US3902425A - Gas generator device within an enclosure - Google Patents

Gas generator device within an enclosure Download PDF

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Publication number
US3902425A
US3902425A US413423A US41342373A US3902425A US 3902425 A US3902425 A US 3902425A US 413423 A US413423 A US 413423A US 41342373 A US41342373 A US 41342373A US 3902425 A US3902425 A US 3902425A
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United States
Prior art keywords
envelope
gas
liquid
enclosure
reactant liquid
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Expired - Lifetime
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US413423A
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English (en)
Inventor
Bernard J Kurtzemann
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Etat Francais
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Etat Francais
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Publication of US3902425A publication Critical patent/US3902425A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B63SHIPS OR OTHER WATERBORNE VESSELS; RELATED EQUIPMENT
    • B63CLAUNCHING, HAULING-OUT, OR DRY-DOCKING OF VESSELS; LIFE-SAVING IN WATER; EQUIPMENT FOR DWELLING OR WORKING UNDER WATER; MEANS FOR SALVAGING OR SEARCHING FOR UNDERWATER OBJECTS
    • B63C9/00Life-saving in water
    • B63C9/08Life-buoys, e.g. rings; Life-belts, jackets, suits, or the like
    • B63C9/18Inflatable equipment characterised by the gas-generating or inflation device
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J7/00Apparatus for generating gases
    • B01J7/02Apparatus for generating gases by wet methods

