US3807149A - Moisture exchanger for gaseous media - Google Patents

Moisture exchanger for gaseous media Download PDF

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Publication number
US3807149A
US3807149A US00150189A US15018971A US3807149A US 3807149 A US3807149 A US 3807149A US 00150189 A US00150189 A US 00150189A US 15018971 A US15018971 A US 15018971A US 3807149 A US3807149 A US 3807149A
Authority
US
United States
Prior art keywords
carrier
media
exchanger
moisture
salt
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US00150189A
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English (en)
Inventor
P Norback
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
MUNTERS C IND AB
MUNTERS C INDUSTRIVAGEN SW AB
Original Assignee
MUNTERS C IND AB
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by MUNTERS C IND AB filed Critical MUNTERS C IND AB
Application granted granted Critical
Publication of US3807149A publication Critical patent/US3807149A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24FAIR-CONDITIONING; AIR-HUMIDIFICATION; VENTILATION; USE OF AIR CURRENTS FOR SCREENING
    • F24F13/00Details common to, or for air-conditioning, air-humidification, ventilation or use of air currents for screening
    • F24F13/30Arrangement or mounting of heat-exchangers
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24FAIR-CONDITIONING; AIR-HUMIDIFICATION; VENTILATION; USE OF AIR CURRENTS FOR SCREENING
    • F24F3/00Air-conditioning systems in which conditioned primary air is supplied from one or more central stations to distributing units in the rooms or spaces where it may receive secondary treatment; Apparatus specially designed for such systems
    • F24F3/12Air-conditioning systems in which conditioned primary air is supplied from one or more central stations to distributing units in the rooms or spaces where it may receive secondary treatment; Apparatus specially designed for such systems characterised by the treatment of the air otherwise than by heating and cooling
    • F24F3/14Air-conditioning systems in which conditioned primary air is supplied from one or more central stations to distributing units in the rooms or spaces where it may receive secondary treatment; Apparatus specially designed for such systems characterised by the treatment of the air otherwise than by heating and cooling by humidification; by dehumidification
    • F24F3/1411Air-conditioning systems in which conditioned primary air is supplied from one or more central stations to distributing units in the rooms or spaces where it may receive secondary treatment; Apparatus specially designed for such systems characterised by the treatment of the air otherwise than by heating and cooling by humidification; by dehumidification by absorbing or adsorbing water, e.g. using an hygroscopic desiccant
    • F24F3/1423Air-conditioning systems in which conditioned primary air is supplied from one or more central stations to distributing units in the rooms or spaces where it may receive secondary treatment; Apparatus specially designed for such systems characterised by the treatment of the air otherwise than by heating and cooling by humidification; by dehumidification by absorbing or adsorbing water, e.g. using an hygroscopic desiccant with a moving bed of solid desiccants, e.g. a rotary wheel supporting solid desiccants
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24FAIR-CONDITIONING; AIR-HUMIDIFICATION; VENTILATION; USE OF AIR CURRENTS FOR SCREENING
    • F24F2203/00Devices or apparatus used for air treatment
    • F24F2203/10Rotary wheel
    • F24F2203/1032Desiccant wheel
    • F24F2203/1036Details
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24FAIR-CONDITIONING; AIR-HUMIDIFICATION; VENTILATION; USE OF AIR CURRENTS FOR SCREENING
    • F24F2203/00Devices or apparatus used for air treatment
    • F24F2203/10Rotary wheel
    • F24F2203/104Heat exchanger wheel

