US3929680A - Liquid detergent composition - Google Patents
Liquid detergent composition Download PDFInfo
- Publication number
- US3929680A US3929680A US352053A US35205373A US3929680A US 3929680 A US3929680 A US 3929680A US 352053 A US352053 A US 352053A US 35205373 A US35205373 A US 35205373A US 3929680 A US3929680 A US 3929680A
- Authority
- US
- United States
- Prior art keywords
- benzene
- detergent composition
- liquid detergent
- alkyl
- solubilizing agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/18—Hydrocarbons
Definitions
- This invention relates to a liquid detergent composition. More particularly, this invention relates to a liquid detergent composition having excellent low temperature stability and containing an anionic surfactant and- /or a non-ionic surfactant, and solubilizing agents.
- liquid detergent compositions comprise, for instance, an alkyl benzene sulfonate and, incorporated therein, one or more solubilizing agents, for instance, lower alcohols such as ethanol, benzene sulfonates, lower alkyl benzene sulfonates such as p-toluene sulfonates, glycols such as propylene glycol, acetyl benzene sulfonates, acetamides, pyridine carboxylic acid amides, benzoates and urea.
- these detergent compositions are inevitably defective in that white turbidity or phase separation is brought about at low temperatures.
- the object of this invention is to provide a liquid detergent composition which possesses excellent low temperature stability
- the gist of this invention resides in a liquid detergent composition comprising as active ingredients at least one member selected from anionic surfactants and non-ionic surfactants and at least two solubilizing agents, characterized in that as one solubilizing agent there is used about 3 to about 30% by weight, based on the amount of the above surfactants, of an aliphatic saturated hydrocarbon having 6 to 14 carbon atoms on the average or an alkyl benzene containing an alkyl group having 6 to 14 carbon atoms on the average.
- the aliphatic saturated hydrocarbon used as one embodiment of the indispensable solubilizing agent in the composition of this invention contains 6 to 14 carbon atoms on the average, and it may be of either the normal form or the iso-form or a mixture thereof.
- kerosene, fluid paraffin and petroleum fractions containing as the main component such saturated hydrocarbon as mentioned above can be used.
- the alkyl benzene used as the other embodiment of the indispensable solubilizing agent in the composition of this invention contains a straight or branched alkyl group having 6 to 14 carbon atoms on the average.
- alkyl benzene hexyl benzene, octyl benzene, nonyl benzene, dodecyl benzene and tetradecyl benzene.
- solubilizing agents can be used as the other solubilizing agent in the composition of this invention.
- lower alcohols such as methanol, ethanol and isopropyl alcohol
- glycols such as ethylene glycol and propylene glycol
- acetamides such as ethylene glycol and propylene glycol
- acetamides such as ethylene glycol and propylene glycol
- acetamides such as ethylene glycol and propylene glycol
- aromatic carboxylic acid salts such as benzoates and salicylates
- urea The salts included in this group, i.e. the various sulfonates and aromatic carboxylic acid salts, are usually alkali metal salts (sodium or potassium), ammoni
- the anionic surfactant that the composition of this invention can contain, there can be mentioned, for instance, straight or branched alkyl benzene sulfonates, alkyl sulfuric acids ester salts, alkane sulfonates, a-olefin sulfonates, salts of polyoxyethylene alkyl or alkylphenyl ether sulfuric acid esters, and ether carboxylates expressed by the general formula R-O(CH C- H O),,R'COOM in which R is an alkyl or alkenyl group having 8 to 22 carbon atoms or an alkyl phenyl group in which the alkyl group has 6 to 17 carbon atoms, R is an alkylene group having 1 to 4 carbon atoms, M stands for a water-soluble cation, and n is a number from 1 to 30.
- the anionic surfactant is an alkali metal salt such as sodium or potassium, ammonium salt or an alkanolamine salt such as mono-,
- non-ionic surfactant there may be exemplified polyoxyethylene alkyl ethers in which the alkyl group has 8 to 18 carbon atoms and 4 to 14 oxyethylene units and polyoxyethylene alkyl phenyl ethers in which the alkyl group has from 8 to 12 carbon atoms and 6 to 12 oxyethylene units.
