US3886736A - Combustion apparatus for gas turbine - Google Patents
Combustion apparatus for gas turbine Download PDFInfo
- Publication number
- US3886736A US3886736A US411497A US41149773A US3886736A US 3886736 A US3886736 A US 3886736A US 411497 A US411497 A US 411497A US 41149773 A US41149773 A US 41149773A US 3886736 A US3886736 A US 3886736A
- Authority
- US
- United States
- Prior art keywords
- chamber
- array
- fuel
- disposed
- ports
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23R—GENERATING COMBUSTION PRODUCTS OF HIGH PRESSURE OR HIGH VELOCITY, e.g. GAS-TURBINE COMBUSTION CHAMBERS
- F23R3/00—Continuous combustion chambers using liquid or gaseous fuel
- F23R3/02—Continuous combustion chambers using liquid or gaseous fuel characterised by the air-flow or gas-flow configuration
- F23R3/04—Air inlet arrangements
- F23R3/10—Air inlet arrangements for primary air
- F23R3/12—Air inlet arrangements for primary air inducing a vortex
- F23R3/14—Air inlet arrangements for primary air inducing a vortex by using swirl vanes
Definitions
- ABSTRACT [30] Foreign Applicatlon Priority Data Nov. 9. m2 Japan 47-l1l6l9
- a gas turbine having a Combustion Chamber with fuel nozzle is encompassed by a plurality of annular 52 us. Cl 60/3974 R; 239/400; 239/402; P m Chambers which are pp ith a pr 239/4O6 1zed fluid. The fluid is directed obliquely through ports 51 Int. Cl. 3051) 7/10; FOZc 3/00 f a fuel Stream being p y into the combus- 5 n w f Search 60/3974 R 3974 13; tion chamber.
- the fluid also adds to the turbulence within the fuel vortex to reduce the [56] References Cited carbon pollutant outflow.
- This invention relates to combustion apparatus for a gas turbine, and more particularly to means for mixing fluid streams with the fuel to atomize. disperse or convolute the fuel to provide complete combustion thereof.
- a combustion apparatus for a gas turbine when made in accordance with this invention, cornprises a fuel supply conduit having a pore in fluid communication with a combustion chamber to direct the flow of fuel to the combustion chamber, an atomizing fluid chamber having an opening disposed to direct atomizing fluid to converge with the fluid flowing into the combustion chamber, an annular chamber disposed to encircle the fuel supply conduit having one end thereof in communication with the combustion chamber, the other end being in communication with the compressor portion of the gas turbine, the annular chamber having a plurality of angularly directed vanes so disposed therein to cause air flowing therethrough to follow a vortecular path as it leaves the exit end of the annular chamber and enters the combustion chamber, and generally radially inwardly disposed and generally radially outwardly disposed angularly directed annular array of ports, through which air is passed, which aid the vortecular motion and inner turbulence of the fuel-air mixture in the combustion chamber.
- FIG. 2 is a view taken along lines ll-ll of FIG. 1;
- FIG. 3 is a view taken along lines Illlll of FIG. 2.
- FIG. 1 wherein there is shown a combustion apparatus 10 for a gas turbine, not shown, having a combustion chamber 12, a compressor 13, to supply pressurized air for combustion, and a supply conduit 14 to supply atomizing fluid to atomize the fuel.
- a fuel supply conduit 16 delivers fuel to a fuel supply nozzle 18 which has at least one pore or opening 19 from which fuel is sprayed into the combustion chamber 12.
- An outer plenum chamber 20 encircles the combustion apparatus 10 and it is in communication with an air source through a plurality of ports 22 disposed in a cylindrical outer wall 24 of the plenum chamber 20.
- a plurality of angularly directed vanes 26 are fastened to and extend generally radially outward from an inner cylindrical wall 28 of the plenum chamber 20. The angularly directed vanes 26 are adapted to cause the air flowing through the plenum chamber 20 to follow a convolute path, directed at an angle of 30 to to axis of the combustion chamber 12, as it enters that combustion chamber.
- a frustoconical baffle 30 has its small diameter end fastened to the inner wall 28 of the plenum chamber 20 and has a plurality of annularly disposed ports of jets 32 angularly directed to 30 to 35 from the axis of the combustion chamber 12.