Definitions

  • a moisture exchanger for gaseous media which comprises an exchanger body composed by a carrier for a moisture absorbing or hygroscopic material and formed with channels extending from end to end for the passage of the media.
  • the carrier has the shape of thin layers or foils, such as paper of cellulose or asbestos. Also plastic substances or glass fibres may come into consideration.
  • the layer material shall primarily be fibrous, i.e., composed of, or covered with, fine fibres or threads.
  • the channels or passageways extending from end to end in the exchanger body can be formed by making every second layer plane and every interposed second layer corrugated with the corrugations extending in mutually parallel relationship or possibly also by forming the layers to. a honeycomb pattern or providing them with widenings or other spacer elements, ensuring that the layers are spaced from one another.
  • the layers may be wound up spirally to form a cylindrical body. If the layers abut against one another, they can be interconnected at the places of contact.
  • the moisture exchanger is of .the regenerative type it has a casing to which are connected inlets and outlets for, respectively, the gas, such as air, which is to be desiccated and a gas, such as air, which is heated and serves to remove the moisture taken up by the exchanger body.
  • the channels or passageways of the exchanger body are caused alternately to communicate with inlets and outlets, respectively, for the air to be conditioned and for the regenerating gas.
  • the exchanger body may be rotatable in which case it moves with low speed between a dewatering'zone and a regenerating zone of the moisture exchanger.
  • the exchanger body is stationary while a reversal of the flow of the two media is brought about by means of valves or the like.
  • the moisture exchanger can also be used for ventilation of a room or space in which case both consumed room air on its way out, and fresh air on its way into, the room or space, exchange both heat and moisture within the exchanger.
  • the moisture exchanger can produce simultaneously with the desiccation also the heat exchange between two media.
  • the moisture exchanger may form part of an air conditioning system as is shown, e.g., in the U.S. Pat. No. 2,926,502.
  • the carrier in itself hasa moisture absorbing'capacity which at'all events is insignificant, itis caused to take up a particular, moisture absorbing material. it is known to use for this purpose finally powdered silica gel. It is also known to impregnate the carrier with a hygroscopic salt such as lithium chloride, lithium bromide or calcium chloride.
  • a hygroscopic salt such as lithium chloride, lithium bromide or calcium chloride.
  • Such a salt is capable of absorbing a great quantity of moisture in, relation to its own weight, thus if the salt e.g., is contained in an amount equal to 10 percent by weight in a carrier of asbestos paper, the amount of moisture which can be absorbed can equal from between 25 and 50 up to 100 percent of the weight of the carrier. in return, such salts have no particular great capacity of deep desiccation.
  • lithium chloride is capable of desiccating air down to a relative moisture content of l to 2 percent, but on the other hand is capable of absorbing
  • molecular sieves which may consist of synthetically produced crystalline, metallic aluminum silicates which have been activated for adsorption by removal of their water of hydration.
  • Such molecular sieves obtain a very fine porousity and have a great affinity to water.
  • the pores of the molecular sieve have high equal size molecular dimensions which afford to them a high adsorbing capacity within 'a limited range of the relative moisture of the gas.
  • the molecular sieves consist of crystalline zeolites which have the basic formula Mz/ o Al Q -xsiO vHQO wIiere M i'QZtitJnEfikYn'ifie'"valeiie. in spite of some similarity in composition, they differ thoroughly from the gel-type amorphous aluminumsilicates, commonly referred to as zeolites, and used for making water soft. The last-mentioned material does not exhibit any selectivity based on molecular size.
