US3833494A - Method of manufacturing a lanthanum hexaboride-activated cathode for an electric discharge tube - Google Patents

Method of manufacturing a lanthanum hexaboride-activated cathode for an electric discharge tube Download PDF

Info

Publication number
US3833494A
US3833494A US00356620A US35662073A US3833494A US 3833494 A US3833494 A US 3833494A US 00356620 A US00356620 A US 00356620A US 35662073 A US35662073 A US 35662073A US 3833494 A US3833494 A US 3833494A
Authority
US
United States
Prior art keywords
lanthanum hexaboride
manufacturing
electric discharge
discharge tube
layer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US00356620A
Other languages
English (en)
Inventor
Stratum A Van
N Mitra
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
US Philips Corp
Original Assignee
US Philips Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by US Philips Corp filed Critical US Philips Corp
Application granted granted Critical
Publication of US3833494A publication Critical patent/US3833494A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Images

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J9/00—Apparatus or processes specially adapted for the manufacture, installation, removal, maintenance of electric discharge tubes, discharge lamps, or parts thereof; Recovery of material from discharge tubes or lamps
    • H01J9/02—Manufacture of electrodes or electrode systems
    • H01J9/04—Manufacture of electrodes or electrode systems of thermionic cathodes
    • H01J9/042—Manufacture, activation of the emissive part

Definitions

  • the invention relates to a method of manufacturing a cathode for an electric discharge tube in which a layer of lanthanum hexaboride is cataphoretically provided on a rhenium support and is sintered.
  • the invention furthermore relates to a cathode manufactured in this manner.
  • the cataphoretically provided layer is slowly heated to a temperature of l,500 to l,550C and maintained at said final temperature for maximum 30 seconds until a smooth and shining surface is obtained, after which a second layer of lanthanum hexaboride is cataphoretically provided and also heated to a temperature of 1,500 to l,550C and maintained at said temperature for maximum 2 minutes.
  • a layer of rhenium boride is formed all over the surface of the rhenium wire and rhenium wire as a result of excessive boride formation ing example.
  • 1 denotes a part of a hard glass bottom in which two wires 2 and 3 of an iron-nickel-cobalt alloy are present.
  • a rhenium wire 4 of 0.18 mm diameter is welded to the lead-in wires 2 and 3. After firing the rhenium wire in hydrogen gas at 1,600C for 2 minutes, it is covered from a lanthanum boride suspension (unpurified LaB with a 50 p. thick layer. Said layer is heated for 5 minutes and sintered in hydrogen at 1,530C for 15 seconds. The layer becomes smooth and shining. A 20 microns thick layer of lanthanum hexaboride is then cataphoretically provided, said layer being sintered in hydrogen at l,550C for 2 minutes.
  • the cathode After sealing the bottom 1 in a tube and after evacuation thereof, the cathode is degassed at 1,600C for a few seconds. The cathode is then activated at 1,500C for 5 to 30 minutes.
  • the saturation emission (measured with pulses) is 10 Alcm
  • the life at said temperature is more than 8,000 hours.
  • the cathodes according to the invention are suitable for use in high voltage apparatus such as X-ray tubes, rectifier tubes and also in electron beam welding apparatus, electron microscopes and the like, in which comparatively poor vacuum conditions occur and which cathodes are exposed to air repeated times.
  • high voltage apparatus such as X-ray tubes, rectifier tubes and also in electron beam welding apparatus, electron microscopes and the like, in which comparatively poor vacuum conditions occur and which cathodes are exposed to air repeated times.
  • said cathodes are also suitable.
  • a method of manufacturing a cathode for an electric discharge tube in which a layer of lanthanum hexaboride is cataphoretically provided on a rhenium support and sintered characterized in that the cataphoretically provided layer is slowly heated to a temperature of l,500 to l,550C and maintained at said final temperature formaximum 30 seconds until a smooth and shining surface is obtained, after which a second layer of lanthanum hexaboride is cataphoretically provided and also heated to a temperature of l,500 to l,550C and maintained at said temperature for maximum 2 minutes.

Landscapes

  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Solid Thermionic Cathode (AREA)
  • Gas-Filled Discharge Tubes (AREA)
US00356620A 1972-05-30 1973-05-02 Method of manufacturing a lanthanum hexaboride-activated cathode for an electric discharge tube Expired - Lifetime US3833494A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
NL7207275A NL167796C (nl) 1972-05-30 1972-05-30 Werkwijze voor het vervaardigen van een met lanthaanhexaboride geactiveerde kathode voor een elektrische ontladingsbuis.

