US3872309A - Radiographic intensifying screens - Google Patents
Radiographic intensifying screens Download PDFInfo
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- US3872309A US3872309A US303388A US30338872A US3872309A US 3872309 A US3872309 A US 3872309A US 303388 A US303388 A US 303388A US 30338872 A US30338872 A US 30338872A US 3872309 A US3872309 A US 3872309A
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- United States
- Prior art keywords
- fluorescent
- intensifying screen
- combination according
- screen combination
- substrate
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- 239000000463 material Substances 0.000 claims abstract description 27
- -1 silver halide Chemical class 0.000 claims abstract description 27
- 239000000126 substance Substances 0.000 claims abstract description 27
- 229910052751 metal Inorganic materials 0.000 claims abstract description 26
- 239000002184 metal Substances 0.000 claims abstract description 26
- 229910052709 silver Inorganic materials 0.000 claims abstract description 26
- 239000004332 silver Substances 0.000 claims abstract description 26
- 239000000758 substrate Substances 0.000 claims description 61
- 239000012790 adhesive layer Substances 0.000 claims description 21
- 229910052771 Terbium Inorganic materials 0.000 claims description 16
- GZCRRIHWUXGPOV-UHFFFAOYSA-N terbium atom Chemical compound [Tb] GZCRRIHWUXGPOV-UHFFFAOYSA-N 0.000 claims description 14
- 239000000203 mixture Substances 0.000 claims description 12
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 10
- 239000005864 Sulphur Substances 0.000 claims description 10
- 239000011230 binding agent Substances 0.000 claims description 10
- 229910052736 halogen Inorganic materials 0.000 claims description 10
- 238000000034 method Methods 0.000 claims description 10
- 229910052688 Gadolinium Inorganic materials 0.000 claims description 9
- UIWYJDYFSGRHKR-UHFFFAOYSA-N gadolinium atom Chemical compound [Gd] UIWYJDYFSGRHKR-UHFFFAOYSA-N 0.000 claims description 9
- 150000002367 halogens Chemical class 0.000 claims description 9
- 229910052746 lanthanum Inorganic materials 0.000 claims description 9
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 claims description 9
- 229910052727 yttrium Inorganic materials 0.000 claims description 8
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 claims description 8
- 229910052692 Dysprosium Inorganic materials 0.000 claims description 7
- 229910052693 Europium Inorganic materials 0.000 claims description 7
- OGPBJKLSAFTDLK-UHFFFAOYSA-N europium atom Chemical compound [Eu] OGPBJKLSAFTDLK-UHFFFAOYSA-N 0.000 claims description 7
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 6
- KBQHZAAAGSGFKK-UHFFFAOYSA-N dysprosium atom Chemical compound [Dy] KBQHZAAAGSGFKK-UHFFFAOYSA-N 0.000 claims description 6
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 6
- 230000000191 radiation effect Effects 0.000 claims description 6
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 6
- 229910052721 tungsten Inorganic materials 0.000 claims description 6
- 239000010937 tungsten Substances 0.000 claims description 6
- 229910052691 Erbium Inorganic materials 0.000 claims description 5
- 229910052689 Holmium Inorganic materials 0.000 claims description 5
- 229910052765 Lutetium Inorganic materials 0.000 claims description 5
- 229910052779 Neodymium Inorganic materials 0.000 claims description 5
- 229910052777 Praseodymium Inorganic materials 0.000 claims description 5
- 229910052772 Samarium Inorganic materials 0.000 claims description 5
- 229910052775 Thulium Inorganic materials 0.000 claims description 5
- 229910052769 Ytterbium Inorganic materials 0.000 claims description 5
- UYAHIZSMUZPPFV-UHFFFAOYSA-N erbium Chemical compound [Er] UYAHIZSMUZPPFV-UHFFFAOYSA-N 0.000 claims description 5
- KJZYNXUDTRRSPN-UHFFFAOYSA-N holmium atom Chemical compound [Ho] KJZYNXUDTRRSPN-UHFFFAOYSA-N 0.000 claims description 5
- UPIZSELIQBYSMU-UHFFFAOYSA-N lanthanum;sulfur monoxide Chemical compound [La].S=O UPIZSELIQBYSMU-UHFFFAOYSA-N 0.000 claims description 5
- OHSVLFRHMCKCQY-UHFFFAOYSA-N lutetium atom Chemical compound [Lu] OHSVLFRHMCKCQY-UHFFFAOYSA-N 0.000 claims description 5
- 150000002739 metals Chemical class 0.000 claims description 5
- QEFYFXOXNSNQGX-UHFFFAOYSA-N neodymium atom Chemical compound [Nd] QEFYFXOXNSNQGX-UHFFFAOYSA-N 0.000 claims description 5
- 239000000123 paper Substances 0.000 claims description 5
- PUDIUYLPXJFUGB-UHFFFAOYSA-N praseodymium atom Chemical compound [Pr] PUDIUYLPXJFUGB-UHFFFAOYSA-N 0.000 claims description 5
- 229910052761 rare earth metal Inorganic materials 0.000 claims description 5
- 150000002910 rare earth metals Chemical class 0.000 claims description 5
- KZUNJOHGWZRPMI-UHFFFAOYSA-N samarium atom Chemical compound [Sm] KZUNJOHGWZRPMI-UHFFFAOYSA-N 0.000 claims description 5
