US3769060A - Specific processed cloths and a method of producing the same - Google Patents

Specific processed cloths and a method of producing the same Download PDF

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Publication number
US3769060A
US3769060A US00111252A US3769060DA US3769060A US 3769060 A US3769060 A US 3769060A US 00111252 A US00111252 A US 00111252A US 3769060D A US3769060D A US 3769060DA US 3769060 A US3769060 A US 3769060A
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Prior art keywords
agent
cloth
agents
processed
processing agents
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H Hasegawa
S Nakanishi
S Ida
K Hosokawa
K Kajino
K Ueda
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Kanegafuchi Spinning Co Ltd
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Kanegafuchi Spinning Co Ltd
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Priority claimed from JP1017970A external-priority patent/JPS5244959B1/ja
Priority claimed from JP8568270A external-priority patent/JPS4921275B1/ja
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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M23/00—Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
    • D06M23/16—Processes for the non-uniform application of treating agents, e.g. one-sided treatment; Differential treatment
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M23/00—Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S428/00—Stock material or miscellaneous articles
    • Y10S428/907—Resistant against plant or animal attack
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S428/00—Stock material or miscellaneous articles
    • Y10S428/92—Fire or heat protection feature
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S428/00—Stock material or miscellaneous articles
    • Y10S428/92—Fire or heat protection feature
    • Y10S428/921—Fire or flameproofing
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S428/00—Stock material or miscellaneous articles
    • Y10S428/922—Static electricity metal bleed-off metallic stock
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24802—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
    • Y10T428/2481—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.] including layer of mechanically interengaged strands, strand-portions or strand-like strips

Definitions

  • Those parts which respectively provide the fabric or sheet material with different chemical or physical properties may consist of a large number of small zones substantially uniformly distributed on the surface of the fabric or sheet material, or may be two surfaces, i.e., one surface and the reverse surface.
  • the proposed processes enable a fabric or sheet material to be finished with a plurality of finishing agents which are incompatible with one another.
  • the present invention relates to cloths whose physical and chemical properties are modified by a plurality of processing agents and a method of producing the same.
  • cloths used herein means various materials for clothings and industry and the like, for example, woven fabrics, knitted goods, unwoven fabrics, sheets, felts, bats, carpets, films, laminated cloths, etc.
  • the means for applying a plurality of processing agents on a cloth include treating the cloth with a bath containing a mixture of a plurality of processing agents or treating the cloth serially with separate baths containing different processing agents but in both cases, both the surfaces of the cloth are throughout processed uniformly with a bath, because the treating bath has a permeability into the cloth.
  • any one of the antistatic-agents provided with a hygroscopic function and the elastic agents provided with a water repellent function covers the other agent and hence both effects are mutually eliminated or reduced and it is impossible to develop both the properties simultaneously and efficiently.
  • the object of the present invention is to provide novel processed cloths developing each of the effects of different processing agents plurally and efficiently, which cloths have been treated with a plurality of processing agents having different functions.
  • the specific processed cloth of the present invention is characterized in that a large number of small zones distributed substantially uniformly on the cloth surface or the whole of one surface of the cloth is treated with a processing agent and at least one part of a portion other than said treated zones or the whole of the other surface of the cloth is treated with a second processing agent having a function different from the first processing agent.
  • the object can be fully attained and in an extreme case, even when only the periphery of the cloth is processed, a desired antistatic cloth can be obtained.
  • a silicone processing is made throughout the surface of the cloth in order to improve the elastic property of the cloth and to provide crease proofness, the cloth loses its hygroscopicity, while if such a processing agent is applied so as to be deposited on a large number of distributed small zones, the cloth can be provided with the crease resistance while maintaining the hygroscopicity or vapor permeability.
  • a crease proofing agent such as tetraoxane and an antistatic agent and an antiflaming agent
  • the effects of the treatments owing to each processing agent that is, the crease resistance and wash wear property due to tetraoxane, the antistatic property due to the antistatic agent and the flame resisting property due to the antiflaming agent can be provided on knitted goods and woven fabrics.
  • the present invention has been accomplished by utilizing these facts skillfully.
  • the method of producing the above described specific processed cloth comprises:
  • a processing agent for a cloth is deposited on a large number of small zones substantially uniformly distributed on a surface of a cloth or over all of one surface of the cloth.
  • the processing agent is deposited on a proper pattern uniformly distributed on the cloth surface, for example, pointlike, spot-like, parallel line-like, stripe-like, mosaiclike, mesh-like pattern and the like.
