US3800180A - Halogen incandescent lamp containing bromine and phosphorus - Google Patents
Halogen incandescent lamp containing bromine and phosphorus Download PDFInfo
- Publication number
- US3800180A US3800180A US00353673A US35367373A US3800180A US 3800180 A US3800180 A US 3800180A US 00353673 A US00353673 A US 00353673A US 35367373 A US35367373 A US 35367373A US 3800180 A US3800180 A US 3800180A
- Authority
- US
- United States
- Prior art keywords
- phosphorus
- lamps
- lamp
- halogen incandescent
- bromine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229910052736 halogen Inorganic materials 0.000 title claims abstract description 9
- 150000002367 halogens Chemical class 0.000 title claims abstract description 8
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 title claims description 15
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 title claims description 13
- 229910052794 bromium Inorganic materials 0.000 title claims description 13
- 229910052698 phosphorus Inorganic materials 0.000 title claims description 13
- 239000011574 phosphorus Substances 0.000 title claims description 13
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 title claims description 11
- PHSPJQZRQAJPPF-UHFFFAOYSA-N N-alpha-Methylhistamine Chemical compound CNCCC1=CN=CN1 PHSPJQZRQAJPPF-UHFFFAOYSA-N 0.000 claims abstract description 13
- 238000010494 dissociation reaction Methods 0.000 claims abstract description 4
- 230000005593 dissociations Effects 0.000 claims abstract description 4
- 239000011261 inert gas Substances 0.000 claims description 2
- 239000007789 gas Substances 0.000 description 21
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- 239000007788 liquid Substances 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- -1 PHOSPHORUS Halogen Chemical class 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229910052721 tungsten Inorganic materials 0.000 description 2
- 239000010937 tungsten Substances 0.000 description 2
- 229910052786 argon Inorganic materials 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000003738 black carbon Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01K—ELECTRIC INCANDESCENT LAMPS
- H01K1/00—Details
- H01K1/52—Means for obtaining or maintaining the desired pressure within the vessel
- H01K1/54—Means for absorbing or absorbing gas, or for preventing or removing efflorescence, e.g. by gettering
- H01K1/56—Means for absorbing or absorbing gas, or for preventing or removing efflorescence, e.g. by gettering characterised by the material of the getter
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01K—ELECTRIC INCANDESCENT LAMPS
- H01K1/00—Details
- H01K1/50—Selection of substances for gas fillings; Specified pressure thereof
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01K—ELECTRIC INCANDESCENT LAMPS
- H01K3/00—Apparatus or processes adapted to the manufacture, installing, removal, or maintenance of incandescent lamps or parts thereof
- H01K3/22—Exhausting, degassing, filling, or cleaning vessels
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02B—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
- Y02B20/00—Energy efficient lighting technologies, e.g. halogen lamps or gas discharge lamps
Definitions
- Phosphorus in these lamps is said to perform a function which is comparable with that of hydrogen, namely it should prevent a direct reaction between the relatively cold parts of the tungsten filament body and bromine present in the lamp. Such an attack of these parts leads to a shorter lifetime of the lamp.
- a halogen lamp is understood to mean a lamp which is proportioned in such a manner that during operation the wall of the envelope everywhere assumes a temperature at which tungsten halides formed in the lamp cannot condense.
- the invention has for its object to completely obviate this risk in halogen incandescent lamps containing phosphorus and bromine.
- the gas atmosphere in the lamp contains phosphorus tribromide or its dissociation products.
- Lamps according to the invention may be obtained by introducing phosphorus tribromide in vapour form into the lamps. It has been found that in lamps having a lifetime of 1000 hours and more optimum results are generally obtained when the partial pressure of phosphorus tribromide upon filling in the lamp is between 2 and 6 Torr. Blackening quickly occurs at pressures of less than 2 Torr and the filament is attacked at pressures of more than 6 torr. Lamps according to the invention can reach lifetimes of more than 2000 hours.
- the sole FIGURE diagrammatically shows an arrangement for filling a number of lamps 1 to 7 with a phosphorus tribromide-containing gas atmosphere.
- the arrangement comprises a reservoir 8 which contains liquid phosphorus tribromide.
- the reservoir 8 is present in a liquid bath 9 in which the reservoir 8 can be maintained at a constant temperature associated with the desired phosphorus tribromide vapour pressure.
- the liquid bath may be filled, for example, with water.
- the reservoir 8 is connected to the duct 11 by means of a tap 10.
- the lamps l to 7 are connected to this duct 11 over the gas spaces 1A to 7A. Furthermore the duct 11 is connected via three taps l2, l3 and 14 to a vacuum pump, a reservoir having a rinsing gas and a reservoir having a rare gas and/or nitrogen (not shown). The entire arrangement shown may consist of glass.