- 238000012216 screening Methods 0.000 claims description 5
- NAWDYIZEMPQZHO-UHFFFAOYSA-N ytterbium Chemical compound [Yb] NAWDYIZEMPQZHO-UHFFFAOYSA-N 0.000 claims description 5
- 239000002131 composite material Substances 0.000 claims description 4
- 229920006158 high molecular weight polymer Polymers 0.000 claims description 4
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 claims description 4
- 229920000642 polymer Polymers 0.000 claims description 4
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 3
- SKQWEERDYRHPFP-UHFFFAOYSA-N [Y].S=O Chemical compound [Y].S=O SKQWEERDYRHPFP-UHFFFAOYSA-N 0.000 claims description 3
- 229920000180 alkyd Polymers 0.000 claims description 3
- 229910052797 bismuth Inorganic materials 0.000 claims description 3
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 claims description 3
- 239000004744 fabric Substances 0.000 claims description 3
- 239000011521 glass Substances 0.000 claims description 3
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 3
- 229910052737 gold Inorganic materials 0.000 claims description 3
- 239000010931 gold Substances 0.000 claims description 3
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 claims description 3
- 229910052753 mercury Inorganic materials 0.000 claims description 3
- 239000002985 plastic film Substances 0.000 claims description 3
- 229920006255 plastic film Polymers 0.000 claims description 3
- 229910052697 platinum Inorganic materials 0.000 claims description 3
- XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical compound S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 claims description 3
- 229920003051 synthetic elastomer Polymers 0.000 claims description 3
- 239000005061 synthetic rubber Substances 0.000 claims description 3
- 229910052715 tantalum Inorganic materials 0.000 claims description 3
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 claims description 3
- 229910052714 tellurium Inorganic materials 0.000 claims description 3
- PORWMNRCUJJQNO-UHFFFAOYSA-N tellurium atom Chemical compound [Te] PORWMNRCUJJQNO-UHFFFAOYSA-N 0.000 claims description 3
- 229910052716 thallium Inorganic materials 0.000 claims description 3
- BKVIYDNLLOSFOA-UHFFFAOYSA-N thallium Chemical compound [Tl] BKVIYDNLLOSFOA-UHFFFAOYSA-N 0.000 claims description 3
- 229910052718 tin Inorganic materials 0.000 claims description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 2
- 230000001678 irradiating effect Effects 0.000 claims description 2
- 229910052760 oxygen Inorganic materials 0.000 claims description 2
- 239000001301 oxygen Substances 0.000 claims description 2
- 230000001681 protective effect Effects 0.000 claims description 2
- LNBHUCHAFZUEGJ-UHFFFAOYSA-N europium(3+) Chemical compound [Eu+3] LNBHUCHAFZUEGJ-UHFFFAOYSA-N 0.000 claims 1
- 125000005843 halogen group Chemical group 0.000 claims 1
- 239000010410 layer Substances 0.000 description 30
- 230000005855 radiation Effects 0.000 description 26
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 10
- 239000011888 foil Substances 0.000 description 7
- 239000000839 emulsion Substances 0.000 description 5
- 229920001084 poly(chloroprene) Polymers 0.000 description 5
- 239000000020 Nitrocellulose Substances 0.000 description 4
- FJWGYAHXMCUOOM-QHOUIDNNSA-N [(2s,3r,4s,5r,6r)-2-[(2r,3r,4s,5r,6s)-4,5-dinitrooxy-2-(nitrooxymethyl)-6-[(2r,3r,4s,5r,6s)-4,5,6-trinitrooxy-2-(nitrooxymethyl)oxan-3-yl]oxyoxan-3-yl]oxy-3,5-dinitrooxy-6-(nitrooxymethyl)oxan-4-yl] nitrate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O)O[C@H]1[C@@H]([C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@@H](CO[N+]([O-])=O)O1)O[N+]([O-])=O)CO[N+](=O)[O-])[C@@H]1[C@@H](CO[N+]([O-])=O)O[C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O FJWGYAHXMCUOOM-QHOUIDNNSA-N 0.000 description 4
- 238000010521 absorption reaction Methods 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 229920001220 nitrocellulos Polymers 0.000 description 4
- 238000001429 visible spectrum Methods 0.000 description 3
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- 206010070834 Sensitisation Diseases 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- 239000012298 atmosphere Substances 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 229920002301 cellulose acetate Polymers 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 2
- 230000003993 interaction Effects 0.000 description 2
- 238000010030 laminating Methods 0.000 description 2
- 230000000149 penetrating effect Effects 0.000 description 2
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 2
- 239000004926 polymethyl methacrylate Substances 0.000 description 2
- 238000006862 quantum yield reaction Methods 0.000 description 2
- 238000002601 radiography Methods 0.000 description 2
- 239000011541 reaction mixture Substances 0.000 description 2
