US3843525A - Method of extinguishing fires - Google Patents
Method of extinguishing fires Download PDFInfo
- Publication number
- US3843525A US3843525A US00311905A US31190572A US3843525A US 3843525 A US3843525 A US 3843525A US 00311905 A US00311905 A US 00311905A US 31190572 A US31190572 A US 31190572A US 3843525 A US3843525 A US 3843525A
- Authority
- US
- United States
- Prior art keywords
- fire
- parts
- weight
- extinguishing
- container
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title claims abstract description 13
- 239000000203 mixture Substances 0.000 claims abstract description 32
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 14
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims abstract description 10
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 7
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 claims abstract description 6
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims abstract description 6
- 229940037003 alum Drugs 0.000 claims abstract description 6
- 239000001099 ammonium carbonate Substances 0.000 claims abstract description 6
- 235000012501 ammonium carbonate Nutrition 0.000 claims abstract description 6
- 239000001110 calcium chloride Substances 0.000 claims abstract description 6
- 229910001628 calcium chloride Inorganic materials 0.000 claims abstract description 6
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims abstract description 5
- 235000019353 potassium silicate Nutrition 0.000 claims abstract description 5
- 239000011780 sodium chloride Substances 0.000 claims abstract description 5
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000007864 aqueous solution Substances 0.000 claims abstract description 3
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 abstract description 4
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 12
- 239000000243 solution Substances 0.000 description 11
- 239000007789 gas Substances 0.000 description 9
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 8
- 238000006243 chemical reaction Methods 0.000 description 6
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 5
- 239000001095 magnesium carbonate Substances 0.000 description 5
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 4
- 239000001569 carbon dioxide Substances 0.000 description 4
- 229910002092 carbon dioxide Inorganic materials 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 208000011893 Febrile infection-related epilepsy syndrome Diseases 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000011575 calcium Substances 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 239000011777 magnesium Substances 0.000 description 3
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- 238000010790 dilution Methods 0.000 description 2
- 239000012895 dilution Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000779 smoke Substances 0.000 description 2
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 2
- 235000017557 sodium bicarbonate Nutrition 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- 239000011345 viscous material Substances 0.000 description 2
- 206010000369 Accident Diseases 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 241000282414 Homo sapiens Species 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical class [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 description 1
- 235000019270 ammonium chloride Nutrition 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 239000000295 fuel oil Substances 0.000 description 1
- XLYOFNOQVPJJNP-ZSJDYOACSA-N heavy water Substances [2H]O[2H] XLYOFNOQVPJJNP-ZSJDYOACSA-N 0.000 description 1
- 230000000266 injurious effect Effects 0.000 description 1
- 244000144972 livestock Species 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- -1 polyethylene Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 235000008001 rakum palm Nutrition 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- PFUVRDFDKPNGAV-UHFFFAOYSA-N sodium peroxide Chemical compound [Na+].[Na+].[O-][O-] PFUVRDFDKPNGAV-UHFFFAOYSA-N 0.000 description 1
- 238000004901 spalling Methods 0.000 description 1
- 230000002269 spontaneous effect Effects 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000006058 strengthened glass Substances 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
Images
Classifications
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D1/00—Fire-extinguishing compositions; Use of chemical substances in extinguishing fires
- A62D1/0007—Solid extinguishing substances
- A62D1/0014—Powders; Granules
Definitions
- a fire-extinguishing composition and a fire extinguisher device for use thereof are presented.
- Said fire-extinguishing composition comprises a composition having the following components in aproximately the proportions by weight as indicated:
- This invention relates to a fire-extinguishing composition and a fire extinguisher for the application thereof.
- the invention also relates to a method of extinguishing fires, as well as to a method of making a fire extinguisher.