Publications (1)

Publication Number Publication Date
US3833494A true US3833494A (en) 1974-09-03

Family

ID=19816153

Family Applications (1)

Application Number Title Priority Date Filing Date
US00356620A Expired - Lifetime US3833494A (en) 1972-05-30 1973-05-02 Method of manufacturing a lanthanum hexaboride-activated cathode for an electric discharge tube

Country Status (9)

Country Link
US (1) US3833494A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
JP (1) JPS5524224B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
CA (1) CA994280A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
CH (1) CH574677A5 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
DE (1) DE2325273C3 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
FR (1) FR2186725B1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
GB (1) GB1378620A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
NL (1) NL167796C (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
SE (1) SE382886B (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5128475A (ja) * 1974-09-04 1976-03-10 Hitachi Ltd Magunetoroninkyokukotai
JPS51118362A (en) * 1975-04-10 1976-10-18 Natl Inst For Res In Inorg Mater Heat electon radiating cathode
JPS5231652A (en) * 1975-09-04 1977-03-10 Natl Inst For Res In Inorg Mater Electron microscope
JPS5231651A (en) * 1975-09-04 1977-03-10 Natl Inst For Res In Inorg Mater Scan-type electron microscope
US4019081A (en) * 1974-10-25 1977-04-19 Bbc Brown Boveri & Company Limited Reaction cathode
US4054946A (en) * 1976-09-28 1977-10-18 Bell Telephone Laboratories, Incorporated Electron source of a single crystal of lanthanum hexaboride emitting surface of (110) crystal plane
US4055780A (en) * 1975-04-10 1977-10-25 National Institute For Researches In Inorganic Materials Thermionic emission cathode having a tip of a single crystal of lanthanum hexaboride
US4482839A (en) * 1981-05-29 1984-11-13 Denki Kagaku Kogyo Kabushiki Kaisha Thermionic emission cathode and preparation thereof
US5142652A (en) * 1990-08-20 1992-08-25 Siemens Aktiengesellschaft X-ray arrangement comprising an x-ray radiator having an elongated cathode
US5170422A (en) * 1990-08-20 1992-12-08 Siemens Aktiengesellschaft Electron emitter for an x-ray tube
EP1983546A1 (en) * 2007-04-20 2008-10-22 PANalytical B.V. X-ray cathode and tube
US20100301736A1 (en) * 2007-11-30 2010-12-02 Toshiyuki Morishita Electron emitting source and manufacturing method of electron emitting source
US20150002009A1 (en) * 2012-07-03 2015-01-01 National Institute For Materials Science Metal hexaboride cold field emitter, method of fabricating same, and electron gun

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2117795A (en) * 1982-04-06 1983-10-19 Standard Telephones Cables Ltd Fabricating capacitors; forming ceramic films
GB8611967D0 (en) * 1986-05-16 1986-10-29 English Electric Valve Co Ltd Directly heated cathodes
JPS6489242A (en) * 1987-09-30 1989-04-03 Mitsubishi Electric Corp Electrode for discharge light source
DE4026297A1 (de) * 1990-08-20 1992-02-27 Siemens Ag Roentgenanordnung
DE4026300A1 (de) * 1990-08-20 1992-02-27 Siemens Ag Elektronenemitter einer roentgenroehre
DE4026298A1 (de) * 1990-08-20 1992-02-27 Siemens Ag Roentgenroehre mit einem elektronenemitter
DE10245392B3 (de) * 2002-09-28 2004-01-08 Vtd Vakuumtechnik Dresden Gmbh Rohrförmige Hohlkathode für hohe elektrische Leistungen
CN104223613B (zh) 2014-09-26 2016-09-28 京东方科技集团股份有限公司 智能手环显示控制系统及智能手环

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3312856A (en) * 1963-03-26 1967-04-04 Gen Electric Rhenium supported metallic boride cathode emitters
US3498897A (en) * 1967-07-25 1970-03-03 Ford Motor Co Method for manufacturing multilayered product
US3630770A (en) * 1969-04-30 1971-12-28 Gen Electric Method for fabricating lanthanum boride cathodes

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3312856A (en) * 1963-03-26 1967-04-04 Gen Electric Rhenium supported metallic boride cathode emitters
US3498897A (en) * 1967-07-25 1970-03-03 Ford Motor Co Method for manufacturing multilayered product
US3630770A (en) * 1969-04-30 1971-12-28 Gen Electric Method for fabricating lanthanum boride cathodes

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
L. Favreau, Cataphoretic Coating Lanthanum Boride on Rhenium Filaments, Rev. Sci. Inst., Vol. 36, pages 856 857, (1965). *