  • zeolites which to advantage can be used for desiccation, those types may be mentioned which commercially have the denominations 4A and 13X, PQYLafilld the fqllo s ne q Type 13X: Na [(AlO (SiO 276F1 0 The sodium ions in type 4A can be replaced by six calcium ions.
  • a moisture adsorbing substance of the kind now described can also be defined as a solid fine powder of crystalline aluminium silicates based on alkali metals or alkali-earth metals, the water of hydration of which has been removed. They may consist of natural or synthetic zeolites or molecular sieves.
  • the material can be admixed as a powder into the fibre pulp suspension of which the carrier, such as the cellulose or asbestos paper, is manufactured or the mate rial can be supplied to the finished paper after the exchanger body has been built up.
  • the quantity of material may amount from 10 to 25 up to percent and even more of the weight of the carrier.
  • the carrier of the exchanger body is supplied with moisture absorbing substances of both kinds'mentioned above, i.e., firstly a water soluble salt and secondly a solid material of the type of zeolite or molecular sieve.
  • the secondmentioned material has in this connection the particular effect of having the capcity of desiccating a gas such as air'to a very low relative moisture content such as less than 0.1 percent.
  • the molecular sieve has a limited capacity only of adsorbing moisture and according to the invention the two components constitute complements to one another in a'particularly advantageous manner.
  • the salt has to manage the preliminary coarse desiccation of the air whereas the other material effects the final desiccation to a very low moisture content.
  • the two components can be distributed evenly over the entire exchanger body, even if it is particularly advantageous to subdivide the same into two zones, a first zone which is initially met bythe gas or air to be desiccated and which is impregnated with the salt whereas a second zone at the outlet side of the channels or passageways is impregnated with the molecular sieve or the like means.
  • the first zone may have a greater extension in the direction-of flow of gas to be desiccated through the channels or passageways of the exchanger body than the secondzone.
  • layers having a thickness of one or some few tenths of a millimeter consist of cellulose or'asbestos.
  • the asbestos paper contains organic constituents to obtain required joining of the asbestos fibres. These constituents are removed after the exchanger body has been built up by burning away said constituents as is evident from the US. Pat. No. 3,231,409.
  • a moisture exchanger for gaseous media which comprises a carrier for moisture absorbing material formed with channels extending from end to end for the passage of the media, said material consisting of two components, firstly, a water-soluble salt, and secondly, a water-insoluble, solid molecular sieve, said salt having the greater absorbing capacity with respect to the quantity of moisture, and said sieve being of such nature as to possess the capacity of desiccating the media to a lower relative moisture content than said salt.
  • a moisture exchanger for gaseous media comprising a fibrous carrier for moisture absorbing material in sheet form arranged in layers and having a plurality of channels extending from end to end of the carrier for passageway therethrough of the media,
  • said material being of two kinds, namely, a water soluble salt and a molecular sieve, the sheets being arranged so that the media pass over the salt-carrying sheets before passing over the sieve-carrying sheets.
  • every second layer of the carrier is plane and every interposed layer is corrugated, the corrugations being parallel to one another and forming with the plane layers the passageways for the media.
  • the crystalline aluminum silicate is in powder form admixed into the fibres of the carrier sheets, and is selected from the group consisting of crystalline alluminum silicates of alkali metals and alkali earth metals.

