US3853677A - Roll made of non-woven cloth - Google Patents

Roll made of non-woven cloth Download PDF

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US3853677A
US3853677A US00320305A US32030573A US3853677A US 3853677 A US3853677 A US 3853677A US 00320305 A US00320305 A US 00320305A US 32030573 A US32030573 A US 32030573A US 3853677 A US3853677 A US 3853677A
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roll
woven cloth
elements
rolls
coefficient
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US00320305A
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M Kai
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Toho Yogyo Co Ltd
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Toho Yogyo Co Ltd
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16CSHAFTS; FLEXIBLE SHAFTS; ELEMENTS OR CRANKSHAFT MECHANISMS; ROTARY BODIES OTHER THAN GEARING ELEMENTS; BEARINGS
    • F16C13/00Rolls, drums, discs, or the like; Bearings or mountings therefor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29DPRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
    • B29D99/00Subject matter not provided for in other groups of this subclass
    • B29D99/0032Producing rolling bodies, e.g. rollers, wheels, pulleys or pinions
    • B29D99/0035Producing rolling bodies, e.g. rollers, wheels, pulleys or pinions rollers or cylinders having an axial length of several times the diameter, e.g. for embossing, pressing, or printing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29LINDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2031/00Other particular articles
    • B29L2031/32Wheels, pinions, pulleys, castors or rollers, Rims
    • B29L2031/324Rollers or cylinders having an axial length of several times the diameter, e.g. embossing, pressing or printing

