司 一种钛铁矿浮选捕收剂
CN115351053A (zh) * 2022-09-23 2022-11-18 攀钢集团攀枝花钢铁研究院有限公司 一种氯化尾渣的处理方法

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