US3904543A - Detergent film - Google Patents

Detergent film Download PDF

Info

Publication number
US3904543A
US3904543A US386343A US38634373A US3904543A US 3904543 A US3904543 A US 3904543A US 386343 A US386343 A US 386343A US 38634373 A US38634373 A US 38634373A US 3904543 A US3904543 A US 3904543A
Authority
US
United States
Prior art keywords
water
detergent
solution
parts
film
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US386343A
Other languages
English (en)
Inventor
James G Knighten
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
DowBrands Inc
ATK Launch Systems LLC
Original Assignee
Morton Norwich Products Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Morton Norwich Products Inc filed Critical Morton Norwich Products Inc
Priority to US386343A priority Critical patent/US3904543A/en
Priority to GB2913174A priority patent/GB1437855A/en
Priority to JP49075474A priority patent/JPS5747239B2/ja
Priority to CA206,384A priority patent/CA1033257A/en
Priority to FR7427310A priority patent/FR2240286B1/fr
Priority to DE2438052A priority patent/DE2438052A1/de
Application granted granted Critical
Publication of US3904543A publication Critical patent/US3904543A/en
Assigned to DOW CHEMICAL COMPANY, THE MIDLAND MICHIGAN 48640 A CORP OF DE reassignment DOW CHEMICAL COMPANY, THE MIDLAND MICHIGAN 48640 A CORP OF DE ASSIGNMENT OF ASSIGNORS INTEREST. Assignors: MORTON THIOKOL INC
Assigned to DOWBRANDS INC. reassignment DOWBRANDS INC. ASSIGNMENT OF ASSIGNORS INTEREST. Assignors: DOW CHEMICAL COMPANY, THE
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/06Powder; Flakes; Free-flowing mixtures; Sheets

Definitions

  • Still another object of this invention is the provision of a detergent in precursor form which substantially alleviates the above mentioned problems of the detergent trade.
  • Another object of this invention is to provide a deter gent composition that is safe to substantially allsurfaces in high concentrations for short periods of time if applied directly to a surface moistened with water.
  • a solution comprising water, a nonionic detergent of the class consisting of ethoxylated alkyl phenols, preferably an ethoxylated nonyl or octyl phenol containing from 9 to mols of ethylene oxide repeating units; a resin of the alkylene maleic anhydride type such as a methyl vinyl ether maleic anhydride copolymer or ethylene maleic anhydride copolymer, preferably the former; and a small amount of an alkaline agent such as an alkali hydroxide, preferaby sodium hydroxide is composed and briefly heated at elevated temperature, about F, for a short time period, about 30 minutes, during which interaction between the nonionic and the polymer occurs resulting in partial esterification of the carboxyl groups of the copolymer.
  • a nonionic detergent of the class consisting of ethoxylated alkyl phenols, preferably an ethoxylated nonyl or octyl phenol containing from
  • the mixture is allowed to cool; then cast upon a suitable surface and allowed to dry either spontaneously or by supplying hot air to the exposed surface.
  • suitable surface examples include glass, plastic treated surfaces such as polyethylene, polyvinyl chloride and Teflon.
  • the film prepared as just described can be of any desired thickness. It can be readily stripped from the receiving surface and cut to any desired dimension. For example, a film having a thickness of about 18 mils and an area of about 18 square inches when dissolved in one gallon of water provides an effective detergent solution.
  • a pliant, non-tacky, self-sustaining film having a water content of about 2% by weight and formed by casting upon a receptive surface to permit evaporation of water from a solution consisting of about 83 parts of water, 10 parts of an ethoxylated nonyl phenol having from 9l() mols. of ethylene oxide, 4 parts of methyl vinyl ether maleic anhydride copolymer, and about 3 parts of a 20% w/w sodium hydroxide solution; said solution being heated to about 195F. for about thirty minutes, then cooled to the point of clarity at which the pH is about 4.0-4.4.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Moulding By Coating Moulds (AREA)
  • Casting Or Compression Moulding Of Plastics Or The Like (AREA)
US386343A 1973-08-07 1973-08-07 Detergent film Expired - Lifetime US3904543A (en)

Priority Applications (6)

Application Number Priority Date Filing Date Title
US386343A US3904543A (en) 1973-08-07 1973-08-07 Detergent film
GB2913174A GB1437855A (en) 1973-08-07 1974-07-01 Detergent film
JP49075474A JPS5747239B2 (enExample) 1973-08-07 1974-07-03
FR7427310A FR2240286B1 (enExample) 1973-08-07 1974-08-06
CA206,384A CA1033257A (en) 1973-08-07 1974-08-06 Detergent film
DE2438052A DE2438052A1 (de) 1973-08-07 1974-08-07 Biegsame, selbsttragende folie zur herstellung von detergens-loesungen

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US386343A US3904543A (en) 1973-08-07 1973-08-07 Detergent film

Publications (1)

Publication Number Publication Date
US3904543A true US3904543A (en) 1975-09-09

Family

ID=23525200

Family Applications (1)

