US3904543A - Detergent film - Google Patents
Detergent film Download PDFInfo
- Publication number
- US3904543A US3904543A US386343A US38634373A US3904543A US 3904543 A US3904543 A US 3904543A US 386343 A US386343 A US 386343A US 38634373 A US38634373 A US 38634373A US 3904543 A US3904543 A US 3904543A
- Authority
- US
- United States
- Prior art keywords
- water
- detergent
- solution
- parts
- film
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/06—Powder; Flakes; Free-flowing mixtures; Sheets
Definitions
- Still another object of this invention is the provision of a detergent in precursor form which substantially alleviates the above mentioned problems of the detergent trade.
- Another object of this invention is to provide a deter gent composition that is safe to substantially allsurfaces in high concentrations for short periods of time if applied directly to a surface moistened with water.
- a solution comprising water, a nonionic detergent of the class consisting of ethoxylated alkyl phenols, preferably an ethoxylated nonyl or octyl phenol containing from 9 to mols of ethylene oxide repeating units; a resin of the alkylene maleic anhydride type such as a methyl vinyl ether maleic anhydride copolymer or ethylene maleic anhydride copolymer, preferably the former; and a small amount of an alkaline agent such as an alkali hydroxide, preferaby sodium hydroxide is composed and briefly heated at elevated temperature, about F, for a short time period, about 30 minutes, during which interaction between the nonionic and the polymer occurs resulting in partial esterification of the carboxyl groups of the copolymer.
- a nonionic detergent of the class consisting of ethoxylated alkyl phenols, preferably an ethoxylated nonyl or octyl phenol containing from
- the mixture is allowed to cool; then cast upon a suitable surface and allowed to dry either spontaneously or by supplying hot air to the exposed surface.
- suitable surface examples include glass, plastic treated surfaces such as polyethylene, polyvinyl chloride and Teflon.
- the film prepared as just described can be of any desired thickness. It can be readily stripped from the receiving surface and cut to any desired dimension. For example, a film having a thickness of about 18 mils and an area of about 18 square inches when dissolved in one gallon of water provides an effective detergent solution.
- a pliant, non-tacky, self-sustaining film having a water content of about 2% by weight and formed by casting upon a receptive surface to permit evaporation of water from a solution consisting of about 83 parts of water, 10 parts of an ethoxylated nonyl phenol having from 9l() mols. of ethylene oxide, 4 parts of methyl vinyl ether maleic anhydride copolymer, and about 3 parts of a 20% w/w sodium hydroxide solution; said solution being heated to about 195F. for about thirty minutes, then cooled to the point of clarity at which the pH is about 4.0-4.4.
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Moulding By Coating Moulds (AREA)
- Casting Or Compression Moulding Of Plastics Or The Like (AREA)
Priority Applications (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US386343A US3904543A (en) | 1973-08-07 | 1973-08-07 | Detergent film |
| GB2913174A GB1437855A (en) | 1973-08-07 | 1974-07-01 | Detergent film |
| JP49075474A JPS5747239B2 (enExample) | 1973-08-07 | 1974-07-03 | |
| FR7427310A FR2240286B1 (enExample) | 1973-08-07 | 1974-08-06 | |
| CA206,384A CA1033257A (en) | 1973-08-07 | 1974-08-06 | Detergent film |
