US3905381A

US3905381A - Filament liquid quenching apparatus

Info

Publication number: US3905381A
Application number: US395036A
Authority: US
Inventors: Richard D Meyer
Original assignee: Phillips Petroleum Co
Current assignee: Phillips Petroleum Co
Priority date: 1973-09-07
Filing date: 1973-09-07
Publication date: 1975-09-16
Anticipated expiration: 1992-09-16

Abstract

Melt-spun thermoplastic filaments are liquid quenched in an apparatus equipped with baffles for quieting the surface of said quenching liquid and a weir for maintaining a constant level of quenching liquid. The liquid is removed from said filaments by an apparatus containing an enclosed chamber which is partially defined by a perforated surface over which said filaments pass in contact therewith, said chamber being in communication with means for removing fluids therefrom.

Description

United States Patent Meyer 1 Sept. 16, 1975 [54] FILAMENT LIQUID QUENCHING 2,955,017 10/1960 Boyer 425/68 x APPARATUS 3,087,198 4/1963 Edwards 3,358,980 12/1967 Taylor 134/122 X Inventor: Richard y Greenville, 3,392,580 7/1968 Bain et a1 73 215 [73] Assignee: Phillips Petroleum Company,

Bartl vin Okl Primary ExaminerHarvey C. Hornsby Assistant ExaminerC. K. Moore [22] F1led: Sept. 7, 1973 21 Appl. No.1 395,036 [57] ABSTRACT Melt-spun thermoplastic filaments are liquid quenched [52] [15. CL. 134/122; 15/302; 15/306 A; in an apparatus equipped with baffles for quieting the A 425/71 surface of said quenching liquid and a weir for main- [51] B08B 3/00; B29D 23/06; taining a constant level of quenching liquid. The liquid B29C 25/00 is removed from said filaments by an apparatus con- [58] new of Search 134/64- 122; 425/711 68; taining an enclosed chamber which is partially defined 5/302 306 A by a perforated surface over which said filaments pass in contact therewith, said chamber being in communi- 156] References cued cation with means for removing fluids therefrom.

UNITED STATES PATENTS l,239,60l 9 1917 Hoppes 73 215 5 03mm 7 Drawmg F'gures 2,494,468 H1950 Boryzkowski 425/68 X PATENTEU SEP 1 6 I975 SHEET 1 BF FILAMENT LIQUID QUENCI-IING APPARATUS BACKGROUND OF THE INVENTION The invention relates to an apparatus for liquid quenching melt-spun thermoplastic filaments and an apparatus for removing the quenching liquid from the quenched filaments.

In liquid quenching melt-spun thermoplastic filaments it is desirable that the surface of the quenching liquid be in a quiescent state in the area where the freshly spun filaments enter the liquid. Normally, the

primary cause of turbulence in the quench tank is not the filaments entering the liquid, but rather the passage of the filaments through the tank and particularly the filaments leaving the liquid. The area-where the filaments leave the liquid is usually at the opposite end of the quench tank from where the filaments enter the liquid. However, the turbulence generated by the filaments moving through the tank and leaving the liquid causes waves on the surface of the liquid which travel to the area where the filaments enter the liquid. These waves can splash upon the hot spinning apparatus or spinnerets adversely affecting the uniformity of the filaments and damaging the spinnerets. Also the filaments themselves can be deformed by the direct action of the waves upon them during the quenching process causing irregular drawing of the filaments or the unquenched filaments to fuse together. Consequently to produce uniform liquid quenched filaments it is desirable to maintain the surface of the quenching liquid in a quiescent state.

In addition to problems caused by waves, other problems exist in liquid quenching systems. For example. fluctuation in level of quenching liquid in the quench tank affects the uniformity of the filaments. To reduce this problem the level of quenching liquid is often maintained by using a weir, but due to the meniscus action of most quenching liquids, there is some fluctuation in the quenching liquid level even though a weir is used.

Another problem encountered in liquid quenching systems is removing the liquid from the filaments after the filaments have been quenched. A number of methods have been developed to remove the quench liquid from the filaments, but frequently they abrade, cut or otherwise damage the filaments or affect their uniformity.

