US3929680A - Liquid detergent composition - Google Patents
Liquid detergent composition Download PDFInfo
- Publication number
- US3929680A US3929680A US352053A US35205373A US3929680A US 3929680 A US3929680 A US 3929680A US 352053 A US352053 A US 352053A US 35205373 A US35205373 A US 35205373A US 3929680 A US3929680 A US 3929680A
- Authority
- US
- United States
- Prior art keywords
- benzene
- detergent composition
- liquid detergent
- alkyl
- solubilizing agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000003599 detergent Substances 0.000 title claims abstract description 41
- 239000000203 mixture Substances 0.000 title claims abstract description 37
- 239000007788 liquid Substances 0.000 title claims abstract description 23
- 239000002904 solvent Substances 0.000 claims abstract description 27
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 17
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 12
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 9
- 239000004094 surface-active agent Substances 0.000 claims abstract description 9
- 150000004996 alkyl benzenes Chemical class 0.000 claims abstract description 8
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 8
- -1 alkyl sulfuric acid ester salts Chemical class 0.000 claims description 22
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 12
- 239000004202 carbamide Substances 0.000 claims description 12
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 10
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 9
- LTEQMZWBSYACLV-UHFFFAOYSA-N Hexylbenzene Chemical compound CCCCCCC1=CC=CC=C1 LTEQMZWBSYACLV-UHFFFAOYSA-N 0.000 claims description 8
- KWKXNDCHNDYVRT-UHFFFAOYSA-N dodecylbenzene Chemical compound CCCCCCCCCCCCC1=CC=CC=C1 KWKXNDCHNDYVRT-UHFFFAOYSA-N 0.000 claims description 7
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 6
- 125000005037 alkyl phenyl group Chemical group 0.000 claims description 5
- 150000003869 acetamides Chemical class 0.000 claims description 4
- 150000001558 benzoic acid derivatives Chemical class 0.000 claims description 4
- 150000002334 glycols Chemical class 0.000 claims description 4
- 150000003839 salts Chemical class 0.000 claims description 4
- JZALLXAUNPOCEU-UHFFFAOYSA-N tetradecylbenzene Chemical compound CCCCCCCCCCCCCCC1=CC=CC=C1 JZALLXAUNPOCEU-UHFFFAOYSA-N 0.000 claims description 4
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 3
- 150000005215 alkyl ethers Chemical class 0.000 claims description 3
- 125000002947 alkylene group Chemical group 0.000 claims description 3
- 239000007864 aqueous solution Substances 0.000 claims description 3
- 150000001768 cations Chemical class 0.000 claims description 3
- LIXVMPBOGDCSRM-UHFFFAOYSA-N nonylbenzene Chemical compound CCCCCCCCCC1=CC=CC=C1 LIXVMPBOGDCSRM-UHFFFAOYSA-N 0.000 claims description 3
- CDKDZKXSXLNROY-UHFFFAOYSA-N octylbenzene Chemical compound CCCCCCCCC1=CC=CC=C1 CDKDZKXSXLNROY-UHFFFAOYSA-N 0.000 claims description 3
- 239000002453 shampoo Substances 0.000 claims description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N toluene Substances CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 3
- 239000008096 xylene Substances 0.000 claims description 3
- 125000003342 alkenyl group Chemical group 0.000 claims description 2
- 150000003871 sulfonates Chemical class 0.000 claims description 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 claims 2
- KWOLFJPFCHCOCG-UHFFFAOYSA-N Acetophenone Chemical compound CC(=O)C1=CC=CC=C1 KWOLFJPFCHCOCG-UHFFFAOYSA-N 0.000 claims 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 1
- LVPMIMZXDYBCDF-UHFFFAOYSA-N isocinchomeronic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)N=C1 LVPMIMZXDYBCDF-UHFFFAOYSA-N 0.000 claims 1
- GJAWHXHKYYXBSV-UHFFFAOYSA-N pyridinedicarboxylic acid Natural products OC(=O)C1=CC=CN=C1C(O)=O GJAWHXHKYYXBSV-UHFFFAOYSA-N 0.000 claims 1
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims 1