Definitions

  • This invention relates to rolls made of non-woven cloth in which high molecular material fiber yarns such as polyester, nylon, acrylic and polypropylene are bound with natural fiber yarn such as rayon, cotton and wool by a resineus binder and heat treatment.
  • the nonwoven cloth is cut to in a desired size, is laminated or stacked onto a shaft made of iron, plastics or wood and is axially pressed together to form a roll.
  • the non-woven cloth elements pressed together to make a molded roll of a large coefficient of friction and high shearing stress.
  • the coefficient of friction obtained by the nonwoven roll of the invention is remarkably high compared with that of conventional rubber rolls.
  • the surface hardness of the non-woven roll can be made as desired due to the degree of compression applied when the laminated and mounted non-woven cloth elements are molded, on the basis of the elasticity of the material of the non-woven cloth.
  • the construction of the nonwoven cloth roll is quite uniform as well as the hardness of the roll, due to the non-directional fiber organization of the non-woven cloth.
  • the heat-resistivity is good enough according to the material of the non-woven cloth.
  • a non-woven cloth is made of nylon 43 parts, cotton 18 parts, resinous binding agents 39 parts.
  • the coefficient of water absorption is 8.2 percent, the weight per unit area ZOOfiO gram/m the thickness 1.07 mm and the tensile strength l5.0kg/Scm.
  • a non-woven cloth is made of nylon 28 parts, polyester 28 parts, rayon 14 parts, resinous binding agents 30 parts.
  • the coefficient of water absorption is 52.6 percent, the weight per unit area 180:50 gram/m the thickness 2.60 mm and the tensile strength 5.5 kg/Scm.
  • the non-woven cloth roll of subject application can be utilized in manufacturing pinch rolls, such assnubber rolls, deflector rolls, tension bridle'rolls, wringer rolls, squeezer rolls and wiper rolls.
  • FIG. 1 shows two embodiments of an element of the non-woven cloth roll of the subject invention
  • FIG. 2 is a perspective view of the non-woven cloth roll of the subject invention
  • FIG. 3 is a schematic arrangement of rolls used for measurement of the characteristics of the non-woven cloth roll of the subject invention.
  • FIG. 4 shows the characteristic curve of the nonwoven cloth roll of the subject invention. cl DESCRIP- TION OF THE PREFERRED EMBODIMENTS;
  • non-woven cloth elements 1 and 1' shown in FIG. 1 are of 1.07 mm to 2.60 mm thickness.
  • the elements are cut from a sheet of cloth material and elements 1 and 1' are laminated or stacked onto a shaft- For Pinch Roll For Oiling Roll Hardness 83 i 2 55 2 5 (JISK 630i) Poisson's ratio 0.5 0.3 Module of shearing elasticity 33 30 Coefficient of water absorption 5.8 50.6 Shearing stress l200kg/cm 680-720
  • the most distinguished features of the roll of subject invention are the large coefficient of friction and the high shearing stress.
  • FIG. 3 The large coefficient of friction is verified by using a testing machine of the type diagronmatically shown in FIG. 3.
  • a steel plate 4 of 1.2 mm thickness with palm oil painted on the surface thereof is introduced at 5 and is taken out from an outlet 6 in the direction shown by the arrow.
  • Two pairs of tension bridle rolls 7 and snubber rolls 8 are provided between 5 and 6 and steel plate 4 is passed through the nips'defined by each associated roll 7 and 8.
  • the magnitude of the tension at intake 5 is zero and at outlet 6 is 3.5 tons.
  • Snubber rolls 8 is pressurized with a force of 3 tons as shown by arrow.
  • the angle of deflection of the steel plate is 320 and the speed of the steel plate which passes through the rolls is 400 m/min.
  • the roll of the subject invention makes it possible to treat the steel plate or the like at a high speed without causing any slippage occuring in the steel manuacturing line and any fault such as plate break or plate fold at a high speed which usually accompanies slippage does not exist at all.
  • the large coefficient of friction of the roll causes close adhesion of the roll to the steel plate so that when the roll is utilized as an oil squeezer roll, in the squeez ing operation, the oil film deposited on the steel plate is squeezed sufficiently to leave only a thickness of the oil film necessary for prevention of rust formation on the steel.
  • the full line l denotes the resultant data of the roll of the subject invention and the dotted line II denotes that of a conventional rubber roll.
  • the curves in FIG. 4 teach that oil quantity of the steel plate squeezed is reduced from I liter/ton to 0.46 liter/ton by means of the roll of the subject invention, making a reduction of 64.8 kilo liter a month with a series of lines, in which steel plate of 120 kiloton is processed a month.
  • the roll of the subject invention When the roll of the subject invention is used as a squeeze roll provided in the outlet of a water washing line, the slippage due to hydroplaning phenomena does never occur because of the large coefficient of friction so that the water is squeezed from the steel plate to a remarkable extent.
  • the roll of the subject invention as an oiling roll, two kinds of rolls are combined to constitute a pair of rolls, in the combination the oil being applied at the inlet of the rolls and the excess part of the oil being squeezed at the outlet of the rolls so that any fault due to a trace of oil appearing in the direction of advancing the steel plate at a higher processing velocity is eliminated to fully reduce the rust.
  • a pair of rolls with large coefficient of friction was used at the outlet to successfully improve the adhesion of the roll to the steel plate and to uniformly apply the oil onto the steel plate.
  • the shearing stress of the roll of the subject invention amounts, for example, to 1,200 kg/cm as compared with 620 kg/cm obtainable in a conventional rubber roll and, therefore, no tearing off of the roll results. This means that the full working duration of a single roll can be extended and also the expense for changing the roll is abolished.
  • a roll comprising a shaft having an axis and a plurality of annular disc elements of a non-woven fabric, the fabric consisting of yarns of fibers of a high molecular synthetic resin material and of natural fibers, and a resinous material binding the yarns together, the elements being stacked on the shaft and axially pressed together to form the roll, the improvement comprising the elements being heat treated and axially pressed together so that the roll has a Poissons ratio of about 0.5 and a shearing stress of about 1,200 kg/cm".
  • the roll of claim 1 having a hardness of 83: 2 and a coefficient of water absorption of about 5.8 percent.

Abstract

Fiber yarns such as polyester, nylon, and acrylicare mixed with, cotton or wool and resinous finder, and heat treated to make a non-woven cloth. The non-woven cloth is cut into disc elements which are stacked onto a shaft made of steel, plastics or wood. The laminated non-woven cloth elements are axially pressed together to form a roll having a Poisson''s ratio of 0.5 and a shearing stress of 1200 kg/cm2.