- the vanes 26 and the ports 32 both direct their respective air flows generally parallel to one another. Each air flow adds to and combines with the vortecular motion of the atomizing fuel spray.
- the jets 32 may also direct their air flows normal to the fuel-air vortex to increase the turbulence and fuel-air mixing therein.
- An inner plenum chamber 34 is provided adjacent the fuel nozzle 18 and is supplied with atomizing fluid through the atomizing conduit 14.
- the atomizing fluid flows through an annular opening 36 adjacent the tip of the nozzle 18 and is directed at an angle toward the fuel converging with the fuel flowing into the combustion chamber.
- An intermediate plenum chamber 38 is formed between the inner and outer annular chambers, 34 and 20, respectively, and a plurality of ports 40 are disposed in the inner wall 28 of the outer plenum chamber 20.
- the intermediate annular plenum chamber 38 is in fluid communication with the combustion chamber 12 by a plurality of angularly disposed ports or jets 42, which may be directed at at angle of 30 to with respect to the axis of the combustion chamber. the air flow therethrough being generally parallel to that vortecular air flow pattern caused by the vanes 26 and the outer array of ports 32.
- the array of vanes 26 and the angular arrays of inner and outer ports, 42, and 32, are shown in FIG. 2.
- the object of this invention is to provide a combustion apparatus in which the carbon that is produced in an initial combustion zone is decreased by supplying vortex air in three steps so as widen the angle of the fuel injection cone, thereby making the fuel particle size smaller, effectively improving the ignitability of the fuel and finally shortening the length of the flame.
- the atomization of the fuel is increased by the application ofa swirl flow having the same vortex direction as that of the fuel injection cone. Additionally. the jetted air penetrates the fuel injection cone to provide internal turbulence and mixing thereof.
- a pressure balance piston 44 admits additional air from the combustion air source. which may be a compressor, as shown in FIG.
- a combustion apparatus for a gas turbine having a combustion chamber, a fuel supply. a compressor to supply a pressurized air for combustion, a supply of pressurized atomizing fluid to atomize the fuel, said combustion apparatus comprising:
- a fuel supply nozzle having at least one port in com munication with said combustion chamber and disposed to direct the flow of fuel to said combustion chamber;
- an atomizing fluid chamber having walls which define at least one duct disposed to direct atomizing fluid into said combustion chamber so that it converges with fuel flowing thereto;
- a plenum chamber comprised of walls disposed about said atomizing fluid chamber
- a first array of angularly arranged ports disposed through said wall of said plenum chamber and disposed about said fuel nozzle, said first array of angularly arranged ports providing jets of air to promote vortecular motion to the fuel in said combustion chamber;
- a frustoconical baffle having its small diameter edge attached to said walls of said plenum chamber, said baffle being annularly disposed about said nozzle; a second array of angularly arranged ports disposed through said baffle about said fuel nozzle, said second array of angularly arranged ports providing jets of air to promote mixing and increase vortecular motion of the combustion components; an arcuate chamber disposed radially outwardly of said plenum chamber.
- said arcuate chamber having walls with inlet ports therethrough, said arcuate chamber being in communication with said compressor and said combustion chamber, and a generally radially extending array of vanes disposed across said arcuate chamber for causing the air passing therethrough to have a vortecular motion as it enters the combustion chamber; said first and second arrays of ports and said array of vanes each directing generally the same angle to the fluid passing thereby, with respect to the axis of the combustion chamber;
- said array of vanes and said first and Second arrays of ports being arranged as to cause the air and fuel to follow a vortecular motion, and to increase the turbulence therein, thereby reducing the smoke generated therewith.
- combustion apparatus as recited in claim 1, wh erein said first array of ports have an angle betwee 3Q to 45 with the axis of the combustion chamber, said second array of ports having an angle of 30 to 35 with the axis of the combustion chamber, and said array of vanes having an angle of between 30 to 35 with the axis of the combustion chamber.
- said first array of ports is disposed in an angular array about the downstream end of the fuel nozzle, and said second array of ports are disposed radially outwardly of the said first array of ports.