- hydrocarbon aliphatic saturated hydrocarbon or alkyl benzene as defined above
- the hydrocarbon solubilizing agent to be used as the indispensable solubilizing agent in the composition of this invention is incorporated in an amount of about 3 to about 30% (by weight; the same will apply hereinafter) based on the amount of the surfactant(s), and the weight ratio of said hydrocarbon solubilizing agent to the other solubilizing agent should be preferably from 1/40 to 2/1.
- the composition of this invention is useful as a detergent for foodstuffs and table wares, a shampoo and a heavy or light duty liquid detergent for clothes.
- n-dodecane is effective for improving the low tempera- EXAMPLE 5 ture stability. Especially when sodium xylene sulfonate, urea and triethanol amine are co-present, the effect of i Comparison This invention n-dodecane is remarkable.
- EXAMPLE 6 Comparison This invention Sodium straight-dodecyl t J, benzene sulfonate 15% 1 5% Sodium nonyl phenyl polyethoxy(3) acetate 5% 5% Sodium xylene sulfonate 14% 14% Ethanol 2% 2% Kerosene 2% Turbidity-separation temperature about 2C below C
- EXAMPLE 7 Comparison This invention Sodium nonyl phenyl polyethoxy(3) acetate 20% 20% Urea 5% 5% n-Dodecane 0% 1% Turbidity-separation temperature about C below 12C
- EXAMPLE 8 Comparison This invention Sodium straight-dodecyl benzene sulfonate 20% Ethanol 5% 5% Dodecyl benzene 0% 2.5%
- Tester Terg-O-Tometer Deterent concentration: 0.20% (in city water) Bath ratio: 6 contaminated cloths per 500 cc Washing temperature: 30C
- a liquid detergent composition having improved low temperature stability consisting essentially of an aqueous solution of at least one surfactant selected from the group consisting of anionic surfactants and non-ionic surfactants, the amount of said surfactant being an amount effective for making said detergent composition suitable for washing foodstuffs, tableware or clothes, or as a shampoo; a first solubilizing agent selected from the group consisting of alkanols having one to 3 carbon atoms; benzene sulfonates, p-toluene sulfonates, xylene sulfonates, acetyl benzene sulfonates, glycols, acetamides, pyridine dicarboxylic acid amides, benzoates, salicylates and urea; and a second solubilizing agent selected from the group consisting of hexyl benzene, octyl benzene, nonyl benzene, dodecyl benz
- a liquid detergentcomposition according to claim I in which said non-ionic surfactant is selected from polyoxyethylene alkyl ethers and polyoxyethylene alkyl phenyl ethers.
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP47039886A JPS5139250B2 (nl) | 1972-04-20 | 1972-04-20 |
Publications (1)
Publication Number | Publication Date |
---|---|
US3929680A true US3929680A (en) | 1975-12-30 |
Family
ID=12565446
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US352053A Expired - Lifetime US3929680A (en) | 1972-04-20 | 1973-04-17 | Liquid detergent composition |
Country Status (5)
Country | Link |
---|---|
US (1) | US3929680A (nl) |
JP (1) | JPS5139250B2 (nl) |
DE (1) | DE2319892A1 (nl) |
GB (1) | GB1425749A (nl) |
NL (1) | NL7305502A (nl) |
Cited By (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4180472A (en) * | 1977-10-03 | 1979-12-25 | The Procter & Gamble Company | Detergent compositions for effective oily soil removal |
DE2950382A1 (de) * | 1978-12-26 | 1980-07-17 | Lion Fat Oil Co Ltd | Homogene waessrige alpha -olefinsulfonatmasse und verfahren zu ihrer herstellung |
US4242218A (en) * | 1976-11-08 | 1980-12-30 | Allied Chemical Corporation | Phenol-free photoresist stripper |
US4302348A (en) * | 1980-09-23 | 1981-11-24 | The Drackett Company | Hard surface cleaning compositions |