Description

United States Patent 1191 1111 3,853,677 Kai Dec. 10, 1974 [54] ROLL MADE OF NON-WOVEN CLOTH 3,617,445 11/1971 Brafford 29/132 x 3,707,752 l/l973 Brafford et a1. [75] Inventor: Momsh Kyoto Japan 3,710,469 1/1973 Kitazawa 29/125 [73] Assignee: Toho Yogyo Co., Ltd., Kyot m 3,711,913 1/1973 Galeone et a1... 29/125 Japan 3,730,794 5/1973 Ross 29/132 X [22] Filed: 1973 Primary ExaminerMayer Weinblatt [21] A l, M 320,305 Assistant Examiner-Edith L. Rollins Attorney, Agent, or Firm-Kurt Kelman [30] Foreign Application Priority Data Jan. 24, 1972 Japan 47-009288 [57] ABSTRACT Fiber yarns such as polyester, nylon, and acrylicare [52] US. Cl 161/36, 29/125, 29/132 mixed with, Cotton or wool and resinous fi d and [51] int. Cl B21b 31/08 heat treated to make a homwoven cloth. The [58] Field of Search 29/132, 125; 161/36 woven cloth is cut into disc elements which are stacked onto a shaft made of steel, plastics or wood. [56] References Clted The laminated non-woven cloth elements are axially UNITED STATES PATENTS pressed together to form a roll having a Poissons ratio 1,973,690 9/1934 Laden 1 29/125 Of (15 and a Shearing Stress Of 1200 kg/cmz- 2,801,461 8/1967 Kusters..... 29/125 X 3,588,978 6/1971 Brafford 29/132 x 2 Clams 4 Drawmg Flgul'es PM ETEL SEC] 019% BACKGROUND OF THE INVENTION This invention relates to rolls made of non-woven cloth in which high molecular material fiber yarns such as polyester, nylon, acrylic and polypropylene are bound with natural fiber yarn such as rayon, cotton and wool by a resineus binder and heat treatment. The nonwoven cloth is cut to in a desired size, is laminated or stacked onto a shaft made of iron, plastics or wood and is axially pressed together to form a roll.
It has been'desired for long time to obtain a roll of high coefficient of friction, large shearing stress, good heat-resistivity and strong oil-proofness which are all superior to those obtained by a rubber roll, in order to speed up the processing of iron manufacture, steel making and automobile industry.
SUMMARY OF THE INVENTION According to this invention, the non-woven cloth elements pressed together to make a molded roll of a large coefficient of friction and high shearing stress.
The coefficient of friction obtained by the nonwoven roll of the invention is remarkably high compared with that of conventional rubber rolls. The surface hardness of the non-woven roll can be made as desired due to the degree of compression applied when the laminated and mounted non-woven cloth elements are molded, on the basis of the elasticity of the material of the non-woven cloth. The construction of the nonwoven cloth roll is quite uniform as well as the hardness of the roll, due to the non-directional fiber organization of the non-woven cloth. The heat-resistivity is good enough according to the material of the non-woven cloth.
The representative examples of the non-woven cloths are shown as follows:
I. A non-woven cloth is made of nylon 43 parts, cotton 18 parts, resinous binding agents 39 parts. The coefficient of water absorption is 8.2 percent, the weight per unit area ZOOfiO gram/m the thickness 1.07 mm and the tensile strength l5.0kg/Scm.
2. A non-woven cloth is made of nylon 28 parts, polyester 28 parts, rayon 14 parts, resinous binding agents 30 parts. The coefficient of water absorption is 52.6 percent, the weight per unit area 180:50 gram/m the thickness 2.60 mm and the tensile strength 5.5 kg/Scm.
The non-woven cloth roll of subject application can be utilized in manufacturing pinch rolls, such assnubber rolls, deflector rolls, tension bridle'rolls, wringer rolls, squeezer rolls and wiper rolls.
An embodiment of manufacturing the non-woven roll of the present invention is explained with reference to the drawings.
BRIEF DESCRIPTION OF THE DRAWING:
FIG. 1 shows two embodiments of an element of the non-woven cloth roll of the subject invention,
FIG. 2 is a perspective view of the non-woven cloth roll of the subject invention,
FIG. 3 is a schematic arrangement of rolls used for measurement of the characteristics of the non-woven cloth roll of the subject invention, and
FIG. 4 shows the characteristic curve of the nonwoven cloth roll of the subject invention. cl DESCRIP- TION OF THE PREFERRED EMBODIMENTS;
In the figures, non-woven cloth elements 1 and 1' shown in FIG. 1 are of 1.07 mm to 2.60 mm thickness. The elements are cut from a sheet of cloth material and elements 1 and 1' are laminated or stacked onto a shaft- For Pinch Roll For Oiling Roll Hardness 83 i 2 55 2 5 (JISK 630i) Poisson's ratio 0.5 0.3 Module of shearing elasticity 33 30 Coefficient of water absorption 5.8 50.6 Shearing stress l200kg/cm 680-720 The most distinguished features of the roll of subject invention are the large coefficient of friction and the high shearing stress.