- One of the purposes of this invention is to provide a disaster-preventing fire-extinguishing composition which is suitable for storage and which extinguishes fires with a relatively small amount of stored water or other Water from such sources as rivers or lakes during unexpected earthquakes or other like disasters, when the regular water supply may be cut off. It is an object of the invention to provide a fire-extinguishing composition which can extinguish fires at the initial stage of the fire incident by the application of the said fire-extinguishing composi tion. It is a further object to provide a method and device for fire extinguishment.
- the CO acts as the main fire-extinguishing agent, while the viscous aluminum silicate compounds generated from the water glass, alum, etc., which are the components of the fire extinguishing composition, cooperate with other viscous material, such as sodium dioxide, calcium chloride, etc.. to form a fire-proof membrane or covering over the articles which have not yet burned. This stops the extension of the fire and burning. In other words, it is the covering action of these viscous materials and the fire-extinguishing power of the CO gas which works together to effect fire-extinguishing and fire preventing in a surprisingly efficient manner. Moreover, it is to be observed that the CaCO and MgCO which result from Reaction (III) produce CO gas continuously by repeating Reaction (I) and (II) as long as NaHCO exists in the system.
- FIG. 1 is a perspective view of the fire-extinguisher of the present invention installed in a room of a dwelling or other structure;
- FIG. 2-A is an exploded view of the fire extinguisher showing the several parts of the apparatus.
- FIG. 2-B is a vertical sectional view of the fire extinguisher apparatus.
- 1 is the container which holds the fire extinguishing composition 2 of the present invention.
- 3 is the supporting frame for the fire extinguisher.
- 4 represents the cushion material against which the container 1 is held by the spring band 5.
- FIGS. 2-A and 23-8 there is a specially strengthened glass container 1 in the form of a cylinder, vessel, or some other type, which breaks into small pieces as soon as the container is heated at an elevated temperature below 100 C.
- the container is filled with a fire-extinguishing solution 2 prepared according to the present invention and then the container is sealed.
- Said container is fixed to a supporting frame 3 by means of spring bands with cushion material 4 as interpositioner, and then covered with a cover 7 made of synthetic resin, such as hard polyethylene, etc.
- the fire-extinguisher of the present invention is fixed in place somewhere near combustible materials, for example, on the ceiling (b) of a kitchen room (a), the said container 1 bursts into small pieces through the action of spalling (sudden heating and cooling) as the said spring is heated by the burning cover 7 in a fire accident.
- the fire-extinguishing solution originally contained in the said container spreads, e.g., in form of a mist, over the burning articles by means of the gases generated, and thus exerts a strong fire-extinguishing action.
- the number of fireextinguishers to be used according to the present invention is determined on the ability of the fire extinguisher to put out fires.
- One extinguisher for about every 7-10 m? is preferable, for example.
- the fire-extinguisher of the present invention is also advantageously hung cm. below the ceiling, or fixed on a wall at a place about 10 cm. apart from the ceiling. In any case, it is essential that the fire-extinguisher apparatus be firmly fixed in place on the wall or ceiling.
- the filled extinguisher was fixed on the upper inner wall of a house wherein shavings were heaped. Two liters of a mixture of heavy oil and gasoline were spread thereon and then the shavings were ignited. The fire became stronger and stronger, and 8l7 seconds after ignition, the glass container fixed in the upper side of the room exploded spontaneously owing to the rising flames. Meanwhile, the flames and black smoke changed into a white smoke. The fire was perfectly controlled within 2-5 seconds after the said spontaneous explosion.
- EXAMPLE 2 To illustrate the effect of the concentrated solution of fire-extinguishing composition, according to the present invention, the same solution as in Example 1 was made, but the concentrated fire-extinguishing solution was diluted to times by volume and every 200 g. of it was packed into a vinyl bag. When one of the said 200 g.-bags of the fire-extinguishing composition of the present invention was applied to the fire at its strongest stage (13-15 see. after ignition), the fire was quickly extinguished. In contrast, 4 to 5 of the 200 g.-water-vinyl bags was necessary to extinguish the fire at the same conditions.