US4362638A (en) * | 1980-07-28 | 1982-12-07 | S. C. Johnson & Son, Inc. | Gelled laundry pre-spotter |
US4390466A (en) * | 1981-04-30 | 1983-06-28 | Harold Weinberger | Heavy duty liquid detergent |
US4476043A (en) * | 1982-05-13 | 1984-10-09 | Henkel Corporation | Surfactant product |
US4476044A (en) * | 1982-05-13 | 1984-10-09 | Henkel Corporation | Surfactant product |
US4477372A (en) * | 1982-05-13 | 1984-10-16 | Henkel Corporation | Anionic nonionic surfactant mixture |
US4493370A (en) * | 1983-01-27 | 1985-01-15 | Phillips Petroleum Company | Urea as a cosurfactant in enhanced oil recovery processes |
US4528144A (en) * | 1984-02-27 | 1985-07-09 | Lever Brothers Company | Terpene sulfonate hydrotropes |
US4530801A (en) * | 1984-02-27 | 1985-07-23 | Lever Brothers Company | Nopol derived sulfonates |
US4576738A (en) * | 1984-12-21 | 1986-03-18 | Colgate-Palmolive Company | Hard surface cleaning compositions containing pianane |
US4606851A (en) * | 1984-02-27 | 1986-08-19 | Lever Brothers Company | Method for improving water solubility of surfactants using terpene sulfonate hydrotropes |
US4623483A (en) * | 1984-02-27 | 1986-11-18 | Lever Brothers Company | Method for improving water solubility of surfactants using Nopol derived sulfonates |
US4734215A (en) * | 1985-05-13 | 1988-03-29 | Shell Oil Company | Cleaning composition containing hydrocarbon mixtures |
US4983317A (en) * | 1984-06-08 | 1991-01-08 | The Drackett Company | All purpose cleaner concentrate composition |
EP0857778A2 (en) * | 1997-01-10 | 1998-08-12 | Product Source International, Inc. | Cleaning formulation |
US5863878A (en) * | 1997-08-05 | 1999-01-26 | Church & Dwight Co., Inc. | Clear, homogeneous and temperature-stable liquid laundry detergent product containing blend of anionic, nonionic and amphoteric surfactants |
US6475246B1 (en) | 2000-05-22 | 2002-11-05 | Pariser Industries | Dry cleaning additive, bath, and method |
US20040242448A1 (en) * | 2003-05-27 | 2004-12-02 | Unilever Home & Personal Care Usa, Division Of Conopco, Inc. | Effervescent cleaning composition |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS53127752U (nl) * | 1977-03-17 | 1978-10-11 | ||
JPS566068A (en) * | 1980-04-08 | 1981-01-22 | Yamaha Motor Co Ltd | Controlling device for ignition timing of engine |
JPS5820379U (ja) * | 1981-07-31 | 1983-02-08 | 日産自動車株式会社 | 内燃機関のノツキング防止装置 |
JPS58158168U (ja) * | 1982-04-16 | 1983-10-21 | 日産自動車株式会社 | 火花点火機関 |
JPS61112896A (ja) * | 1985-11-11 | 1986-05-30 | 臼井国際産業株式会社 | 断熱保温細径金属管の製造方法 |
MY101656A (en) * | 1986-09-02 | 1991-12-31 | Colgate Palmolive Co | Laundry pre-spotter composition providing improved oily soil removal. |
JP2700267B2 (ja) * | 1989-02-17 | 1998-01-19 | ミヨシ油脂株式会社 | 液体洗浄剤組成物 |
IT1240734B (it) * | 1990-04-02 | 1993-12-17 | Syremont Spa | Procedimento per la pulitura di matrici porose idrofile |
CA2057442C (en) * | 1990-12-13 | 2001-10-23 | Anthony D. Gough | Hair styling composition |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2901433A (en) * | 1953-07-17 | 1959-08-25 | Pennsalt Chemicals Corp | Cleaning composition |
US3533955A (en) * | 1965-06-15 | 1970-10-13 | Lever Brothers Ltd | Two-phase liquid detergent compositions |
US3658985A (en) * | 1969-07-28 | 1972-04-25 | Colgate Palmolive Co | Oil and fluorescent dye containing luster imparting liquid shampoo |
-
1972
- 1972-04-20 JP JP47039886A patent/JPS5139250B2/ja not_active Expired
-
1973
- 1973-04-17 US US352053A patent/US3929680A/en not_active Expired - Lifetime
- 1973-04-18 NL NL7305502A patent/NL7305502A/xx unknown
- 1973-04-19 DE DE2319892A patent/DE2319892A1/de active Pending
- 1973-04-19 GB GB1905873A patent/GB1425749A/en not_active Expired