- combustion apparatus as recited in claim 1, wherein said second array of ports is directed generally normal to the fuel vortex, the air passing through said second array of ports promoting turbulence and mixing of the'fuel and air within the center of said vortex, thereby reducing carbon and smoke production from the combustion chamber.
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Spray-Type Burners (AREA)
- Air Supply (AREA)
- Pressure-Spray And Ultrasonic-Wave- Spray Burners (AREA)
- Combustion Of Fluid Fuel (AREA)
- Pre-Mixing And Non-Premixing Gas Burner (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP11161972A JPS5342897B2 (he) | 1972-11-09 | 1972-11-09 |
Publications (1)
Publication Number | Publication Date |
---|---|
US3886736A true US3886736A (en) | 1975-06-03 |
Family
ID=14565900
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US411497A Expired - Lifetime US3886736A (en) | 1972-11-09 | 1973-10-31 | Combustion apparatus for gas turbine |
Country Status (8)
Country | Link |
---|---|
US (1) | US3886736A (he) |
JP (1) | JPS5342897B2 (he) |
CA (1) | CA985514A (he) |
CH (1) | CH560356A5 (he) |
DE (1) | DE2355127C2 (he) |
FR (1) | FR2206441B1 (he) |
GB (1) | GB1450190A (he) |
IT (1) | IT996392B (he) |
Cited By (29)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4105163A (en) * | 1976-10-27 | 1978-08-08 | General Electric Company | Fuel nozzle for gas turbines |
US4395874A (en) * | 1980-12-02 | 1983-08-02 | United Technologies Corporation | Fuel nozzles with water injection for gas turbine engines |
US4863105A (en) * | 1985-02-13 | 1989-09-05 | Westinghouse Electric Corp. | High reliability fuel oil nozzle for a gas turbine |
US4996837A (en) * | 1987-12-28 | 1991-03-05 | Sundstrand Corporation | Gas turbine with forced vortex fuel injection |
US5040371A (en) * | 1988-12-12 | 1991-08-20 | Sundstrand Corporation | Fuel injectors for use with combustors |
US5115634A (en) * | 1990-03-13 | 1992-05-26 | Delavan Inc. | Simplex airblade fuel injection method |
US5224333A (en) * | 1990-03-13 | 1993-07-06 | Delavan Inc | Simplex airblast fuel injection |
WO1994000717A1 (en) * | 1992-06-25 | 1994-01-06 | Solar Turbines Incorporated | Low emission combustion system for a gas turbine engine |
US5288021A (en) * | 1992-08-03 | 1994-02-22 | Solar Turbines Incorporated | Injection nozzle tip cooling |
US5467926A (en) * | 1994-02-10 | 1995-11-21 | Solar Turbines Incorporated | Injector having low tip temperature |
US5873237A (en) * | 1997-01-24 | 1999-02-23 | Westinghouse Electric Corporation | Atomizing dual fuel nozzle for a combustion turbine |
US6082113A (en) * | 1998-05-22 | 2000-07-04 | Pratt & Whitney Canada Corp. | Gas turbine fuel injector |
US6289676B1 (en) | 1998-06-26 | 2001-09-18 | Pratt & Whitney Canada Corp. | Simplex and duplex injector having primary and secondary annular lud channels and primary and secondary lud nozzles |
US6533954B2 (en) | 2000-02-28 | 2003-03-18 | Parker-Hannifin Corporation | Integrated fluid injection air mixing system |
US6550696B2 (en) | 2000-02-28 | 2003-04-22 | Adel B. Mansour | Integrated fuel injection and mixing system with impingement cooling face |
US20050217270A1 (en) * | 2004-04-02 | 2005-10-06 | Pratt & Whitney Canada Corp. | Fuel injector head |