  • one processing agent is usually used alone but if the processing agents have no interference and hindrance between one another, two or more processing agents may be used together.
  • a treatment for fixing the applied agent to the cloth for example drying, heating and the like is effected or such a treatment is not effected, after which another processing agent having a function different from the above described processing agent is applied on the spaces between the above described patterns or over all of another surface of the cloth.
  • the cloth in which these processing agents are applied on the small zones, such as mosaic-like, alternating stripe-like pattern and the like or in which each of both the whole surfaces is coated with different processing agents respectively, is subjected to a treatment for fixing the processing agent.
  • the deposited state of two processing agents in the small zone type may be any of the following. Namely both the boundaries in the deposited zones may be in contact with each other or be spaced somewhat or be overlapped to some extent but non-overlapped portions of at least one of the processing agents must be distributed uniformly. Furthermore, when using processing agents not interferring with each other, one of the agents may be arranged in the small zones and the other agent may be applied on the whole surface. The order of the step for applying one of the processing agent on the small zones and the step for applying the other processing agent on the whole surface is not limited. The processing agents to be applied are not limited to two kinds and may be used optionally in a number of more than two depending upon the object.
  • FIG. 1 shows the state where different processing agents are deposited on a stripe-like small zone 1 and the remaining zone 2 respectively.
  • both the zones are arranged so that the edges of both the zones are in contact with each other.
  • the stripes may be longitudinal stripes, transverse stripes or inclined stripes along the longitudinal direction of the cloth but in order to distribute these small zones uniformly throughout the cloth surface, it is desirable that the width and distance of every stripes are substantially equal respectively;
  • FIG. 2 shows the state wherein both the small zones 1 and 2 are spot-like and the zones are spaced from each other and arranged uniformly.
  • the shapes of the spots may be selected optionally in square, circular and the other forms;
  • FIG. 3 shows an embodiment wherein the small zone 1 is arranged in a spot-like or dot-like form and in the remainder 2 another processing agent is distributed in point-like form;
  • FIG. 4 shows the state wherein small zones 1, 2 and 3 deposited different processing agents respectively are distributed uniformly and regularly;
  • FIG. 5 shows an embodiment wherein the small zone 1 and the small zone 2 are partially overlapped at the zone 3. Even in this case, each processing agent has non-overlapped portions uniformly distributed.
  • the means for distributing and depositing the processing agents on the cloth in these patterns may be effected by printing or spraying the processing agent liquid or a solution of a processing agent or a dispersion of the agent in a proper solvent or a paste of a processin g agent mixed with a sizing agent is printed or sprayed in a given pattern and then evaporating, removing or extracting the solvent or the sizing agent.
  • the object can be attained by dispersing and depositing microcapsules containing sealed therein a processing agent on the cloth surface uniformly and breaking the capsules by the action of pressure, heating and the like.
  • Such operations for applying the processing agents are generally carried out by repeating the operations for each of the processing agents employed.
  • repeating the printings it is desirable to arrange the succeeding patterns in the spaces of the preceding patterns but when the permeability of the cloth is high, the processing agent may penetrate and extend from the succeedingly applied zones and overlap with the preceding zones. Accordingly, when the overlapped zones where the effects are reduced by the action of contention and hindrance of mutual processing agents, are formed, it is desired that each area of the applied zones is made small as much as possible to reduce the overlapped portions, or that a processing for restraining the permeability is previously applied to the cloth or a process for printing a paste is adopted. In order to carry out the removal of solvent rapidly, it is effective to apply the processing agent on a heated cloth.
  • an assistant such as a surface active agent is used together with the processing agent or the cloth to be treated is subjected to a preliminary treatment by means of such an assistant.
  • the cloth is a film composed of an organic synthetic thermoplastic polymer
  • the film is previously subjected to a surface active treatment, such as corona discharge treatment and the like.
  • the object of the present invention can be accomplished by combining two spraying treatments.
  • the above described small zones in which the processing agents are deposited should be distributed substantially uniformly over the whole surface of the cloth and a preferred result can be obtained.
  • the width is at most about 2 cm, preferably at most about 1 cm and in the case of the spot-like pattern, the area of one small zone is not more than about 4 cm preferably not more than about l cm.
  • the setting treatment includes generally drying at room temperature or at an elevated temperature, aging, baking, steaming, extraction with a solvent, fixing by a reaction with another chemical and the like, but it is selected properly depending upon the properties of the processing agents deposited on the cloth. If it is possible to carry out the fixing treatment commonly for various deposited processing agents, it is preferred to effect the fixing step at the same time after finished the steps for applying the processing agents.
