US3840399A - Recording sheet for electrostatic photoprinting - Google Patents

Recording sheet for electrostatic photoprinting Download PDF

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Publication number
US3840399A
US3840399A US00274976A US27497672A US3840399A US 3840399 A US3840399 A US 3840399A US 00274976 A US00274976 A US 00274976A US 27497672 A US27497672 A US 27497672A US 3840399 A US3840399 A US 3840399A
Authority
US
United States
Prior art keywords
resin
recording sheet
electrostatic
group
mixture
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US00274976A
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English (en)
Inventor
K Kobayashi
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ricoh Co Ltd
Original Assignee
Ricoh Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ricoh Co Ltd filed Critical Ricoh Co Ltd
Application granted granted Critical
Publication of US3840399A publication Critical patent/US3840399A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G5/00—Recording members for original recording by exposure, e.g. to light, to heat, to electrons; Manufacture thereof; Selection of materials therefor
    • G03G5/02—Charge-receiving layers
    • G03G5/0202—Dielectric layers for electrography
    • G03G5/0205—Macromolecular components
    • G03G5/0211—Macromolecular components obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G5/00—Recording members for original recording by exposure, e.g. to light, to heat, to electrons; Manufacture thereof; Selection of materials therefor
    • G03G5/02—Charge-receiving layers
    • G03G5/0202—Dielectric layers for electrography
    • G03G5/0205—Macromolecular components
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G5/00—Recording members for original recording by exposure, e.g. to light, to heat, to electrons; Manufacture thereof; Selection of materials therefor
    • G03G5/02—Charge-receiving layers
    • G03G5/0202—Dielectric layers for electrography
    • G03G5/0205—Macromolecular components
    • G03G5/0208—Macromolecular components obtained by reactions only involving carbon-to-carbon unsatured bonds
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G5/00—Recording members for original recording by exposure, e.g. to light, to heat, to electrons; Manufacture thereof; Selection of materials therefor
    • G03G5/02—Charge-receiving layers
    • G03G5/0202—Dielectric layers for electrography
    • G03G5/0217—Inorganic components
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
    • Y10T428/259—Silicic material
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31678—Of metal
    • Y10T428/31692—Next to addition polymer from unsaturated monomers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31678—Of metal
    • Y10T428/31703—Next to cellulosic

