US393753A - Joseph r - Google Patents
Joseph r Download PDFInfo
- Publication number
- US393753A US393753A US393753DA US393753A US 393753 A US393753 A US 393753A US 393753D A US393753D A US 393753DA US 393753 A US393753 A US 393753A
- Authority
- US
- United States
- Prior art keywords
- sheet
- pyroxyline
- sheets
- celluloid
- joseph
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000002904 solvent Substances 0.000 description 22
- FJWGYAHXMCUOOM-QHOUIDNNSA-N [(2S,3R,4S,5R,6R)-2-[(2R,3R,4S,5R,6S)-4,5-dinitrooxy-2-(nitrooxymethyl)-6-[(2R,3R,4S,5R,6S)-4,5,6-trinitrooxy-2-(nitrooxymethyl)oxan-3-yl]oxyoxan-3-yl]oxy-3,5-dinitrooxy-6-(nitrooxymethyl)oxan-4-yl] nitrate Chemical class O([C@@H]1O[C@@H]([C@H]([C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O)O[C@H]1[C@@H]([C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@@H](CO[N+]([O-])=O)O1)O[N+]([O-])=O)CO[N+](=O)[O-])[C@@H]1[C@@H](CO[N+]([O-])=O)O[C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O FJWGYAHXMCUOOM-QHOUIDNNSA-N 0.000 description 18
- 238000000034 method Methods 0.000 description 18
- 238000004519 manufacturing process Methods 0.000 description 16
- 229920001220 nitrocellulos Polymers 0.000 description 16
- 229920002160 Celluloid Polymers 0.000 description 14
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 8
- 150000001875 compounds Chemical class 0.000 description 8
- 239000000463 material Substances 0.000 description 8
- 125000004429 atoms Chemical group 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 230000001476 alcoholic Effects 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 235000011194 food seasoning agent Nutrition 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000012466 permeate Substances 0.000 description 2
- -1 pyroxyline compound Chemical class 0.000 description 2
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K71/00—Manufacture or treatment specially adapted for the organic devices covered by this subclass
- H10K71/10—Deposition of organic active material
- H10K71/12—Deposition of organic active material using liquid deposition, e.g. spin coating
- H10K71/13—Deposition of organic active material using liquid deposition, e.g. spin coating using printing techniques, e.g. ink-jet printing or screen printing
- H10K71/135—Deposition of organic active material using liquid deposition, e.g. spin coating using printing techniques, e.g. ink-jet printing or screen printing using ink-jet printing
Definitions
- My invention has for its object to provide an improved process for the manufacture of E collars, culfs, shirt-fronts, playingcards, checks, and various articles from pyroxyline compounds, said articles being produced by K printing thereon any desired pattern in one or more colors.
- the celluloid being in a green or unseasoned condition it contains sufficient of the alcoholic solvents employed in its manufacture to act as a mordant upon the aniline and absorb the color imprinted upon the sheet.
- the atoms of alcohol being in the body of the sheet, greedily absorb the atoms of the coloring-matter, which sink in from the surface and permeate the body of the sheet, the particles of coloringnlatter taking the place of the solvents as the latter evaporate from the sheet. This method therefore insures the permeation of the sheet by the pattern to such a depth as to render the latter practically indelible.
- the printed sheets are then seasoned by any known methodas, for example, by suspending them in a warm room in a current of air of proper temperature.
- the printed and seasoned sheet may then be subjected to heat and pressure to incorporate any remaining portion of the color or. ink which from excess remains on the surface of the sheet of celluloid.
- An imitation of the fiber of linen or muslin may also be produced on the printed sheets by pressure between fiat plates under heat while lying between sheets of said fabrics.
- IVhat I claim is l.
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Nanotechnology (AREA)
- Physics & Mathematics (AREA)
- Composite Materials (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Materials Engineering (AREA)
- Crystallography & Structural Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Coloring (AREA)
- Treatment Of Fiber Materials (AREA)
Description
UNITED STATES PATENT OFFICE.
JOSEPH R. FRANCE, 0F NEIV YORK, N. Y.