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5128475A (ja) * 1974-09-04 1976-03-10 Hitachi Ltd Magunetoroninkyokukotai
US4019081A (en) * 1974-10-25 1977-04-19 Bbc Brown Boveri & Company Limited Reaction cathode
JPS51118362A (en) * 1975-04-10 1976-10-18 Natl Inst For Res In Inorg Mater Heat electon radiating cathode
US4055780A (en) * 1975-04-10 1977-10-25 National Institute For Researches In Inorganic Materials Thermionic emission cathode having a tip of a single crystal of lanthanum hexaboride
JPS5231651A (en) * 1975-09-04 1977-03-10 Natl Inst For Res In Inorg Mater Scan-type electron microscope
JPS5231652A (en) * 1975-09-04 1977-03-10 Natl Inst For Res In Inorg Mater Electron microscope
US4054946A (en) * 1976-09-28 1977-10-18 Bell Telephone Laboratories, Incorporated Electron source of a single crystal of lanthanum hexaboride emitting surface of (110) crystal plane
US4482839A (en) * 1981-05-29 1984-11-13 Denki Kagaku Kogyo Kabushiki Kaisha Thermionic emission cathode and preparation thereof
US5142652A (en) * 1990-08-20 1992-08-25 Siemens Aktiengesellschaft X-ray arrangement comprising an x-ray radiator having an elongated cathode
US5170422A (en) * 1990-08-20 1992-12-08 Siemens Aktiengesellschaft Electron emitter for an x-ray tube
EP1983546A1 (en) * 2007-04-20 2008-10-22 PANalytical B.V. X-ray cathode and tube
US20100301736A1 (en) * 2007-11-30 2010-12-02 Toshiyuki Morishita Electron emitting source and manufacturing method of electron emitting source
US8456076B2 (en) * 2007-11-30 2013-06-04 Denki Kagaku Kogyo Kabushiki Kaisha Electron emitting source and manufacturing method of electron emitting source
US20150002009A1 (en) * 2012-07-03 2015-01-01 National Institute For Materials Science Metal hexaboride cold field emitter, method of fabricating same, and electron gun
US8952605B2 (en) * 2012-07-03 2015-02-10 National Institute For Materials Science Metal hexaboride cold field emitter, method of fabricating same, and electron gun

Also Published As

Publication number Publication date
DE2325273B2 (de) 1980-09-04
FR2186725B1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) 1976-09-17
NL167796B (nl) 1981-08-17
DE2325273A1 (de) 1973-12-13
JPS4944661A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) 1974-04-26
GB1378620A (en) 1974-12-27
CA994280A (en) 1976-08-03
JPS5524224B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) 1980-06-27
NL7207275A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) 1973-12-04
CH574677A5 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) 1976-04-15
FR2186725A1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) 1974-01-11
NL167796C (nl) 1982-01-18
DE2325273C3 (de) 1981-07-09
SE382886B (sv) 1976-02-16

Similar Documents

Publication Publication Date Title
US3833494A (en) Method of manufacturing a lanthanum hexaboride-activated cathode for an electric discharge tube
US4325000A (en) Low work function cathode
US4515528A (en) Hydrocarbon getter pump
US1794810A (en) Incandescent cathode for electric discharge tubes
US3284657A (en) Grain-oriented thermionic emitter for electron discharge devices
US6511632B1 (en) Cathode material of electron beam device and preparation method thereof
US3823453A (en) Method of manufacturing an indirectly heated cathode and cathode manufactured according to this method
US2497110A (en) Method of making electrodes
US3041209A (en) Method of making a thermionic cathode
US3737709A (en) Gas discharge tube comprising mercury vapor and provided with a getter
US3492598A (en) Method for processing gas discharge devices
US3846006A (en) Method of manufacturing of x-ray tube having thoriated tungsten filament
JP2710700B2 (ja) 含浸形陰極の製造法及びこの方法によって得られる陰極
US2275886A (en) Process of activating cathodes
US4200555A (en) Low work function hexaboride electron source
US2417460A (en) Nonemissive electrode for electron tube and method of making the same
US3283195A (en) Cold-cathode glow-discharge tube
US3721848A (en) Camera tube having photoconductive lead monoxide layer on silicon carbide signal plate
SU679001A1 (ru) Способ изготовлени металлопористого термокатода
US3908252A (en) Discharge tube provided with an electrode comprising nickel and aluminum
US1954189A (en) Electric discharge tube
EP0263483B2 (en) Hot cathode in wire form
US4231627A (en) Electron beam tube
JPS58164129A (ja) 硼化デイスペンサ陰極の製造方法
US3113370A (en) Method of making cathode