The large coefficient of friction is verified by using a testing machine of the type diagronmatically shown in FIG. 3. In FIG. 3, a steel plate 4 of 1.2 mm thickness with palm oil painted on the surface thereof is introduced at 5 and is taken out from an outlet 6 in the direction shown by the arrow. Two pairs of tension bridle rolls 7 and snubber rolls 8 are provided between 5 and 6 and steel plate 4 is passed through the nips'defined by each associated roll 7 and 8. The magnitude of the tension at intake 5 is zero and at outlet 6 is 3.5 tons. Snubber rolls 8 is pressurized with a force of 3 tons as shown by arrow. The angle of deflection of the steel plate is 320 and the speed of the steel plate which passes through the rolls is 400 m/min.
The result of the test shows that the coefficient of friction in the dry state is 0.28 and that with some oil adhered it is 0.24, the difference between the two states being small compared with the difference of a conventional rubber roll which amouts to 0.1 under the condition that the coefficient of friction is 0.18 in the dry state and is 0.08 with oil adhered.
' Due to the large coefficient of friction,'the roll of the subject invention makes it possible to treat the steel plate or the like at a high speed without causing any slippage occuring in the steel manuacturing line and any fault such as plate break or plate fold at a high speed which usually accompanies slippage does not exist at all.
This makes the steel manufacturing line quite compact so that the number of rolls can be reduced in the plant.
The large coefficient of friction of the roll causes close adhesion of the roll to the steel plate so that when the roll is utilized as an oil squeezer roll, in the squeez ing operation, the oil film deposited on the steel plate is squeezed sufficiently to leave only a thickness of the oil film necessary for prevention of rust formation on the steel.
This elimination of excess oil film naturaly reduces the consumption of oil and also holds the steel plate rigidly.
The result of a test in which the reduction of oil consumption is verified is shown in FIG. 4, in which the ordinate denotes the oil quantity per liter which is adhered to the steel plate in ton of steel and the abscissa denotes the time.
In the figure, the full line l denotes the resultant data of the roll of the subject invention and the dotted line II denotes that of a conventional rubber roll.
The curves in FIG. 4 teach that oil quantity of the steel plate squeezed is reduced from I liter/ton to 0.46 liter/ton by means of the roll of the subject invention, making a reduction of 64.8 kilo liter a month with a series of lines, in which steel plate of 120 kiloton is processed a month.
When the roll of the subject invention is used as a squeeze roll provided in the outlet of a water washing line, the slippage due to hydroplaning phenomena does never occur because of the large coefficient of friction so that the water is squeezed from the steel plate to a remarkable extent.
In using the roll of the subject invention as an oiling roll, two kinds of rolls are combined to constitute a pair of rolls, in the combination the oil being applied at the inlet of the rolls and the excess part of the oil being squeezed at the outlet of the rolls so that any fault due to a trace of oil appearing in the direction of advancing the steel plate at a higher processing velocity is eliminated to fully reduce the rust. In other words, a pair of rolls with large coefficient of friction was used at the outlet to successfully improve the adhesion of the roll to the steel plate and to uniformly apply the oil onto the steel plate.
The shearing stress of the roll of the subject invention amounts, for example, to 1,200 kg/cm as compared with 620 kg/cm obtainable in a conventional rubber roll and, therefore, no tearing off of the roll results. This means that the full working duration of a single roll can be extended and also the expense for changing the roll is abolished.
What we claim is:
1. In a roll comprising a shaft having an axis and a plurality of annular disc elements of a non-woven fabric, the fabric consisting of yarns of fibers of a high molecular synthetic resin material and of natural fibers, and a resinous material binding the yarns together, the elements being stacked on the shaft and axially pressed together to form the roll, the improvement comprising the elements being heat treated and axially pressed together so that the roll has a Poissons ratio of about 0.5 and a shearing stress of about 1,200 kg/cm".
2. In the roll of claim 1, the roll having a hardness of 83: 2 and a coefficient of water absorption of about 5.8 percent.

