US386247A - Thomas holliday - Google Patents
Thomas holliday Download PDFInfo
- Publication number
- US386247A US386247A US386247DA US386247A US 386247 A US386247 A US 386247A US 386247D A US386247D A US 386247DA US 386247 A US386247 A US 386247A
- Authority
- US
- United States
- Prior art keywords
- holliday
- thomas
- cotton
- nitroso
- fiber
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000835 fiber Substances 0.000 description 20
- 229920000742 Cotton Polymers 0.000 description 16
- 229910044991 metal oxide Inorganic materials 0.000 description 16
- 150000002832 nitroso derivatives Chemical class 0.000 description 12
- 238000004043 dyeing Methods 0.000 description 10
- 235000013311 vegetables Nutrition 0.000 description 10
- KJCVRFUGPWSIIH-UHFFFAOYSA-N 1-Naphthol Chemical compound C1=CC=C2C(O)=CC=CC2=C1 KJCVRFUGPWSIIH-UHFFFAOYSA-N 0.000 description 6
- JWAZRIHNYRIHIV-UHFFFAOYSA-N 2-Naphthol Chemical compound C1=CC=CC2=CC(O)=CC=C21 JWAZRIHNYRIHIV-UHFFFAOYSA-N 0.000 description 6
- 229950011260 betanaphthol Drugs 0.000 description 6
- 239000003086 colorant Substances 0.000 description 6
- 230000015572 biosynthetic process Effects 0.000 description 4
- 238000005755 formation reaction Methods 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- SYUYTOYKQOAVDW-UHFFFAOYSA-N 2-nitrosonaphthalen-1-ol Chemical compound C1=CC=C2C(O)=C(N=O)C=CC2=C1 SYUYTOYKQOAVDW-UHFFFAOYSA-N 0.000 description 2
- 239000001263 FEMA 3042 Substances 0.000 description 2
- 240000007829 Haematoxylum campechianum Species 0.000 description 2
- 229940033123 Tannic Acid Drugs 0.000 description 2
- LRBQNJMCXXYXIU-NRMVVENXSA-N Tannic acid Chemical compound OC1=C(O)C(O)=CC(C(=O)OC=2C(=C(O)C=C(C=2)C(=O)OC[C@@H]2[C@H]([C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)O2)OC(=O)C=2C=C(OC(=O)C=3C=C(O)C(O)=C(O)C=3)C(O)=C(O)C=2)O)=C1 LRBQNJMCXXYXIU-NRMVVENXSA-N 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- SOCTUWSJJQCPFX-UHFFFAOYSA-N dichromate(2-) Chemical compound [O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O SOCTUWSJJQCPFX-UHFFFAOYSA-N 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- 229910000460 iron oxide Inorganic materials 0.000 description 2
- 125000000018 nitroso group Chemical group N(=O)* 0.000 description 2
- GQPLMRYTRLFLPF-UHFFFAOYSA-N nitrous oxide Inorganic materials [O-][N+]#N GQPLMRYTRLFLPF-UHFFFAOYSA-N 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- 235000015523 tannic acid Nutrition 0.000 description 2
- 229920002258 tannic acid Polymers 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/32—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using oxidation dyes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S8/00—Bleaching and dyeing; fluid treatment and chemical modification of textiles and fibers
- Y10S8/916—Natural fiber dyeing
- Y10S8/917—Wool or silk
Definitions
- This invention in dyeing cotton or other vegetable fibers consists in the formation thereon of the various insoluble colored products of the combinations of the nitroso compounds of alpha and beta naphthol with metallic oxides and the production of a further variety of shades of color by the employment of the nitroso compounds in connection with dyestuffs at present in use that produce colors when combined with metallic oxides.
- the nitroso compounds I prefer to use in a finelyprecipitated state, and the metallic oxides which produce good results are those of iron chrome and copper, though some others produce colors.
- the metallic oxides can be fixed in the cotton in any known manner, the depth of color obtainable being varied accord ing to the quantity of oxide fixed in the fiber. Taking, for example, one hundred pounds of cotton hanks on which iron oxide has been fixed and boiling it in water to which, say, twenty pounds of a ten per cent. nitroso-naphthol paste has been added, a green color fast to light will be produced.
