US3902900A - Intermetallic compound materials - Google Patents
Intermetallic compound materials Download PDFInfo
- Publication number
- US3902900A US3902900A US256026A US25602672A US3902900A US 3902900 A US3902900 A US 3902900A US 256026 A US256026 A US 256026A US 25602672 A US25602672 A US 25602672A US 3902900 A US3902900 A US 3902900A
- Authority
- US
- United States
- Prior art keywords
- intermetallic compound
- nickel
- compound material
- chromium
- zirconium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000463 material Substances 0.000 title claims abstract description 35
- 229910000765 intermetallic Inorganic materials 0.000 title claims abstract description 29
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 56
- 239000011651 chromium Substances 0.000 claims abstract description 28
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 28
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims abstract description 27
- 229910052804 chromium Inorganic materials 0.000 claims abstract description 27
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 26
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 26
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 24
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims abstract description 24
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 24
- 229910052726 zirconium Inorganic materials 0.000 claims abstract description 24
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims abstract description 23
- 229910052796 boron Inorganic materials 0.000 claims abstract description 23
- 229910017052 cobalt Inorganic materials 0.000 claims abstract description 23
- 239000010941 cobalt Substances 0.000 claims abstract description 23
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims abstract description 23
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims abstract description 21
- 229910052750 molybdenum Inorganic materials 0.000 claims abstract description 21
- 239000011733 molybdenum Substances 0.000 claims abstract description 21
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 19
- 239000010936 titanium Substances 0.000 claims abstract description 19
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 19
- 229910052715 tantalum Inorganic materials 0.000 claims abstract description 18
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000010955 niobium Substances 0.000 claims abstract description 16
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims abstract description 16
- 229910052721 tungsten Inorganic materials 0.000 claims abstract description 16
- 239000010937 tungsten Substances 0.000 claims abstract description 16
- 229910052758 niobium Inorganic materials 0.000 claims abstract description 15
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000000470 constituent Substances 0.000 abstract description 8
- 239000004411 aluminium Substances 0.000 abstract description 5
- 239000000203 mixture Substances 0.000 abstract description 5
- 238000000034 method Methods 0.000 abstract description 4
- 238000002844 melting Methods 0.000 abstract description 3
- 230000008018 melting Effects 0.000 abstract description 3
- 239000011573 trace mineral Substances 0.000 abstract description 3
- 235000013619 trace mineral Nutrition 0.000 abstract description 3
- 229910045601 alloy Inorganic materials 0.000 description 11
- 239000000956 alloy Substances 0.000 description 11
- 150000001875 compounds Chemical class 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 229910020630 Co Ni Inorganic materials 0.000 description 1
- 229910001005 Ni3Al Inorganic materials 0.000 description 1
- 238000005275 alloying Methods 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910001092 metal group alloy Inorganic materials 0.000 description 1
- PXHVJJICTQNCMI-OUBTZVSYSA-N nickel-60 atom Chemical compound [60Ni] PXHVJJICTQNCMI-OUBTZVSYSA-N 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 230000000750 progressive effect Effects 0.000 description 1
- 239000003870 refractory metal Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C19/00—Alloys based on nickel or cobalt
- C22C19/007—Alloys based on nickel or cobalt with a light metal (alkali metal Li, Na, K, Rb, Cs; earth alkali metal Be, Mg, Ca, Sr, Ba, Al Ga, Ge, Ti) or B, Si, Zr, Hf, Sc, Y, lanthanides, actinides, as the next major constituent
Definitions
- An intermetallic compound material which may be produced by standard vacuum melting techniques, comprises two principal groups of constituents of which a first group includes nickel and at least one of the elements chromium, cobalt, molybdenum and tungsten within the range 72 to 83 atomic per cent, and the second group includes aluminium in combination with at least one of the elements titanium, niobium and tantalum, the material containing the constituents in the proportions, by atomic percentage,
- first group of constituents 72 to 83 second group of constituents 17 to 28 One preferred composition of the intermetallic compound material contains elements of the said first and second groups in the following ranges specified below, in atomic per cent,
- the intermetallic compound material may contain carbon, boron, and zirconium as trace elements.