- 239000004711 α-olefin Substances 0.000 claims 1
- 229930195734 saturated hydrocarbon Natural products 0.000 abstract description 5
- 125000001931 aliphatic group Chemical group 0.000 abstract description 4
- 239000004480 active ingredient Substances 0.000 abstract description 2
- 238000000926 separation method Methods 0.000 description 16
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 15
- 229910052708 sodium Inorganic materials 0.000 description 15
- 239000011734 sodium Substances 0.000 description 15
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 13
- 229940045136 urea Drugs 0.000 description 11
- 229930195733 hydrocarbon Natural products 0.000 description 10
- 150000002430 hydrocarbons Chemical class 0.000 description 10
- 239000004215 Carbon black (E152) Substances 0.000 description 9
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 9
- SNRUBQQJIBEYMU-UHFFFAOYSA-N dodecane Chemical compound CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 9
- 229940094933 n-dodecane Drugs 0.000 description 7
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 4
- 238000009472 formulation Methods 0.000 description 4
- 238000005191 phase separation Methods 0.000 description 4
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 4
- BGHCVCJVXZWKCC-UHFFFAOYSA-N tetradecane Chemical compound CCCCCCCCCCCCCC BGHCVCJVXZWKCC-UHFFFAOYSA-N 0.000 description 4
- 229960004418 trolamine Drugs 0.000 description 4
- 238000005406 washing Methods 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 229940077388 benzenesulfonate Drugs 0.000 description 3
- SRSXLGNVWSONIS-UHFFFAOYSA-N benzenesulfonic acid Chemical class OS(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-N 0.000 description 3
- BNZXJGMVVSASQT-UHFFFAOYSA-N benzenesulfonyl acetate Chemical class CC(=O)OS(=O)(=O)C1=CC=CC=C1 BNZXJGMVVSASQT-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000003350 kerosene Substances 0.000 description 3
- 239000002480 mineral oil Substances 0.000 description 3
- 235000010446 mineral oil Nutrition 0.000 description 3
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical class CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 3
- DIABIDLZBNRSPR-UHFFFAOYSA-N 2-carbamoylpyridine-3-carboxylic acid Chemical class NC(=O)C1=NC=CC=C1C(O)=O DIABIDLZBNRSPR-UHFFFAOYSA-N 0.000 description 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 150000003863 ammonium salts Chemical class 0.000 description 2
- SRSXLGNVWSONIS-UHFFFAOYSA-M benzenesulfonate Chemical compound [O-]S(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-M 0.000 description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical class OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
- 229940071161 dodecylbenzenesulfonate Drugs 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 230000005484 gravity Effects 0.000 description 2
- BKIMMITUMNQMOS-UHFFFAOYSA-N nonane Chemical compound CCCCCCCCC BKIMMITUMNQMOS-UHFFFAOYSA-N 0.000 description 2
- 125000006353 oxyethylene group Chemical group 0.000 description 2
- 239000012188 paraffin wax Substances 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 150000003873 salicylate salts Chemical class 0.000 description 2
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 2
- 235000010234 sodium benzoate Nutrition 0.000 description 2
- 239000004299 sodium benzoate Substances 0.000 description 2
- 229940048842 sodium xylenesulfonate Drugs 0.000 description 2
- QUCDWLYKDRVKMI-UHFFFAOYSA-M sodium;3,4-dimethylbenzenesulfonate Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1C QUCDWLYKDRVKMI-UHFFFAOYSA-M 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- RSJKGSCJYJTIGS-UHFFFAOYSA-N undecane Chemical compound CCCCCCCCCCC RSJKGSCJYJTIGS-UHFFFAOYSA-N 0.000 description 2
- GDJZZWYLFXAGFH-UHFFFAOYSA-M xylenesulfonate group Chemical group C1(C(C=CC=C1)C)(C)S(=O)(=O)[O-] GDJZZWYLFXAGFH-UHFFFAOYSA-M 0.000 description 2