  • the processing agents applicable to the present invention are treating agents, which can be deposited or adsorbed on the cloths to give or modify the particular chemical or physical properties and, for example, shrink proofing agent, antipilling agent, water repelling agent, elastic agent, hygroscopic agent, antistatic agent, stain proofing agent, antiflaming agent, antifusing agent, softening agent, ultraviolet absorbing agent, crease proofing agent, water absorbing agent, heat resisting agent, soil releasing (SR) agent oil repelling agent, moth proofing agent, dust proofing agent, mildew proofing agent, delustering agent and the like may be mentioned.
  • shrink proofing agent for example, shrink proofing agent, antipilling agent, water repelling agent, elastic agent, hygroscopic agent, antistatic agent, stain proofing agent, antiflaming agent, antifusing agent, softening agent, ultraviolet absorbing agent, crease proofing agent, water absorbing agent, heat resisting agent, soil releasing (SR) agent oil repelling agent, moth proofing agent,
  • the above described various processing agents can provide the inherent effect to the cloth alone respectively but when these processing agents are used together and applied on knitted goods and woven fabrics, the applied processing agents interfere with one another in the conventional processes as described above and it is difficult to develop the inherent treating effects brought about by the respective processing agents together, while according to the present invention when ,such a plurality of processing agents are used, the effects of these agents can be developed most efficiently.
  • the shrink proofing agents include the reaction products of phosphorus pentachloride with carboxyl group of ethylene/acrylic acid copolymer, ethylene/methacrylic acid copolymer, ethylene/itaconic acid copolymer, ethylene/methylhydrogen maleate copolymer,
  • ethylene/maleic acid copolymer ethylene/acrylic acid/methyl methacrylate copolymer, ethylene/methacrylic acid/ethyl acrylate copolymer, ethylene/itaconic acid/methyl methacrylate copolymer, ethylene/methylhydrogen maleate/ethyl acrylate copolymer, ethylene/- methacrylic acid/vinyl acetate copolymer, ethylene/acrylic acid/vinyl formate copolymer, ethylene/- propylene/acrylic acid copolymer, ethylene/styrene/acrylic acid copolymer, ethylene/methacrylic acid/acrylonitrile copolymer, ethylene/fumaric acid/vinyl methyl ether copolymer, ethylene/vinyl chloride/acrylic acid copolymer, ethylene/vinylidene chloride/acrylic acid copolymer, ethylene/vinyl fluoride/methacrylic acid copolymer,
  • UV absorbing agents 2-hydroxy-4- octoxybenzophenone, 2,2,4,4'-tetrahydroxybenzophenone, 2-hydroxy-4-methoxybenzophenone, sodium salt of 2,2-dihydroxy-4,4'-dimethoxy-5- sulfobenzophenone, 2,4-dihydroxybenzophenone, 2- hydroxy-4-methoxybenzophenone, 2,2'-dihydroxy- 4,4-dimethoxybenzophenone and di-p-n-nonylphenol isophthalate are frequently used.
  • water repellent agents use may be made of dialkyl-polysiloxanediol, alkylhydrogen polysiloxane, alkylpyridium halide, Werner type metal complex, the other long chain aliphatic derivatives and the like and particularly alkylhydrogen polysiloxane is used in many cases.
  • the most preferable one is methylhydrogen polysiloxane having a viscosity of less than centistokes.
  • antistatic agents use may be made of, for example anionic, cationic, amphoteric or non-ionic compounds.