It is an object of theinvention to provide apparatus to liquid quench melt-spun thermoplastic filaments.

Another object of the invention is to provide a quench tank with a quiescent liquid surface.

Still another object of the invention is to provide a quench tank with a weir which minimizes the meniscus effect of the quenching liquid on the level of quenching liquid in the tank.

Yet another object of the invention is an apparatus for removing quenchingliquid from the filaments without damaging or affecting the uniformity of the yarn.

SUMMARY OF THE INVENTION In accordance with the invention there is provided apparatus for liquid quenching melt-spun thermoplastic filaments comprising, in combination: a quench tank containing baffles to calm the quench liquid; a weir located in a quiescent area to minimize the meniscus action of the quench liquid and to maintain a constant liquid level of quench liquid in the quench tank;

and an apparatus for removing the quench liquid from the filaments.

Further according to the invention there is provided an assembly useful for removing liquid from the filaments comprising, in combination: a chamber which contains perforations in a surface over which filaments pass in contact therewith and a means in communication with said chamber for removing fluids therefrom.

BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is a diametric view, partly cut away, of a combined apparatus in accordance with the invention.

FIG. 2 is a sectional view of the quench tank of FIG. 1 showing the baffles and the path of the filaments through the quench tank.

FIGS. 3, 4 and 5 are elevation views of the baffles of FIGS. 1 and 2 showing cutouts for the filaments and perforated areas for quench liquid circulation.

FIG. 6 is an elevation, partly cutaway, of the weir of FIG. 1.

FIG.'7 is a diametric view, partly cutaway, of apparatus used to remove the quench ments.

DETAILED DESCRIPTION OF THE INVENTION Referring now to the drawings wherein like reference numerals are employed to denote like elements, the invention will be more fully explained. FIG. 1 illustrates a combination of the invention wherein thermoplastic filaments 2-are extruded through spinnerets -I. As the filaments 2 leave the surface of the spinnerets 1, they pass through air for a distance 3 or some other gaseous atmosphere prior to entering the quench liquid. Since the quench liquid is normally considerably cooler than the temperature of the spinnerets l, the quench liquid must not contact the spinnerets or damage to the spinnerets may result. The filaments 2 then pass into the quench liquid 4 at point 6. The filaments 2 pass through the liquid over a guide means 8 through slots l0, l2 and 14 in the baffles 16, I8 and 20 respectively. The filaments 2 pass out of the quench liquid 4 at point 22 and through quench liquid removal means generally denoted by reference numeral 24 and onto further processing.

The quench liquid 4 is contained in a tank, generally denoted by reference numeral 26. The tank 26 is equipped with a weir, generally denoted by reference numeral 28 to control the level of quench liquid in the tank within a narrow range. Quench liquid enters the tank through conduit 36 and perforated conduit 37 and exits the tank through opening 38 after it spills into weir pot 40. A bafile 39 is provided above perforated conduit 37 to minimize turbulence due to the incoming quench liquid. The liquid 4 can be recirculated and conditioned if desired or it can be. discarded after it passes through the tank. Frequently where water is used as the quenching liquid, tap water is fed to the tank and discarded after passing through outlet 38. The liquid 4 can pass freely through the

perforated sections

30, 32 and 34 in

baffles

16, 18 and 20 respectively.

FIG. 2 illustrates the path of filaments 2 through the liquid 4. The distance the filaments travel from the surface of.the spinnerets to the quench liquid, denoted by numeral 3, varies with the particular process, but it is usually in the range of from l/16 to 2 /2 inches.

