US3899402A - Method of tapping aluminum from a cell for electrolytic recovery of aluminum - Google Patents

Method of tapping aluminum from a cell for electrolytic recovery of aluminum Download PDF

Info

Publication number
US3899402A
US3899402A US436161A US43616174A US3899402A US 3899402 A US3899402 A US 3899402A US 436161 A US436161 A US 436161A US 43616174 A US43616174 A US 43616174A US 3899402 A US3899402 A US 3899402A
Authority
US
United States
Prior art keywords
cell
aluminum
tapping
anode beam
resistance
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US436161A
Other languages
English (en)
Inventor
Kiranendu B Chaudhuri
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Alcan Holdings Switzerland AG
Original Assignee
Alusuisse Holdings AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Alusuisse Holdings AG filed Critical Alusuisse Holdings AG
Application granted granted Critical
Publication of US3899402A publication Critical patent/US3899402A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Images

Classifications

    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
    • C25C3/00—Electrolytic production, recovery or refining of metals by electrolysis of melts
    • C25C3/06—Electrolytic production, recovery or refining of metals by electrolysis of melts of aluminium
    • C25C3/20—Automatic control or regulation of cells

Definitions

  • FIG. 1 shows a schematic vertical section in the longitudinal direction through part of an electrolysis cell.
  • the aluminum l4 separated at the cathode lies on the carbon bottom 15 of the cell.
  • the surface 16 of the liquid aluminum constitutes the cathode.
  • iron cathode bars 17 in this case transverse to the longitudinal direction of the cell, which conduct the electrical direct current from the carbon lining 11 of the cell laterally outwards.
  • Anodes 18 of amorphous carbon dip. from above into the fluoride melt l0, and supply the direct current to the electrolyte. They are firmly connected via conductor rods 19 and by clamps 20 with the anode beam 21.
  • the anode beam can consist of one or more conducting bars.
  • the current flows from the cathode bars 17 of one cell to the anode beam 21 of the following cell through conventional bus bars, not shown. From the anode beam 21 it flows through the conductor rods 19, the anodes 18, the electrolyte 10, the liquid aluminum 14, and the carbon lining 11 to the cathode bars 17.
  • the electrolyte 10 is covered with a crust 22 of solidified melt and a layer of aluminum oxide 23 lying above it. Cavities 25 occur in operation between electrolyte l0 and the solidified crust 22.
  • the thickness of the ledge 24 determines the horizontal ex tent of the bath of fluid aluminum l4 and electrolyte 10. With rising temperature, the thickness of the ledge 24 generally decreases, with falling temperature generally increases.
  • the average distance d from the lower sides 26 of the anodes to the upper surface 16 of the liquid aluminum which is also known as the interpolar distance, can be adjusted by lifting or lowering of the anode beam 21 with the help of the lifting mechanismus 27, which are mounted on pillars 28. This operates on all the anodes.
  • Each anode can however be adjusted by raising or lowering singly, if the respective clamp 20 is opened, the conductor rod 19 is shifted relatively to the anode beam 21 and finally the clamp 20 is again closed.
  • the anodes are consumed continuously on their lower face by about 1.5 to 2 cms per day (anode burning) according to the type of cell, and simultaneously the level of the liquid aluminum rises by about the same amount because of the separation of aluminum at the cathode.
  • the horizontal surface which contains the totality of the lower faces of the anodes of a cell, is known as the anode table.
  • anodes are used which, during the electrolytic operation, are continually baked from a green electrode paste in a steel jacket by the heat of the cell.
  • the direct current is supplied by lateral steel rods or from above by vertical steel rods. These anodes are renewed as required by pouring green electrode paste into the steel jacket.
  • the aluminum 14 produced electrolytically which collects on the carbon bottom of the cell, is generally tapped once a day from the cell, eg by conventional sucking devices. Generally the level of the liquid aluminum 14 is brought back to an optimum value for each type of cell. This value corresponds to the desired metal level, which can be the starting level.