  • the antistatic agents having a durability, as the anionic antistatic agents are, for example, ammonium polyacrylate, alkali metal salts of copolymer of styrene/vinylacetate/methy] methacrylate with maleic anhydride (or ethylene oxide addition product), carboxylic acid compounds, such as Werner type complex prepared from chromium chloride and l,2,3,4-butanetetracarboxylic acid, polyester derivatives, such as esters of styrene/maleic anhydride copolymer with polyethylene glycol or polyhydric alcohol, copolymer of higher fatty acid bis (hydroxyalkyl) amide with maleic anhydride and the like, sulfonic acid derivatives, such as polyvinylsulfonic acid, polystyrenesulfonic acid, polyvinyltoluenesulfonic acid
  • quaternary ammonium salt obtained by reacting diethylaminoethylmethacrylate with dimethyl sulfate, acrylate derivatives, such as triacryloylhexahydrotriazine derivative, acrylic amide derivatives, such as a polymer of acrylic amide, methy lene urea, a polymer of melaminemonomethyleneacrylic amide, a polymer of acrylic amide-propylbutyloxymethyl morpholinium chloride, vinyl ether derivatives, such as polyvinyl-Z-chloroethyl ether pyridinium salt, a polymer of unsaturated ureide ether from aminoethyl vinyl ether and isocyanate, a quaternary ammonium salt of copolymer of vinyl cyclohexyl ether and diethylaminovinyl ether, vinyl nitrogen derivatives, such as a quaternary salt of
  • non-ionic antistatic agents use may be made of acrylates, such as a copolymer of polyethylene glycol ester and acrylic amide, ethylene oxide derivatives, such as a reaction product of melamine, formaldehyde and ethylene oxide, an addition product of phenol resin and ethylene oxide, an addition product of cellulose and ethylene oxide, a reaction product of polyethylene glycol and chlorohydrin, a copolymer of dimethyl terephthalate with ethylene glycol and polyethylene glycol, use of combination of tolylene-diisocyanate and polyethylene glycol, use of combination of polyacetal from polyethylene glycol and dimethylol urea, polyester of polyethylene glycol with maleic acid and itaconic acid, use of combination of polyethylene glycol and 1,3,5- triacryloyl-hexahydro-S-triazine, amide compounds, such as N-methoxymethylated polyamide, N,N'- dimethyl-N,N '-bishydroxymethyladipic,
  • amphoteric antistatic agents include alanine type, imidazoline type, carboxylic acid type, dicarboxylic acid type, diamine type, betaine type and sulfobetaine type.
  • the cationic antistatic agents are preferable in view of the effect and antiwashing property.
  • softening agents such as long chain alkyl sulphates, cationic agents, such as long chain alkyl quaternary ammonium salts, betaine type of amphoteric agents and the like.
  • m 2 to and R" represents hydrogen or methyl group
  • RF represents a linear or branched perfluoroalkyl group having three to 18 carbon atoms
  • n represents an alkyl group having zero to 16 carbon atoms and R represents hydrogen or methyl group
  • RF represents a linear or branched perfluoroalkyl group having three to 21 carbon atoms
  • m represents an alkyl group having zero to five carbon atoms
  • R and R represent alkyl groups having one to 19 carbon atoms
  • B represents or [RF ]A'Z, wherein [RF"] is a linear or branched perfluoroalkyl group having three to 20 carbon atoms
  • A is O- or -S- and Z is a triazine or pyridine ring.
  • the soil releasing agents include, for example a reaction product of poly-(N-methylperfluorooctane-sulfon amide-ethyl) acetate-ethylperfluorooctanoate and polyethyleneimine, a copolymer having polyoxyethylene group, which is obtained by copolymerizing dimethyl terephthalate, ethylene glycol and polyethylene glycol, a copolymer having polyoxyethylene group, which is obtained by copolymerizing dimethyl terephthalate, l,4-bis-hydroxymethylcyclohexane and poly (oxyethylene) glycol.
  • inorganic processing agents such as alumina sol, silica sol and the like and they are used in an amount of 0.1 to 10 percent by weight based on the fibers, preferably 0.4 to 3 percent by weight.
  • oil repelling agents use may be made of mainly low molecular substances or polymers containing fluorine atom and further the substances having soil releasing property may be used.
  • fluorine-containing compounds for example mention may be made of the above described stain proofing agents.
  • the soil releasing agents include, for example a reaction product of poly-(N-methyl-perfluorooctanesulfonamide-ethyl) acetate, ethyl-perfluorooctanoate and polyethyleneimine, and a copolymer having polyoxyethylene group, which is obtained by copolymerizing dimethyl terephthalate, ethylene glycol and polyethylene glycol.
  • the dust proofing agents include, for example in organic agents, such as alumina sol, silica sol and the like.
  • antiflaming agents use may be made of mainly compounds containing phosphorus or halogen, for example 2,3-dibromopropyl phosphate, trisdichloropropyl phosphate, l,2,3,4-tetrabromoethane, tetrakishydroxy-dimethyl phosphonium chloride, tris-2- chloroethyl phosphate, tris-aziridinyl-phosphin oxide, bis-B-chloroethyl phosphate, dialkyl phosphate carboxymethylolamide, dimethylol phosphono-propylene monomethylol amide, chloroparaffin, diammonium hydrogen phosphate, ammonium sulfamate, ammonium phosphate, borax and boric acid.