- 230000008313 sensitization Effects 0.000 description 2
- GRVFOGOEDUUMBP-UHFFFAOYSA-N sodium sulfide (anhydrous) Chemical compound [Na+].[Na+].[S-2] GRVFOGOEDUUMBP-UHFFFAOYSA-N 0.000 description 2
- 230000003595 spectral effect Effects 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- PBYZMCDFOULPGH-UHFFFAOYSA-N tungstate Chemical compound [O-][W]([O-])(=O)=O PBYZMCDFOULPGH-UHFFFAOYSA-N 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 239000001856 Ethyl cellulose Substances 0.000 description 1
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 1
- 229920000459 Nitrile rubber Polymers 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 230000002238 attenuated effect Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 229910003460 diamond Inorganic materials 0.000 description 1
- 239000010432 diamond Substances 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 229920001249 ethyl cellulose Polymers 0.000 description 1
- 235000019325 ethyl cellulose Nutrition 0.000 description 1
- 239000010408 film Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- BAZGIOYKWQZSCP-UHFFFAOYSA-N lutetium sulfur monoxide Chemical compound [Lu].O=S BAZGIOYKWQZSCP-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- JRKOTWNXVJULFC-UHFFFAOYSA-N n-ethyl-n-methyl-3-pyrrolidin-3-ylbenzamide;hydrochloride Chemical compound Cl.CCN(C)C(=O)C1=CC=CC(C2CNCC2)=C1 JRKOTWNXVJULFC-UHFFFAOYSA-N 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
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Images
Classifications
-
- G—PHYSICS
- G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
- G21K—TECHNIQUES FOR HANDLING PARTICLES OR IONISING RADIATION NOT OTHERWISE PROVIDED FOR; IRRADIATION DEVICES; GAMMA RAY OR X-RAY MICROSCOPES
- G21K4/00—Conversion screens for the conversion of the spatial distribution of X-rays or particle radiation into visible images, e.g. fluoroscopic screens
Definitions
- M is at least one of the metals yttrium, lanthanum.
- M is at least one of the rare earth metals dysprosium, erbium, europium, holmium, neodymium, praseodymium, samarium, terbium, thulium or ytterbium,
- X is sulphur or halogen
- n 0.0002 to 0.2
- l w is 1 when X is halogen or is 2 when X is sulphur.
- the intensifying effect of such screens is based on the emission of secondary X-rays and electrons formed by the absorption of primary incident X-rays.
- metal screens act as a filter for scattered radiation of lower energy and effectively absorb low energy rays obliquely impinging onto the metal screen.
- Fluorescent screens which contain a layer or sheet comprising solid substances, e.g., calcium tungstate that fluoresce under the influence of X-ray radiation, have been used, e.g., in the field of medical X-ray. However, they are less effective when more energetic X-rays or gamma rays are used, the absorption of the penetrating X-ray and gamma radiation in the fluorescent screens being inversely proportional to their energy. A higher absorption can be obtained by increasing the thickness but such at the expense of a loss in image sharpness. Moreover, secondary scattered radiation originating from the radiographically exposed object by impinging on a fluorescent screen, e.g., a calcium tungstate screen, gives rise to the production of radiographic images of low gradation when silver halide recording materials are used.
- solid substances e.g., calcium tungstate that fluoresce under the influence of X-ray radiation
- Such a combination provides a high gain in effective interaction of radiation with photographic materials of the silver halide type without substantial loss of image quality.
- This high gain in effective interaction may be explained by the fact that the partial transformation of the initial high energy radiation in the metallic screen yields secondary radiation of low energy (X-rays and electrons) that are better absorbed in this lower energy state by the fluorescent substance and give rise to fluorescence radiation mainly in the ultraviolet and visible light range for which silver halide recording materials are inherently particularly sensitive or can be made sensitive by spectral sensitization.
- the fluorescent layer is kept rather thin.
- the light emitted by the fluorescent screen is effectively absorbed by the silver halide grains of a silver halide emulsion layer and radiographic images of improved sharpness and characterized by an increased gradation are obtained.
- ultraviolet radiation and visible light yield steeper gradation images than X-ray radiation directly interacting with silver halide emulsion layers.
- the screen assembly further also offers the advantage of increasing the gradation as a result of the attenuation by the metallic screen of the scattered radiation originating from the object that is radiographed.