As shown in FIG. 3, opening 10 is large enough for the filaments to pass through it without touching the liquid from the filabaffle. The perforated section 30 is located in the lower portion of the baffle 16]). The apertures 42 therein andtheperforated section itself 30 are ofsufficient size to permit adequate circulation but minimize turbulence of the quench liquid. It is within the scope of the invention that the entire baffle be perforated and also that the perforated section be constructed such that it is removable so that a new perforated section with different size apertures can be installed. It is suggested that the tank 26 be constructed such that baffles '16, 18 and 20 are removable. In addition for'most convenient operation, the lowerportion of

baffles

16, 18 and 20 designated by reference numerals 16b, 18b and 20b respectively can be separable from the upper portion of saidbaffles designated by reference numerals 16b, 18a and 20a respectively. This allows for simplification during startup in'that the up'per'portion of said baffles are removed until the line is in operation, thus eliminating the need to thread the'filaments through the holes in the baffle's. Although successful results have been obtained using three baffles in the tank, it is understood that the invention is not limited to three baffles. The baffles are used to produce a calm surface in the area where the filaments enter the quench liquid, reference numeral 6, and depending'on the particular'quench liquid, lineal speed of the filaments me, one or more baffles may be required. 1 Y

As shownin F G. 4, baffle 18 is nearly identical to baffle 16 except that the opening 12' for the filaments is located nearer the surface of the quench liquid. The

perforated section 32 and the apertures 42 therein are of sufficient size to permit circulation but to minimize turbulence of the quench liquid.

As shown in FIG.5, filament opening 14 of baffle 20' is progressively nearer the surface of the quench liquid' 1. This tends to dampen the movement of the quench liquid 4'through the tank 26. Also deepening the tank in the area where the filaments leave the quench liquid- 22 tends to dampen the movement of-the quench liquid through the tank. In fact, it may be possible to remove all-but one baffle nearest the spinnerets 1, if the tank is large enough. Normally, however, plant space is limited'andrela'tively small tanks are required, thus making it desirable to use two or more baffles.

Referring to FIG. 6, to minimize the meniscus action of the quench liquid, notches 44 are cut into the upper rim of the weir. It is preferred to mill the notches for uniformity and thus better control of the liquid level in the tank. It is desirable to construct the weir in such a manner that it canbe raised or lowered to adjust the liquid level in the tank and thus vary the distance of the liquid from the spinneret. One such method is to construct the wei'r'standpipe 46 in two sections. Theupper section 461: is threaded inside and the lower section 46b is threaded outside in order to receiveth'e upper section 46a. It is important to insure that the weir is level for proper weir action. The weir notches'44 can vary widely in width, depth, shape and distance apart, but generally they are inthe range of 1/16 to A: inch wide, 1/16 to V2 inch deep, v or u shaped and V2 to 3 inches apart. The weir should be placed in the most quiescent section of the tank; in FIG. l'that .would be in the area nearest the spinnerets 1. Also another suitable location for the weir is between

baffles

16 and 18. The weir can be. constructed in any suitable shape; however. the round shape minimizes the creation of turbulence in the quiescent zone during adjustment of the weir height, when such adjustment is made by turning the weir.- Y

- Referring toFIG. 7, the filament quench liquid removal means comprises a chamber 48 having apertures 50 located in the upper portion 52. It is recommended that the apertures 50 be located so that they cover the entire width of the upper portion-52 in order that all of the filaments will pass. over at least some of the holes. The chamber 48 is provided with openings 54 for connection to a vacuum means (not shown) for removing quench liquid, air or other fluids from chamber 48. The size of apertures 50are normally in the range of from 1/64 to A; inch in diameter and A; to /2 inch spaced apart. The apparatus 24 can be tapered from the inlet 56 to the outlet 58 to conform the upper portion 52 to the shape of. the filament tow passing over said portion.

Also inlet guides 60 are provided at the inlet 56 of said apparatus. 1

i EXAMPLE tus according to the invention.

The quench tank was 58 /2 inches long and34 inches wide. The' depth of the tank was 30 inches for a distance of 37/2 inches measured from the spinneret end and .then the-bottom was sloped upward 40 from horizontaLThe tank-at-the sloped end had a minimum depth of 12 inches.

In general, the greaterthe volume of quench liquid in thetank, less turbulence is transmitted and thus fewer. 'baffles are required. The above apparatus was constructed with a sloping bottom due to space limitation and it was not the preferred design.