- SYSZENVIJHPFNL-UHFFFAOYSA-N (alpha-D-mannosyl)7-beta-D-mannosyl-diacetylchitobiosyl-L-asparagine, isoform B (protein) Chemical compound COC1=CC=C(I)C=C1 SYSZENVIJHPFNL-UHFFFAOYSA-N 0.000 description 1
- CMCBDXRRFKYBDG-UHFFFAOYSA-N 1-dodecoxydodecane Chemical compound CCCCCCCCCCCCOCCCCCCCCCCCC CMCBDXRRFKYBDG-UHFFFAOYSA-N 0.000 description 1
- RXXCIBALSKQCAE-UHFFFAOYSA-N 3-methylbutoxymethylbenzene Chemical compound CC(C)CCOCC1=CC=CC=C1 RXXCIBALSKQCAE-UHFFFAOYSA-N 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 102000001708 Protein Isoforms Human genes 0.000 description 1
- 108010029485 Protein Isoforms Proteins 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- BHEOSNUKNHRBNM-UHFFFAOYSA-N Tetramethylsqualene Natural products CC(=C)C(C)CCC(=C)C(C)CCC(C)=CCCC=C(C)CCC(C)C(=C)CCC(C)C(C)=C BHEOSNUKNHRBNM-UHFFFAOYSA-N 0.000 description 1
- ZZXDRXVIRVJQBT-UHFFFAOYSA-M Xylenesulfonate Chemical compound CC1=CC=CC(S([O-])(=O)=O)=C1C ZZXDRXVIRVJQBT-UHFFFAOYSA-M 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 235000015278 beef Nutrition 0.000 description 1
- 150000007942 carboxylates Chemical class 0.000 description 1
- DIOQZVSQGTUSAI-NJFSPNSNSA-N decane Chemical compound CCCCCCCCC[14CH3] DIOQZVSQGTUSAI-NJFSPNSNSA-N 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000004851 dishwashing Methods 0.000 description 1
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N dodecahydrosqualene Natural products CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 1
- UJZFSGLNSCOISQ-UHFFFAOYSA-N dodecane hexadecane Chemical compound CCCCCCCCCCCC.CCCCCCCCCCCCCCCC UJZFSGLNSCOISQ-UHFFFAOYSA-N 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- YCOZIPAWZNQLMR-UHFFFAOYSA-N heptane - octane Natural products CCCCCCCCCCCCCCC YCOZIPAWZNQLMR-UHFFFAOYSA-N 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- DIOQZVSQGTUSAI-UHFFFAOYSA-N n-butylhexane Natural products CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- IBBMAWULFFBRKK-UHFFFAOYSA-N picolinamide Chemical class NC(=O)C1=CC=CC=N1 IBBMAWULFFBRKK-UHFFFAOYSA-N 0.000 description 1
- 239000010499 rapseed oil Substances 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 229940031439 squalene Drugs 0.000 description 1
- TUHBEKDERLKLEC-UHFFFAOYSA-N squalene Natural products CC(=CCCC(=CCCC(=CCCC=C(/C)CCC=C(/C)CC=C(C)C)C)C)C TUHBEKDERLKLEC-UHFFFAOYSA-N 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 229940071104 xylenesulfonate Drugs 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/18—Hydrocarbons
Definitions
- This invention relates to a liquid detergent composition. More particularly, this invention relates to a liquid detergent composition having excellent low temperature stability and containing an anionic surfactant and- /or a non-ionic surfactant, and solubilizing agents.
- liquid detergent compositions comprise, for instance, an alkyl benzene sulfonate and, incorporated therein, one or more solubilizing agents, for instance, lower alcohols such as ethanol, benzene sulfonates, lower alkyl benzene sulfonates such as p-toluene sulfonates, glycols such as propylene glycol, acetyl benzene sulfonates, acetamides, pyridine carboxylic acid amides, benzoates and urea.
- these detergent compositions are inevitably defective in that white turbidity or phase separation is brought about at low temperatures.
- the object of this invention is to provide a liquid detergent composition which possesses excellent low temperature stability
- the gist of this invention resides in a liquid detergent composition comprising as active ingredients at least one member selected from anionic surfactants and non-ionic surfactants and at least two solubilizing agents, characterized in that as one solubilizing agent there is used about 3 to about 30% by weight, based on the amount of the above surfactants, of an aliphatic saturated hydrocarbon having 6 to 14 carbon atoms on the average or an alkyl benzene containing an alkyl group having 6 to 14 carbon atoms on the average.