Definitions

  • lr- 9/321 vice can be used to expel water contained in ballast 724179 3/1903 Goldstemm 9/324 tanks of submarines, or to inflate inflation balloons, 867 966 10/1907 FUCI'IS 1 atmospheric balloons, or the 923,801 6/1909 Bargar 9/321 1.014.546 l/19l2 Wich 9/323 7 Claims, 2 Drawing Flgures GAS GENERATOR DEVICE WITHIN AN ENCLOSURE BACKGROUND OF THE INVENTION
  • the present invention relates to a device for generation of gas by reaction of a liquid with a solid or another liquid.
  • the field involved is that of production of gas in an enclosure, which may be inflatable, or an enclosure that is to be made floatable. e.g. ballast tank, submerged buoy or inflatable balloon.
  • the water contained in the ballast tank can be driven out by gas compressed at a pressure above the hydrostatic pressure that prevails at the submersion depth.
  • This compressed gas may be furnished by receptacles filled with a compressed gas at higher pressure, which is expanded.
  • Such arrangements are heavy and bulky.
  • a second method consists in producing a release of gas from a reaction of a liquid or solid material that occupies little space.
  • hot gas generators employing propellants. These generators require an envelope that is resistent to immersion pressure in case of submarine use, and to high internal pressure.
  • generators using propellants release hot gases that may entail serious difficulties, namely the possibility of corroding certain temperature sensitive apparatus or materials, eg joints made of rubber or elastomeric materials.
  • An object of the present invention is to develop a gas generator intended to fill an enclosure with gas, the device being of low bulk, light in weight and inexpensive, releasing a considerable amount of gas per unit of weight, and readily remote-controlled, and able to function under very high pressures.
  • the envelope is filled with a liquid that does not react with the solid or liquid material.
  • the solid or liquid material is preferably a calcium or lithium hydride which reacts with water, producing a release of hydrogen.
  • the liquid that fills the envelope may be a mineral oil or petrolatum, for example: these substances do not react on calcium or lithium hydride.
  • said envelope contains. in addition, an explosive charge, and means are provided for remote control of the detonation of said charge, to cause tearing of the envelope.
  • the invention is thus a new product constituted by a gas generator for filling an enclosure.
  • the generator is very light and of little bulk. In fact, the ratio between the weight and volume of the solid or liquid product on the one hand and the volume of gas obtained on the other is very low, and the supplementary weight and bulk introduced by an entirely flexible envelope are negligible. Thus 0.6 liters of solid carbide release 1000 liters of gas at atmospheric pressure.
  • the generator can operate under very high pressures, of several hundred bars, corresponding to immersion to several thousand meters.
  • the flexible envelope transmits the hydrostatic pressures integrally. It is not therefore subject to any constraints, and it can tolerate very high pressures.
  • the envelope is filled with a liquid, e.g. petrolatum.
  • the remote control of the start of release of gas is readily effected by tearing the envelope.
  • the firing of an explosive charge is a preferred means for effecting this telecommand, because there are many conventional ways to trigger a pyrotechnic charge either by electric conductors, by electromagnetic, or acoustic signals.
  • the gas release is produced very rapidly, as soon as the carbide is put into contact with water, which allows triggering an operation at a precise instant.
  • the generator of the invention can be used for inflation of atmospheric balloons because of its lightness and because it releases hydrogen, which is lighter than air.
  • Generators of the invention can be made inexpensively, which makes it possible to use them in applications that do not require large volumes of gas, e.g. for inflation of buoys, inflation floats or atmospheric balloons.
  • FIG. I is a diagrammatic view in section of a device of the invention, placed in a water-filled enclosure.
  • FIG. 2 is a diagrammatic view in section of a device of the invention, attached to an inflatable balloon.
  • FIG. 1 shows an enclosure 1 filled with water, e.g. submarine ballast, a buoy, a tank or a bell. This enclosure is submerged and presents at the base at least one opening 6 with a grid 7 across which it communicates with the medium that surrounds it.
  • water e.g. submarine ballast, a buoy, a tank or a bell.
  • This enclosure is submerged and presents at the base at least one opening 6 with a grid 7 across which it communicates with the medium that surrounds it.
  • a device of the invention intended to produce a release of gas at the desired time in enclosure 1, forming a bubble in the upper part and modifying the buoyancy of enclosure 1.
  • the device of the invention is shown on a scale that is considerably larger than that of enclosure 1.
  • the device of the invention comprises a sealed envelope 2 which is flexible and which may be torn, containing a solid or liquid material, eg calcium or lithium hydride 3, bathed in petrolatum 4.
  • a solid or liquid material eg calcium or lithium hydride 3, bathed in petrolatum 4.
  • envelope 2 also contains an explosive charge 5, it can be fired at a distance.
  • FIG. 2 shows another application.
  • a device of the invention is hooked to a submerged inflatable balloon 8, eg an inflation balloon for floating a submerged body.
  • the device of the invention serves to inflate balloon 8 at a specific moment, by remote-controlled inflation.
  • the device comprises a reaction chamber 9 furnished in its lower part with an opening 10 that is in communication with the aqueous medium, and in the upper part with openings 11 for passage of gases which communicate with the interior of balloon 8.
  • Chamber 9 is filled with water.
  • a closed envelope l3 sealed at its two ends by diaphragms 14a and 1412, which are readily torn.
  • Envelope 13 if filled with petrolatum 15, in which there are immersed particles of calcium or lithium hydride l6, and explosive charges 17a and 17b, furnished with a remote-controlled triggering device, acting for instance by means of acoustic waves.
  • a device similar to that of FIG. 2 can be used to inflate atmospheric balloons.
  • a device of the invention can be utilized to drive out water contained in submarine ballast tanks as well as in a reservoir, buoy or submerged bell, or to inflate submarine inflation balloons or atompsheric balloons, this listing not being limitative.
  • a gas generator device for an enclosure comprising a sealed, flexible, deformable envelope which, in
  • a solid gas generating material for releasing a gas when in contact with the reactant liquid
  • said envelope further containing a nonreactant liquid and means for tearing said envelope at a desired time so as to put said solid material into contact with said reactant liquid to release said gas into the enclosure, said envelope tearing means comprising an explosive charge and said device further including means for providing remote-controlled denotation of said charge to thereby cause tearing of said envelope.
  • a device as in claim I wherein said non-reactant liquid in the envelope comprises a mineral oil.
  • said deformable envelope comprises a pouch.
  • a gas generating device comprising a reaction chamber furnished in its lower part with an opening for the passage of a liquid and in its upper part with an orifice for the passage of a gas, an enclosure surmounted above said reaction chamber positioned to receive gas from said reaction chamber, a sealed, flexible deformable envelope inside said reaction chamber which, in use, is surrounded by a reactant liquid which enters said chamber through said opening and inside of which is disposed a solid gas generating material for releasing a gas when in contact with the reactant liquid, said envelope further containing a non-reactant liquid and means for tearing said envelope at a desired time, to put said solid material into' contact with the liquid in said reaction chamber to release said gas through said orifice into said enclosure, said envelope tearing means comprising an explosive charge, and said device further including means for providing remote-controlled detonation of said charge to thereby cause tearing of said envelope.
  • a gas generator device for an enclosure comprising a sealed, flexible, deformable envelope which, in use, is surrounded by a high pressure reactant liquid and inside of which is disposed a solid gas generating material for releasing a gas when in contact with the reactant liquid, said envelope further containing a nonreactant liquid, said device further comprising means for tearing said envelope at a desired time so as to put said liquid material into contact with said reactant liquid to release said gas into the enclosure, said envelope tearing means comprising an explosive charge and said device further including means for providing remotecontrolled denotation of said charge to thereby cause tearing of said envelope.

