US3903319A - Chemical nickel plating - Google Patents
Chemical nickel plating Download PDFInfo
- Publication number
- US3903319A US3903319A US323566A US32356673A US3903319A US 3903319 A US3903319 A US 3903319A US 323566 A US323566 A US 323566A US 32356673 A US32356673 A US 32356673A US 3903319 A US3903319 A US 3903319A
- Authority
- US
- United States
- Prior art keywords
- bath
- nickel
- plating
- set forth
- process set
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
- C23C18/31—Coating with metals
- C23C18/32—Coating with nickel, cobalt or mixtures thereof with phosphorus or boron
- C23C18/34—Coating with nickel, cobalt or mixtures thereof with phosphorus or boron using reducing agents
- C23C18/36—Coating with nickel, cobalt or mixtures thereof with phosphorus or boron using reducing agents using hypophosphites
Definitions
- the inven- 2,694,019 11 1954 Gutzeit 117 130 E also includes a method for Preventing the delmit 2,774,688 12/1956 Girard 117 130 E of nickel on heating and Containing equipment which 2,872,354 2/1959 Lee 117/130 E consists of connecting the equipment anodically to 21 2,893,929 7/1959 Schnable 204/32 S X small direct current.
- Chemical nickel plating of catalytic materials may be accomplished by treating such materials with a buffered aqueous solution containing a nickel salt and hypophosphite ion. This plating procedure is temperature sensitive and must normally be conducted just below the boiling point of the bath (90-l00C.), in order to achieve a high rate of nickel deposition. These high temperatures have a detrimental effect on the bath stability and result in wasted deposition of nickel on equipment used for heating and holding the solution.
- Nickel is deposited on the catalytic surface as a result of reduction of nickel cations by the hypophosphite reducing agent. This reduction results in the formation of orthophosphite ions as a by-product, which by-product eventually precipitates as the nickel salt as the plating reaction proceeds.
- the precipitate serves to accelerate decomposition of the plating bath by providing additional surfaces for the deposition of nickel.
- the precipitate is also objectionable in causing a rough and unsatisfactory nickel deposit on the catalytic surface.
- High hypophosphite ion concentrations, utilized in previous high speed baths, are responsible for an increased tendency toward formation of a nickel orthophosphite precipitate and also result in an increased consumption of reducing agent.
- Another object of the invention is to provide an improved process of the character described which employs a bath of the nickel cation-hypophosphite ion type which utilizes a low concentration of hypophosphite reducing agent.
- Another object of the invention is to provide an improved plating bath of the type described which contains a complexing and wetting agent as an additive.
- a further object of the invention is to provide an improved plating bath of the type described which contains a fluoride exaltant, succinates and lactates as exaltants, chelating agents and buffers, together with boric acid and ammonium hydroxide as buffers.
- Still another objective of the invention is to provide an improved process of the type described in which nickel is prevented from depositing on heating and containing equipment by application of a small direct current to the bath in such a way that the heating and containing equipment are connected anodically.
- the invention consists of the discovery of a new process for the chemical nickel plating of catalytic materials.
- the plating bath utilized in this process consists of an aqueous solution Containing nickel cations and a low concentration of hypophosphite ion together with a series of additives which include exaltants, chelating agents and buffers such as fluorides, succinates, lead salts, lactic acid, boric acid, and a complexing and wetting agent such as an alkylphenoxy(ethyleneoxy)ethanol.
- the bath is preferably adjusted to pH 55.5
- the invention also includes a method for preventing the deposit of nickel on heating and containing equipment which consists of connecting the equipment anodically to a small direct current.
- the composition of the bath is such that a nickel coating, containing 4-8% phosphorus, is deposited on the catalytic surface at a rate of 20-28 microns per hour for a new bath and l8-23 microns per hour for a maintained bath.
- the optimum load (parts to be plated) is within the range of -100 square inches of surface area per gallon of solution.
- Alkylphenoxypoly(ethyleneoxy)ethanols which have the following general structure, have been found to be particularly suitable:
- R represents one or more alkyl substitutents having from 5-18 carbon atoms and n is a number from 6 to 20 with an optimal value of 19.
- the complexing and wetting agent reduces the surface tension of the plating bath and permits a free evolution of hydrogen gas during the catalytic reduction process.