  • 2,3-dibromopropyl phosphate trisdichloropropyl phosphate, l,2,3,4-tetrabromoethane, tetrakishydroxy
  • organopolysiloxane is effective and the above described dialkyl-polysiloxanediol and alkyl hydrogen polysiloxane are mainly used.
  • urea derivatives use may be made of urea derivatives, triazine derivatives, triazone derivatives, dihydrazide derivatives, hydrazine derivatives, alkylcarbamate derivatives, acetal derivatives, organic silicone series prepolymers, and polyurethane prepolymers.
  • urea derivatives dimethylol compounds are used in many cases, for example dimethylol urea, dimethylol-ethylene urea, dimethylolpropylene urea, and dimethylol-dihydroxyethylene urea.
  • the triazine derivatives include trimethylolmelamine and hexamethylolmelamine.
  • the triazone derivatives include dimethyloltriazone.
  • the hydrazide derivatives include methylolated product of dihydrazide.
  • the hydrazine derivatives include dimethylolated product of symmetric hydrazine.
  • the alkyl carbamate derivatives include dimethylolmethylcarbamate, dimethylolethylcarbamate, dimethylolpropylcarbamate, and dimethylolbutylcarbamate.
  • dialkylpolysiloxane diols are used in many cases, for example dimethylpolysiloxane diol and diethylpolysiloxane diol having a viscosity of at least centistokes, preferably at least 2,000 centistrokes.
  • the prepolymers having a high polymerization degree of a viscosity of at least 1,000 centistokes, preferably at least 3,000 centistokes are used as the prepolymers having a high polymerization degree of a viscosity of at least 1,000 centistokes, preferably at least 3,000 centistokes are used.
  • tetraoxane of methylol derivatives can be preferably used.
  • Tetraoxane is a tetramer of aldehyde and even if it is fixed on knitted goods or woven fabrics alone, the crease proofing property or the wash wear property can be provided on the cloths.
  • the water absorbing agents or moisture absorbing agents are mainly polyester compounds and polyamide compounds containing a hydrating group and include relatively low molecular weight carboxylic acid and sulfonic acid derivatives.
  • the polyester compounds are mainly a copolymer containing hydrating polyoxyalkylene group, which is a copolymer of polyoxyalkylene glycol having an avarage molecular weight of 300 to 6,000, particularly poly (oxyethylene) glycol or alkoxypoly (oxyalkylene) glycol, particularly methoxyl poly (oxyethylene) glycol with dimethyl terephthalate and ethylene glycol, for example a copolymer of dimethyl terephthalate, ethylene glycol, and polyoxyethylene glycol and a copolymer of dimethyl terephthalate, ethylene glycol and methoxy-poly (oxyethylene) glycol.
  • polyamide compounds use may be made of mainly N-methoxymethyl-polyhexamethylene adipamide and the addition product of a lactam or a derivative thereof with polyalkylene glycol is particularly preferable and an addition product of caprolactam oligomer having a polymerization degree of at most 5 with 2 to 50 mole of alkylene oxide having at most four carbon atoms is the most excellent in the treating effect and durability.
  • the elastic agents include polyorganosiloxane prepolymers or urethane prepolymers.
  • polyorganosiloxane prepolymers use may be made of polyorganosiloxane diols and alkyl hydrogen polysiloxanes.
  • the polyorganosiloxane diols are shown by the general formula HO (SiRR'O),, H
  • Dialkyl polysiloxane diol, diphenyl polysiloxane diol and alkyl phenyl polysiloxane diol are most frequently used and particularly dimethyl polysiloxane diol is the most preferable.
  • the viscosity of polyorganosiloxane diol is 1,000 to 100,000 centistokes, preferably 5,000 to 50,000 centistokes.
  • the alkyl hydrogen polysiloxane is somewhat poor in view of the elasticity of the formed film as compared with polyorganosiloxane diol but is advantageous in view of the water repellent property.
  • the alkyl groups in alkyl hydrogen polysiloxane include methyl, ethyl, propyl and butyl groups but methyl hydrogen polysiloxane is the most preferable.
  • the viscosity is preferred to be at most 1,000 centistokes, preferably 5 to 50 centistokes.
  • the polyurethane prepolymers to be used in the present invention have urethane bonds or urea bonds in the molecular chain and have isocyanate group in the end and such prepolymers can be produced by reacting a compound having active hydrogen with a compound having isocyanate group.