- the reservoir 8 is meanwhile brought to the temperature associated with the desired phosphorus tribromide vapour pressure. This temperature is 4C at 0.5 Torr, 9C at 1 Torr and 17C at 2 Torr.
- the use of a higher pressure than approximately 2 Torr is not desirable because then there is the risk that PBr condenses in the lamps l-7, the gas spaces lA-7A or the duct 1 1.
- tap 12 is closed and tap 10 is opened.
- the gas spaces and the lamps tap 10 is closed and tap 14 is opened so that argon having the desired pressure, for example, 1 atmosphere is introduced into the lamps l-7.
- Tap 14 is subsequently closed and the connection between the gas spaces lA-7A and duct 11 is sealed off and the lamps with the associated gas spaces are removed.
- the lamps are then immersed in liquid nitrogen so that the mixture of gases present in the gas space and the lamp condenses in the lamp. Subsequently the connection between the lamp and the associated gas space is sealed off and the gas space is removed. In this manner a gas pressure of more than 1 atmosphere is obtained in the lamp, depending on the relative volume of the gas space.
- the lamps may then be operated and phosphorus tribromide present in the lamp, possibly partly in a liquid form, immediately decomposes to phosphorus and bromine.
Landscapes
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Discharge Lamp (AREA)
- Vessels And Coating Films For Discharge Lamps (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
NL7205485A NL7205485A (forum.php) | 1972-04-22 | 1972-04-22 |
Publications (1)
Publication Number | Publication Date |
---|---|
US3800180A true US3800180A (en) | 1974-03-26 |
Family
ID=19815900
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US00353673A Expired - Lifetime US3800180A (en) | 1972-04-22 | 1973-04-23 | Halogen incandescent lamp containing bromine and phosphorus |
Country Status (9)
Country | Link |
---|---|
US (1) | US3800180A (forum.php) |
JP (1) | JPS4921985A (forum.php) |
BE (1) | BE798556A (forum.php) |
CA (1) | CA974567A (forum.php) |
DE (1) | DE2316554C3 (forum.php) |
FR (1) | FR2181905B1 (forum.php) |
GB (1) | GB1408469A (forum.php) |
IT (1) | IT983991B (forum.php) |
NL (1) | NL7205485A (forum.php) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5034656A (en) * | 1989-09-26 | 1991-07-23 | General Electric Company | Tungsten halogen lamp including phosphorous and bromine |
US6384530B1 (en) * | 1988-11-22 | 2002-05-07 | General Electric Company | Fill for high temperature tungsten-halogen lamps |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2920222A (en) * | 1957-08-13 | 1960-01-05 | Duro Test Corp | Electric lamp |
-
1972
- 1972-04-22 NL NL7205485A patent/NL7205485A/xx unknown
-
1973
- 1973-04-03 DE DE2316554A patent/DE2316554C3/de not_active Expired
- 1973-04-18 FR FR7314173A patent/FR2181905B1/fr not_active Expired
- 1973-04-19 GB GB1896373A patent/GB1408469A/en not_active Expired
- 1973-04-19 JP JP48043698A patent/JPS4921985A/ja active Pending
- 1973-04-19 IT IT23190/73A patent/IT983991B/it active
- 1973-04-20 BE BE130286A patent/BE798556A/xx unknown
- 1973-04-23 US US00353673A patent/US3800180A/en not_active Expired - Lifetime
- 1973-04-24 CA CA170,067A patent/CA974567A/en not_active Expired
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2920222A (en) * | 1957-08-13 | 1960-01-05 | Duro Test Corp | Electric lamp |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6384530B1 (en) * | 1988-11-22 | 2002-05-07 | General Electric Company | Fill for high temperature tungsten-halogen lamps |
US5034656A (en) * | 1989-09-26 | 1991-07-23 | General Electric Company | Tungsten halogen lamp including phosphorous and bromine |
Also Published As
Publication number | Publication date |
---|---|
DE2316554B2 (de) | 1977-10-27 |
JPS4921985A (forum.php) | 1974-02-26 |
DE2316554A1 (de) | 1973-11-08 |
FR2181905B1 (forum.php) | 1976-09-10 |
BE798556A (fr) | 1973-10-22 |
NL7205485A (forum.php) | 1973-10-24 |
DE2316554C3 (de) | 1978-06-22 |
CA974567A (en) | 1975-09-16 |
FR2181905A1 (forum.php) | 1973-12-07 |
GB1408469A (en) | 1975-10-01 |
IT983991B (it) | 1974-11-11 |
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