- the absorption and emission properties of the combined metallic screen and fluorescent substance screen have to be such that as much as possible of the high energy radiation is transformed in the metallic screen in secondary radiation suited for generating in the fluorescent substances of the fluorescent screen'a fluorescence radiation in a wavelength range to whichthe silver halide grains are inherently particularly sensitive or are made particularly sensitive by spectral sensitization.
- a rad-iographic intensifying screen combination that is particularly useful for radiographic recording of information with a silver halide recording material, which combination comprises (l) at least one metallic layer or sheet composed of or containing at least one metal having an atomic number in the range of 46 to 83, and (2) at least one fluorescent layer or sheet which, in working relationship with said metal(s) consists of or contains at least one fluorescent substance within the scope of the following general formula:
- M is at least one of the metals yttrium, lanthanum,
- M is at least one of the rare earth metals dysprosium, erbium, europium, holmium, neodymium, praseo dymium, samarium, terbium,thulium or ytterbium,
- X is sulphur or halogen
- n 0.0002 to 0.2
- w is 1 when X is halogen or is 2 when X is sulphur.
- radiographic When using the term radiographic, recording we designate thereby a recording technique that makes use of penetrating radiation, which includes highly energetic radiation such as X-rays, beta rays, or fast electrons, e.g., as obtained in an electron microscope,
- the fluorescent screen transforms the absorbed X-ray radiation (e.g., 60 kV X-ray radiation) with a high quantum yield in radiation of wavelength bands situated in the 320 to the 450 nm wavelength range.
- the terbium activated yttrium oxysulphide compounds falling within the scope of the above general formula.
- terbium-activated gadolinium or lanthanum oxysulphides falling within the scope of the above general formula are used.
- an europium(IlI)-activated mixed oxysulphide of yttrium and lanthanum falling within the scope of the above general formula is used.
- gadoliniumor lanthanum or lutetium oxysulphide activated with terbium or dysprosium is particularly useful for its high visible light'emission capacity.
- a preferred ratio by weight of (A) and (B) is 25:75.
- a fluorescence over the whole visible spectrum can be obtained.
- Such combination is particularly useful for the recording on silver halide recording elements that are made spectrally sensitive for light of the whole visible spectrum.
- the selected fluorescent substance(s) is(are) applied in the form of at least one layer or sheet.
- a said layer or sheet is preferably constructed to a thickness of 0.05 to 0.5 mm and contains the fluorescent substance(s) dispersed in a binder.
- binder is, e.g., an organic high molecular weight polymer.
- Preferred binding agents are cellulose nitrate, ethylcellulose, cellulose acetate, polyvinyl acetate, polystyrene, polyvinyl butyral, polymethyl methacrylate and the like.
- the proportion of high molecular weight polymer to fluorescent material is generally within the range of 5-15% by weight.
- a preferred grain size of the fluorescent substances is in the range of 5-50 u.
- the surface of the fluorescent material layer may be protected against moisture and mechanical damage by a coating of an organic high polymer applied at a thickness of 0.001 to 0.05 mm.
- Such protecting coating is, e.g., a thin film of cellulose nitrate, cellulose acetate, polymethyl methacrylate and the like.
- An appropriate screening dye for use in combination with fluorescent screens emitting in the green part of the visible spectrum is, e.g., Rouge Feu Neozapon (C.l. Solvent Red 119).
- the metallic screen may be composed of a single supported or self-supporting metal layer or of a plurality of superposed metal layers.
- the metallic screen or a plurality of screen layers may be composed of or incorporates a pure metal having an atomic number as mentioned or may be composed of an alloy containing such metal.
- the intensifying screen combination contains at least one metallic screen layer, which consists of or of which at least 50% by weight is constituted by a metal or metals having an atomic number or having atomic numbers in the range 46 to 83.
- Preferred metallic screens mainly (at least 50% by weight) contain or consist of silver. tin, tellurium, thallium. tungsten, platinum, gold, mercury, tantalum, lead or bismuth or mixtures or alloys thereof in layer or sheet form. Among them tungsten and silver offer a electron rays emitted by the metal foil is obtained and the scattered radiation is eliminated as completely as possible. Suitable supported metal layers can be formed by metallic vapour deposition. Metallic foils of suitable thickness may be obtained by rolling.
- the metallic screen may have a grooved or indented surface as described in the U5. Pat. No. 3,584,216 of Joseph F. Tinney issued June 8, 1971.
- the metallic screen element (layer(s) or sheet(s)) is supported by the same support as used for the fluorescent screen element.
- Such support is composed, e.g., of paper, glass, cloth or plastic film, the latter supports being preferably of about 0.2 mm in thickness.
- the metallic screen element is preferably interposed between the support and the fluorescent material layer(s) and adheres thereto e.g. by means of an adhesive layer.