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2901433A (en) * | 1953-07-17 | 1959-08-25 | Pennsalt Chemicals Corp | Cleaning composition |
US3533955A (en) * | 1965-06-15 | 1970-10-13 | Lever Brothers Ltd | Two-phase liquid detergent compositions |
US3658985A (en) * | 1969-07-28 | 1972-04-25 | Colgate Palmolive Co | Oil and fluorescent dye containing luster imparting liquid shampoo |
Cited By (24)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4242218A (en) * | 1976-11-08 | 1980-12-30 | Allied Chemical Corporation | Phenol-free photoresist stripper |
US4180472A (en) * | 1977-10-03 | 1979-12-25 | The Procter & Gamble Company | Detergent compositions for effective oily soil removal |
DE2950382A1 (de) * | 1978-12-26 | 1980-07-17 | Lion Fat Oil Co Ltd | Homogene waessrige alpha -olefinsulfonatmasse und verfahren zu ihrer herstellung |
US4362638A (en) * | 1980-07-28 | 1982-12-07 | S. C. Johnson & Son, Inc. | Gelled laundry pre-spotter |
US4302348A (en) * | 1980-09-23 | 1981-11-24 | The Drackett Company | Hard surface cleaning compositions |
US4390466A (en) * | 1981-04-30 | 1983-06-28 | Harold Weinberger | Heavy duty liquid detergent |
US4476043A (en) * | 1982-05-13 | 1984-10-09 | Henkel Corporation | Surfactant product |
US4476044A (en) * | 1982-05-13 | 1984-10-09 | Henkel Corporation | Surfactant product |
US4477372A (en) * | 1982-05-13 | 1984-10-16 | Henkel Corporation | Anionic nonionic surfactant mixture |
US4493370A (en) * | 1983-01-27 | 1985-01-15 | Phillips Petroleum Company | Urea as a cosurfactant in enhanced oil recovery processes |
US4528144A (en) * | 1984-02-27 | 1985-07-09 | Lever Brothers Company | Terpene sulfonate hydrotropes |
US4530801A (en) * | 1984-02-27 | 1985-07-23 | Lever Brothers Company | Nopol derived sulfonates |
US4606851A (en) * | 1984-02-27 | 1986-08-19 | Lever Brothers Company | Method for improving water solubility of surfactants using terpene sulfonate hydrotropes |
US4623483A (en) * | 1984-02-27 | 1986-11-18 | Lever Brothers Company | Method for improving water solubility of surfactants using Nopol derived sulfonates |
US4983317A (en) * | 1984-06-08 | 1991-01-08 | The Drackett Company | All purpose cleaner concentrate composition |
US4576738A (en) * | 1984-12-21 | 1986-03-18 | Colgate-Palmolive Company | Hard surface cleaning compositions containing pianane |
US4734215A (en) * | 1985-05-13 | 1988-03-29 | Shell Oil Company | Cleaning composition containing hydrocarbon mixtures |
EP0857778A2 (en) * | 1997-01-10 | 1998-08-12 | Product Source International, Inc. | Cleaning formulation |
EP0857778A3 (en) * | 1997-01-10 | 1998-10-28 | Product Source International, Inc. | Cleaning formulation |
US5863878A (en) * | 1997-08-05 | 1999-01-26 | Church & Dwight Co., Inc. | Clear, homogeneous and temperature-stable liquid laundry detergent product containing blend of anionic, nonionic and amphoteric surfactants |
US6475246B1 (en) | 2000-05-22 | 2002-11-05 | Pariser Industries | Dry cleaning additive, bath, and method |
US20040242448A1 (en) * | 2003-05-27 | 2004-12-02 | Unilever Home & Personal Care Usa, Division Of Conopco, Inc. | Effervescent cleaning composition |
WO2004106477A1 (en) * | 2003-05-27 | 2004-12-09 | Unilever N.V. | Effervescent cleaning composition |
US6933266B2 (en) | 2003-05-27 | 2005-08-23 | Unilever Home & Personal Care Usa, Division Of Conopco, Inc. | Effervescent cleaning composition for use in fabric washing |
Also Published As
Publication number | Publication date |
---|---|
NL7305502A (nl) | 1973-10-23 |
JPS492804A (nl) | 1974-01-11 |
JPS5139250B2 (nl) | 1976-10-27 |
DE2319892A1 (de) | 1973-10-31 |
GB1425749A (en) | 1976-02-18 |
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