  • the organic diisocyanates to be used for the production of the prepolymers include 1,5-naphthalene diisocyanate, 4,4-diphenyl methane diisocyanate, 2,6- tolylene diisocyanate, 2,4-tolylene diisocyanate, methylene bis (4-phenyl isocyanate), m-phenylene diisocyanate, p-phenylene diisocyanate, diphenylmethane-3,3'- dimentyl-4,4'-diisocyanate, xylene diisocyanate, cyclohexylene diisocyanate, 1,6-hexamethylene diisocyanate, dimethyl diisocyanate, 4,4'-dicyclohexylmethane diisocyanate, methylcyclohexylene diisocyanate and the like.
  • the active hydrogen compounds to be used for the formation of long chain segments are mainly diols and triols having a linear structure and also include polyols.
  • the triols for example glycerin-propylene oxide adduct is used.
  • the diols polyalkylene oxide glycols, such as poly-1,2propyle'ne oxide glycol, polyethylene oxide glycol, ethylene oxide/propylene oxide copolymer glycol are preferable.
  • the molecular weight of the diols is preferred to be at most 5,000.
  • the prepolymers are preferred to be high molecular weight and 3,000 to 50,000, more preferably 10,000 to 25,000 and the isocyanate group is 1 to 3 percent, preferably 1.5 to 2.5 percent.
  • the present invention it is possible to use polyorganosiloxane prepolymer and urethane prepolymer together.
  • the isocyanate group in the polyurethane prepolymer and the hydroxyl group in the polyorganosiloxane diol form a block copolymer through the polyaddition reaction and the thus.
  • treated cloth is low in the waxy touch and has a feeling enriched in weight feeling and thickness as compared with the case when the urethane polymer of silicone polymer is used alone.
  • the above described conditions concerning the urethane prepolymer are preferable for the formation of the block copolymer and the ratio of the mixture is preferred to be from :2 to 2:10.
  • an addition of a catalyst is preferable in order to carry out the hardening of the prepolymer under a practical industrial condition and in the case of polyorganosiloxane prepolymer, the use of catalyst is necessary.
  • Dibutyltin dilaurate, dibutyltin octanoate, dibutyltin diethyl hexonate, chelate tin and the like are preferable but the catalyst is not limited thereto. They are used within the range of l to 30 percent by weight, preferably 3 to 10 percent by weight based on polyorganosiloxane prepolymer alone or in admixture.
  • a primer may be used together with the above catalyst in order to deposit the formed polymer on the fibers.
  • the primers are, for example silane isocyanate, alkoxysilane, silane acetate, vinylthrichlorosilane, vinyl-tris (B-methoxyethoxy) silane.
  • the amount of polyorganosiloxane prepolymer and urethane prepolymer to be used in the present invention is 0.1 to 10 percent by weight, preferably 0.2 to 3 percent by weight based on the fibers.
  • the amount of less than 0.1 percent by weight can not attain the satisfactory effect and the amount of more than 10 percent by weight is not preferable in the texture of the finished base cloth.
  • soil releasing agents use may be made of carboxymethyl cellulose, hydroxyethyl cellulose, starch, water soluble polyvinyl alcohol, a block copolymer of polyethylene glycol and polyethylene terephthalate, a reaction product of an amino resin and polyethylene glycol, a reaction product of polyamide and polyethylene glycol, an acrylate/acrylic acid copolymer, an acrylate/methylol acrylic amide copolymer and acrylic acid/acrylic amide copolymer.
  • polyurethane compounds having a high polymerization degree for example the above described elastic processing urethane prepolymer, reactive acrylate resins, butadiene latex and the like.
  • moth proofing agents and mildew proofing agents use may be made of pentachlorophenol, sodium salt of pentachlorophenol, metal salts of naphthenic acid, cetyl pyridium bromide, dimethylbenzyl ammonium phosphate, trimethylcetyl ammonium pentachlorophosphate, tributyltin phthalate mercuric chloride, phenyl mercuric chloride, phenyl mercuric acetate, phenyl mercuric oleate, phenyl mercuric urea, phenyl mercuric p-toluene-sulfonanilide, phenyl mercuric triethanol ammonium acetate, ethyl mercuric chloride, ethyl mercuric oleate, ethyl mercuric ptoluene sulfonanilide, bistributyltin oxide, tributy
  • tetraoxane is usually applied on knitted goods or woven fabrics as an aqueous solution.