- Suitable adhesive layers for bonding the metallic foil or other element to the fluorescent material layer are composed of an organic high polymer such as synthetic rubber, for example, neoprene, nitrile rubber, etc., polyvinyl butyral, alkyd resin and the like.
- the thickness of the adhesive layer is preferably as thin as possible and below 10 u, since the amplifying effect of the metallic screen element is lowered by increasing the thickness of said adhesive layer.
- An adhesive layer' may be used for bonding the supporting layer to the metal foil or other metallic screen element and such adhesive layer may be identical to that used for adhering the fluorescent material to such screen element.
- the thickness of a said adhesive layer between the support layer and the metallic screen need not necessarily be smaller than 10 u.
- the intensifying effect of the metallic screenfluorescent screen combination used according to the present invention is particularly high when X-rays of an energy above kV or the commonly known high energetic gamma-rays are used in the radiographic process.
- radiographic images of high contrast are obtained rapidly.
- Example 1 The present invention is illustrated by the following examples and by the drawing which is a cross-section of the screen structure of Example 1.
- EXAMPLE 1 A solution of neoprene in toluene is spray-coated on a surface of a 0.03 mm tungsten foil to form an adhesive layer 2 of 0.015 mm in thickness when dried. By a laminating press the thus obtained material is pressed with its adhesive layer in contact with a paper sheet 4 of 0.2 mm in thickness.
- Gd O S activated with traces of Tb 300 g cellulose nitrate 36 g dibutyl phthalate 11 g butyl acetate 450 g was applied. After drying the fluorescent coating 5 containing fluorescent substance 7 dispersed in binder 6 had a thickness of 0.12 mm.
- Gd O S activated with traces of Tb has been prepared as follows: 1 mole of Gd O and 0.01 mole of Tb O were blended together with Na S and kept in an inert atmosphere (N at l,100C for 3 hours. The reaction mixture was then washed in hot water to remove the soluble sodium sulphide reaction product.
- the so prepared fluorescent material emits green light under the effect of X-rays proceeding from a 100 kV generator.
- Said intensifying screen material is particularly suitable for forming radiographs in light-sensitive silver halide materials spectrally sensitized to green light.
- EXAMPLE 2 A solution of neoprene in toluene is spray-coated on a surface of a 0.03 mm silver foil to form an adhesive layer of 0.015 mm in thickness when dried. By a laminating press the thus obtained material is pressed with its adhesive layer in contact with a paper sheet of 0.2 mm in thickness.
- the so prepared fluorescent material emits ultraviolet radiation and blue light.
- the composite intensifying screen has been exposed in combination with a spectrally non-sensitized radiographic silver halide film, the X-rays being produced under 60 kV. Sharp contrasty radiographic images have been obtained.
- a radiographic intensifying screen combination suited for use in radiographic recording of information with a silver halide recording material, said combination comprising (1) a metallic substrate including at least one metal having an atomic number in the range of 46 to 83, and (2) at least one fluorescent substrate in working relationship with said metal and including at least one fluorescent substance having the formula:
- M is at least one of the-metals selected from the group consisting of yttrium, lanthanum, gadolinium and lutetium,
- M is at least one of the rare earth metals selected from the group consisting of hysprosium, erbium, europium, holmium, neodymium, praseodymium, samarium, terbium, thulium and ytterbium,
- X is selected from the group consisting of sulphur and halogen
- n 0.0002 to 0.2
- w 1 when X is halogen and 2 when Xis sulphur.
- said metallic substrate mainly contains a member of the group consisting of silver, tin, tellurium, thallium, tungsten, platinum, gold, mercury, tantalum, lead and bismuth and mixtures thereof.
- the fluorescent substrate includes a member of the group consisting of gadolinium and lanthanum oxysulphide activated with terbium.
- the fluorescent substrate includes a oxysulphide of yttrium and lanthanum activated with europium(IlI).
- An intensifying screen combination according to claim 1 which includes a plurality of fluorescent substrates having the same or different composition.
- a method of recording information comprising the steps of information-wise irradiating an intensifying screen to X-rays or gamma-rays and of receiving the fluorescent light emitted by the intensifying screen "onto a photographic material which is sensitive to said fluorescent light, wherein in said method the intensifying screen comprises:
- At least one metallic substrate containing at least one metal having an atomic number in the range of 46 to 83, and 2. at least one fluorescent substrate which is arranged in conjunction with said metallic substrate in such a way that electrons emitted by said metal can penetrate into the fluorescent substrate, said fluorescent substrate containing at least one fluorescent substance having the formula:
- M is at least one of the metals selected from the group consisting of yttrium, lanthanum, gadolinium and lutetium,
- M is at least one of the rare earth metals selected from the group consisting of dysprosium, erbium, europium, holmium, neodymium, praseodymium, samarium, terbium, thulium and ytterbium,
- O oxygen
- X is a member of the group selected from sulphur and halogen
- n 0.0002 to 0.2
- w 1 when X is halogen and 2 when X is sulphur.