- the alkylphenoxypoly(ethyleneoxy)ethanols are particularly satisfactory in view of their ability to withstand high temperatures and their stability toward the reducing and acidic nature of the bath.
- a small direct current of 0.06-0.09 amp/cm may be applied with the equipment connected anodically in order to maintain constant passivation of the equipment.
- the pH was adjusted to a value of 5-5.5 with ammo nium hydroxide and plating was conducted at a temperature of 82C. This plating bath was utilized without application of an electric current and contains lead sulfate as an anti-catalyst retarder to maintain the rate of nickel deposition within optimum limits.
- the nickel deposit was bright and was applied at a rate of 20-28 microns/hour.
- the pH was adjusted to a value of 55.5 with ammonium hydroxide and plating was conducted at a temperature of 77-85C. This bath was operated with the application of a 0.06-0.09 amp/cm direct current with the heating and containing equipment connected anodically.
- the nickel deposit was bright and was applied at a rate of 20-28 microns/hour.
- R represents one or more alkyl substituents having from 5 to 18 carbon atoms and n is a number from 6 to 20 with an optimal value of 19.
- R represents one or more alkyl substituents which possess from 5 to 18 carbon atoms and n is a number from 6 to 20 with an optimal value of 19.
Landscapes
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Chemically Coating (AREA)
Abstract
A process for the chemical nickel plating of catalytic materials wherein the plating bath utilized in the process consists of an aqueous solution containing nickel cations and a low concentration of hypophosphite ion together with a series of additives which include fluorides, succinates, a lead salt, lactic acid, boric acid, and a complexing and wetting agent such as an alkylphenoxy(ethyleneoxy)ethanol and wherein the bath is adjusted to pH 5-5.5 with ammonium hydroxide and is operated at a temperature of 75*-85*C. The invention also includes a method for preventing the deposit of nickel on heating and containing equipment which consists of connecting the equipment anodically to a small direct current.
Description
United States Patent El-Mohamad Sept. 2, 1975 CHEMICAL NICKEL PLATING OTHER PUBLICATIONS [751 Inventor: Zlad Huntsfille IBM Tech. DiSCl. 131111., v61. 9, N0. 11, April 1967.
Kirk-Othmer, Encyclopedia Of Chem. Tech., 2nd Ed., [73] Assignee: GTE Automatic Electric 1969 pp. 533-536.
Laboratories Incorporated, Northlake, Ill. Primary ExaminerRalph S. Kendall [22] Filed: Jan. 15, 1973 l N 323 566 [57] ABSTRACT [2]] App O" A process for the chemical nickel plating of catalytic materials wherein the plating bath utilized in the process consists of an aqueous solution containing nickel 427/438 cations and a low concentration of hypophosphite ion [51] Int. Cl.2 together a eries of additives which include fluo- Field Of Search 117/130 E, 47 rides, succinates, a lead salt, lactic acid, boric acid,
1 18/620, 204/147 and a complexing and wetting agent such as an alkylphenoxy(ethyleneoxy)ethanol and wherein the bath is References Cited adjusted to pH 5-5.5 with ammonium hydroxide and UNITED STATES PATENTS is operated at a temperature of 7585C. The inven- 2,694,019 11 1954 Gutzeit 117 130 E also includes a method for Preventing the delmit 2,774,688 12/1956 Girard 117 130 E of nickel on heating and Containing equipment which 2,872,354 2/1959 Lee 117/130 E consists of connecting the equipment anodically to 21 2,893,929 7/1959 Schnable 204/32 S X small direct current.
3,485,725 l2/l969 Koretzky 117/130 E X 3,667,972 6/1972 Coll-Palagos 117 130 E x 9 Clams, N0 Drawlngs CHEMICAL NICKEL PLATING BACKGROUND OF THE INVENTION Chemical nickel plating of catalytic materials may be accomplished by treating such materials with a buffered aqueous solution containing a nickel salt and hypophosphite ion. This plating procedure is temperature sensitive and must normally be conducted just below the boiling point of the bath (90-l00C.), in order to achieve a high rate of nickel deposition. These high temperatures have a detrimental effect on the bath stability and result in wasted deposition of nickel on equipment used for heating and holding the solution.