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Drying Of Gases (AREA)
US00150189A 1970-06-08 1971-06-04 Moisture exchanger for gaseous media Expired - Lifetime US3807149A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
SE07930/70A SE350329B (zh) 1970-06-08 1970-06-08

Publications (1)

Publication Number Publication Date
US3807149A true US3807149A (en) 1974-04-30

Family

ID=20272680

Family Applications (1)

Application Number Title Priority Date Filing Date
US00150189A Expired - Lifetime US3807149A (en) 1970-06-08 1971-06-04 Moisture exchanger for gaseous media

Country Status (5)

Country Link
US (1) US3807149A (zh)
JP (1) JPS578900Y2 (zh)
FR (1) FR2096024A5 (zh)
GB (1) GB1351527A (zh)
SE (1) SE350329B (zh)

Cited By (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4012206A (en) * 1972-12-02 1977-03-15 Gas Developments Corporation Air cleaning adsorption process
US4134743A (en) * 1970-03-31 1979-01-16 Gas Developments Corporation Desiccant apparatus and method
US4289513A (en) * 1978-03-27 1981-09-15 The Mead Corporation Activated sorbtion paper and products produced thereby
US4391667A (en) * 1980-04-25 1983-07-05 Aktiebolaget Carl Munters Method of preparing cells to enable one fluid to be affected by another fluid
US4402717A (en) * 1980-05-22 1983-09-06 Daikin Kogyo Co., Ltd. Apparatus for removing moisture and odors
US5057128A (en) * 1990-07-03 1991-10-15 Flakt, Inc. Rotary adsorption assembly
WO1991016964A1 (en) * 1990-05-08 1991-11-14 Unisearch Limited Dehumidifier
AU636759B2 (en) * 1990-05-08 1993-05-06 Unisearch Limited Dehumidifier
US5435958A (en) * 1993-08-02 1995-07-25 Munters Corporation Method for making a humidity exchanger medium
US5505769A (en) * 1993-08-02 1996-04-09 Munters Corporation Titanium silicate aerogel element and humidity exchanger using matrix of aerogel element
US5542968A (en) * 1995-01-24 1996-08-06 Laroche Industries, Inc. Enthalphy Wheel
US5580369A (en) * 1995-01-30 1996-12-03 Laroche Industries, Inc. Adsorption air conditioning system
US5650221A (en) * 1995-07-06 1997-07-22 Laroche Industries, Inc. High strength, low pressure drop sensible and latent heat exchange wheel
US5660048A (en) * 1996-02-16 1997-08-26 Laroche Industries, Inc. Air conditioning system for cooling warm moisture-laden air
US5758508A (en) * 1996-02-05 1998-06-02 Larouche Industries Inc. Method and apparatus for cooling warm moisture-laden air
US5860284A (en) * 1996-07-19 1999-01-19 Novel Aire Technologies, L.L.C. Thermally regenerated desiccant air conditioner with indirect evaporative cooler
US6358300B1 (en) * 2000-03-28 2002-03-19 Honeywell Commercial Vehicle Systems Co. Lithium chloride desiccant for trailer air dryer and pressure swing dehydration
US7033421B1 (en) 2003-01-17 2006-04-25 Uop Llc Sorption cooling for handheld tools
US20070000382A1 (en) * 2005-06-30 2007-01-04 Ackley Mark W Silver-exchanged zeolites and methods of manufacture therefor
US20070000383A1 (en) * 2005-06-30 2007-01-04 Ackley Mark W Adsorbent and catalyst mixtures
US20100025629A1 (en) * 2004-11-09 2010-02-04 Multisorb Technologies, Inc. Humidity control device

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4622660B2 (ja) * 2005-04-28 2011-02-02 三菱化学株式会社 吸着素子

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2926502A (en) * 1954-07-12 1960-03-01 Lizenzia A G Air conditioning system
US3001607A (en) * 1958-11-04 1961-09-26 Exxon Research Engineering Co Chlorine separation process
US3161488A (en) * 1961-01-18 1964-12-15 Socony Mobil Oil Co Inc Water adsorption process
US3231409A (en) * 1961-01-09 1966-01-25 Munters Carl Georg Method of heat treating an inorganic fibrous body for moisture transfer and/or heat
US3306006A (en) * 1964-03-23 1967-02-28 Universal Oil Prod Co Separation of gas mixtures utilizing plural sorbent zones in series and parallel
US3307617A (en) * 1962-01-30 1967-03-07 Munters Carl Georg Method in the manufacture of an exchanger packing and exchanger packing manufactured according to said method
US3312041A (en) * 1963-09-30 1967-04-04 Products Company Van Drier and method
US3377225A (en) * 1966-04-25 1968-04-09 Munters Carl Georg Method for the manufacture of gas conditioning packing
US3534562A (en) * 1967-04-14 1970-10-20 Koninklujke Nl Zout Ind Nv Method of liquefying gaseous chlorine containing water vapour

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2926502A (en) * 1954-07-12 1960-03-01 Lizenzia A G Air conditioning system
US3001607A (en) * 1958-11-04 1961-09-26 Exxon Research Engineering Co Chlorine separation process
US3231409A (en) * 1961-01-09 1966-01-25 Munters Carl Georg Method of heat treating an inorganic fibrous body for moisture transfer and/or heat
US3161488A (en) * 1961-01-18 1964-12-15 Socony Mobil Oil Co Inc Water adsorption process
US3307617A (en) * 1962-01-30 1967-03-07 Munters Carl Georg Method in the manufacture of an exchanger packing and exchanger packing manufactured according to said method
US3312041A (en) * 1963-09-30 1967-04-04 Products Company Van Drier and method
US3306006A (en) * 1964-03-23 1967-02-28 Universal Oil Prod Co Separation of gas mixtures utilizing plural sorbent zones in series and parallel
US3377225A (en) * 1966-04-25 1968-04-09 Munters Carl Georg Method for the manufacture of gas conditioning packing
US3534562A (en) * 1967-04-14 1970-10-20 Koninklujke Nl Zout Ind Nv Method of liquefying gaseous chlorine containing water vapour