- the fluorescent substrate includes a member of the group consisting of gadolinium and lanthanum oxysulphide activated with terbium.
Landscapes
- Physics & Mathematics (AREA)
- Engineering & Computer Science (AREA)
- General Engineering & Computer Science (AREA)
- High Energy & Nuclear Physics (AREA)
- Conversion Of X-Rays Into Visible Images (AREA)
- Luminescent Compositions (AREA)
- Silver Salt Photography Or Processing Solution Therefor (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB6105071A GB1389024A (en) | 1971-12-31 | 1971-12-31 | Radiographic intensifying screens |
Publications (1)
Publication Number | Publication Date |
---|---|
US3872309A true US3872309A (en) | 1975-03-18 |
Family
ID=10486529
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US303388A Expired - Lifetime US3872309A (en) | 1971-12-31 | 1972-11-03 | Radiographic intensifying screens |
Country Status (8)
Country | Link |
---|---|
US (1) | US3872309A (enrdf_load_stackoverflow) |
JP (1) | JPS4881582A (enrdf_load_stackoverflow) |
BE (1) | BE792387A (enrdf_load_stackoverflow) |
CA (1) | CA968073A (enrdf_load_stackoverflow) |
DE (1) | DE2260858A1 (enrdf_load_stackoverflow) |
FR (1) | FR2167011A5 (enrdf_load_stackoverflow) |
GB (1) | GB1389024A (enrdf_load_stackoverflow) |
IT (1) | IT975679B (enrdf_load_stackoverflow) |
Cited By (27)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3980887A (en) * | 1973-08-27 | 1976-09-14 | U.S. Radium Corporation | Silicon sensitized rare earth oxysulfide phosphors |
US4054798A (en) * | 1975-11-14 | 1977-10-18 | Tokyo Shibaura Electric Co., Ltd. | X-ray conversion screens |
US4101781A (en) * | 1977-06-27 | 1978-07-18 | Hewlett-Packard Company | Stable fiber optic scintillative x-ray screen and method of production |
US4138361A (en) * | 1976-03-18 | 1979-02-06 | Agfa-Gevaert N.V. | Radiation-conversion screens |
US4149083A (en) * | 1976-03-18 | 1979-04-10 | Agfa-Gevaert N.V. | Radiographic intensifying screens |
US4256965A (en) * | 1979-01-15 | 1981-03-17 | The United States Of America As Represented By The Secretary Of The Navy | High energy fluoroscopic screen |
US4297584A (en) * | 1977-04-11 | 1981-10-27 | Lockheed Missiles & Space Company, Inc. | Rare earth phosphors and phosphor screens |
US4398093A (en) * | 1979-08-14 | 1983-08-09 | Etat Francais, Represente Par Le Ministere De L'environnement Et De Cadre De Vie, Laboratoire Central Des Ponts Et Chaussess | Converter for converting non-luminous photons into luminous photons |
DE3212405A1 (de) * | 1982-04-02 | 1983-10-13 | Siemens AG, 1000 Berlin und 8000 München | Mit terbium aktivierter yttriumoxisulfid-leuchtstoff |
US4486486A (en) * | 1982-03-15 | 1984-12-04 | Kasei Optonix, Ltd. | Radiographic image conversion screens |
US4499159A (en) * | 1984-04-13 | 1985-02-12 | General Electric Company | X-ray image converters utilizing rare earth oxyhalide phosphors |
US4507560A (en) * | 1980-06-13 | 1985-03-26 | Gte Products Corporation | Terbium-activated gadolinium oxysulfide X-ray phosphor |
US4712011A (en) * | 1985-04-03 | 1987-12-08 | U.S. Philips Corporation | X-ray image intensifier tube including a luminescent layer which absorbs secondary radiation |
US4764946A (en) * | 1984-11-05 | 1988-08-16 | Innofinance Altalanos Innovacios Penzwtezet | Method and modifying body for influencing the effect of X-ray or gamma radiation on a target sensitive to the radiation |
US4839266A (en) * | 1986-04-29 | 1989-06-13 | E. I. Du Pont De Nemours And Company | Recording system for irradiation therapy |
US5025163A (en) * | 1989-12-01 | 1991-06-18 | Eastman Kodak Company | Radiographic imaging screen |
US5334843A (en) * | 1992-08-17 | 1994-08-02 | Zeman Herbert D | Composite scintillator screen |
WO2000056837A1 (en) * | 1999-03-19 | 2000-09-28 | Rutgers, The State University | Rare earth doped host materials |
USRE37536E1 (en) | 1982-11-26 | 2002-02-05 | Uab Research Foundation | Split energy level radiation detection |
EP1223464A3 (en) * | 2001-01-10 | 2004-04-14 | Eastman Kodak Company | Light-weight imaging assemblies for oncology portal imaging |