- Amt. of Water needed for fire-extinguishment Amt. of diluted fire-extinguishing solution needed for fire-extinguishment :4-5 (for 100 times diluted solution)
- the optimal degree of dilution depends upon the kinds of the burning articles and the environments.
- Method of extinguishing fire in a building which comprises using a fire-extinguishing composition consisting essentially of an aqueous solution of (a) from about 7.0 to about 7.5 parts by weight of burnt alum,
- composition of claim 3 which composition is diluted with up to about 100 parts by volume of water.
- composition of claim 2 which composition is diluted with up to about 100 parts by volume of water.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Business, Economics & Management (AREA)
- Emergency Management (AREA)
- Fire-Extinguishing Compositions (AREA)
- Fireproofing Substances (AREA)
- Fire-Extinguishing By Fire Departments, And Fire-Extinguishing Equipment And Control Thereof (AREA)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US382020A US3918526A (en) | 1971-12-09 | 1973-07-23 | Fire-extinguishing device |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP46099043A JPS4863597A (enrdf_load_stackoverflow) | 1971-12-09 | 1971-12-09 |
Publications (1)
Publication Number | Publication Date |
---|---|
US3843525A true US3843525A (en) | 1974-10-22 |
Family
ID=14236441
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US00311905A Expired - Lifetime US3843525A (en) | 1971-12-09 | 1972-12-04 | Method of extinguishing fires |
Country Status (2)
Country | Link |
---|---|
US (1) | US3843525A (enrdf_load_stackoverflow) |
JP (1) | JPS4863597A (enrdf_load_stackoverflow) |
Cited By (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4904399A (en) * | 1989-03-31 | 1990-02-27 | Amoco Corporation | Process for preventing grease fires in steel mills and other metal processing mills |
US5423385A (en) * | 1992-07-30 | 1995-06-13 | Spectronix Ltd. | Fire extinguishing methods and systems |
US5425426A (en) * | 1992-03-19 | 1995-06-20 | Spectronix Ltd. | Fire extinguishing methods and systems |
US5441114A (en) * | 1993-02-16 | 1995-08-15 | Spectronix Ltd. | Portable system for extinguishing a fire |
US20070029518A1 (en) * | 2005-08-08 | 2007-02-08 | Shigeaki Hatakeyama | Process for producing extinguishing agent |
US20100000746A1 (en) * | 2005-08-08 | 2010-01-07 | Kariya Koushi | Process for producing extinguishing agent and throw-type fire extinguisher |
US20120199781A1 (en) * | 2009-10-23 | 2012-08-09 | Rueda-Nunez Jose Luis | Chemical composition for fighting forest fires and process for obtaining thereof |
CN107137857A (zh) * | 2017-05-18 | 2017-09-08 | 徐西元 | 一种配制水基灭火剂的组合物及其制备和使用方法 |
WO2020247780A1 (en) * | 2019-06-07 | 2020-12-10 | Frs Group, Llc | Long-term fire retardant with an organophosphate and methods for making and using same |
US10960250B2 (en) | 2019-06-07 | 2021-03-30 | Frs Group, Llc | Long-term fire retardant with corrosion inhibitors and methods for making and using same |
US11040229B2 (en) * | 2012-01-18 | 2021-06-22 | Acell Industries Limited | Fire suppression system |
WO2022032160A1 (en) * | 2020-08-07 | 2022-02-10 | Critchley Jacob | Utility and appliance fire suppression system |
US11395934B2 (en) | 2020-12-15 | 2022-07-26 | Frs Group, Llc | Long-term fire retardant with magnesium sulfate and corrosion inhibitors and methods for making and using same |
US11975231B2 (en) | 2022-03-31 | 2024-05-07 | Frs Group, Llc | Long-term fire retardant with corrosion inhibitors and methods for making and using same |