  • An important characteristic value in the operation of a cell is its electrical base voltage. This is established empirically for each cell having regard to its age, the condition of the carbon lining 11, the composition of the electrolyte melt 10 as well as the cell current intensity and current density. For the establishment of the base voltage regard is also had to the horizontal extent of the cathode surface 16, which is influenced by the thickness of the lateral ledge 24.
  • R is the ohmic base resistance in ohms
  • U the base voltage in volts
  • 1.65 the back electromotive force in volts
  • J the instantaneous cell current intensity in amps.
  • interpolar distance must have an optimum value. If the cell is so operated that the horizontal extent of the cathode surface 16 remains unchanged, then generally the rise in level of the liquid aluminum above the carbon bottom is equal to the burning away of the anodes at their lower face. Thecell is designed so that these conditions are reached. If then in these circumstances one wants to tap the metal to an extent which will return the metal level to a starting level, then it is sufficient just to tap a height of liquid metal that corresponds to the burning away of the anodes. In practice the actual interpolar distance is from time to time, e.g. between two tapping operations, larger or smaller than the optimum interpolar distance.
  • the departures are substantially caused by irregular rise in the level of the liquid aluminum above the carbon bottom, by irregular burning away of the anodes at their lower face, and by variation in the horizontal extent of the cathode surface 16 as a consequence of alteration of the thickness of the lateral ledge 24. If in this circumstance one taps the metal in a cell exactly by the amount which corresponds to the burning away of the anodes, then one does not reach the desired metal level in the cell, but the cell is over or under tapped, that is to say one has tapped too much or too little metal.
  • My invention relates to a method of tapping aluminum from a cell for electrolytic recovery of aluminum in accordance with automatic determination of the metal height to be tapped.
  • the method according to my invention allows the metal height to be tapped to be accurately determined, having regard to the varying thickness of the lateral ledge, the burning away of the anodes, the varying interpolar distance and the desired metal level, and the cell thereupon to be tapped to the desired metal level.
  • the method according to my invention for tapping aluminum from a cell for recovery of aluminum by electrolysis of aluminum oxide dissolved in a fluoride melt comprises the following operationaLsteps carried out in succession:
  • the instantaneous ohmic cell resistance is calculated, the instantaneous values over a certain period of time are smoothed and the difference AR between this smoothed cell resistance and the base resistance established for each cell is calcu lated;
  • the anode beam is raised or lowered, in order to match the existing ohmic resistance with the ohmic base resistance
  • the difference AB of the vertical levels of the anode beam is calculated from two values, of which the first is taken 30 to minutes after the normal cell service following the previous tapping operation, and the second is taken 30 to 60 minutes after the last normal cell service before the next tapping operation referred to at (e) below;
  • the metal height H (mm) to be tapped is calculated according to the equation in which J signifies the mean direct current in ki loamps, r the time in hours which has passed between successive tapping operations, and f a proportionality factor kA h DESCRIPTION OF THE PREFERRED EMBODIMENT Below an advantageous example of a method according to my invention is described.
  • the cell voltage U and the cell direct current intensity J are sampled at regular time intervals, e.g. every 10 to 60 seconds, and the cell resistance is calculated from this according to the equation:
  • R is the instantaneous ohmic resistance in ohms
  • U is the instantaneous cell voltage in volts
  • 1.65 the back electromotive force in volts
  • J the cell direct current intensity in amperes.
  • the level of the anode beam of the cell is read off by the computer.
  • J, R and the value of the level of the anode beam are stored in the computer.
  • the values for R calculated by the computer are smoothed over a predetermined period of time, e.g. 10 minutes, and are compared at regular time intervals, e.g. every 10 to 15 minutes, with the base resistance R,, of the cell.
  • the computer notices a difference AR between the smoothed value and R and if this difference exceeds a limiting value previously given to the computer and stored in it, then an order is issued by the computer, in accordance with which the anode beam is raised or lowered, until the instantaneous resistance is substantially equal to the base resistance of the cell. This adjustment is carried out 30 to 60 minutes after a normal cell service.