  • concentration of tetraoxane in the aqueous solution is selected variously depending upon the kind of knitted goods or woven fabrics to be treated, the means depositing it on them, the kind of the processing agents other than tetraoxane or with or without the drying treatment after the applying treatment and it is difficult to determine the concentration generally and the concentration is preferred to be 0.05 to 25 percent by weight, more particularly 0.5 to 20 percent by weight, most preferably 2 to 15 percent by weight.
  • Tetraoxane can be easily dissolved in water at room temperature but the solubility of tetraoxane at room temperature is about 5 to 8 per cent and in hot water, for example at 80C, it reaches more than 13 percent, so that it is desirable to dissolve tetraoxane in water at a high temperature.
  • a dispersing agent for example, anionic, cationic or nonionic various surfactants.
  • dispersing agent is used together it is possible to obtain a dispersion having a stable high concentration, for example more than 15 percent by weight of tetraoxane even at room temperature.
  • a desirable result can be obtained by existing various catalysts to be used generally in theprocessing for crease proofing or wash wear, for example ammonium salts, organic amine salts or metal salts (for example, magnesium chloride, zinc nitrate or zinc fluoride etc.) together.
  • the amount of the catalyst used is generally l/l0 to 1/2, preferably 1/4 to l/ (weight ratio) based on tetraoxane.
  • the most effective result can be obtained by applying tetraoxane on knitted goods or woven fabrics together with a sizing agent.
  • sizing agents can react with tetraoxane to fix tetraoxane on knitted goods or woven fabrics, but it is difficult to remove the sizing agent by washing and the knitted goods and woven fabrics become rigid, so that it is necessary to take account of the selection of the sizing agent deeply.
  • sizing agents particularly propylene glycol ester of alginic acid, after it is deposited on knitted goods or woven fabrics together with tetraoxane, can be easily removed by washing with water and give an excellent effect resulting from tetraoxane to the cloth without hardening the cloth, so that it is the best sizing agent.
  • tetraoxane and the other processing agents are deposited on the respective separate positions of the surface of knitted goods or woven fabrics.
  • the order of the depositing treatment is not particularly defined and after the deposition of tetraoxane, the other processing agents may be deposited or the deposition treatments may be effected in the reverse order. Alternatively, if it is possible to deposit the processing agents in different positions, a plurality of processing agents may be deposited simultaneously in one step.
  • Tetraoxane can be deposited on knitted goods or woven fabrics in an aqeuous solution but if tetraoxane can be deposited on the given portion of the cloth surface in a desired state, the process is not particularly limited and various depositing processes or printing processes are applicable in relation to the depositing condition or means of the processing agents other than tetraoxane.
  • the processing agents other than tetraoxane are applied directly or in the solution state suitable for each processing agent on knitted goods or woven fabrics.
  • Tetraoxane and the other processing agents in the process of the present invention are fixed so that they occupy at least 20%, preferably at least 40 percent of the surface area of the cloth (the sum of the upper surface and the under surface).
  • tetraoxane When tetraoxane is deposited on the cloth according to the present invention, it is desirable to select the concentration, viscosity or depositing condition of the solution so as not to penetrate to tetraoxane from the applied surface into the opposite surface. Because when a processing agent other than tetraoxane is applied on the opposite surface to the surface applied with tetraoxane, it is difficult to provide the effect of the processing agent satisfactorily on the cloth.
  • Tetraoxane may be applied on the upper surface or the under surface of the cloth or on both the surfaces and the processing agents other than tetraoxane also may be applied on the upper surface or the under surface of the cloth or on both the surfaces and such application is variously determined depending upon the kind of processing agent, the depositing state or the depositing means.
  • tetraoxane when tetraoxane is applied over all of one surface of the cloth, tetraoxane or the other processing agents are partially applied on the other surface.
  • the amount of tetraoxane deposited is 0.05 to 25 percent by weight, preferably 0.5 to 15 percent by weight based on the cloth. Particularly when tetraoxane is partially deposited, even if the amount is small, the effect can be fully developed.
  • the apparatuses for applying tetraoxane and the other processing agent on the cloth include, for example rollers textile printing machines, such as relief printing or intaglio printing machine, textile printing machines, such as manual or automatic screen printing machine or paper printing machines, such as relief printing or intaglio printing machine or a mangle.
  • textile printing machines such as relief printing or intaglio printing machine
  • textile printing machines such as manual or automatic screen printing machine or paper printing machines, such as relief printing or intaglio printing machine or a mangle.