- This invention relates to intermetallic compound ma- 2 melt is fully degassed. chromium and any refractory metals are added under partial pressure of argon. Aluminum, titanium and zirconium are then added under vacuum and the metal cast into ingot form. Conterials and in particular to metal alloys having a base of 5 vcntional casting techniques have produced materials tri-nickel aluminide (Ni Al). having acceptable high temperature strengths and due- The majority of high temperature structural compotilities.
- An intermetallic compound material according to the g/ with a Similar melting Point to V197- Its tensile invention comprises two principal groups of constitund ep/ pture prop rties are Shown in Tables V ents of which one group includes nickel and one or and VI respectlvelymore of the elements chromium, cobalt, molybdenum TABLE 1] and tungsten within the range 72 to 83 atomic per cent, T V197 and the second group includes aluminium and one or properties ijnidirecfionany more of the elements titanium, n1ob1um and tantalum Test conventionally cast solidified temper- UTS (tsi) 71 elong- UTS (tsi) "/1 elongw1th1n the range 17 to 2 8 atomlc per cent.
- const1tuents are m the followmg 20C 50 3 56 7 ranges (spec1fied 1n atom1c per cent).
- Unidirectionally cast solidified Additional trace elements are 0.05 to 0.5 carbon, st nditions ife I liife q i 0.01 to 0.1 boron, and 0.01 to 0.2 zirconium (all i r) e r) ic cenm es 19 151 900C 37 27 atom g d t l I din to the 8 mi 1000C 17 8 50 65 lntermeta 1c compoun ma er1a s accor g 2 Si 50C
- An intermetallic compound material composed of in atomic percent. about 64.7 nickel. 3.7 chromium. 6.9 cobalt, 1.3 molybdenum. 17.2 aluminum, 5.9 titanium, 0.2 carbon. 0.05 boron, and 0.05 zirconium.
- An intermctallic compound material composed of in atomic percent, about 64.2 nickel. 3.3 chromium. 7.1 cobalt, 0.8 molybdenum. 0.4 tungsten, 19.0 aluminum, 2.3 titanium, l.3 niobium, 1.3 tantalum, 0.2 carbon, 0.05 boron, and 0.05 zirconium.
- An intermetallic compound material composed of in atomic percent, about 62.8 nickel, 3.2 chromium, 7.3 cobalt. 0.7 molybdenum, 0.4 tungsten, 20.2 aluminum, 1.1 titanium, 2.1 niobium, 1.9 tantalum, 0.2 carbon, 0.05 boron. and 0.05 zirconium.
- An intermetallic compound material composed of in atomic percent, about 64.5 nickel, 3.4 chromium, 7.2 cobalt, 0.7 molybdenum, 0.5 tungsten, 18.0 aluminum, 3.7 titanium, 0.8 niobium, 0.9 tantalum, 0.2 carbon, 0.05 boron, and 0.05 zirconium.
- An intermetallic compound material composed of in atomic percent, about 61.5 nickel, 5.1 chromium, 7.9 cobalt, 1.8 tungsten, 19.9 aluminum, 3.5 tantalum, 02 carbon, 0.05 boron, and 0.05 zirconium.
- An intermetallic compound material composed of in atomic percent, about 62.9 nickel, 2.8 chromium, 6.5 cobalt, 1.0 molybdenum, 21.1 aluminum, 5.4 tantalum, 0.2 carbon, 0.05 boron, and 0.05 zirconium.
- An intermetallic compound material composed of in atomic percent, about 64.8 nickel. 3.2 chromium, 6.8 cobalt, l.l molybdenum, 19.0 aluminum, 4.8 niobium 0.2 carbon, 0.05 boron, and 0.05 zirconium.
- An intermctallic compound material composed of in atomic percent, about 60.7 nickel, 4.0 chromium, 10.5 cobalt, 0.1 molybdenum, 13.7 aluminum, 10.7 titanium, 0.2 carbon. 0.05 boron, and 0.05 zirconium.
- An intermetallic compound material composed of in atomic percent, about 71.6 nickel, 4.0 chromium, l.l molybdenum, 18.9 aluminum, 2.l titanium, 2.0 niobium, 0.2 carbon, 0.05 boron, and 0.05 zirconium.