Application Number Title Priority Date Filing Date
US386343A Expired - Lifetime US3904543A (en) 1973-08-07 1973-08-07 Detergent film

Country Status (6)

Country Link
US (1) US3904543A (enExample)
JP (1) JPS5747239B2 (enExample)
CA (1) CA1033257A (enExample)
DE (1) DE2438052A1 (enExample)
FR (1) FR2240286B1 (enExample)
GB (1) GB1437855A (enExample)

Cited By (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4532063A (en) * 1983-08-15 1985-07-30 S. C. Johnson & Son, Inc. Dissolvable bleach sheet
US4557852A (en) * 1984-04-09 1985-12-10 S. C. Johnson & Son, Inc. Polymer sheet for delivering laundry care additive and laundry care product formed from same
US4797221A (en) * 1985-09-12 1989-01-10 S. C. Johnson & Son, Inc. Polymer sheet for delivering laundry care additive and laundry care product formed from same
US20060127458A1 (en) * 2004-12-15 2006-06-15 Melba Kiser Single use personal care sheet
WO2007034471A3 (en) * 2005-09-26 2007-05-31 Samuel Icht Detergent printed film
EP2226379A1 (en) * 2009-03-02 2010-09-08 Dizolve Group Corporation Dissolvable laundry detergent sheet
US8785361B2 (en) 2010-07-02 2014-07-22 The Procter & Gamble Company Detergent product and method for making same
US9074305B2 (en) 2010-07-02 2015-07-07 The Procter & Gamble Company Method for delivering an active agent
US9163205B2 (en) 2010-07-02 2015-10-20 The Procter & Gamble Company Process for making films from nonwoven webs
US9464264B2 (en) 2014-02-06 2016-10-11 Dizolve Group Corp. Method and apparatus for making a laundry detergent sheet
US11021812B2 (en) 2010-07-02 2021-06-01 The Procter & Gamble Company Filaments comprising an ingestible active agent nonwoven webs and methods for making same
US11434586B2 (en) 2010-07-02 2022-09-06 The Procter & Gamble Company Filaments comprising an active agent nonwoven webs and methods for making same
US11679066B2 (en) 2019-06-28 2023-06-20 The Procter & Gamble Company Dissolvable solid fibrous articles containing anionic surfactants
US11795417B2 (en) 2020-02-24 2023-10-24 Dizolve Group Corporation Dissolvable sheet containing a cleaning active and method of making same
US11925698B2 (en) 2020-07-31 2024-03-12 The Procter & Gamble Company Water-soluble fibrous pouch containing prills for hair care
US12403083B2 (en) 2021-08-30 2025-09-02 The Procter & Gamble Company Dissolvable solid structure comprising first and second polymeric structurants
US12527727B2 (en) 2017-01-27 2026-01-20 The Procter & Gamble Company Compositions in the form of dissolvable solid structures
US12540238B2 (en) 2022-03-10 2026-02-03 The Procter & Gamble Company Dissolvable solid structure having first and second layers
US12576013B2 (en) 2021-12-17 2026-03-17 The Procter & Gamble Company Dissolvable solid fibrous shampoo articles containing salts

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2925915C2 (de) * 1979-06-27 1982-04-15 Lee, Yong Hwa, 4000 Düsseldorf Verfahren zur Herstellung folienartig dünner Schaumseifenbänder sowie Anordnung und Vorrichtungen zur Durchführung des Verfahrens
GB2164339A (en) * 1984-09-11 1986-03-19 Ciba Geigy Ag Polymaleic anhydride derivatives

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US261897A (en) * 1882-08-01 Josef bankmann
US1648778A (en) * 1922-08-14 1927-11-08 David W Mitchell Book soap
US2356168A (en) * 1941-08-16 1944-08-22 Clarence W Mabley Soap leaf
US3328309A (en) * 1963-10-21 1967-06-27 Gen Aniline & Film Corp Stabilized liquid heavy duty detergent composition
US3359206A (en) * 1964-05-21 1967-12-19 Koppers Co Inc Floating soap
US3457176A (en) * 1964-10-16 1969-07-22 Monsanto Co Liquid detergent processes
US3591508A (en) * 1967-12-07 1971-07-06 Monsanto Co Process for making heavy duty liquid detergent compositions
US3679592A (en) * 1970-08-17 1972-07-25 Monsanto Co Cleansing and soil preventive composition
US3729421A (en) * 1970-08-04 1973-04-24 C Gibson Soap cone and holder

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US261897A (en) * 1882-08-01 Josef bankmann
US1648778A (en) * 1922-08-14 1927-11-08 David W Mitchell Book soap
US2356168A (en) * 1941-08-16 1944-08-22 Clarence W Mabley Soap leaf
US3328309A (en) * 1963-10-21 1967-06-27 Gen Aniline & Film Corp Stabilized liquid heavy duty detergent composition
US3359206A (en) * 1964-05-21 1967-12-19 Koppers Co Inc Floating soap
US3457176A (en) * 1964-10-16 1969-07-22 Monsanto Co Liquid detergent processes
US3591508A (en) * 1967-12-07 1971-07-06 Monsanto Co Process for making heavy duty liquid detergent compositions
US3729421A (en) * 1970-08-04 1973-04-24 C Gibson Soap cone and holder
US3679592A (en) * 1970-08-17 1972-07-25 Monsanto Co Cleansing and soil preventive composition