Definitions

  • a recording Sheet for electrostatic Photopriming cording to the present invention is provided with an 521 US. 01 117/201, 117/218, 252/500 insulating recording layer which is a resin formed on a 51 1111.0 B44d l/18 Conductive Surface of an electrically conductive 9- [58] Field of Search 117/201, 218; 96/1.8; Port, wherein Said resin is a mixture of resin Soluble 52 5 in organic solvents and also capable of swelling or soluble in water and a resin soluble in organiesolvents 5 References Cited but insoluble in water, the weight ratio of the former UNITED STATES PATENTS resin to the total weight of said mixture being in the range of 0.5 40 wt%.
  • the present invention relates to a recording sheet for use in electrostatic photoprinting, which has an improved aptitude for writing thereon particularly with aqueous ink.
  • Recording sheets for electrostatic photoprinting generally comprise a paper support in which one or both sides are electrically conductive with' recording resin layer formed on a side which is processed for electric conductivity.
  • the following methods are generally employed: (1) the electrostatic recording process, in which an original image is traced photoelectrically and the resulting electric signal corresponding to said image is introduced to a needle electrode, an electrostatic latent image corresponding to the original image is formed on the recording layer through electrification by discharging electricity from the electrode to the recording layer of the recording sheet according to said electric signal, and the thus formed latent image is developed with a dry or wet developer; and the (2) electrostatic latent image transferring process, wherein an electrostatic latent image is impressed on the photoconductive layer of an electrophotographic sensitive material by the conventional electrophotography, the thus formed latent image is transferred to the recording layer of the recording sheet, and then development is effected as described above.
  • the resins used to form the recording layer for these electrostatic recording sheets include such insulating resins as alkyd resin, epoxy resin, shellac, saturated polyester, polyethylene, vinyl acetate resin, vinyl chloride resin, vinyl acetate-vinyl chloride copolymer, styrene-butadiene copolymer, polymethyl methacrylate (US. Pat. No. 3,075,859), etc.
  • insulating resins as alkyd resin, epoxy resin, shellac, saturated polyester, polyethylene, vinyl acetate resin, vinyl chloride resin, vinyl acetate-vinyl chloride copolymer, styrene-butadiene copolymer, polymethyl methacrylate (US. Pat. No. 3,075,859), etc.
  • recording layers including these resins are generally lacking in hydroscopicity and writability with a pencil or fountain pen because their surfaces are too smooth.
  • the quantity of the inorganic pigment which is added to the recording layer for this purpose varies with writing instruments: to make it writable with a pencil, a small quantity will do, while to make it writable with a fountain pen using aqueous ink, a large quantity is required.
  • a recording layer containing a large quantity of inorganic pigment is unsatisfactory because it has been found to discharge its surface electricity. No recording sheet is known which is suitable for writing with both a pencil and a fountain pen.
  • the object ofthe present invention is to provide recording sheets for use in electrostatic photoprinting, which compensate for the aforementioned defects and, more particularly, improve writability in aqueous ink in particular without impairing the electrostatic properties of the recording layer of the sheets.
  • the present invention relates to re.- cording sheets for use in electrostatic photoprinting which are provided with insulating recording resin layers on the conductive surface of an electrically conductive support, wherein said resin is a mixture composed of a resin soluble in organic solvent and also capable of swelling or soluble in water and a resin soluble in organic solvent but insoluble in water, the weight ratio of the former resin to the total weight of said mixture being in the range of 0.5 40 wt%.
  • Said resin soluble in organic solvent and also capable of swelling or soluble in water includes derivatives of cellulose such as hydroxypropylmethyl cellulose, ethyl hydroxyethyl cellulose, ethyl methyl cellulose, hydroxymethyl cellulose, homopolymers or copolymers formed from at least one member selected from the following group of A monomers, or copolymers formed from at least one member selected from the following group of A monomers and at least one member selected from the following group of B monomers:
  • propylene-glycol vinyl methyl ether, maleic acid, maleic anhydride, ucr lic acid acryl amide, and vinyl pyrro idone B ethylene, styrene, vinyl acetate, acrylic monomers:
  • polyethylene glycol polydiethylene glycol, polypropylene glycol,polyvinyl methyl ether, polymaleic acid, polymaleic anhydride, polyacrylic acid, po-
  • polyvinyl pyrrolidone poly(vinyl methyl ether-maleic acid), poly(vinyl methyl ether-maleic anhydride), poly-(vinyl methyl ether-acrylic acid), poly(vinyl methyl ether-acryl amide), poly(vinyl methyl ether-vinyl pryrrolidone), poly(maleic acid-acrylic acid), poly(- maleic acid-acryl amide), poly(acrylic acid-vinyl pyrrolidone), poly(acryl amide-vinyl pyrrolidone), poly(ethylene glyeol-diethylene glycol), poly(ethylene glycol-propylene glycol), poly(vinyl methyl ether-maleic acid-acrylic acid),