EP2003398A2 (en) * | 2007-06-14 | 2008-12-17 | Pratt & Whitney Canada Corp. | Fuel nozzle providing shaped fuel spray |
US20100132364A1 (en) * | 2008-12-01 | 2010-06-03 | Myers Geoffrey D | Fuel nozzle detachable burner tube |
US20140060059A1 (en) * | 2012-09-06 | 2014-03-06 | United Technologies Corporation | Fuel delivery system with a cavity coupled fuel injector |
US20140246518A1 (en) * | 2013-03-01 | 2014-09-04 | Delavan Inc | Fuel nozzle with discrete jet inner air swirler |
US8893500B2 (en) | 2011-05-18 | 2014-11-25 | Solar Turbines Inc. | Lean direct fuel injector |
US8919132B2 (en) | 2011-05-18 | 2014-12-30 | Solar Turbines Inc. | Method of operating a gas turbine engine |
US9182124B2 (en) | 2011-12-15 | 2015-11-10 | Solar Turbines Incorporated | Gas turbine and fuel injector for the same |
US11421883B2 (en) | 2020-09-11 | 2022-08-23 | Raytheon Technologies Corporation | Fuel injector assembly with a helical swirler passage for a turbine engine |
US11649964B2 (en) | 2020-12-01 | 2023-05-16 | Raytheon Technologies Corporation | Fuel injector assembly for a turbine engine |
US11754287B2 (en) | 2020-09-11 | 2023-09-12 | Raytheon Technologies Corporation | Fuel injector assembly for a turbine engine |
US11808455B2 (en) | 2021-11-24 | 2023-11-07 | Rtx Corporation | Gas turbine engine combustor with integral fuel conduit(s) |
US11846249B1 (en) | 2022-09-02 | 2023-12-19 | Rtx Corporation | Gas turbine engine with integral bypass duct |
US12116934B2 (en) | 2023-02-10 | 2024-10-15 | Rtx Corporation | Turbine engine fuel injector with oxygen circuit |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5412607U (he) * | 1977-06-29 | 1979-01-26 | ||
DE3026832A1 (de) * | 1980-07-16 | 1982-02-11 | Klöckner-Humboldt-Deutz AG, 5000 Köln | Zerstaeuberduese fuer kontinuierliche brennstoffeinspritzung |
FR2495229B1 (fr) * | 1980-12-02 | 1987-07-03 | United Technologies Corp | Buse d'injection de carburant a double ouverture pour moteur a turbine a gaz |
US5813232A (en) * | 1995-06-05 | 1998-09-29 | Allison Engine Company, Inc. | Dry low emission combustor for gas turbine engines |
DE102008026459A1 (de) * | 2008-06-03 | 2009-12-10 | E.On Ruhrgas Ag | Brenner, insbesondere für eine Verbrennungseinrichtung in einer Gasturbinenanlage |
KR101371291B1 (ko) * | 2012-05-04 | 2014-03-07 | 고등기술연구원연구조합 | 비 용융 및 부분 용융형 분류층 가스화기 |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3498055A (en) * | 1968-10-16 | 1970-03-03 | United Aircraft Corp | Smoke reduction combustion chamber |
US3684186A (en) * | 1970-06-26 | 1972-08-15 | Ex Cell O Corp | Aerating fuel nozzle |
US3700173A (en) * | 1970-12-30 | 1972-10-24 | Combustion Eng | Diffuser |
US3733169A (en) * | 1972-02-22 | 1973-05-15 | D Lefebvre | Flame retention head assembly |
US3735930A (en) * | 1970-11-30 | 1973-05-29 | Mitsubishi Heavy Ind Ltd | Fuel injection nozzle |
US3777983A (en) * | 1971-12-16 | 1973-12-11 | Gen Electric | Gas cooled dual fuel air atomized fuel nozzle |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2305265A (en) * | 1942-05-01 | 1942-12-15 | Letourneau Inc | Sealing boot assembly |
US2968925A (en) * | 1959-11-25 | 1961-01-24 | William E Blevans | Fuel nozzle head for anti-coking |
DE1625948A1 (de) * | 1967-12-23 | 1970-12-03 | Bizerba Werke Kraut Kg Wilh | Daempfer fuer ein in einem Gehaeuse pulsierendes Steuerorgan |