  • the values of the level of the anode beam before and after each movement are read by the computer, for instance by means of the potentiometer, and are stored in the computer.
  • the dimensions of f are mm/kA.h, and it undertakes the conversion of kiloamp hours into millimetres of anode burning away. Usually fis in the range 0.0056 to 0.0063.
  • AB in millimetres is a difference between two levels of the anode beam.
  • the difference AB of the levels of the anode beam reference is made to the following two values of level.
  • the first value is taken 30 to 60 minutes after the normal service following the previous tapping operation.
  • the second value is taken 30 to 60 minutes after the last normal service before the next tapping operation.
  • the times at which the two values of level are taken need not be equally far in time from the respective normal service. From the two values the difference AB is obtained.
  • FIG. 2 illustrates in a diagram the times at which the level of the anode beam is taken.
  • 50 is the instant of a previous tapping operation, 51 the instant of the first normal cell service following it.
  • the first value of the level of the anode beam is taken.
  • the next normal tapping operation occurs the next normal tapping operation.
  • the instant 54 occurs the last normal service before the tapping operation 53.
  • the instant 55 which lies 30 to 60 minutes after the normal cell service 54, the second value of the level of the anode beam is taken.
  • the taking of the levels of the anode beam at the mentioned determined times after a normal service on the cell is important, because during this time the alumina concentration in a cell reaches its maximum value. During this time the influence of alumina concentration on the cell voltage is practically negligible.
  • The-tenn-AB in the formula H J,', t'.f+ AB has its origin ir'ft he'results'of possible variation in the thickness of the lateral ledge of the cell. If the difference AB is equal to zerogth'en one can conclude that there isno alteration in the ledge thickness. All'other values of AB indicate an'alteration of the ledge thickness.
  • the presence of AB in the formula means that in a long run, that is over a length-of time covering several successive tapping operations, the level of the aluminum is repeatedly returned to an optimum level, and hence the thickness 'of the lateral ledge cannot undergo progressive change, but only minor irregular changesaround a mean value.
  • this value of the level should not be employed for obtaining the difference AB.
  • either AB is arbitrarily set equal to zero, or the provision of the level of the anode beam is again undertaken 30 to 60 minutes after the next following normal service.
  • AB in this case is again arbitrarily set as nil, or the level of the anode beam 30 to 60 minutes after the previous normal service is provided from data stored in the computer.
  • the accuracy of the tapping depends on the devices available.
  • the device a conventional sucking device for example, can be controlled by a computer. Then the computer starts the tapping, observes the metal level by simultaneous lowering of the anode beam so as to keep the ohmic resistance of the cell constant, and interrupts the tapping operation as soon as the metal level has been reduced by the given height.
  • the advantages of the method according to the invention lie in the fact that the metal height to be tapped is automatically determined and that this determination gives more accurate results in comparison with existing technique. If one always taps the metal height calculated according to the invention, a uniform tapping in ensured, and thus an excessive or insufficient tapping from the cell is avoided. Thus a uniform cell operation is achieved, which leads to improvement of the current efficiency and of the specific electrical energy consumption.
  • a method of tapping aluminum from a cell for recovery of aluminum by electrolysis of aluminum oxide dissolved in a fluoride melt comprising the following operational steps:
  • the instantaneous ohmic cell resistance is calculated, the instantaneous values over a certain period of time are smoothed and the difference AR between this smoothed cell resistance and the base resistance established for each cell is calculated;
  • the metal height H (mm) to be tapped is calculated according to the equation in which J signifies the mean direct current in kiloamps, t the time in hours which has passed between 8 successive tapping operations, and f a proportionality factor (mm/kA h) e. tapping is carried out to reduce the metal level by the height given by the equation under (d).