- the aliphatic saturated hydrocarbon used as one embodiment of the indispensable solubilizing agent in the composition of this invention contains 6 to 14 carbon atoms on the average, and it may be of either the normal form or the iso-form or a mixture thereof.
- kerosene, fluid paraffin and petroleum fractions containing as the main component such saturated hydrocarbon as mentioned above can be used.
- the alkyl benzene used as the other embodiment of the indispensable solubilizing agent in the composition of this invention contains a straight or branched alkyl group having 6 to 14 carbon atoms on the average.
- alkyl benzene hexyl benzene, octyl benzene, nonyl benzene, dodecyl benzene and tetradecyl benzene.
- solubilizing agents can be used as the other solubilizing agent in the composition of this invention.
- lower alcohols such as methanol, ethanol and isopropyl alcohol
- glycols such as ethylene glycol and propylene glycol
- acetamides such as ethylene glycol and propylene glycol
- acetamides such as ethylene glycol and propylene glycol
- acetamides such as ethylene glycol and propylene glycol
- aromatic carboxylic acid salts such as benzoates and salicylates
- urea The salts included in this group, i.e. the various sulfonates and aromatic carboxylic acid salts, are usually alkali metal salts (sodium or potassium), ammoni
- the anionic surfactant that the composition of this invention can contain, there can be mentioned, for instance, straight or branched alkyl benzene sulfonates, alkyl sulfuric acids ester salts, alkane sulfonates, a-olefin sulfonates, salts of polyoxyethylene alkyl or alkylphenyl ether sulfuric acid esters, and ether carboxylates expressed by the general formula R-O(CH C- H O),,R'COOM in which R is an alkyl or alkenyl group having 8 to 22 carbon atoms or an alkyl phenyl group in which the alkyl group has 6 to 17 carbon atoms, R is an alkylene group having 1 to 4 carbon atoms, M stands for a water-soluble cation, and n is a number from 1 to 30.
- the anionic surfactant is an alkali metal salt such as sodium or potassium, ammonium salt or an alkanolamine salt such as mono-,
- non-ionic surfactant there may be exemplified polyoxyethylene alkyl ethers in which the alkyl group has 8 to 18 carbon atoms and 4 to 14 oxyethylene units and polyoxyethylene alkyl phenyl ethers in which the alkyl group has from 8 to 12 carbon atoms and 6 to 12 oxyethylene units.
- hydrocarbon aliphatic saturated hydrocarbon or alkyl benzene as defined above
- the hydrocarbon solubilizing agent to be used as the indispensable solubilizing agent in the composition of this invention is incorporated in an amount of about 3 to about 30% (by weight; the same will apply hereinafter) based on the amount of the surfactant(s), and the weight ratio of said hydrocarbon solubilizing agent to the other solubilizing agent should be preferably from 1/40 to 2/1.
- the composition of this invention is useful as a detergent for foodstuffs and table wares, a shampoo and a heavy or light duty liquid detergent for clothes.
- n-dodecane is effective for improving the low tempera- EXAMPLE 5 ture stability. Especially when sodium xylene sulfonate, urea and triethanol amine are co-present, the effect of i Comparison This invention n-dodecane is remarkable.
- EXAMPLE 6 Comparison This invention Sodium straight-dodecyl t J, benzene sulfonate 15% 1 5% Sodium nonyl phenyl polyethoxy(3) acetate 5% 5% Sodium xylene sulfonate 14% 14% Ethanol 2% 2% Kerosene 2% Turbidity-separation temperature about 2C below C
- EXAMPLE 7 Comparison This invention Sodium nonyl phenyl polyethoxy(3) acetate 20% 20% Urea 5% 5% n-Dodecane 0% 1% Turbidity-separation temperature about C below 12C
- EXAMPLE 8 Comparison This invention Sodium straight-dodecyl benzene sulfonate 20% Ethanol 5% 5% Dodecyl benzene 0% 2.5%
- Tester Terg-O-Tometer Deterent concentration: 0.20% (in city water) Bath ratio: 6 contaminated cloths per 500 cc Washing temperature: 30C
- a liquid detergent composition having improved low temperature stability consisting essentially of an aqueous solution of at least one surfactant selected from the group consisting of anionic surfactants and non-ionic surfactants, the amount of said surfactant being an amount effective for making said detergent composition suitable for washing foodstuffs, tableware or clothes, or as a shampoo; a first solubilizing agent selected from the group consisting of alkanols having one to 3 carbon atoms; benzene sulfonates, p-toluene sulfonates, xylene sulfonates, acetyl benzene sulfonates, glycols, acetamides, pyridine dicarboxylic acid amides, benzoates, salicylates and urea; and a second solubilizing agent selected from the group consisting of hexyl benzene, octyl benzene, nonyl benzene, dodecyl benz
- a liquid detergentcomposition according to claim I in which said non-ionic surfactant is selected from polyoxyethylene alkyl ethers and polyoxyethylene alkyl phenyl ethers.