- An intermctallic compound material composed of in atomic percent, about 64.6 nickel, 3.9 chromium, 7.1 cobalt, 1.0 tungsten, 19.5 aluminum, 3.6 tantalum,
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Turbine Rotor Nozzle Sealing (AREA)
- Manufacture Of Alloys Or Alloy Compounds (AREA)
- Powder Metallurgy (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US432392A US3922168A (en) | 1971-05-26 | 1974-01-10 | Intermetallic compound materials |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB1715071A GB1381859A (en) | 1971-05-26 | 1971-05-26 | Trinickel aluminide base alloys |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US3902900A true US3902900A (en) | 1975-09-02 |
Family
ID=10090166
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US256026A Expired - Lifetime US3902900A (en) | 1971-05-26 | 1972-05-23 | Intermetallic compound materials |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US3902900A (OSRAM) |
| JP (1) | JPS5549144B1 (OSRAM) |
| DE (1) | DE2225280A1 (OSRAM) |
| FR (1) | FR2139080B1 (OSRAM) |
| GB (1) | GB1381859A (OSRAM) |
| IT (1) | IT958061B (OSRAM) |
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4478791A (en) * | 1982-11-29 | 1984-10-23 | General Electric Company | Method for imparting strength and ductility to intermetallic phases |
| US4492672A (en) * | 1982-04-19 | 1985-01-08 | The United States Of America As Represented By The Secretary Of The Navy | Enhanced microstructural stability of nickel alloys |
| US4518442A (en) * | 1981-11-27 | 1985-05-21 | United Technologies Corporation | Method of producing columnar crystal superalloy material with controlled orientation and product |
| US4530727A (en) * | 1982-02-24 | 1985-07-23 | The United States Of America As Represented By The Department Of Energy | Method for fabricating wrought components for high-temperature gas-cooled reactors and product |
| US4609528A (en) * | 1985-10-03 | 1986-09-02 | General Electric Company | Tri-nickel aluminide compositions ductile at hot-short temperatures |
| US4613480A (en) * | 1985-10-03 | 1986-09-23 | General Electric Company | Tri-nickel aluminide composition processing to increase strength |
| US4613368A (en) * | 1985-10-03 | 1986-09-23 | General Electric Company | Tri-nickel aluminide compositions alloyed to overcome hot-short phenomena |
| US4650519A (en) * | 1985-10-03 | 1987-03-17 | General Electric Company | Nickel aluminide compositions |
| FR2588573A1 (fr) * | 1985-10-11 | 1987-04-17 | Us Energy | Aluminiures de nickel et aluminiures de nickel-fer pour l'utilisation dans des environnements oxydants |
| US4676829A (en) * | 1985-10-03 | 1987-06-30 | General Electric Company | Cold worked tri-nickel aluminide alloy compositions |
| EP0287808A1 (de) * | 1987-04-10 | 1988-10-26 | Vacuumschmelze GmbH | Nickelbasis-Lot für Hochtemperatur-Lötverbindungen |
| US6238620B1 (en) * | 1999-09-15 | 2001-05-29 | U.T.Battelle, Llc | Ni3Al-based alloys for die and tool application |
| US6736442B2 (en) * | 2001-11-30 | 2004-05-18 | Collins & Aikman Products & Co. | Floor coverings for vehicles having integrated air and lighting distribution |
| CN102011195A (zh) * | 2010-11-23 | 2011-04-13 | 北京科技大学 | 一种定向凝固高铌钛铝合金单晶的制备方法 |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0009831B1 (fr) * | 1978-07-28 | 1984-01-18 | Aldo Polidoro | Brûleur atmosphérique à gaz avec des groupes de fentes de passage du mélange gaz combustible-air comburant |
| US4961905A (en) * | 1988-12-13 | 1990-10-09 | United Technologies Corporation | Nickel aluminide materials having toughness and ductility at low temperatures |
| US5207846A (en) * | 1989-04-10 | 1993-05-04 | General Electric Company | Tantalum-containing superalloys |
| AU624463B2 (en) * | 1989-04-10 | 1992-06-11 | General Electric Company | Tantalum-containing superalloys |
| US5338379A (en) * | 1989-04-10 | 1994-08-16 | General Electric Company | Tantalum-containing superalloys |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3617397A (en) * | 1969-02-19 | 1971-11-02 | United Aircraft Corp | Cast nickel-base alloy |