Cited By (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4134743A (en) * 1970-03-31 1979-01-16 Gas Developments Corporation Desiccant apparatus and method
US4012206A (en) * 1972-12-02 1977-03-15 Gas Developments Corporation Air cleaning adsorption process
US4289513A (en) * 1978-03-27 1981-09-15 The Mead Corporation Activated sorbtion paper and products produced thereby
US4391667A (en) * 1980-04-25 1983-07-05 Aktiebolaget Carl Munters Method of preparing cells to enable one fluid to be affected by another fluid
US4402717A (en) * 1980-05-22 1983-09-06 Daikin Kogyo Co., Ltd. Apparatus for removing moisture and odors
WO1991016964A1 (en) * 1990-05-08 1991-11-14 Unisearch Limited Dehumidifier
AU636759B2 (en) * 1990-05-08 1993-05-06 Unisearch Limited Dehumidifier
US5057128A (en) * 1990-07-03 1991-10-15 Flakt, Inc. Rotary adsorption assembly
US5435958A (en) * 1993-08-02 1995-07-25 Munters Corporation Method for making a humidity exchanger medium
US5505769A (en) * 1993-08-02 1996-04-09 Munters Corporation Titanium silicate aerogel element and humidity exchanger using matrix of aerogel element
US5542968A (en) * 1995-01-24 1996-08-06 Laroche Industries, Inc. Enthalphy Wheel
US5580369A (en) * 1995-01-30 1996-12-03 Laroche Industries, Inc. Adsorption air conditioning system
US5650221A (en) * 1995-07-06 1997-07-22 Laroche Industries, Inc. High strength, low pressure drop sensible and latent heat exchange wheel
US5758508A (en) * 1996-02-05 1998-06-02 Larouche Industries Inc. Method and apparatus for cooling warm moisture-laden air
US5660048A (en) * 1996-02-16 1997-08-26 Laroche Industries, Inc. Air conditioning system for cooling warm moisture-laden air
US5890372A (en) * 1996-02-16 1999-04-06 Novelaire Technologies, L.L.C. Air conditioning system for cooling warm moisture-laden air
US5860284A (en) * 1996-07-19 1999-01-19 Novel Aire Technologies, L.L.C. Thermally regenerated desiccant air conditioner with indirect evaporative cooler
US6358300B1 (en) * 2000-03-28 2002-03-19 Honeywell Commercial Vehicle Systems Co. Lithium chloride desiccant for trailer air dryer and pressure swing dehydration
US7033421B1 (en) 2003-01-17 2006-04-25 Uop Llc Sorption cooling for handheld tools
US20100025629A1 (en) * 2004-11-09 2010-02-04 Multisorb Technologies, Inc. Humidity control device
US7959719B2 (en) * 2004-11-09 2011-06-14 Multisorb Technologies, Inc. Humidity control device
US20070000383A1 (en) * 2005-06-30 2007-01-04 Ackley Mark W Adsorbent and catalyst mixtures
US7455718B2 (en) * 2005-06-30 2008-11-25 Praxair Technology, Inc. Silver-exchanged zeolites and methods of manufacture therefor
US20090101011A1 (en) * 2005-06-30 2009-04-23 Mark William Ackley Silver-exchanged zeolites and methods of manufacture therefor
US20070000382A1 (en) * 2005-06-30 2007-01-04 Ackley Mark W Silver-exchanged zeolites and methods of manufacture therefor
US7662213B2 (en) * 2005-06-30 2010-02-16 Praxair Technology, Inc. Silver-exchanged zeolites and methods of manufacture therefor
US7722702B2 (en) 2005-06-30 2010-05-25 Praxair Technology, Inc. Adsorbent and catalyst mixtures
US8221718B2 (en) 2005-06-30 2012-07-17 Praxair Technology, Inc. Silver-exchanged zeolites and methods of manufacture therefor

Also Published As

Publication number Publication date
SE350329B (zh) 1972-10-23
DE2127138B2 (de) 1976-12-09
JPS55167421U (zh) 1980-12-02
JPS578900Y2 (zh) 1982-02-20
FR2096024A5 (zh) 1972-02-11
DE2127138A1 (de) 1971-12-16
GB1351527A (en) 1974-05-01

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