PROCESS OF MANUFACTURING ARTICLES FROM COMPOUNDS OF PYROXYLINE.
SPECIFICATION forming part of Letters Patent No. 393,753, dated December 4, 1888.
Application filed March 3, 1888. Serial No. 266,043. (No model.)
To all whom, it may concern:
Be it known that I, JOSEPH R. FRANCE, a I, citizen of the United States, residing at New York, in the county of New York and State of New York, have invented new and useful E Improvements in Process of Manufacturing Articles from Compounds of Pyroxylinc, of i which the following is a specification.
My invention has for its object to provide an improved process for the manufacture of E collars, culfs, shirt-fronts, playingcards, checks, and various articles from pyroxyline compounds, said articles being produced by K printing thereon any desired pattern in one or more colors.
It is the purpose of my invention to provide a process of manufacture whereby the ornamental patterns imprinted upon the sheet of pyroxyline compound shall be practically indelible; and the invention consists in certain improvements upon the process contained in an application filed by me September 8, 1887, Serial No, flail-ll.
I-Ieretofore in the manufacture of articles of the class described it has been customary to print upon a sheet of celluloid or other compound of pyroxyline by applying to the surface thereof an aniline ink dissolved in some material which is a solvent of celluloid. In this process, however, the printing is done upon sheets which have been as thoroughly seasoned as practicable, and from which the solvents employed in the manufacture of the celluloid have been practically eliminated. The result has been that the solvents of pyroxyline by which the ink is held in. solution. can act upon the surface of the celluloid sheet upon which they are laid, and before the solvents can effect a substantial result they are evaporated, producing only a surface eifect, which soon wears off. To avoid this objection and to print an indelible pattern upon the sheet of celluloid or other compound of pyroxyline, I take these sheets when they leave the sheeting-machine, or as soon thereafter as practicable-at a time when the surfaces of said sheets have been exposed to but little evaporation. In this condition. they contain a large proportion of the alcohols 0r solvents used in their manufacture, and may therefore be properly termed green or un- 5 seasoned. Upon these unseasoned sheets I print any desired pattern in any usual manner, employing for this purpose an aniline l ink or color dissolved in any material which is also a solvent of pyroxyline. The celluloid being in a green or unseasoned condition it contains sufficient of the alcoholic solvents employed in its manufacture to act as a mordant upon the aniline and absorb the color imprinted upon the sheet. The atoms of alcohol, being in the body of the sheet, greedily absorb the atoms of the coloring-matter, which sink in from the surface and permeate the body of the sheet, the particles of coloringnlatter taking the place of the solvents as the latter evaporate from the sheet. This method therefore insures the permeation of the sheet by the pattern to such a depth as to render the latter practically indelible. The printed sheets are then seasoned by any known methodas, for example, by suspending them in a warm room in a current of air of proper temperature. The printed and seasoned sheet may then be subjected to heat and pressure to incorporate any remaining portion of the color or. ink which from excess remains on the surface of the sheet of celluloid. An imitation of the fiber of linen or muslin may also be produced on the printed sheets by pressure between fiat plates under heat while lying between sheets of said fabrics.
IVhat I claim is l. The process of manufacturing articles from pyroxyline compounds, said process con sisting in printing upon a sheet of said material while in a green or unseasoned condition with an ink or color dissolved in a substance which is also a solvent of pyroxyline, substantially as described.
The process of manufacturii'ig articles from compounds of pyroxyline, said process consisting in printing the desired pattern upon said material as the sheets come from the sheeting mechanism or as soon thereafter as practicable before the solvents contained have evaporated, the ink employed being an aniline color dissolved in some substance which is also a solvent of pyroxyline and then seasoning the printed sheets, substantially as described.
In testimony whereof I am my signature in presence of two witnesses.
JOSEPH R. FRANCE.
\Vitnesses:
GEORGE E. HAND, WM. H. MEEKs.
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US393753A true US393753A (en) | 1888-12-04 |
Family
ID=2462722
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US393753D Expired - Lifetime US393753A (en) | Joseph r |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US393753A (en) |
-
0
- US US393753D patent/US393753A/en not_active Expired - Lifetime
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