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Ocean & Marine Engineering (AREA)
  • Feeding, Discharge, Calcimining, Fusing, And Gas-Generation Devices (AREA)
  • Toys (AREA)
US413423A 1972-11-23 1973-11-07 Gas generator device within an enclosure Expired - Lifetime US3902425A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR7241588A FR2207885B1 (es) 1972-11-23 1972-11-23

Publications (1)

Publication Number Publication Date
US3902425A true US3902425A (en) 1975-09-02

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Application Number Title Priority Date Filing Date
US413423A Expired - Lifetime US3902425A (en) 1972-11-23 1973-11-07 Gas generator device within an enclosure

Country Status (6)

Country Link
US (1) US3902425A (es)
CA (1) CA1023134A (es)
FR (1) FR2207885B1 (es)
GB (1) GB1425590A (es)
IT (1) IT998890B (es)
NL (1) NL7315920A (es)

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4929214A (en) * 1987-11-02 1990-05-29 Liebermann Ron B Inflatable enclosure and means to inflate same
US5012719A (en) * 1987-06-12 1991-05-07 Gt-Devices Method of and apparatus for generating hydrogen and projectile accelerating apparatus and method incorporating same
US5779269A (en) * 1996-12-06 1998-07-14 Olin Corporation Propellant module assembly
US5803492A (en) * 1994-05-31 1998-09-08 Morton International, Inc. Fuel containment for fluid fueled airbag inflators
US20040137810A1 (en) * 2002-12-20 2004-07-15 Van Mil Jeroen Vincenl Flotation device and method of manufacturing the same
US20070009324A1 (en) * 2004-03-09 2007-01-11 Clark Brent A Emergency warning device rapid deployment system
US20100192798A1 (en) * 2009-01-30 2010-08-05 Raytheon Company Buoyancy dissipater and method to deter an errant vessel
US8371204B2 (en) 2010-04-30 2013-02-12 Raytheon Company Bubble weapon system and methods for inhibiting movement and disrupting operations of vessels
US8402895B2 (en) 2010-04-30 2013-03-26 Raytheon Company Vortice amplified diffuser for buoyancy dissipater and method for selectable diffusion
US20140069667A1 (en) * 2011-03-10 2014-03-13 Pyroalliance Device for extinguishing a fire
CN116238666A (zh) * 2023-03-09 2023-06-09 深海技术科学太湖实验室 一种专用于深海环境的气囊充气式打捞装置及使用方法

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3435075A1 (de) * 1984-09-25 1986-03-27 Diehl GmbH & Co, 8500 Nürnberg Gasgenerator, verfahren zum gewinnen von reaktionsgasen und verwendung eines metallhydrides sowie seiner reaktionsgase
US4744300A (en) * 1984-09-25 1988-05-17 Diehl Gmbh & Co. Utilization of metal hydride and acidic reagent for the accelerating of masses and propulsion devices for applying such materials
DE19827380B4 (de) * 1998-06-19 2005-10-06 Rheinmetall W & M Gmbh Rohrwaffe
TWI260344B (en) 2001-01-12 2006-08-21 Safe Hydrogen Llc A method of operating a hydrogen-fueled device

Citations (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US719654A (en) * 1902-08-11 1903-02-03 John Ewing Jr Marine life-preserver.
US724279A (en) * 1902-03-25 1903-03-31 Benjamin Goldstein Life-preserver.
US867966A (en) * 1906-06-18 1907-10-15 Caspar Fuchs Marine life-saving apparatus.
US923801A (en) * 1908-09-14 1909-06-08 Frederick C Bargar Life-saving device.
US1014546A (en) * 1910-05-18 1912-01-09 Ferdinand J Wich Life-preserver.
US1458822A (en) * 1922-01-16 1923-06-12 Elijah T Halter Life-saving device
US1806786A (en) * 1931-05-26 glaus
US1879726A (en) * 1931-12-30 1932-09-27 Berger Emil Swimming device with automatic gas filling
US2149616A (en) * 1937-10-09 1939-03-07 Clarence V Mcguire Life preserver
US2642693A (en) * 1947-07-22 1953-06-23 Francis V Broady Apparatus for retrieving fishing tackle or the like
US3372996A (en) * 1963-10-14 1968-03-12 Foote Mineral Co Underwater gas generator
US3636874A (en) * 1965-03-31 1972-01-25 Us Navy Method and means for dispersing chemical agents