Nickel is deposited on the catalytic surface as a result of reduction of nickel cations by the hypophosphite reducing agent. This reduction results in the formation of orthophosphite ions as a by-product, which by-product eventually precipitates as the nickel salt as the plating reaction proceeds. The precipitate serves to accelerate decomposition of the plating bath by providing additional surfaces for the deposition of nickel. The precipitate is also objectionable in causing a rough and unsatisfactory nickel deposit on the catalytic surface. High hypophosphite ion concentrations, utilized in previous high speed baths, are responsible for an increased tendency toward formation of a nickel orthophosphite precipitate and also result in an increased consumption of reducing agent.
OBJECTS OF THE INVENTION It is an object of the present invention to provide an improved chemical process of plating with nickel which can be utilized at the convenient and relatively low temperature of 7585C. without the sacrifice of a rapid rate of nickel deposition.
Another object of the invention is to provide an improved process of the character described which employs a bath of the nickel cation-hypophosphite ion type which utilizes a low concentration of hypophosphite reducing agent.
Another object of the invention is to provide an improved plating bath of the type described which contains a complexing and wetting agent as an additive.
A further object of the invention is to provide an improved plating bath of the type described which contains a fluoride exaltant, succinates and lactates as exaltants, chelating agents and buffers, together with boric acid and ammonium hydroxide as buffers.
Still another objective of the invention is to provide an improved process of the type described in which nickel is prevented from depositing on heating and containing equipment by application of a small direct current to the bath in such a way that the heating and containing equipment are connected anodically. Other objects will appear hereinafter.
BRIEF SUMMARY OF THE INVENTION The invention consists of the discovery ofa new process for the chemical nickel plating of catalytic materials. The plating bath utilized in this process consists of an aqueous solution Containing nickel cations and a low concentration of hypophosphite ion together with a series of additives which include exaltants, chelating agents and buffers such as fluorides, succinates, lead salts, lactic acid, boric acid, and a complexing and wetting agent such as an alkylphenoxy(ethyleneoxy)ethanol. The bath is preferably adjusted to pH 55.5
(e.g. with ammonium hydroxide) and is capable of being operated at a temperature of 85C.
The invention also includes a method for preventing the deposit of nickel on heating and containing equipment which consists of connecting the equipment anodically to a small direct current.
DETAILED DESCRIPTION OF THE INVENTION Utilization of a relatively low bath temperature of 7585C. affords an improved bath stability which can be further improved by use of a low concentration of hypophosphite ion. This is accomplished, without sacrifice of a high rate of nickel deposition, by the use of fluoride ion as an exaltant together with succinates and lactates as exaltants, chelating agents, and buffers. The bath is preferentially utilized at a pH of 5-5.5 which can be controlled by the use of materials such as boric acid and ammonium hydroxide. The composition of the bath is such that a nickel coating, containing 4-8% phosphorus, is deposited on the catalytic surface at a rate of 20-28 microns per hour for a new bath and l8-23 microns per hour for a maintained bath. The optimum load (parts to be plated) is within the range of -100 square inches of surface area per gallon of solution.
The high surface tension of the plating bath can result in nonuniform deposition of nickel and excessive pitting of the deposit. Addition of a complexing and wetting agent corrects this difficulty and results in the formation of a uniform, nonporous, nonpitted and bright nickel deposit. Alkylphenoxypoly(ethyleneoxy)ethanols, which have the following general structure, have been found to be particularly suitable:
where R represents one or more alkyl substitutents having from 5-18 carbon atoms and n is a number from 6 to 20 with an optimal value of 19. The complexing and wetting agent reduces the surface tension of the plating bath and permits a free evolution of hydrogen gas during the catalytic reduction process. The alkylphenoxypoly(ethyleneoxy)ethanols are particularly satisfactory in view of their ability to withstand high temperatures and their stability toward the reducing and acidic nature of the bath.
In order to prevent wasted nickel from depositing on heating and containing equipment, a small direct current of 0.06-0.09 amp/cm may be applied with the equipment connected anodically in order to maintain constant passivation of the equipment.
The best mode contemplated for the practice of this invention is illustrated by the following examples.