US20040174917A1 (en) * | 1999-03-19 | 2004-09-09 | Rutgers, The State University | Optically transparent nanocomposite materials |
US20040262536A1 (en) * | 2003-06-30 | 2004-12-30 | Van Den Bergh Rudy | Rare earth activated rare earth oxysulfide phosphor for direct X-ray detection |
EP1493798A1 (en) * | 2003-06-30 | 2005-01-05 | Agfa-Gevaert | Rare earth activated lutetium oxysulfide phosphor for direct x-ray detection. |
US20050002490A1 (en) * | 2003-06-30 | 2005-01-06 | Bergh Rudy Van Den | Rare earth activated lutetium oxyorthosilicate phosphor for direct X-ray detection |
US20060038134A1 (en) * | 2004-06-08 | 2006-02-23 | Fuji Photo Film Co., Ltd. | Radiographic intensifying screen |
US20060214109A1 (en) * | 2005-03-25 | 2006-09-28 | General Electric Company | Detector assembly and method of manufacture |
US20060261722A1 (en) * | 2005-05-23 | 2006-11-23 | General Electric Company | Phosphor admixture, phosphor screen and imaging assembly |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4070583A (en) * | 1976-12-13 | 1978-01-24 | General Electric Company | Rare earth oxyhalide phosphors coactivated with terbium, thulium |
JPS54107692A (en) * | 1978-02-10 | 1979-08-23 | Dainippon Toryo Kk | Radiant ray intensifying paper |
US4195228A (en) * | 1978-05-19 | 1980-03-25 | General Electric Company | Color contrast radiographic device |
DE3275420D1 (en) * | 1982-03-15 | 1987-03-12 | Kasei Optonix | Radiographic image conversion screens |
GB2119396B (en) * | 1982-04-26 | 1985-11-20 | Gen Electric | Multi-layer x-ray screens |
US4481416A (en) * | 1982-12-20 | 1984-11-06 | General Electric Company | Thermoluminescent coactivated rare earth oxyhalide phosphors and x-ray image converters utilizing said phosphors |
JPS59189200U (ja) * | 1983-03-11 | 1984-12-15 | 化成オプトニクス株式会社 | 放射線増感紙 |
JPS6195351A (ja) * | 1984-10-17 | 1986-05-14 | Kasei Optonix Co Ltd | 増感紙 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3584216A (en) * | 1968-09-12 | 1971-06-08 | Bendix Corp | Radiographic intensifying screen |
US3617743A (en) * | 1968-10-23 | 1971-11-02 | Gen Electric | X-ray image convertors utilizing lanthanum and gadolinium oxyhalide luminescent materials activated with terbium |
US3617285A (en) * | 1969-10-21 | 1971-11-02 | William Joseph Staudenmayer | Light intensifying screens |
-
0
- BE BE792387D patent/BE792387A/nl unknown
-
1971
- 1971-12-31 GB GB6105071A patent/GB1389024A/en not_active Expired
-
1972
- 1972-11-03 US US303388A patent/US3872309A/en not_active Expired - Lifetime
- 1972-11-06 CA CA155,670A patent/CA968073A/en not_active Expired
- 1972-12-11 FR FR7244093A patent/FR2167011A5/fr not_active Expired
- 1972-12-12 JP JP47124702A patent/JPS4881582A/ja active Pending
- 1972-12-13 DE DE2260858A patent/DE2260858A1/de active Pending
- 1972-12-14 IT IT86292/72A patent/IT975679B/it active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3584216A (en) * | 1968-09-12 | 1971-06-08 | Bendix Corp | Radiographic intensifying screen |
US3617743A (en) * | 1968-10-23 | 1971-11-02 | Gen Electric | X-ray image convertors utilizing lanthanum and gadolinium oxyhalide luminescent materials activated with terbium |
US3617285A (en) * | 1969-10-21 | 1971-11-02 | William Joseph Staudenmayer | Light intensifying screens |
Cited By (33)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3980887A (en) * | 1973-08-27 | 1976-09-14 | U.S. Radium Corporation | Silicon sensitized rare earth oxysulfide phosphors |
US4054798A (en) * | 1975-11-14 | 1977-10-18 | Tokyo Shibaura Electric Co., Ltd. | X-ray conversion screens |
US4138361A (en) * | 1976-03-18 | 1979-02-06 | Agfa-Gevaert N.V. | Radiation-conversion screens |
US4149083A (en) * | 1976-03-18 | 1979-04-10 | Agfa-Gevaert N.V. | Radiographic intensifying screens |
US4297584A (en) * | 1977-04-11 | 1981-10-27 | Lockheed Missiles & Space Company, Inc. | Rare earth phosphors and phosphor screens |
US4101781A (en) * | 1977-06-27 | 1978-07-18 | Hewlett-Packard Company | Stable fiber optic scintillative x-ray screen and method of production |