AT308474B (de) * | 1969-03-20 | 1973-07-10 | List Hans | Körperschallhemmender Verschalungsbauteil zur schallisolierenden Verkleidung von Maschinen, insbesondere Brennkraftmaschinen |
DE2160675C3 (de) * | 1970-12-15 | 1978-04-20 | Mitsubishi Jukogyo K.K., Tokio | Brennereinrichtung für eine Gasturbinenbrennkammer |
AT328229B (de) * | 1971-09-03 | 1976-03-10 | List Hans | Brennkraftmaschine mit schalldammender verschalung |
-
1972
- 1972-11-09 JP JP11161972A patent/JPS5342897B2/ja not_active Expired
-
1973
- 1973-10-31 US US411497A patent/US3886736A/en not_active Expired - Lifetime
- 1973-11-01 GB GB5085673A patent/GB1450190A/en not_active Expired
- 1973-11-01 DE DE2355127A patent/DE2355127C2/de not_active Expired
- 1973-11-02 CH CH1548273A patent/CH560356A5/xx not_active IP Right Cessation
- 1973-11-06 IT IT53532/73A patent/IT996392B/it active
- 1973-11-08 CA CA185,381A patent/CA985514A/en not_active Expired
- 1973-11-09 FR FR7340018A patent/FR2206441B1/fr not_active Expired
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3498055A (en) * | 1968-10-16 | 1970-03-03 | United Aircraft Corp | Smoke reduction combustion chamber |
US3684186A (en) * | 1970-06-26 | 1972-08-15 | Ex Cell O Corp | Aerating fuel nozzle |
US3735930A (en) * | 1970-11-30 | 1973-05-29 | Mitsubishi Heavy Ind Ltd | Fuel injection nozzle |
US3700173A (en) * | 1970-12-30 | 1972-10-24 | Combustion Eng | Diffuser |
US3777983A (en) * | 1971-12-16 | 1973-12-11 | Gen Electric | Gas cooled dual fuel air atomized fuel nozzle |
US3733169A (en) * | 1972-02-22 | 1973-05-15 | D Lefebvre | Flame retention head assembly |
Cited By (38)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4105163A (en) * | 1976-10-27 | 1978-08-08 | General Electric Company | Fuel nozzle for gas turbines |
US4395874A (en) * | 1980-12-02 | 1983-08-02 | United Technologies Corporation | Fuel nozzles with water injection for gas turbine engines |
US4863105A (en) * | 1985-02-13 | 1989-09-05 | Westinghouse Electric Corp. | High reliability fuel oil nozzle for a gas turbine |
US4996837A (en) * | 1987-12-28 | 1991-03-05 | Sundstrand Corporation | Gas turbine with forced vortex fuel injection |
US5040371A (en) * | 1988-12-12 | 1991-08-20 | Sundstrand Corporation | Fuel injectors for use with combustors |
US5224333A (en) * | 1990-03-13 | 1993-07-06 | Delavan Inc | Simplex airblast fuel injection |
US5115634A (en) * | 1990-03-13 | 1992-05-26 | Delavan Inc. | Simplex airblade fuel injection method |
WO1994000717A1 (en) * | 1992-06-25 | 1994-01-06 | Solar Turbines Incorporated | Low emission combustion system for a gas turbine engine |
US5309709A (en) * | 1992-06-25 | 1994-05-10 | Solar Turbines Incorporated | Low emission combustion system for a gas turbine engine |
US5288021A (en) * | 1992-08-03 | 1994-02-22 | Solar Turbines Incorporated | Injection nozzle tip cooling |
US5467926A (en) * | 1994-02-10 | 1995-11-21 | Solar Turbines Incorporated | Injector having low tip temperature |
US5873237A (en) * | 1997-01-24 | 1999-02-23 | Westinghouse Electric Corporation | Atomizing dual fuel nozzle for a combustion turbine |
US6082113A (en) * | 1998-05-22 | 2000-07-04 | Pratt & Whitney Canada Corp. | Gas turbine fuel injector |
US6289676B1 (en) | 1998-06-26 | 2001-09-18 | Pratt & Whitney Canada Corp. | Simplex and duplex injector having primary and secondary annular lud channels and primary and secondary lud nozzles |