EXAMPLE I An aqueous plating bath possessing the following composition was utilized:
Nickel sulfate 37 g/l Sodium hypophosphite 20 g/] Sodium succinatc 21 g/l Sodium fluoride 5 g/l Boric acid l2 g/l -Continued Lactic acid 21 g/l Alkylphenoxypoly(ethyleneoxy)- ethanol ().25 ml/l Lead sulfate I ppm The pH was adjusted to a value of 5-5.5 with ammo nium hydroxide and plating was conducted at a temperature of 82C. This plating bath was utilized without application of an electric current and contains lead sulfate as an anti-catalyst retarder to maintain the rate of nickel deposition within optimum limits. The nickel deposit was bright and was applied at a rate of 20-28 microns/hour.
EXAMPLE [I An aqueous plating bath possessing the following composition was utilized:
Nickel sulfate 39 g/l Sodium hypophosphite l8 g/l Sodium succinate 18.5 g/l Sodium fluoride 5.6 g/l Boric acid 12 g/l Lactic acid 21 g/l Alkylphcnoxypoly(ethyeneoxy)- ethanol 0.25 ml/l The pH was adjusted to a value of 55.5 with ammonium hydroxide and plating was conducted at a temperature of 77-85C. This bath was operated with the application of a 0.06-0.09 amp/cm direct current with the heating and containing equipment connected anodically. The nickel deposit was bright and was applied at a rate of 20-28 microns/hour.
The invention is hereby claimed as follows:
1. The process of chemically plating a catalytic surface with nickel by treating the surface with an aqueous bath consisting essentially of a nickel salt, a hypophosphite, a complexing and wetting agent, a fluoride exaltant, a lead salt, succinates and lactates as exaltants, chelating agents and buffers, together with boric acid and ammonium hydroxide as buffers wherein the concentration of hypophosphite is approximately 0.l to 0.3 mole/liter and the nickel ion concentration is approximately 0.2 to 0.3 mole/liter.
2. The process set forth in claim 1, wherein the complexing and wetting agent is an alkylphenoxypoly(ethyleneoxy)ethanol having the following structure:
where R represents one or more alkyl substituents having from 5 to 18 carbon atoms and n is a number from 6 to 20 with an optimal value of 19.
3. The process set forth in claim 1, wherein the initial pH of the bath is in the approximate range of 5.0 to 5.5.
4. The process set forth in claim 1, wherein the plating bath is utilized at a temperature in the approximate range of 85C.
5. The process of chemically plating a catalytic surface with nickel by treating the surface with an aqueous bath consisting essentially of a nickel salt, a hypophosphite, a complexing and wetting agent, a fluoride exaltant, succinates and lactates as exaltants, chelating agents and buffers, together with boric acid and ammonium hydroxide as buffers, wherein the concentration of hypophosphite is in the approximate range of 0.1 to 0.3 mole/liter and the nickel ion concentration is in the approximate range of 0.2 to 0.3 mole/liter, and wherein a small direct current is applied to the bath with the plating equipment connected anodically.
6. The process set forth in claim 5, wherein the initial pH of the bath is in the approximate range of 5.0 to 5.5.
7. The process set forth in claim 5, wherein the complexing and wetting agent is an alkylphenoxypoly(ethylcneoxy)ethanol having the following structure:
where R represents one or more alkyl substituents which possess from 5 to 18 carbon atoms and n is a number from 6 to 20 with an optimal value of 19.
8. The process set forth in claim 5, wherein the plating bath is utilized at a temperature in the approximate range of 7585C.
9. The process set forth in claim 5, wherein the direct current applied to the bath is in the approximate range of 0.060.09 amp/cm?
Claims (9)
1. The process of chemically plating a catalytic surface with nickel by treating the surface with an aqueous bath consisting essentially of a nickel salt, a hypophosphite, a complexing and wetting agent, a fluoride exaltant, a lead salt, succinates and lactates as exaltants, chelating agents and buffers, together with boric acid and ammonium hydroxide as buffers wherein the concentration of hypophosphite is approximately 0.1 to 0.3 mole/liter and the nickel ion concentration is approximately 0.2 to 0.3 mole/liter.
2. The process set forth in claim 1, wherein the complexing and wetting agent is an alkylphenoxypoly(ethyleneoxy)ethanol having the following structure:
3. The process set forth in claim 1, wherein the initial pH of the bath is in the approximate range of 5.0 to 5.5.
4. The process set forth in claim 1, wherein the plating bath is utilized at a temperature in the approximate range of 75*-85*C.