  • the recording sheet according to the present invention is prepared by applying a solution obtained by dissolving any of the above exemplified resins together with a resin of the type which may be used in conventional electrostatic recording sheets which is soluble in organic solvents but is neither capable of swelling nor soluble in water, such as saturated polyester, polymethyl methacrylate, polyethyl methacrylate, polystyrene, polyvinyl butyral, epoxy resin, alkyd resin, polyethylene, polyvinyl chloride, styrene-butadiene copolymer, vinyl acetate-vinyl chloride copolymer, vinyl chloride-vinylidene chloride copolymer, in an appropriate organic solvent, or a dispersion obtained by adding at least one inorganic-pigment to said solution, if desired, onto the conductive surface of an electrically conductive support to the extent of about 2 20 g/m in dry weight to thereby ,form a recording layer thereon.
  • the first resin which is capable of swelling or soluble in water, to be employed for the present invention should also be soluble in organic solvents to ensure its uniform dispersion in the resulting recording layer.
  • the percentage of the first resin to the total weight of resins contained in the recording layer should be in the range of 0.5 40 wt%. When the amount is less than 0.5 wt%, improvement of the writability cannot be expected, while in case it is more than 40 wt%, the hydroscopic property, or water absorbability, excessively increases with resulting deterioration of the electrostatic properties when the product is used at high humidity.
  • the recording layer according to the present invention can contain inorganic pigments to the extent of 1 30 wt% based on the total weight of resins.
  • inorganic pigments for this purpose, barium titanate, titanium oxide, calcium sulfate, lithopone, silica, etc. having the grain size in the range of 0.001 p. are applicable.
  • paper having its one side or both sides processed for electric conductivity, metal-laminated paper, metal foil and the like are applicable.
  • Example 1 By applying polyvinyl benzyl-quaternary ammonium chloride at the rate of 2 g/m onto one side of a slick paper consisting of 60 parts by weight of needle-leaved tree kraft pulp and 40 parts by weight of broad-leaved tree kraft pulp and weighing 55 g/m an electrically conductive paper support was prepared. Subsequently, by forming a recording layer through application of a solution having the following composition to the conductive surface of said support to a dry weight of 10 g/m an electrostatic recording sheet was prepared.
  • Example 3 I When an electric recording sheet was prepared in the same way as in Example 2 except for substituting ethyl hydroxy ethyl cellulose for hydroxy propyl methyl cellulose in the solution (2), and this recording sheet was tested. It proved excellent in writability in aqueous ink.
  • Example 4 When an electrostatic recording sheet was prepared in the same way 'asin Example 2 except for substituting ethyl methyl cellulose for hydroxy propyl methyl cellulose in the solution (2), and this recording sheet was tested on its properties, it proved excellent in writability in aqueous ink.
  • Example 7 A dispersion was first prepared by adding 10 parts by weight of titanium oxide to a mixture of the solution (5) having the following composition:
  • Example 8 By applying-this dispersion onto the conductive surface of the same electrically conductive paper support as that in Example 1 to a dry weight of 10 g/m an electrostatic recording sheet was prepared. Subsequently, the image was formed on this recording sheet in the same way as in Example 1. When tests were conducted on the writability in aqueous ink and in pencil, the results were quite excellent, and the fixability was also satisfactory.
  • Example 8 By applying a solution having the following composition:
  • Example 9 An electrostatic recording sheet was prepared by applying a dispersion having the following composition:
  • Example 10 By applying a solution having the following composition:
  • Example 11 A coating liquid was prepared by adding 30 parts by weight of silica to a solution having the following composition:
  • Example 12 An electrostatic recording sheet was prepared in the same way as that in Example 1 1 except for substituting barium titanate for silica. The electrostatic properties and the writability of this electrostatic recording sheet were satisfactory.
  • Example 13 An electrostatic recording sheet was prepared in the same way as that in Example 1 1 except for substituting titanium oxide for silica. The electrostatic properties and the writability of this electrostatic recording sheet were satisfactory.
  • Example 14 An electrostatic recording sheet was prepared in the same way as that in Example 1 1 except for substituting calcium sulfate for silica. The electrostatic properties and the writability of this electrostatic recording sheet were satisfactory.
  • Example 15 An electrostatic recording sheet was prepared in the same way as that in Example 1 1 except for substituting lithopone for silica. The electrostatic properties and the writability of this electrostatic recording sheet were satisfactory.
  • a recording sheet for use in electrostatic photoprinting having an insulating recording resin layer formed on the conductive surface of an electrically conductive support, wherein said resin is a mixture compound composed of a first resin soluble in organic solvent and capable of swelling or soluble in water, and a second resin soluble in organic solvent but insoluble in water, the weight ratio of the first resin to the total weight of the mixture being from 0.5 -40 wt%; said first resin being selected from the group consisting of hydroxy propyl methyl cellulose, ethyl hydroxy ethyl cellulose, ethyl methyl cellulose, hydroxy methyl cellulose, polymers or copolymers consisting of at least one monomer selected from the A monomer group consisting of ethylene glycol, diethylene glycol, propylene glycol, vinyl methyl ether, maleic acid, maleic anhydride, acrylic acid, acryl amide and vinyl pyrrolidone, and copolymers consisting of at least one monomer selected from the A monomer group and at least one
  • a recording sheet as defined in claim I wherein said mixture is selected from the group consisting of the following mixtures:

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  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Photoreceptors In Electrophotography (AREA)
  • Electrophotography Using Other Than Carlson'S Method (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Laminated Bodies (AREA)
  • Paper (AREA)
US00274976A 1971-08-03 1972-07-25 Recording sheet for electrostatic photoprinting Expired - Lifetime US3840399A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP46057945A JPS5246096B2 (enrdf_load_stackoverflow) 1971-08-03 1971-08-03

Publications (1)

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US3840399A true US3840399A (en) 1974-10-08

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Family Applications (1)

Application Number Title Priority Date Filing Date
US00274976A Expired - Lifetime US3840399A (en) 1971-08-03 1972-07-25 Recording sheet for electrostatic photoprinting

Country Status (3)

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US (1) US3840399A (enrdf_load_stackoverflow)
JP (1) JPS5246096B2 (enrdf_load_stackoverflow)
DE (1) DE2237008C3 (enrdf_load_stackoverflow)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3930080A (en) * 1973-03-20 1975-12-30 Kanzaki Paper Mfg Co Ltd Electrostatic recording materials
US4165308A (en) * 1978-05-26 1979-08-21 Monsanto Company Coating compositions comprising polymer blends containing polystyrene or poly(α-methyl styrene)
US4167602A (en) * 1978-05-26 1979-09-11 Monsanto Company Electrographic recording material
WO1980000014A1 (en) * 1978-06-06 1980-01-10 Ludlow Corp An improved dielectric product and process for the preparation thereof
US4375486A (en) * 1980-07-10 1983-03-01 Ludlow Corporation Process of making a dielectric product
US4540628A (en) * 1980-11-18 1985-09-10 John R. Koza Hydrophilic sheet and method of making

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5719418B2 (enrdf_load_stackoverflow) * 1973-05-02 1982-04-22
JPS5826021B2 (ja) * 1974-10-14 1983-05-31 株式会社リコー セイデンシヤシンヨウキロクザイリヨウノ セイゾウホウホウ
JPS5510146U (enrdf_load_stackoverflow) * 1978-07-03 1980-01-23
JPS5849412B2 (ja) * 1979-10-19 1983-11-04 国産金属工業株式会社 ステアリングシヤフトロツク
JPS5849413B2 (ja) * 1979-10-23 1983-11-04 国産金属工業株式会社 ステアリングシヤフトロツク
US4339505A (en) * 1980-02-25 1982-07-13 Desoto, Inc. Electrographic coatings containing acrylamide copolymers
US4400441A (en) * 1980-02-25 1983-08-23 Desoto, Inc. Electrographic coating containing aqueous emulsion copolymerized acrylamide copolymers
JPS57158551U (enrdf_load_stackoverflow) * 1981-03-27 1982-10-05
US4503111A (en) * 1983-05-09 1985-03-05 Tektronix, Inc. Hydrophobic substrate with coating receptive to inks

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3930080A (en) * 1973-03-20 1975-12-30 Kanzaki Paper Mfg Co Ltd Electrostatic recording materials
US4165308A (en) * 1978-05-26 1979-08-21 Monsanto Company Coating compositions comprising polymer blends containing polystyrene or poly(α-methyl styrene)
US4167602A (en) * 1978-05-26 1979-09-11 Monsanto Company Electrographic recording material
WO1980000014A1 (en) * 1978-06-06 1980-01-10 Ludlow Corp An improved dielectric product and process for the preparation thereof
US4303720A (en) * 1978-06-06 1981-12-01 Ludlow Corporation Dielectric product
US4375486A (en) * 1980-07-10 1983-03-01 Ludlow Corporation Process of making a dielectric product
US4540628A (en) * 1980-11-18 1985-09-10 John R. Koza Hydrophilic sheet and method of making

Also Published As

Publication number Publication date
DE2237008C3 (de) 1975-07-03
DE2237008B2 (enrdf_load_stackoverflow) 1974-11-21
JPS4825536A (enrdf_load_stackoverflow) 1973-04-03
JPS5246096B2 (enrdf_load_stackoverflow) 1977-11-21
DE2237008A1 (de) 1973-02-15

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