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Electrolytic Production Of Metals (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
US436161A 1973-08-09 1974-01-24 Method of tapping aluminum from a cell for electrolytic recovery of aluminum Expired - Lifetime US3899402A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CH1149873A CH587357A5 (fr) 1973-08-09 1973-08-09

Publications (1)

Publication Number Publication Date
US3899402A true US3899402A (en) 1975-08-12

Family

ID=4374067

Family Applications (1)

Application Number Title Priority Date Filing Date
US436161A Expired - Lifetime US3899402A (en) 1973-08-09 1974-01-24 Method of tapping aluminum from a cell for electrolytic recovery of aluminum

Country Status (19)

Country Link
US (1) US3899402A (fr)
JP (1) JPS5216842B2 (fr)
AT (1) AT336908B (fr)
BE (1) BE818301A (fr)
BR (1) BR7406584D0 (fr)
CA (1) CA1072042A (fr)
CH (1) CH587357A5 (fr)
EG (1) EG11460A (fr)
FR (1) FR2240304B1 (fr)
GB (1) GB1456569A (fr)
IE (1) IE39732B1 (fr)
IS (1) IS1028B6 (fr)
IT (1) IT1017985B (fr)
NL (1) NL7406672A (fr)
NO (1) NO138606C (fr)
PH (1) PH11055A (fr)
SE (1) SE406481B (fr)
TR (1) TR17753A (fr)
ZA (1) ZA743702B (fr)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4857157A (en) * 1987-04-21 1989-08-15 Aluminium Pechiney Process and apparatus for controlling solid electrolyte additions to electrolytic cells for aluminum production
US5876585A (en) * 1996-05-29 1999-03-02 Schenk; Rodney J. Anode clamp
US20100090850A1 (en) * 2008-10-15 2010-04-15 Alcoa Inc. Systems, methods and apparatus for tapping a metal electrolysis cell
CN101528990B (zh) * 2006-11-03 2011-03-09 力拓加铝国际有限公司 用于出料金属的设备和方法
CN104911634A (zh) * 2015-05-07 2015-09-16 北方工业大学 一种根据阳极导电能力评价电解槽阳极电流分布的方法
CN104962951A (zh) * 2015-07-24 2015-10-07 武汉大学 一种修补吸铝管的方法
WO2019025891A1 (fr) * 2017-08-01 2019-02-07 Dubai Aluminium Pjsc Cellule électrolytique pour la production d'aluminium, avec entraînements d'anodes individuels

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3660256A (en) * 1967-12-07 1972-05-02 Gen Electric Method and apparatus for aluminum potline control

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3660256A (en) * 1967-12-07 1972-05-02 Gen Electric Method and apparatus for aluminum potline control

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4857157A (en) * 1987-04-21 1989-08-15 Aluminium Pechiney Process and apparatus for controlling solid electrolyte additions to electrolytic cells for aluminum production
US5876585A (en) * 1996-05-29 1999-03-02 Schenk; Rodney J. Anode clamp
CN101528990B (zh) * 2006-11-03 2011-03-09 力拓加铝国际有限公司 用于出料金属的设备和方法
AU2007314114B2 (en) * 2006-11-03 2011-09-22 Rio Tinto Alcan International Limited An apparatus and a method for tapping metal
US20100090850A1 (en) * 2008-10-15 2010-04-15 Alcoa Inc. Systems, methods and apparatus for tapping a metal electrolysis cell
US8199023B2 (en) 2008-10-15 2012-06-12 Alcoa Inc. Systems, methods and apparatus for tapping a metal electrolysis cell
CN104911634A (zh) * 2015-05-07 2015-09-16 北方工业大学 一种根据阳极导电能力评价电解槽阳极电流分布的方法
CN104962951A (zh) * 2015-07-24 2015-10-07 武汉大学 一种修补吸铝管的方法
CN104962951B (zh) * 2015-07-24 2017-03-29 武汉大学 一种修补吸铝管的方法
WO2019025891A1 (fr) * 2017-08-01 2019-02-07 Dubai Aluminium Pjsc Cellule électrolytique pour la production d'aluminium, avec entraînements d'anodes individuels