| DE2438052A DE2438052A1 (de) | 1973-08-07 | 1974-08-07 | Biegsame, selbsttragende folie zur herstellung von detergens-loesungen |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US386343A US3904543A (en) | 1973-08-07 | 1973-08-07 | Detergent film |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US3904543A true US3904543A (en) | 1975-09-09 |
Family
ID=23525200
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US386343A Expired - Lifetime US3904543A (en) | 1973-08-07 | 1973-08-07 | Detergent film |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US3904543A (enExample) |
| JP (1) | JPS5747239B2 (enExample) |
| CA (1) | CA1033257A (enExample) |
| DE (1) | DE2438052A1 (enExample) |
| FR (1) | FR2240286B1 (enExample) |
| GB (1) | GB1437855A (enExample) |
Cited By (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4532063A (en) * | 1983-08-15 | 1985-07-30 | S. C. Johnson & Son, Inc. | Dissolvable bleach sheet |
| US4557852A (en) * | 1984-04-09 | 1985-12-10 | S. C. Johnson & Son, Inc. | Polymer sheet for delivering laundry care additive and laundry care product formed from same |
| US4797221A (en) * | 1985-09-12 | 1989-01-10 | S. C. Johnson & Son, Inc. | Polymer sheet for delivering laundry care additive and laundry care product formed from same |
| US20060127458A1 (en) * | 2004-12-15 | 2006-06-15 | Melba Kiser | Single use personal care sheet |
| WO2007034471A3 (en) * | 2005-09-26 | 2007-05-31 | Samuel Icht | Detergent printed film |
| EP2226379A1 (en) * | 2009-03-02 | 2010-09-08 | Dizolve Group Corporation | Dissolvable laundry detergent sheet |
| US8785361B2 (en) | 2010-07-02 | 2014-07-22 | The Procter & Gamble Company | Detergent product and method for making same |
| US9074305B2 (en) | 2010-07-02 | 2015-07-07 | The Procter & Gamble Company | Method for delivering an active agent |
| US9163205B2 (en) | 2010-07-02 | 2015-10-20 | The Procter & Gamble Company | Process for making films from nonwoven webs |
| US9464264B2 (en) | 2014-02-06 | 2016-10-11 | Dizolve Group Corp. | Method and apparatus for making a laundry detergent sheet |
| US11021812B2 (en) | 2010-07-02 | 2021-06-01 | The Procter & Gamble Company | Filaments comprising an ingestible active agent nonwoven webs and methods for making same |
| US11434586B2 (en) | 2010-07-02 | 2022-09-06 | The Procter & Gamble Company | Filaments comprising an active agent nonwoven webs and methods for making same |
| US11679066B2 (en) | 2019-06-28 | 2023-06-20 | The Procter & Gamble Company | Dissolvable solid fibrous articles containing anionic surfactants |
| US11795417B2 (en) | 2020-02-24 | 2023-10-24 | Dizolve Group Corporation | Dissolvable sheet containing a cleaning active and method of making same |
| US11925698B2 (en) | 2020-07-31 | 2024-03-12 | The Procter & Gamble Company | Water-soluble fibrous pouch containing prills for hair care |
| US12403083B2 (en) | 2021-08-30 | 2025-09-02 | The Procter & Gamble Company | Dissolvable solid structure comprising first and second polymeric structurants |
| US12527727B2 (en) | 2017-01-27 | 2026-01-20 | The Procter & Gamble Company | Compositions in the form of dissolvable solid structures |
| US12540238B2 (en) | 2022-03-10 | 2026-02-03 | The Procter & Gamble Company | Dissolvable solid structure having first and second layers |
| US12576013B2 (en) | 2021-12-17 | 2026-03-17 | The Procter & Gamble Company | Dissolvable solid fibrous shampoo articles containing salts |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2925915C2 (de) * | 1979-06-27 | 1982-04-15 | Lee, Yong Hwa, 4000 Düsseldorf | Verfahren zur Herstellung folienartig dünner Schaumseifenbänder sowie Anordnung und Vorrichtungen zur Durchführung des Verfahrens |