The baffles corresponding. to

baffles

20, 18 and 16 of FIG; 2 were spaced 15, 26 and 38 inches, respectively, measured from the end where the filaments leave the quench liquid: The baffle corresponding to baffle 20 was 33% inches wide and 25 inches deep. The perforated area was 29% inches wide, 12 inches deep, centered on the baffle 2 inches from the bottom and had 0.250 inch holes on 5/16 inch centers providing 58 percent open area. The tow opening was 14 inches wide, 2/2 inches deep and centered on the baffle 2% inches from the top. 7

The baffle corresponding to baffle 18 was 33% inches wide and 30 inches deep. The perforated area was 29% inches wide, 12 inches deep, centered on the baffle 2 inches from the bottom and had 0.125 inch holes on 3/16 inch centers providing 40 percent openarea. The tow opening was 18 inches wide, 3 inches deep'and centered-on the baffle 7 inches from the top.

The baffle corresponding to baffle 16 was 33% inches wide and 30 inch deep. The perforated area was 29% inches wide, 10 inches deep, centered on the baffle 2 inches from the bottom and had 169 0.045 inch holes per square inch providing 27 percent open area. The

.tow opening was 24 inches wide, 4 inches deep and centered on the baffle 12 inches from the top.

The weir was 6 inches inside diameter with A inch deep notches spaced 2 inches around the top. The weir was positioned between baffles corresponding to baffles l6 and 18 of FIG. 2.

The quench liquid removal means comprised two troughs as illustrated in FIGS. 1 and 7. Each trough had an inlet width of 3 inches and tapered to 1 inch at the outlet end. The holes in the bottom plates were 1/16 inch in diameter and as close as possible.

The quench liquid was water and the bath temperature was maintained at approximately 116F. The spinnerets were operated at a distance of between 1% inches to 1/16 inch from the surface of the quench liquid. The vacuum on the quench liquid removal means varied between 3 to 5 inches of water. The tow denier for both spinnerets was 438,000 with a line speed of from 266 to 300 feet per minute.

The above-described apparatus provided a quiescent quench liquid surface in the area of the spinnerets to the extent that the spinnerets could be operated continuously within 1/16 of an inch of the quench liquid. Also it is noted that in the area where the filaments were leaving the quench liquid, waves over 1 inch were being produced. In addition the filaments leaving the quench liquid removal means were not cut or damaged and were dry to the touch.

What is claimed is:

1. Apparatus for liquid quenching melt-spun thermoplastic filaments comprising:

a tank for storing a quench liquid;

at least one baffle in said quench tank to dampen the movement of quench liquid wherein said baffle contains an opening through which said filaments pass and a perforated area to permit circulation of said quench liquid but which reduces turbulence of said quench liquid;

a means for guiding said filaments through said tank;

and

a weir to control the level of quench liquid in said tank.

2. The apparatus of claim 1 wherein at least two baffles are provided and the perforations in said baffles arc progressively smaller in baffles progressively nearer to the area where the filaments enter the quench liquid.

3. The apparatus of claim 2 wherein said weir is located in a quiescent area of the tank.

4. The apparatus to claim 3 wherein the weir is adjustable in order to raise or lower the level of the quench liquid in the tank.

5. The apparatus of claim 3 wherein said weir has a vertical cylindrical wall and has notches in the upper rim of the wall in the range of l/16 to /2 inch wide, 1/16 to /2 inch deep and /2 to 3 inches apart.

Claims

1. Apparatus for liquid quenching melt-spun thermoplastic filaments comprising: a tank for storing a quench liquid; at least one baffle in said quench tank to dampen the movement of quench liquid wherein said baffle contains an opening through which said filaments pass and a perforated area to permit circulation of said quench liquid but which reduces turbulence of said quench liquid; a means for guiding said filaments through said tank; and a weir to control the level of quench liquid in said tank.

2. The apparatus of claim 1 wherein at least two baffles are provided and the perforations in said baffles are progressively smaller in baffles progressively nearer to the area where the filaments enter the quench liquid.

5. The apparatus of claim 3 wherein said weir has a vertical cylindrical wall and has notches in the upper rim of the wall in the range of 1/16 to 1/2 inch wide, 1/16 to 1/2 inch deep and 1/2 to 3 inches apart.