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1517836A (fr) * 1966-12-19 1968-03-22 Nikex Nehezipari Kulkere Procédé et installation pour remonter à la surface des objets se trouvant sous l'eau
FR1604229A (es) * 1968-12-12 1971-10-04

Patent Citations (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1806786A (en) * 1931-05-26 glaus
US724279A (en) * 1902-03-25 1903-03-31 Benjamin Goldstein Life-preserver.
US719654A (en) * 1902-08-11 1903-02-03 John Ewing Jr Marine life-preserver.
US867966A (en) * 1906-06-18 1907-10-15 Caspar Fuchs Marine life-saving apparatus.
US923801A (en) * 1908-09-14 1909-06-08 Frederick C Bargar Life-saving device.
US1014546A (en) * 1910-05-18 1912-01-09 Ferdinand J Wich Life-preserver.
US1458822A (en) * 1922-01-16 1923-06-12 Elijah T Halter Life-saving device
US1879726A (en) * 1931-12-30 1932-09-27 Berger Emil Swimming device with automatic gas filling
US2149616A (en) * 1937-10-09 1939-03-07 Clarence V Mcguire Life preserver
US2642693A (en) * 1947-07-22 1953-06-23 Francis V Broady Apparatus for retrieving fishing tackle or the like
US3372996A (en) * 1963-10-14 1968-03-12 Foote Mineral Co Underwater gas generator
US3636874A (en) * 1965-03-31 1972-01-25 Us Navy Method and means for dispersing chemical agents

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5012719A (en) * 1987-06-12 1991-05-07 Gt-Devices Method of and apparatus for generating hydrogen and projectile accelerating apparatus and method incorporating same
US4929214A (en) * 1987-11-02 1990-05-29 Liebermann Ron B Inflatable enclosure and means to inflate same
US5803492A (en) * 1994-05-31 1998-09-08 Morton International, Inc. Fuel containment for fluid fueled airbag inflators
US5779269A (en) * 1996-12-06 1998-07-14 Olin Corporation Propellant module assembly
US20040137810A1 (en) * 2002-12-20 2004-07-15 Van Mil Jeroen Vincenl Flotation device and method of manufacturing the same
US6974357B2 (en) * 2002-12-20 2005-12-13 Jeroen Vincent van Mil Flotation device and method of manufacturing the same
US20070009324A1 (en) * 2004-03-09 2007-01-11 Clark Brent A Emergency warning device rapid deployment system
US20100192798A1 (en) * 2009-01-30 2010-08-05 Raytheon Company Buoyancy dissipater and method to deter an errant vessel
US7895948B2 (en) * 2009-01-30 2011-03-01 Raytheon Company Buoyancy dissipater and method to deter an errant vessel
US8371204B2 (en) 2010-04-30 2013-02-12 Raytheon Company Bubble weapon system and methods for inhibiting movement and disrupting operations of vessels
US8402895B2 (en) 2010-04-30 2013-03-26 Raytheon Company Vortice amplified diffuser for buoyancy dissipater and method for selectable diffusion
US20140069667A1 (en) * 2011-03-10 2014-03-13 Pyroalliance Device for extinguishing a fire
US9808661B2 (en) * 2011-03-10 2017-11-07 Pyroalliance Device for extinguishing a fire
CN116238666A (zh) * 2023-03-09 2023-06-09 深海技术科学太湖实验室 一种专用于深海环境的气囊充气式打捞装置及使用方法
CN116238666B (zh) * 2023-03-09 2024-01-26 深海技术科学太湖实验室 一种专用于深海环境的气囊充气式打捞装置及使用方法

Also Published As

Publication number Publication date
FR2207885A1 (es) 1974-06-21
CA1023134A (en) 1977-12-27
NL7315920A (es) 1974-05-27
IT998890B (it) 1976-02-20
FR2207885B1 (es) 1977-04-08
GB1425590A (en) 1976-02-18

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