| GB2164339A (en) * | 1984-09-11 | 1986-03-19 | Ciba Geigy Ag | Polymaleic anhydride derivatives |
Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US261897A (en) * | 1882-08-01 | Josef bankmann | ||
| US1648778A (en) * | 1922-08-14 | 1927-11-08 | David W Mitchell | Book soap |
| US2356168A (en) * | 1941-08-16 | 1944-08-22 | Clarence W Mabley | Soap leaf |
| US3328309A (en) * | 1963-10-21 | 1967-06-27 | Gen Aniline & Film Corp | Stabilized liquid heavy duty detergent composition |
| US3359206A (en) * | 1964-05-21 | 1967-12-19 | Koppers Co Inc | Floating soap |
| US3457176A (en) * | 1964-10-16 | 1969-07-22 | Monsanto Co | Liquid detergent processes |
| US3591508A (en) * | 1967-12-07 | 1971-07-06 | Monsanto Co | Process for making heavy duty liquid detergent compositions |
| US3679592A (en) * | 1970-08-17 | 1972-07-25 | Monsanto Co | Cleansing and soil preventive composition |
| US3729421A (en) * | 1970-08-04 | 1973-04-24 | C Gibson | Soap cone and holder |
-
1973
- 1973-08-07 US US386343A patent/US3904543A/en not_active Expired - Lifetime
-
1974
- 1974-07-01 GB GB2913174A patent/GB1437855A/en not_active Expired
- 1974-07-03 JP JP49075474A patent/JPS5747239B2/ja not_active Expired
- 1974-08-06 CA CA206,384A patent/CA1033257A/en not_active Expired
- 1974-08-06 FR FR7427310A patent/FR2240286B1/fr not_active Expired
- 1974-08-07 DE DE2438052A patent/DE2438052A1/de active Pending
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US261897A (en) * | 1882-08-01 | Josef bankmann | ||
| US1648778A (en) * | 1922-08-14 | 1927-11-08 | David W Mitchell | Book soap |
| US2356168A (en) * | 1941-08-16 | 1944-08-22 | Clarence W Mabley | Soap leaf |
| US3328309A (en) * | 1963-10-21 | 1967-06-27 | Gen Aniline & Film Corp | Stabilized liquid heavy duty detergent composition |
| US3359206A (en) * | 1964-05-21 | 1967-12-19 | Koppers Co Inc | Floating soap |
| US3457176A (en) * | 1964-10-16 | 1969-07-22 | Monsanto Co | Liquid detergent processes |
| US3591508A (en) * | 1967-12-07 | 1971-07-06 | Monsanto Co | Process for making heavy duty liquid detergent compositions |
| US3729421A (en) * | 1970-08-04 | 1973-04-24 | C Gibson | Soap cone and holder |
| US3679592A (en) * | 1970-08-17 | 1972-07-25 | Monsanto Co | Cleansing and soil preventive composition |
Cited By (28)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4532063A (en) * | 1983-08-15 | 1985-07-30 | S. C. Johnson & Son, Inc. | Dissolvable bleach sheet |
| US4557852A (en) * | 1984-04-09 | 1985-12-10 | S. C. Johnson & Son, Inc. | Polymer sheet for delivering laundry care additive and laundry care product formed from same |
| US4797221A (en) * | 1985-09-12 | 1989-01-10 | S. C. Johnson & Son, Inc. | Polymer sheet for delivering laundry care additive and laundry care product formed from same |
| US20060127458A1 (en) * | 2004-12-15 | 2006-06-15 | Melba Kiser | Single use personal care sheet |
| WO2007034471A3 (en) * | 2005-09-26 | 2007-05-31 | Samuel Icht | Detergent printed film |
| US20080242572A1 (en) * | 2005-09-26 | 2008-10-02 | Samuel Icht | Detergent Printed Film |
| EP2226379A1 (en) * | 2009-03-02 | 2010-09-08 | Dizolve Group Corporation | Dissolvable laundry detergent sheet |
| US10894005B2 (en) | 2010-07-02 | 2021-01-19 | The Procter & Gamble Company | Detergent product and method for making same |