Also Published As

Publication number Publication date
CA1072042A (fr) 1980-02-19
FR2240304B1 (fr) 1978-01-27
ATA650874A (de) 1976-09-15
EG11460A (en) 1977-10-31
NO138606B (no) 1978-06-26
JPS5039611A (fr) 1975-04-11
SE406481B (sv) 1979-02-12
AT336908B (de) 1977-06-10
DE2438078B2 (de) 1976-09-16
NL7406672A (nl) 1975-02-11
NO138606C (no) 1978-10-04
IE39732L (en) 1975-02-09
FR2240304A1 (fr) 1975-03-07
IS2212A7 (is) 1975-02-10
GB1456569A (en) 1976-11-24
SE7406685L (fr) 1975-02-10
JPS5216842B2 (fr) 1977-05-12
IT1017985B (it) 1977-08-10
CH587357A5 (fr) 1977-04-29
BE818301A (fr) 1974-11-18
TR17753A (tr) 1976-07-01
AU7169074A (en) 1976-01-29
NO742841L (fr) 1975-03-10
IS1028B6 (is) 1980-04-14
IE39732B1 (en) 1978-12-20
ZA743702B (en) 1975-06-25
DE2438078A1 (de) 1975-02-20
PH11055A (en) 1977-10-25
BR7406584D0 (pt) 1975-05-27

Similar Documents

Publication Publication Date Title
US5006209A (en) Electrolytic reduction of alumina
CA1338052C (fr) Reduction electrolytique de l'alumine
US4243502A (en) Cathode for a reduction pot for the electrolysis of a molten charge
US20190032232A1 (en) Systems and methods of protecting electrolysis cells
CA1164823A (fr) Agencement d'electrodes dans une pile de fabrication de l'aluminium a partir de sels en fusion
NO742889L (fr)
US20060254925A1 (en) Measuring duct offgas temperatures to improve electrolytic cell energy efficiency
GB1169012A (en) Furnace and Process for Producing, in Fused Bath, Metals from their Oxides, and Electrolytic Furnaces having Multiple Cells formed by Horizontal Bipolar Carbon Electrodes
US20180209056A1 (en) Systems and methods of protecting electrolysis cell sidewalls
US3899402A (en) Method of tapping aluminum from a cell for electrolytic recovery of aluminum
US3900371A (en) Method of controlling the thickness of the lateral ledges in a cell for the electrolytic recovery of aluminum
CA1224746A (fr) Cuve d'affinage de l'aluminium
US3723286A (en) Aluminum reduction cell
US4124465A (en) Protecting tube
US3850768A (en) Method of controlling the supply of al{11 o{11 {0 during the operation of a cell for electrolytic recovery of aluminum
US3829365A (en) Method of operating a cell for the recovery of aluminum by electrolysis of aluminum oxide in a fluoride melt
RU2722605C1 (ru) Электролизер для производства алюминия
RU2696124C1 (ru) Электролизер для производства алюминия
CN103993332A (zh) 一种节能铝电解槽及其辅助极
US2959527A (en) Self-restoring anode in multi-cell furnaces particularly for the electrolytic production of aluminum
US3859184A (en) Method of operation of a cell for recovery of aluminium byelectrolysis of aluminium oxide in a fluoride melt
US3503857A (en) Method for producing magnesium ferrosilicon
EP0380645A4 (en) Apparatus and method for the electrolytic production of metals
RU2742633C1 (ru) Способ получения алюминия электролизом криолитоглиноземных расплавов
CA1193573A (fr) Methode d'exploitation stable d'une pile electrolytique pour l'aluminium