- the metallic oxides can be employed when fixed on the fiber either by means of dyeing processes or the means usually employed by calico-printers.
- Dyestuffs-such as logwood, fustiealizarine, &c.ean be used in the same bath as the nitroso body, and will vary the resulting colors, or they can be used either before or after.
- Cotton or other vegetable fibers can be dyed either in a raw or finished state,or in any state of manufacture.
- I claim- 1 The dyeing of cotton or other vegetable fiber by the formation thereon of the colored products of the combination of the nitroso compounds of alpha or beta naphthol with metallic oxides, substantially as described.
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Coloring (AREA)
Description
UNITED STATES PATENT OFFICE.
THOMAS HOLLIDAY, OF HUDDERSFIELD, COUNTY OF YORK, ENGLAND, ASSIGNOR TO READ HOLLIDAY & SONS, OF SAME PLACE.
PROCESS OF DYEING.
FsPECIPICATION forming part of Letters Patent No. 386,247,dr.ted July 17, 1888.
(No specimens.)
To-aZZ whom it may concern.-
Be it known that I, THOMAS HOLLIDAY, a subject ofthe Queen of Great Britain, residing in Huddersfield, in the county of York, England, have invented certain new and useful Improvements in Dyeing Cotton or other Vegetable Fibers, of which the following is a specification.
This invention in dyeing cotton or other vegetable fibers consists in the formation thereon of the various insoluble colored products of the combinations of the nitroso compounds of alpha and beta naphthol with metallic oxides and the production of a further variety of shades of color by the employment of the nitroso compounds in connection with dyestuffs at present in use that produce colors when combined with metallic oxides.
The nitroso compounds I prefer to use in a finelyprecipitated state, and the metallic oxides which produce good results are those of iron chrome and copper, though some others produce colors. The metallic oxides can be fixed in the cotton in any known manner, the depth of color obtainable being varied accord ing to the quantity of oxide fixed in the fiber. Taking, for example, one hundred pounds of cotton hanks on which iron oxide has been fixed and boiling it in water to which, say, twenty pounds of a ten per cent. nitroso-naphthol paste has been added, a green color fast to light will be produced.
It is not always necessary to-fix on the fiber the metallic oxide before the application of the nitrous compound, as when oil or tannic acid has been applied to the cotton it will absorb ,l'romawarm bath of nitroso-naphtholsufficient of that body to produce color when afterward heated in a bath ofa metallic salt-such as bichromate ofpotash orsnlphate ofironthough in some cases a metallic salt and nitroso compound may be present in the bath at the same time and the color formed as fast as an oxide is deposited on the fiber. I prefer the separate treatments already mentioned.
The metallic oxides can be employed when fixed on the fiber either by means of dyeing processes or the means usually employed by calico-printers.
Dyestuffs-such as logwood, fustiealizarine, &c.ean be used in the same bath as the nitroso body, and will vary the resulting colors, or they can be used either before or after.
Cotton or other vegetable fibers can be dyed either in a raw or finished state,or in any state of manufacture.
Having explained the nature of the invention and method of carrying it into effect, I would have it understood that, without confining myselfto the details given,l disclaim herein the invention set forth in Letters Patent Ne. 362,835, granted to me May 10, 1887, which relates to the treatment of animal fibers.
I claim- 1. The dyeing of cotton or other vegetable fiber by the formation thereon of the colored products of the combination of the nitroso compounds of alpha or beta naphthol with metallic oxides, substantially as described.
2. Cotton or other vegetable fiber colored with the combination of the nitroso compounds of alpha or beta naphthol with metallic oxide.
In witness whereof I have hereunto signed my name in the presence of two subscribing witnesses.
THOM AS HOLLIDAY.
Vitnesses:
C. W. WHITMAN,
Consular A gent. Tnonxs H. BARRON,
lllorset Place, Huddersfield.
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US386247A true US386247A (en) | 1888-07-17 |
Family
ID=2455231
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US386247D Expired - Lifetime US386247A (en) | Thomas holliday |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US386247A (en) |
-
0
- US US386247D patent/US386247A/en not_active Expired - Lifetime
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