US4256965A (en) * | 1979-01-15 | 1981-03-17 | The United States Of America As Represented By The Secretary Of The Navy | High energy fluoroscopic screen |
US4398093A (en) * | 1979-08-14 | 1983-08-09 | Etat Francais, Represente Par Le Ministere De L'environnement Et De Cadre De Vie, Laboratoire Central Des Ponts Et Chaussess | Converter for converting non-luminous photons into luminous photons |
US4507560A (en) * | 1980-06-13 | 1985-03-26 | Gte Products Corporation | Terbium-activated gadolinium oxysulfide X-ray phosphor |
US4529647A (en) * | 1982-03-15 | 1985-07-16 | Kasei Optonix, Ltd. | Radiographic image conversion screens |
US4486486A (en) * | 1982-03-15 | 1984-12-04 | Kasei Optonix, Ltd. | Radiographic image conversion screens |
US4536436A (en) * | 1982-03-15 | 1985-08-20 | Kasei Optonix, Ltd. | Radiographic image conversion screens |
DE3212405A1 (de) * | 1982-04-02 | 1983-10-13 | Siemens AG, 1000 Berlin und 8000 München | Mit terbium aktivierter yttriumoxisulfid-leuchtstoff |
USRE37536E1 (en) | 1982-11-26 | 2002-02-05 | Uab Research Foundation | Split energy level radiation detection |
US4499159A (en) * | 1984-04-13 | 1985-02-12 | General Electric Company | X-ray image converters utilizing rare earth oxyhalide phosphors |
US4764946A (en) * | 1984-11-05 | 1988-08-16 | Innofinance Altalanos Innovacios Penzwtezet | Method and modifying body for influencing the effect of X-ray or gamma radiation on a target sensitive to the radiation |
US4712011A (en) * | 1985-04-03 | 1987-12-08 | U.S. Philips Corporation | X-ray image intensifier tube including a luminescent layer which absorbs secondary radiation |
US4839266A (en) * | 1986-04-29 | 1989-06-13 | E. I. Du Pont De Nemours And Company | Recording system for irradiation therapy |
US5025163A (en) * | 1989-12-01 | 1991-06-18 | Eastman Kodak Company | Radiographic imaging screen |
US5334843A (en) * | 1992-08-17 | 1994-08-02 | Zeman Herbert D | Composite scintillator screen |
US7094361B2 (en) | 1999-03-19 | 2006-08-22 | Rutgers, The State University | Optically transparent nanocomposite materials |
WO2000056837A1 (en) * | 1999-03-19 | 2000-09-28 | Rutgers, The State University | Rare earth doped host materials |
US6699406B2 (en) * | 1999-03-19 | 2004-03-02 | Rutgers, The State University | Rare earth doped host materials |
US20040174917A1 (en) * | 1999-03-19 | 2004-09-09 | Rutgers, The State University | Optically transparent nanocomposite materials |
EP1223464A3 (en) * | 2001-01-10 | 2004-04-14 | Eastman Kodak Company | Light-weight imaging assemblies for oncology portal imaging |
US20040262536A1 (en) * | 2003-06-30 | 2004-12-30 | Van Den Bergh Rudy | Rare earth activated rare earth oxysulfide phosphor for direct X-ray detection |
US20050002490A1 (en) * | 2003-06-30 | 2005-01-06 | Bergh Rudy Van Den | Rare earth activated lutetium oxyorthosilicate phosphor for direct X-ray detection |
EP1493798A1 (en) * | 2003-06-30 | 2005-01-05 | Agfa-Gevaert | Rare earth activated lutetium oxysulfide phosphor for direct x-ray detection. |
US20060038134A1 (en) * | 2004-06-08 | 2006-02-23 | Fuji Photo Film Co., Ltd. | Radiographic intensifying screen |
US20060214109A1 (en) * | 2005-03-25 | 2006-09-28 | General Electric Company | Detector assembly and method of manufacture |
US7214947B2 (en) | 2005-03-25 | 2007-05-08 | General Electric Company | Detector assembly and method of manufacture |
US20060261722A1 (en) * | 2005-05-23 | 2006-11-23 | General Electric Company | Phosphor admixture, phosphor screen and imaging assembly |
US7586252B2 (en) | 2005-05-23 | 2009-09-08 | General Electric Company | Phosphor screen and imaging assembly |
Also Published As
Publication number | Publication date |
---|---|
JPS4881582A (enrdf_load_stackoverflow) | 1973-10-31 |
CA968073A (en) | 1975-05-20 |
BE792387A (nl) | 1973-06-07 |
GB1389024A (en) | 1975-04-03 |
IT975679B (it) | 1974-08-10 |
FR2167011A5 (enrdf_load_stackoverflow) | 1973-08-17 |
DE2260858A1 (de) | 1973-07-05 |
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