| US11944693B2 (en) | 2010-07-02 | 2024-04-02 | The Procter & Gamble Company | Method for delivering an active agent |
| US9163205B2 (en) | 2010-07-02 | 2015-10-20 | The Procter & Gamble Company | Process for making films from nonwoven webs |
| US9175250B2 (en) | 2010-07-02 | 2015-11-03 | The Procter & Gamble Company | Fibrous structure and method for making same |
| US9421153B2 (en) | 2010-07-02 | 2016-08-23 | The Procter & Gamble Company | Detergent product and method for making same |
| US12194118B2 (en) | 2010-07-02 | 2025-01-14 | The Procter & Gamble Company | Detergent product and method for making same |
| US9074305B2 (en) | 2010-07-02 | 2015-07-07 | The Procter & Gamble Company | Method for delivering an active agent |
| US8785361B2 (en) | 2010-07-02 | 2014-07-22 | The Procter & Gamble Company | Detergent product and method for making same |
| US11021812B2 (en) | 2010-07-02 | 2021-06-01 | The Procter & Gamble Company | Filaments comprising an ingestible active agent nonwoven webs and methods for making same |
| US11434586B2 (en) | 2010-07-02 | 2022-09-06 | The Procter & Gamble Company | Filaments comprising an active agent nonwoven webs and methods for making same |
| US11970789B2 (en) | 2010-07-02 | 2024-04-30 | The Procter & Gamble Company | Filaments comprising an active agent nonwoven webs and methods for making same |
| US11944696B2 (en) | 2010-07-02 | 2024-04-02 | The Procter & Gamble Company | Detergent product and method for making same |
| US10639825B2 (en) | 2014-02-06 | 2020-05-05 | Dizolve Group Corporation | Method and apparatus for making a laundry detergent sheet |
| US9464264B2 (en) | 2014-02-06 | 2016-10-11 | Dizolve Group Corp. | Method and apparatus for making a laundry detergent sheet |
| US12527727B2 (en) | 2017-01-27 | 2026-01-20 | The Procter & Gamble Company | Compositions in the form of dissolvable solid structures |
| US11679066B2 (en) | 2019-06-28 | 2023-06-20 | The Procter & Gamble Company | Dissolvable solid fibrous articles containing anionic surfactants |
| US11795417B2 (en) | 2020-02-24 | 2023-10-24 | Dizolve Group Corporation | Dissolvable sheet containing a cleaning active and method of making same |
| US11925698B2 (en) | 2020-07-31 | 2024-03-12 | The Procter & Gamble Company | Water-soluble fibrous pouch containing prills for hair care |
| US12403083B2 (en) | 2021-08-30 | 2025-09-02 | The Procter & Gamble Company | Dissolvable solid structure comprising first and second polymeric structurants |
| US12576013B2 (en) | 2021-12-17 | 2026-03-17 | The Procter & Gamble Company | Dissolvable solid fibrous shampoo articles containing salts |
| US12540238B2 (en) | 2022-03-10 | 2026-02-03 | The Procter & Gamble Company | Dissolvable solid structure having first and second layers |
Also Published As
| Publication number | Publication date |
|---|---|
| FR2240286A1 (enExample) | 1975-03-07 |
| DE2438052A1 (de) | 1975-02-20 |
| JPS5747239B2 (enExample) | 1982-10-07 |
| FR2240286B1 (enExample) | 1978-02-17 |
| CA1033257A (en) | 1978-06-20 |
| GB1437855A (en) | 1976-06-03 |
| JPS5039708A (enExample) | 1975-04-12 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| AS | Assignment |
Owner name: DOW CHEMICAL COMPANY, THE MIDLAND MICHIGAN 48640 A Free format text: ASSIGNMENT OF ASSIGNORS INTEREST.;ASSIGNOR:MORTON THIOKOL INC;REEL/FRAME:004354/0531 |
|
| AS | Assignment |
Owner name: DOWBRANDS INC., INDIANA Free format text: ASSIGNMENT OF ASSIGNORS INTEREST.;ASSIGNOR:DOW CHEMICAL COMPANY, THE;REEL/FRAME:005755/0625 Effective date: 19910619 |