Cited By (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4532063A (en) * 1983-08-15 1985-07-30 S. C. Johnson & Son, Inc. Dissolvable bleach sheet
US4557852A (en) * 1984-04-09 1985-12-10 S. C. Johnson & Son, Inc. Polymer sheet for delivering laundry care additive and laundry care product formed from same
US4797221A (en) * 1985-09-12 1989-01-10 S. C. Johnson & Son, Inc. Polymer sheet for delivering laundry care additive and laundry care product formed from same
US20060127458A1 (en) * 2004-12-15 2006-06-15 Melba Kiser Single use personal care sheet
WO2007034471A3 (en) * 2005-09-26 2007-05-31 Samuel Icht Detergent printed film
US20080242572A1 (en) * 2005-09-26 2008-10-02 Samuel Icht Detergent Printed Film
EP2226379A1 (en) * 2009-03-02 2010-09-08 Dizolve Group Corporation Dissolvable laundry detergent sheet
US10894005B2 (en) 2010-07-02 2021-01-19 The Procter & Gamble Company Detergent product and method for making same
US11944693B2 (en) 2010-07-02 2024-04-02 The Procter & Gamble Company Method for delivering an active agent
US9163205B2 (en) 2010-07-02 2015-10-20 The Procter & Gamble Company Process for making films from nonwoven webs
US9175250B2 (en) 2010-07-02 2015-11-03 The Procter & Gamble Company Fibrous structure and method for making same
US9421153B2 (en) 2010-07-02 2016-08-23 The Procter & Gamble Company Detergent product and method for making same
US12194118B2 (en) 2010-07-02 2025-01-14 The Procter & Gamble Company Detergent product and method for making same
US9074305B2 (en) 2010-07-02 2015-07-07 The Procter & Gamble Company Method for delivering an active agent
US8785361B2 (en) 2010-07-02 2014-07-22 The Procter & Gamble Company Detergent product and method for making same
US11021812B2 (en) 2010-07-02 2021-06-01 The Procter & Gamble Company Filaments comprising an ingestible active agent nonwoven webs and methods for making same
US11434586B2 (en) 2010-07-02 2022-09-06 The Procter & Gamble Company Filaments comprising an active agent nonwoven webs and methods for making same
US11970789B2 (en) 2010-07-02 2024-04-30 The Procter & Gamble Company Filaments comprising an active agent nonwoven webs and methods for making same
US11944696B2 (en) 2010-07-02 2024-04-02 The Procter & Gamble Company Detergent product and method for making same
US10639825B2 (en) 2014-02-06 2020-05-05 Dizolve Group Corporation Method and apparatus for making a laundry detergent sheet
US9464264B2 (en) 2014-02-06 2016-10-11 Dizolve Group Corp. Method and apparatus for making a laundry detergent sheet
US12527727B2 (en) 2017-01-27 2026-01-20 The Procter & Gamble Company Compositions in the form of dissolvable solid structures
US11679066B2 (en) 2019-06-28 2023-06-20 The Procter & Gamble Company Dissolvable solid fibrous articles containing anionic surfactants
US11795417B2 (en) 2020-02-24 2023-10-24 Dizolve Group Corporation Dissolvable sheet containing a cleaning active and method of making same
US11925698B2 (en) 2020-07-31 2024-03-12 The Procter & Gamble Company Water-soluble fibrous pouch containing prills for hair care
US12403083B2 (en) 2021-08-30 2025-09-02 The Procter & Gamble Company Dissolvable solid structure comprising first and second polymeric structurants
US12576013B2 (en) 2021-12-17 2026-03-17 The Procter & Gamble Company Dissolvable solid fibrous shampoo articles containing salts
US12540238B2 (en) 2022-03-10 2026-02-03 The Procter & Gamble Company Dissolvable solid structure having first and second layers

Also Published As

Publication number Publication date
FR2240286A1 (enExample) 1975-03-07
DE2438052A1 (de) 1975-02-20
JPS5747239B2 (enExample) 1982-10-07
FR2240286B1 (enExample) 1978-02-17
CA1033257A (en) 1978-06-20
GB1437855A (en) 1976-06-03
JPS5039708A (enExample) 1975-04-12

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Legal Events

Date Code Title Description
AS Assignment

Owner name: DOW CHEMICAL COMPANY, THE MIDLAND MICHIGAN 48640 A

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST.;ASSIGNOR:MORTON THIOKOL INC;REEL/FRAME:004354/0531

AS Assignment

Owner name: DOWBRANDS INC., INDIANA

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST.;ASSIGNOR:DOW CHEMICAL COMPANY, THE;REEL/FRAME:005755/0625

Effective date: 19910619