Claims (2)

1. IN A ROLL COMPRISING A SHAFT HAVING AN AXIS AND A PLURALITY OF ANNULAR DISC ELEMENTS OF A NON-WOVEN FABRIC, THE FABRIC CONSISTING OF YARNS OF FIBERS OF A HIGH MOLECULAR SYNTHETIC RESIN MATERIAL AND OF NATURAL FIBERS, AND A RESINOUS MATERIAL BINDING THE YARNS TOGETHER, THE ELEMENTS BEING STACKED ON THE SHAFT AND AXIALLY PRESSED TOGETHER TO FORM THE ROLL, THE IMPROVEMENT COMPRISING THE ELEMENTS BEING HEAT TREATED AND AXIALLY PRESSED TOGETHER SO THAT THE ROLL HAS A POISSON''S RATIO OF ABOUT 0.5 AND A SHEARING STRESS OF ABOUT 1,200 KG/CM2.
2. In the roll of claim 1, the roll having a hardness of 83* + or - 2* and a coefficient of water absorption of about 5.8 percent.
US00320305A 1972-01-24 1973-01-02 Roll made of non-woven cloth Expired - Lifetime US3853677A (en)

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Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4669163A (en) * 1985-12-12 1987-06-02 Minnesota Mining And Manufacturing Company Polyolefin fiber roll
US4766996A (en) * 1983-09-30 1988-08-30 Garrett Aerospace Rollers with oriented fiber reinforcement and method
US4913943A (en) * 1985-11-12 1990-04-03 Minnesota Mining And Manufacturing Company Dampener roll cover and methods of preparation and use thereof
US5038448A (en) * 1989-09-28 1991-08-13 A. Gusmer, Inc. Fiber roll with polyester fiber filler
US5097596A (en) * 1989-11-07 1992-03-24 Consolidated Papers, Inc. Supercalender roll and method of making same
US5247740A (en) * 1992-11-05 1993-09-28 Minnesota Mining And Manufacturing Company Method and apparatus for cutting a keyway in a mill roll
WO1997044513A1 (en) * 1996-05-20 1997-11-27 Minnesota Mining And Manufacturing Company Surface conditioning articles and process for making same
US5765256A (en) * 1993-08-19 1998-06-16 Minnesota Mining And Manufacturing Company Nonwoven cleaning brush
US6300261B1 (en) 1998-11-20 2001-10-09 3M Innovative Properties Company Self-healing articles resistant to oxidizing agents
US20120090540A1 (en) * 2008-04-04 2012-04-19 Belanger, Inc. Automotive tire dressing applicator
US10316463B2 (en) * 2016-12-21 2019-06-11 Nccm Company, Llc Non-woven covered roller

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2554215Y2 (en) * 1991-07-08 1997-11-17 日本バイリーン株式会社 Chemical resistant industrial roll
JP2675490B2 (en) * 1992-09-01 1997-11-12 川崎製鉄株式会社 Rolls for high-speed plate passing in wet processing lines for metal strips

Citations (8)

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US1973690A (en) * 1932-01-26 1934-09-11 Lade Archibald Calendering machine
US2801461A (en) * 1954-07-30 1957-08-06 Kusters Eduard Rolls for use in squeezing liquids from textiles and the like and a method of producing such rolls
US3588978A (en) * 1968-12-18 1971-06-29 Beloit Corp Grooved roll for paper-making
US3617445A (en) * 1968-12-18 1971-11-02 Beloit Corp Roll composition
US3707752A (en) * 1970-10-28 1973-01-02 Beloit Corp Roll covering
US3710469A (en) * 1970-11-04 1973-01-16 N Kitazawa Oiling roller
US3711913A (en) * 1971-03-24 1973-01-23 V Galeone Method of making a composite roll
US3730794A (en) * 1968-04-17 1973-05-01 Grace W R & Co Method of producing a novel compressible roll