5. THE PROCESS OF CHEMICALLY PLATING A CATALYTIC SURFACE WITH NICKE BY TREATING THE SURFACE WITH AN AQUEOUS BATH CONSISTING ESSENTIALLY OF A NICKEL SALT, A HYPOPHOSPHITE, A COMPLEXING AND WETTING AGENT, A FLUORIDE EXALTANT, SUCCINATES AND LACTATES AS EXALTANTS, CHELATING AGENTS AND BUFFERS, TOGETHER WITH BORIC ACID AND AMMONIUM HYDROXIDE AS BUFFERS, WHEREIN THE CONCENTRATION OF HYPOPHOSPHITE IS IN THEAPPROXIMATE RANGE OF 0.1 TO 0.3 MOLE/LITER AND THE NICKEL ION CONCENTRATION IS IN THE APPROXIMATE RANGE OF 0.2 TO 0.3 MOLE/LITER, AND WHEREIN A SMALL DIRECT CURRENT IS APPLIED TO THE BATH WITH THE PLATING EQUIPMENT CONNECTED ANODIACALLY.
6. The process set forth in claim 5, wherein the initial pH of the bath is in the approximate range of 5.0 to 5.5.
7. The process set forth in claim 5, wherein the complexing and wetting agent is an alkylphenoxypoly(ethyleneoxy)ethanol having the following structure:
8. The process set forth in claim 5, wherein the plating bath is utilized at a temperature in the approximate range of 75*-85*C.
9. The process set forth in claim 5, wherein the direct current applied to the bath is in the approximate range of 0.06-0.09 amp/cm2.
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US323566A US3903319A (en) | 1973-01-15 | 1973-01-15 | Chemical nickel plating |
CA185,297A CA1003283A (en) | 1973-01-15 | 1973-11-08 | Chemical nickel plating |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US323566A US3903319A (en) | 1973-01-15 | 1973-01-15 | Chemical nickel plating |
Publications (1)
Publication Number | Publication Date |
---|---|
US3903319A true US3903319A (en) | 1975-09-02 |
Family
ID=23259766
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US323566A Expired - Lifetime US3903319A (en) | 1973-01-15 | 1973-01-15 | Chemical nickel plating |
Country Status (2)
Country | Link |
---|---|
US (1) | US3903319A (en) |
CA (1) | CA1003283A (en) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4125642A (en) * | 1977-08-25 | 1978-11-14 | The United States Of America As Represented By The United States Department Of Energy | Method for conducting electroless metal-plating processes |
US4265940A (en) * | 1977-04-04 | 1981-05-05 | Fuji Photo Optical Co., Ltd. | Pressure applying rollers for instant photographic cameras and method of producing the same |
US4391841A (en) * | 1980-03-28 | 1983-07-05 | Kollmorgen Technologies Corporation | Passivation of metallic equipment surfaces in electroless copper deposition processes |
EP0109529A1 (en) * | 1982-10-22 | 1984-05-30 | Bayer Ag | Surface provided with a black metal coating |
WO2009046427A1 (en) * | 2007-10-05 | 2009-04-09 | Enthone Inc. | Method for galvanotechnical coating of substrate surfaces |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2694019A (en) * | 1952-04-23 | 1954-11-09 | Gen Am Transport | Processes of chemical nickel plating and baths therefor |
US2774688A (en) * | 1954-06-01 | 1956-12-18 | Robert J Girard | Nickel plating by chemical reduction |
US2872354A (en) * | 1954-12-31 | 1959-02-03 | Gen Am Transport | Processes of continuous chemical nickel plating |
US2893929A (en) * | 1955-08-03 | 1959-07-07 | Philco Corp | Method for electroplating selected regions of n-type semiconductive bodies |
US3485725A (en) * | 1965-10-08 | 1969-12-23 | Ibm | Method of increasing the deposition rate of electroless solutions |
US3667972A (en) * | 1970-06-11 | 1972-06-06 | Stauffer Chemical Co | Chemical nickel plating baths |
-
1973
- 1973-01-15 US US323566A patent/US3903319A/en not_active Expired - Lifetime
- 1973-11-08 CA CA185,297A patent/CA1003283A/en not_active Expired
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2694019A (en) * | 1952-04-23 | 1954-11-09 | Gen Am Transport | Processes of chemical nickel plating and baths therefor |
US2774688A (en) * | 1954-06-01 | 1956-12-18 | Robert J Girard | Nickel plating by chemical reduction |