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP47039886A JPS5139250B2 (en, 2012) | 1972-04-20 | 1972-04-20 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US3929680A true US3929680A (en) | 1975-12-30 |
Family
ID=12565446
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US352053A Expired - Lifetime US3929680A (en) | 1972-04-20 | 1973-04-17 | Liquid detergent composition |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US3929680A (en, 2012) |
| JP (1) | JPS5139250B2 (en, 2012) |
| DE (1) | DE2319892A1 (en, 2012) |
| GB (1) | GB1425749A (en, 2012) |
| NL (1) | NL7305502A (en, 2012) |
Cited By (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4180472A (en) * | 1977-10-03 | 1979-12-25 | The Procter & Gamble Company | Detergent compositions for effective oily soil removal |
| DE2950382A1 (de) * | 1978-12-26 | 1980-07-17 | Lion Fat Oil Co Ltd | Homogene waessrige alpha -olefinsulfonatmasse und verfahren zu ihrer herstellung |
| US4242218A (en) * | 1976-11-08 | 1980-12-30 | Allied Chemical Corporation | Phenol-free photoresist stripper |
| US4302348A (en) * | 1980-09-23 | 1981-11-24 | The Drackett Company | Hard surface cleaning compositions |
| US4362638A (en) * | 1980-07-28 | 1982-12-07 | S. C. Johnson & Son, Inc. | Gelled laundry pre-spotter |
| US4390466A (en) * | 1981-04-30 | 1983-06-28 | Harold Weinberger | Heavy duty liquid detergent |
| US4476043A (en) * | 1982-05-13 | 1984-10-09 | Henkel Corporation | Surfactant product |
| US4476044A (en) * | 1982-05-13 | 1984-10-09 | Henkel Corporation | Surfactant product |
| US4477372A (en) * | 1982-05-13 | 1984-10-16 | Henkel Corporation | Anionic nonionic surfactant mixture |
| US4493370A (en) * | 1983-01-27 | 1985-01-15 | Phillips Petroleum Company | Urea as a cosurfactant in enhanced oil recovery processes |
| US4528144A (en) * | 1984-02-27 | 1985-07-09 | Lever Brothers Company | Terpene sulfonate hydrotropes |
| US4530801A (en) * | 1984-02-27 | 1985-07-23 | Lever Brothers Company | Nopol derived sulfonates |
| US4576738A (en) * | 1984-12-21 | 1986-03-18 | Colgate-Palmolive Company | Hard surface cleaning compositions containing pianane |
| US4606851A (en) * | 1984-02-27 | 1986-08-19 | Lever Brothers Company | Method for improving water solubility of surfactants using terpene sulfonate hydrotropes |
| US4623483A (en) * | 1984-02-27 | 1986-11-18 | Lever Brothers Company | Method for improving water solubility of surfactants using Nopol derived sulfonates |
| US4734215A (en) * | 1985-05-13 | 1988-03-29 | Shell Oil Company | Cleaning composition containing hydrocarbon mixtures |
| US4983317A (en) * | 1984-06-08 | 1991-01-08 | The Drackett Company | All purpose cleaner concentrate composition |
| EP0857778A3 (en) * | 1997-01-10 | 1998-10-28 | Product Source International, Inc. | Cleaning formulation |
| US5863878A (en) * | 1997-08-05 | 1999-01-26 | Church & Dwight Co., Inc. | Clear, homogeneous and temperature-stable liquid laundry detergent product containing blend of anionic, nonionic and amphoteric surfactants |
| US6475246B1 (en) | 2000-05-22 | 2002-11-05 | Pariser Industries | Dry cleaning additive, bath, and method |
| US20040242448A1 (en) * | 2003-05-27 | 2004-12-02 | Unilever Home & Personal Care Usa, Division Of Conopco, Inc. | Effervescent cleaning composition |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS53127752U (en, 2012) * | 1977-03-17 | 1978-10-11 | ||