WO2025087810A1 (de) | 2023-10-24 | 2025-05-01 | Hiscotech Ug | Verfahren zur brandbekämpfung und -prävention und feuer- und brandstoppagens |
-
1971
- 1971-12-09 JP JP46099043A patent/JPS4863597A/ja active Pending
-
1972
- 1972-12-04 US US00311905A patent/US3843525A/en not_active Expired - Lifetime
Cited By (44)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4904399A (en) * | 1989-03-31 | 1990-02-27 | Amoco Corporation | Process for preventing grease fires in steel mills and other metal processing mills |
WO1990012079A1 (en) * | 1989-03-31 | 1990-10-18 | Amoco Corporation | Process for preventing grease fires in steel mills and other metal processing mills |
US5425426A (en) * | 1992-03-19 | 1995-06-20 | Spectronix Ltd. | Fire extinguishing methods and systems |
US5423385A (en) * | 1992-07-30 | 1995-06-13 | Spectronix Ltd. | Fire extinguishing methods and systems |
US5610359A (en) * | 1993-02-16 | 1997-03-11 | Spector; Yechiel | Method of generating non-toxic smoke |
US5492180A (en) * | 1993-02-16 | 1996-02-20 | Spectronix Ltd. | Painting wall surfaces with an ignitable solid-fuel composition which generates a fire-extinguishing particulate aerosol |
US5492179A (en) * | 1993-02-16 | 1996-02-20 | Spectronix Ltd. | System for extinguishing a fire in a volume for delivery from a distance |
US5588493A (en) * | 1993-02-16 | 1996-12-31 | Spectronix Ltd. | Fire extinguishing methods and systems |
US5441114A (en) * | 1993-02-16 | 1995-08-15 | Spectronix Ltd. | Portable system for extinguishing a fire |
US20070029518A1 (en) * | 2005-08-08 | 2007-02-08 | Shigeaki Hatakeyama | Process for producing extinguishing agent |
US20100000746A1 (en) * | 2005-08-08 | 2010-01-07 | Kariya Koushi | Process for producing extinguishing agent and throw-type fire extinguisher |
US8080169B2 (en) | 2005-08-08 | 2011-12-20 | Bonex, Inc. | Process for producing extinguishing agent and throw-type fire extinguisher |
US20120199781A1 (en) * | 2009-10-23 | 2012-08-09 | Rueda-Nunez Jose Luis | Chemical composition for fighting forest fires and process for obtaining thereof |
US8647524B2 (en) * | 2009-10-23 | 2014-02-11 | José Luis RUEDA-NÚÑEZ | Chemical composition for fighting forest fires and process for obtaining thereof |
US11040229B2 (en) * | 2012-01-18 | 2021-06-22 | Acell Industries Limited | Fire suppression system |
CN107137857A (zh) * | 2017-05-18 | 2017-09-08 | 徐西元 | 一种配制水基灭火剂的组合物及其制备和使用方法 |
US11344760B2 (en) | 2019-06-07 | 2022-05-31 | Frs Group, Llc | Long-term fire retardant with corrosion inhibitors and methods for making and using same |
US10960249B2 (en) | 2019-06-07 | 2021-03-30 | Frs Group, Llc | Long-term fire retardant with corrosion inhibitors and methods for making and using same |
US10960251B1 (en) | 2019-06-07 | 2021-03-30 | Frs Group, Llc | Long-term fire retardant with corrosion inhibitors and methods for making and using same |
US10960250B2 (en) | 2019-06-07 | 2021-03-30 | Frs Group, Llc | Long-term fire retardant with corrosion inhibitors and methods for making and using same |
US11041063B2 (en) | 2019-06-07 | 2021-06-22 | Frs Group, Llc | Long-term fire retardant with an organophosphate and methods for making and using same |
US11819722B1 (en) | 2019-06-07 | 2023-11-21 | Frs Group, Llc | Long-term fire retardant with corrosion inhibitors and methods for making and using same |
WO2020247780A1 (en) * | 2019-06-07 | 2020-12-10 | Frs Group, Llc | Long-term fire retardant with an organophosphate and methods for making and using same |