US2872354A (en) * | 1954-12-31 | 1959-02-03 | Gen Am Transport | Processes of continuous chemical nickel plating |
US2893929A (en) * | 1955-08-03 | 1959-07-07 | Philco Corp | Method for electroplating selected regions of n-type semiconductive bodies |
US3485725A (en) * | 1965-10-08 | 1969-12-23 | Ibm | Method of increasing the deposition rate of electroless solutions |
US3667972A (en) * | 1970-06-11 | 1972-06-06 | Stauffer Chemical Co | Chemical nickel plating baths |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4265940A (en) * | 1977-04-04 | 1981-05-05 | Fuji Photo Optical Co., Ltd. | Pressure applying rollers for instant photographic cameras and method of producing the same |
US4125642A (en) * | 1977-08-25 | 1978-11-14 | The United States Of America As Represented By The United States Department Of Energy | Method for conducting electroless metal-plating processes |
US4391841A (en) * | 1980-03-28 | 1983-07-05 | Kollmorgen Technologies Corporation | Passivation of metallic equipment surfaces in electroless copper deposition processes |
EP0109529A1 (en) * | 1982-10-22 | 1984-05-30 | Bayer Ag | Surface provided with a black metal coating |
US4535032A (en) * | 1982-10-22 | 1985-08-13 | Bayer Aktiengesellschaft | Black-metallized substrate surfaces |
US4657786A (en) * | 1982-10-22 | 1987-04-14 | Bayer Aktiengesellschaft | Black-metallized substrate surfaces |
WO2009046427A1 (en) * | 2007-10-05 | 2009-04-09 | Enthone Inc. | Method for galvanotechnical coating of substrate surfaces |
Also Published As
Publication number | Publication date |
---|---|
CA1003283A (en) | 1977-01-11 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US2532283A (en) | Nickel plating by chemical reduction | |
SE7907373L (en) | PROCEDURE KIT FOR CONTINUOUS ELECTROPHERIC COPPER PREPARATION UNDER THE USE OF A HYPOPHOSPHITE REDUCING AGENT IN THE PRESENT OF COBOLK AND NICKELION AND COMPOSITION FOR EXERCISE OF PROCEDURAL KIT | |
US3032436A (en) | Method and composition for plating by chemical reduction | |
US3925170A (en) | Method and composition for producing bright palladium electrodepositions | |
US2658841A (en) | Process of chemical nickel plating and bath therefor | |
US2532284A (en) | Cobalt plating by chemical reduction | |
US2935425A (en) | Chemical nickel plating processes and baths therefor | |
US3264199A (en) | Electroless plating of metals | |
US2929742A (en) | Electroless deposition of nickel | |
KR880006380A (en) | Manufacturing method of electroless copper plating solution and electroless plating copper | |
US3140188A (en) | Bath compositions for chemical plating of metals containing boron nitrogen compounds nd an organic solubilizing compound | |
GB2053284A (en) | Palladium alloy plate | |
US3024134A (en) | Nickel chemical reduction plating bath and method of using same | |
US3903319A (en) | Chemical nickel plating | |
US4341846A (en) | Palladium boron plates by electroless deposition alloy | |
US3178311A (en) | Electroless plating process | |
US4279951A (en) | Method for the electroless deposition of palladium | |
US3617343A (en) | Process for the chemical nickel-plating of nonmetallic articles | |
US2819187A (en) | Chemical nickel plating processes and baths therefor | |
US2916401A (en) | Chemical reduction nickel plating bath | |
US3775265A (en) | Method of plating copper on aluminum | |
US3274022A (en) | Palladium deposition | |
US3697296A (en) | Electroless gold plating bath and process | |
US3416955A (en) | Electroless cobalt plating bath | |
US3198659A (en) | Thin nickel coatings |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
AS | Assignment |
Owner name: AG COMMUNICATION SYSTEMS CORPORATION, 2500 W. UTOP Free format text: ASSIGNMENT OF ASSIGNORS INTEREST.;ASSIGNOR:GTE COMMUNICATION SYSTEMS CORPORATION;REEL/FRAME:005060/0501 Effective date: 19881228 |