| JPS566068A (en) * | 1980-04-08 | 1981-01-22 | Yamaha Motor Co Ltd | Controlling device for ignition timing of engine |
| JPS5820379U (ja) * | 1981-07-31 | 1983-02-08 | 日産自動車株式会社 | 内燃機関のノツキング防止装置 |
| JPS58158168U (ja) * | 1982-04-16 | 1983-10-21 | 日産自動車株式会社 | 火花点火機関 |
| MY101656A (en) * | 1986-09-02 | 1991-12-31 | Colgate Palmolive Co | Laundry pre-spotter composition providing improved oily soil removal. |
| JP2700267B2 (ja) * | 1989-02-17 | 1998-01-19 | ミヨシ油脂株式会社 | 液体洗浄剤組成物 |
| IT1240734B (it) * | 1990-04-02 | 1993-12-17 | Syremont Spa | Procedimento per la pulitura di matrici porose idrofile |
| AU647849B2 (en) * | 1990-12-13 | 1994-03-31 | Unilever Plc | Hair styling composition |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2901433A (en) * | 1953-07-17 | 1959-08-25 | Pennsalt Chemicals Corp | Cleaning composition |
| US3533955A (en) * | 1965-06-15 | 1970-10-13 | Lever Brothers Ltd | Two-phase liquid detergent compositions |
| US3658985A (en) * | 1969-07-28 | 1972-04-25 | Colgate Palmolive Co | Oil and fluorescent dye containing luster imparting liquid shampoo |
-
1972
- 1972-04-20 JP JP47039886A patent/JPS5139250B2/ja not_active Expired
-
1973
- 1973-04-17 US US352053A patent/US3929680A/en not_active Expired - Lifetime
- 1973-04-18 NL NL7305502A patent/NL7305502A/xx unknown
- 1973-04-19 DE DE2319892A patent/DE2319892A1/de active Pending
- 1973-04-19 GB GB1905873A patent/GB1425749A/en not_active Expired
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2901433A (en) * | 1953-07-17 | 1959-08-25 | Pennsalt Chemicals Corp | Cleaning composition |
| US3533955A (en) * | 1965-06-15 | 1970-10-13 | Lever Brothers Ltd | Two-phase liquid detergent compositions |
| US3658985A (en) * | 1969-07-28 | 1972-04-25 | Colgate Palmolive Co | Oil and fluorescent dye containing luster imparting liquid shampoo |
Cited By (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4242218A (en) * | 1976-11-08 | 1980-12-30 | Allied Chemical Corporation | Phenol-free photoresist stripper |
| US4180472A (en) * | 1977-10-03 | 1979-12-25 | The Procter & Gamble Company | Detergent compositions for effective oily soil removal |
| DE2950382A1 (de) * | 1978-12-26 | 1980-07-17 | Lion Fat Oil Co Ltd | Homogene waessrige alpha -olefinsulfonatmasse und verfahren zu ihrer herstellung |
| US4362638A (en) * | 1980-07-28 | 1982-12-07 | S. C. Johnson & Son, Inc. | Gelled laundry pre-spotter |
| US4302348A (en) * | 1980-09-23 | 1981-11-24 | The Drackett Company | Hard surface cleaning compositions |
| US4390466A (en) * | 1981-04-30 | 1983-06-28 | Harold Weinberger | Heavy duty liquid detergent |
| US4476043A (en) * | 1982-05-13 | 1984-10-09 | Henkel Corporation | Surfactant product |
| US4476044A (en) * | 1982-05-13 | 1984-10-09 | Henkel Corporation | Surfactant product |
| US4477372A (en) * | 1982-05-13 | 1984-10-16 | Henkel Corporation | Anionic nonionic surfactant mixture |
| US4493370A (en) * | 1983-01-27 | 1985-01-15 | Phillips Petroleum Company | Urea as a cosurfactant in enhanced oil recovery processes |
| US4528144A (en) * | 1984-02-27 | 1985-07-09 | Lever Brothers Company | Terpene sulfonate hydrotropes |
| US4530801A (en) * | 1984-02-27 | 1985-07-23 | Lever Brothers Company | Nopol derived sulfonates |
| US4606851A (en) * | 1984-02-27 | 1986-08-19 | Lever Brothers Company | Method for improving water solubility of surfactants using terpene sulfonate hydrotropes |