| US3653987A (en) * | 1970-06-01 | 1972-04-04 | Special Metals Corp | Nickel base alloy |
| US3677835A (en) * | 1970-10-16 | 1972-07-18 | United Aircraft Corp | Homogeneous nickel-base superalloy castings |
| US3767479A (en) * | 1972-02-14 | 1973-10-23 | Gen Electric | Multicomponent eutectics for high temperature applications |
-
1971
- 1971-05-26 GB GB1715071A patent/GB1381859A/en not_active Expired
-
1972
- 1972-05-23 US US256026A patent/US3902900A/en not_active Expired - Lifetime
- 1972-05-24 DE DE19722225280 patent/DE2225280A1/de not_active Withdrawn
- 1972-05-25 FR FR727218764A patent/FR2139080B1/fr not_active Expired
- 1972-05-25 IT IT50493/72A patent/IT958061B/it active
- 1972-05-26 JP JP5240872A patent/JPS5549144B1/ja active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3617397A (en) * | 1969-02-19 | 1971-11-02 | United Aircraft Corp | Cast nickel-base alloy |
| US3653987A (en) * | 1970-06-01 | 1972-04-04 | Special Metals Corp | Nickel base alloy |
| US3677835A (en) * | 1970-10-16 | 1972-07-18 | United Aircraft Corp | Homogeneous nickel-base superalloy castings |
| US3767479A (en) * | 1972-02-14 | 1973-10-23 | Gen Electric | Multicomponent eutectics for high temperature applications |
Cited By (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4518442A (en) * | 1981-11-27 | 1985-05-21 | United Technologies Corporation | Method of producing columnar crystal superalloy material with controlled orientation and product |
| US4530727A (en) * | 1982-02-24 | 1985-07-23 | The United States Of America As Represented By The Department Of Energy | Method for fabricating wrought components for high-temperature gas-cooled reactors and product |
| US4492672A (en) * | 1982-04-19 | 1985-01-08 | The United States Of America As Represented By The Secretary Of The Navy | Enhanced microstructural stability of nickel alloys |
| US4478791A (en) * | 1982-11-29 | 1984-10-23 | General Electric Company | Method for imparting strength and ductility to intermetallic phases |
| US4676829A (en) * | 1985-10-03 | 1987-06-30 | General Electric Company | Cold worked tri-nickel aluminide alloy compositions |
| US4609528A (en) * | 1985-10-03 | 1986-09-02 | General Electric Company | Tri-nickel aluminide compositions ductile at hot-short temperatures |
| US4613480A (en) * | 1985-10-03 | 1986-09-23 | General Electric Company | Tri-nickel aluminide composition processing to increase strength |
| US4613368A (en) * | 1985-10-03 | 1986-09-23 | General Electric Company | Tri-nickel aluminide compositions alloyed to overcome hot-short phenomena |
| US4650519A (en) * | 1985-10-03 | 1987-03-17 | General Electric Company | Nickel aluminide compositions |
| FR2588573A1 (fr) * | 1985-10-11 | 1987-04-17 | Us Energy | Aluminiures de nickel et aluminiures de nickel-fer pour l'utilisation dans des environnements oxydants |
| NL8602570A (nl) * | 1985-10-11 | 1987-05-04 | Us Energy | Nikkel-aluminiumlegering. |
| EP0287808A1 (de) * | 1987-04-10 | 1988-10-26 | Vacuumschmelze GmbH | Nickelbasis-Lot für Hochtemperatur-Lötverbindungen |
| US4900638A (en) * | 1987-04-10 | 1990-02-13 | Vacuumschmelze Gmbh | Nickel-base solder for high-temperature solder joints |
| US6238620B1 (en) * | 1999-09-15 | 2001-05-29 | U.T.Battelle, Llc | Ni3Al-based alloys for die and tool application |
| US6736442B2 (en) * | 2001-11-30 | 2004-05-18 | Collins & Aikman Products & Co. | Floor coverings for vehicles having integrated air and lighting distribution |
| CN102011195A (zh) * | 2010-11-23 | 2011-04-13 | 北京科技大学 | 一种定向凝固高铌钛铝合金单晶的制备方法 |
| CN102011195B (zh) * | 2010-11-23 | 2012-06-06 | 北京科技大学 | 一种定向凝固高铌钛铝合金单晶的制备方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| FR2139080A1 (OSRAM) | 1973-01-05 |
| DE2225280A1 (de) | 1972-12-07 |
| JPS5549144B1 (OSRAM) | 1980-12-10 |
| GB1381859A (en) | 1975-01-29 |
| FR2139080B1 (OSRAM) | 1973-07-13 |
| IT958061B (it) | 1973-10-20 |
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