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DE361437C (en) * 1916-07-15 1922-10-14 Georg Mehlhorn Elastic calender roll, the circumference of which is formed from cotton fiber discs
DE872490C (en) * 1951-05-01 1953-04-02 Eduard Kuesters Roller, especially for squeezing moisture out of textiles
DE930386C (en) * 1952-05-15 1955-07-14 Kuesters Eduard Roller, especially for squeezing moisture out of textiles
US3525367A (en) * 1969-01-06 1970-08-25 North American Rockwell Loom tension control apparatus

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1973690A (en) * 1932-01-26 1934-09-11 Lade Archibald Calendering machine
US2801461A (en) * 1954-07-30 1957-08-06 Kusters Eduard Rolls for use in squeezing liquids from textiles and the like and a method of producing such rolls
US3730794A (en) * 1968-04-17 1973-05-01 Grace W R & Co Method of producing a novel compressible roll
US3588978A (en) * 1968-12-18 1971-06-29 Beloit Corp Grooved roll for paper-making
US3617445A (en) * 1968-12-18 1971-11-02 Beloit Corp Roll composition
US3707752A (en) * 1970-10-28 1973-01-02 Beloit Corp Roll covering
US3710469A (en) * 1970-11-04 1973-01-16 N Kitazawa Oiling roller
US3711913A (en) * 1971-03-24 1973-01-23 V Galeone Method of making a composite roll

Cited By (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4766996A (en) * 1983-09-30 1988-08-30 Garrett Aerospace Rollers with oriented fiber reinforcement and method
US4913943A (en) * 1985-11-12 1990-04-03 Minnesota Mining And Manufacturing Company Dampener roll cover and methods of preparation and use thereof
US4669163A (en) * 1985-12-12 1987-06-02 Minnesota Mining And Manufacturing Company Polyolefin fiber roll
EP0227375A2 (en) * 1985-12-12 1987-07-01 Minnesota Mining And Manufacturing Company Polyolefin fiber roll and method of making the same
AU581350B2 (en) * 1985-12-12 1989-02-16 Minnesota Mining And Manufacturing Company Polyolefin fiber roll and method of making the same
EP0227375A3 (en) * 1985-12-12 1989-03-08 Minnesota Mining And Manufacturing Company Polyolefin fiber roll and method of making the same
US5038448A (en) * 1989-09-28 1991-08-13 A. Gusmer, Inc. Fiber roll with polyester fiber filler
US5097596A (en) * 1989-11-07 1992-03-24 Consolidated Papers, Inc. Supercalender roll and method of making same
US5247740A (en) * 1992-11-05 1993-09-28 Minnesota Mining And Manufacturing Company Method and apparatus for cutting a keyway in a mill roll
US5439335A (en) * 1992-11-05 1995-08-08 Minnesota Mining And Manufacturing Company Apparatus for cutting a keyway in a mill roll
US5765256A (en) * 1993-08-19 1998-06-16 Minnesota Mining And Manufacturing Company Nonwoven cleaning brush
WO1997044513A1 (en) * 1996-05-20 1997-11-27 Minnesota Mining And Manufacturing Company Surface conditioning articles and process for making same
US6042918A (en) * 1996-05-20 2000-03-28 3M Innovative Properties Company Surface conditioning articles and process for making same
US6300261B1 (en) 1998-11-20 2001-10-09 3M Innovative Properties Company Self-healing articles resistant to oxidizing agents
US20120090540A1 (en) * 2008-04-04 2012-04-19 Belanger, Inc. Automotive tire dressing applicator
US8601972B2 (en) * 2008-04-04 2013-12-10 Belanger, Inc. Automotive tire dressing applicator
US10316463B2 (en) * 2016-12-21 2019-06-11 Nccm Company, Llc Non-woven covered roller

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DE2301050B2 (en) 1980-10-23
BE786266A (en) 1972-11-03
JPS4877247A (en) 1973-10-17
DE2301050C3 (en) 1982-05-19
DE2301050A1 (en) 1973-08-02

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