| US4623483A (en) * | 1984-02-27 | 1986-11-18 | Lever Brothers Company | Method for improving water solubility of surfactants using Nopol derived sulfonates |
| US4983317A (en) * | 1984-06-08 | 1991-01-08 | The Drackett Company | All purpose cleaner concentrate composition |
| US4576738A (en) * | 1984-12-21 | 1986-03-18 | Colgate-Palmolive Company | Hard surface cleaning compositions containing pianane |
| US4734215A (en) * | 1985-05-13 | 1988-03-29 | Shell Oil Company | Cleaning composition containing hydrocarbon mixtures |
| EP0857778A3 (en) * | 1997-01-10 | 1998-10-28 | Product Source International, Inc. | Cleaning formulation |
| US5863878A (en) * | 1997-08-05 | 1999-01-26 | Church & Dwight Co., Inc. | Clear, homogeneous and temperature-stable liquid laundry detergent product containing blend of anionic, nonionic and amphoteric surfactants |
| US6475246B1 (en) | 2000-05-22 | 2002-11-05 | Pariser Industries | Dry cleaning additive, bath, and method |
| US20040242448A1 (en) * | 2003-05-27 | 2004-12-02 | Unilever Home & Personal Care Usa, Division Of Conopco, Inc. | Effervescent cleaning composition |
| WO2004106477A1 (en) * | 2003-05-27 | 2004-12-09 | Unilever N.V. | Effervescent cleaning composition |
| US6933266B2 (en) | 2003-05-27 | 2005-08-23 | Unilever Home & Personal Care Usa, Division Of Conopco, Inc. | Effervescent cleaning composition for use in fabric washing |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS492804A (en, 2012) | 1974-01-11 |
| JPS5139250B2 (en, 2012) | 1976-10-27 |
| NL7305502A (en, 2012) | 1973-10-23 |
| DE2319892A1 (de) | 1973-10-31 |
| GB1425749A (en) | 1976-02-18 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US3929680A (en) | Liquid detergent composition | |
| US3579453A (en) | Alkali-soluble surfactant consisting of substituted succinic acid-nonionic ethoxylate blends | |
| US2383737A (en) | Detergent composition | |
| EP0019315B1 (en) | Highly concentrated fatty acid containing liquid detergent compositions | |
| US3755206A (en) | Detergent compositions | |
| EP0200263B1 (en) | Homogeneous concentrated liquid detergent compositions containing ternary surfactant system | |
| JPS61255999A (ja) | 液体洗剤 | |
| US3619119A (en) | Pasty spot-treating compositions for use on textiles | |
| US4002579A (en) | Detergent composition | |
| GB1601652A (en) | Liquid detergents comprising nonionic surfactants | |
| US2943058A (en) | Liquid detergent compositions | |
| US3377290A (en) | Liquid or paste detergent preparations having sulfofatty acid salts as viscosity reducing agents | |
| KR0181979B1 (ko) | 액체 세제 | |
| US3242092A (en) | Wax-containing liquid detergent | |
| US5096621A (en) | Detergent composition containing di-long chain alkyl amine oxides | |
| US5520836A (en) | Liquid detergent | |
| FI60234B (fi) | Foer grov anvaendning avsedd detergentblandning | |
| US3368977A (en) | Built liquid detergent compositions | |
| US2875153A (en) | Detergent compositions | |
| US3057804A (en) | All-weather surface cleaner | |
| US3232879A (en) | Detergent bars having good sudsing and lime soap dispersant characteristics | |
| US3632517A (en) | Synergistic tallow-based detergent compositions | |
| US3239468A (en) | Hard surface cleaning compositions | |
| US3023168A (en) | Heavy duty liquid detergent | |
| US3883447A (en) | Transparent liquid detergent composition |