US7083122B2 (en) | 2000-02-28 | 2006-08-01 | Parker-Hannifin Corporation | Integrated fluid injection air mixing system |
US20030155325A1 (en) * | 2000-02-28 | 2003-08-21 | Mansour Adel B. | Integrated fluid injection air mixing system |
US6533954B2 (en) | 2000-02-28 | 2003-03-18 | Parker-Hannifin Corporation | Integrated fluid injection air mixing system |
US6550696B2 (en) | 2000-02-28 | 2003-04-22 | Adel B. Mansour | Integrated fuel injection and mixing system with impingement cooling face |
US20050217270A1 (en) * | 2004-04-02 | 2005-10-06 | Pratt & Whitney Canada Corp. | Fuel injector head |
US7117678B2 (en) * | 2004-04-02 | 2006-10-10 | Pratt & Whitney Canada Corp. | Fuel injector head |
EP2003398A3 (en) * | 2007-06-14 | 2012-10-03 | Pratt & Whitney Canada Corp. | Fuel nozzle providing shaped fuel spray |
EP2003398A2 (en) * | 2007-06-14 | 2008-12-17 | Pratt & Whitney Canada Corp. | Fuel nozzle providing shaped fuel spray |
US20100132364A1 (en) * | 2008-12-01 | 2010-06-03 | Myers Geoffrey D | Fuel nozzle detachable burner tube |
US8505304B2 (en) * | 2008-12-01 | 2013-08-13 | General Electric Company | Fuel nozzle detachable burner tube with baffle plate assembly |
CN101806460B (zh) * | 2008-12-01 | 2014-11-26 | 通用电气公司 | 燃料喷嘴的可拆式燃烧管 |
US8893500B2 (en) | 2011-05-18 | 2014-11-25 | Solar Turbines Inc. | Lean direct fuel injector |
US8919132B2 (en) | 2011-05-18 | 2014-12-30 | Solar Turbines Inc. | Method of operating a gas turbine engine |
US9182124B2 (en) | 2011-12-15 | 2015-11-10 | Solar Turbines Incorporated | Gas turbine and fuel injector for the same |
US20140060059A1 (en) * | 2012-09-06 | 2014-03-06 | United Technologies Corporation | Fuel delivery system with a cavity coupled fuel injector |
US10619855B2 (en) * | 2012-09-06 | 2020-04-14 | United Technologies Corporation | Fuel delivery system with a cavity coupled fuel injector |
US20140246518A1 (en) * | 2013-03-01 | 2014-09-04 | Delavan Inc | Fuel nozzle with discrete jet inner air swirler |
US9284933B2 (en) * | 2013-03-01 | 2016-03-15 | Delavan Inc | Fuel nozzle with discrete jet inner air swirler |
US11421883B2 (en) | 2020-09-11 | 2022-08-23 | Raytheon Technologies Corporation | Fuel injector assembly with a helical swirler passage for a turbine engine |
US11754287B2 (en) | 2020-09-11 | 2023-09-12 | Raytheon Technologies Corporation | Fuel injector assembly for a turbine engine |
US11649964B2 (en) | 2020-12-01 | 2023-05-16 | Raytheon Technologies Corporation | Fuel injector assembly for a turbine engine |
US11808455B2 (en) | 2021-11-24 | 2023-11-07 | Rtx Corporation | Gas turbine engine combustor with integral fuel conduit(s) |
US11846249B1 (en) | 2022-09-02 | 2023-12-19 | Rtx Corporation | Gas turbine engine with integral bypass duct |
US12116934B2 (en) | 2023-02-10 | 2024-10-15 | Rtx Corporation | Turbine engine fuel injector with oxygen circuit |
Also Published As
Publication number | Publication date |
---|---|
JPS5342897B2 (he) | 1978-11-15 |
DE2355127C2 (de) | 1983-11-03 |
FR2206441A1 (he) | 1974-06-07 |
GB1450190A (en) | 1976-09-22 |
CA985514A (en) | 1976-03-16 |
JPS4968929A (he) | 1974-07-04 |
CH560356A5 (he) | 1975-03-27 |
DE2355127A1 (de) | 1974-05-22 |
IT996392B (it) | 1975-12-10 |
FR2206441B1 (he) | 1976-06-25 |
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