US11607570B2 (en) | 2019-06-07 | 2023-03-21 | Frs Group, Llc | Long-term fire retardant with corrosion inhibitors and methods for making and using same |
US11819723B2 (en) | 2019-06-07 | 2023-11-21 | Frs Group, Llc | Long-term fire retardant with corrosion inhibitors and methods for making and using same |
US11534643B2 (en) | 2019-06-07 | 2022-12-27 | Frs Group, Llc | Long-term fire retardant with corrosion inhibitors and methods for making and using same |
US11554279B2 (en) | 2019-06-07 | 2023-01-17 | Frs Group, Llc | Long-term fire retardant with corrosion inhibitors and methods for making and using same |
US11554280B2 (en) | 2019-06-07 | 2023-01-17 | Frs Group, Llc | Long-term fire retardant with corrosion inhibitors and methods for making and using same |
US11883699B2 (en) * | 2020-08-07 | 2024-01-30 | Jacob Critchley | Utility and appliance fire suppression system |
US20230144663A1 (en) * | 2020-08-07 | 2023-05-11 | Jacob Critchley | Utility and appliance fire suppression system |
WO2022032160A1 (en) * | 2020-08-07 | 2022-02-10 | Critchley Jacob | Utility and appliance fire suppression system |
US11395934B2 (en) | 2020-12-15 | 2022-07-26 | Frs Group, Llc | Long-term fire retardant with magnesium sulfate and corrosion inhibitors and methods for making and using same |
US11628324B2 (en) | 2020-12-15 | 2023-04-18 | Frs Group, Llc | Long-term fire retardant with corrosion inhibitors and methods for making and using same |
US11602658B2 (en) | 2020-12-15 | 2023-03-14 | Frs Group, Llc | Long-term fire retardant with magnesium sulfate and corrosion inhibitors and methods for making and using same |
US11865392B2 (en) | 2020-12-15 | 2024-01-09 | Frs Group, Llc | Long-term fire retardant with corrosion inhibitors and methods for making and using same |
US11865391B2 (en) | 2020-12-15 | 2024-01-09 | Frs Group, Llc | Long-term fire retardant with corrosion inhibitors and methods for making and using same |
US11420084B2 (en) | 2020-12-15 | 2022-08-23 | Frs Group, Llc | Long-term fire retardant with corrosion inhibitors and methods for making and using same |
US11883703B2 (en) | 2020-12-15 | 2024-01-30 | Frs Group, Llc | Long-term fire retardant with magnesium sulfate and corrosion inhibitors and methods for making and using same |
US12214237B2 (en) | 2020-12-15 | 2025-02-04 | Frs Group, Llc | Long-term fire retardant with corrosion inhibitors and methods for making and using same |
US12214236B2 (en) | 2020-12-15 | 2025-02-04 | Frs Group, Llc | Long-term fire retardant with corrosion inhibitors and methods for making and using same |
US11975231B2 (en) | 2022-03-31 | 2024-05-07 | Frs Group, Llc | Long-term fire retardant with corrosion inhibitors and methods for making and using same |
US12053658B2 (en) | 2022-03-31 | 2024-08-06 | Frs Group, Llc | Long-term fire retardant with corrosion inhibitors and methods for making and using same |
US12109446B2 (en) | 2022-03-31 | 2024-10-08 | Frs Group, Llc | Long-term fire retardant with corrosion inhibitors and methods for making and using same |
WO2025087810A1 (de) | 2023-10-24 | 2025-05-01 | Hiscotech Ug | Verfahren zur brandbekämpfung und -prävention und feuer- und brandstoppagens |
Also Published As
Publication number | Publication date |
---|---|
DE2264406A1 (de) | 1973-12-20 |
DE2264406B2 (de) | 1975-09-11 |
JPS4863597A (enrdf_load_stackoverflow) | 1973-09-04 |
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