  • the permeability of tetraoxane solution into the cloth varies depending upon the fineness of yarns, density, knitted or woven structure and the like and therefore it is impossible to make a general statement but, for example when the cloth to be treated is a thin base cloth, such as a broad, the roullete number in a roller printing machine is at least 30, a gravure printing machine is at least 100 meshes and a screen printing machine is at least 200 meshes.
  • the processing agents other than tetraoxane have no such a limitation.
  • the amount of tetraoxane deposited on the cloth by these printing machines is considerablyv smaller than the total deposited amount by means of the immersing padding process, and for example is less than half.
  • the property of the cloth material can be optionally modified by means of different processing agents without causing interference and hindrance of processing agents with one another and the cloth providing each effect of the processing agent together can be produced.
  • the cloth can be variously processed by a plurality of processing agents, which have never been heretofore used together because of the mutually opposing and contending function or shielding function and further by using a much smaller amount of processing agent as compared with the conventional means for processing the cloth, substantially the same effect can be attained. Accordingly, the present invention is very excellent as the means for processing cloth.
  • the cloth obtained by the present invention is provided with a plurality of effects of various processing agents, which have never been previously provided together and the cloth has a novel combined plural properties and feeling and the demand field can be widely broadened.
  • the crease resistance is determined by JlSLlO79-22B process
  • the tear strength is determined by Pendulum process
  • the tensile strength is determined by strip process
  • the bending resistance is determined by Clerk process
  • the water repellent property is determined by JISL-l079-5,24,2 spray process.
  • the soil releasing property is determined by measuring the reflection factor of 550 muby a spectrophotometer (made by HITACHI LTD., EPU-2A type), after treated with the test process for oil stain of Japan Oil Chemical Society.
  • the water absorbing property is determined by expressing the time necessary until 0.02 cc of potassium permanganate solution dropped on a center portion of a circle having a diameter of 3 cm made in a sample spread and reaches the periphery, by second.
  • the frictional electrostatic voltage is measured by Rotary static tester (made by KOA SHOKAI) by using a cotton broad cloth of 60 count yarn as a friction member.
  • the compression elasticity is determined as follows:
  • the thickness after the piled four sheets of cloths are subjected to a load of 10 g/cm for one minute is t
  • the thickness after the cloths are further subjected to a load of 300 g/cm for one minute is and the thickness after the said cloths are left to stand under no load for one minute is t Compression degree [(t t,)/: 1 X
  • Oil repellent property AATCC Test Method Iii-i966 T.
  • Wash and wear property The determination was made from 5th class (best) to lst class (worst) according to small crease grade standard photograph of AATCC TEST METHOD 88A.
  • the washing condition is as follows: A sample of 30 cm X 30 cm was washed with 45 times amount of solution containing l g of Zabu (made by KAO SEKKEN I(.K.', anionic detergent, Trade Mark) in l lof waterb y means of an automatic reversing washing machine at 40C for 15 minutes and then washed with water for 15 minutes and taken out from the washing machine and two points in one end were suspended without squeezing and dried at room temperature. This procedure was repeated five times.
  • Zabu made by KAO SEKKEN I(.K.', anionic detergent, Trade Mark
  • Antiflaming property Test method of the Autonomy Agency of Japan, Law, Article 4, Item 3, No. 5 (practiced on April, 1969).
  • Shrink proofing property Treated with AATCC type launder-o-meter at 60 C for 20 minutes?
  • I I Antifusing property Time (second) until a bore is made on a sample cloth by the fusion of the fiber, when an ignited incense having a diameter of 1 mm is put on the cloth.
  • Test method for oil stain One drop of colored paraffin is fallen on a sample cloth and this cloth is immersed in water and the behavior of the oil drop is observed.
  • Test method for aqueous stain One drop of red ink is fallen on a smaple cloth and this is washed and the removal is observed.
  • Test method for redeposition of wet stain A sample cloth having 3 inch and a flannel having the same area, which has been stained in the following manner are washed together in a launder-o-meter and the redeposition of the stain on the sample is observed.
  • whiteness The opposite reflection factor against a standard white sheet (magnesium oxide) at 440 mp. by means of a spectrophotometer.
  • Natural dust collected through a screen having 250 meshes is added to a cloth of cm X 5 cm in an amount of percent by weight based on the cloth and charged in a glass bottle of 500 cc having a cap together with 10 steel balls having a diameter of 10 mm.
  • the glass bottle is rotated at a rate of 45 raolutions per minute and the sample is taken out after 10 minutes and is treated with a tumbler of 45 revolutions per minute for 5 minutes and the excess dust deposited on the sample is removed and then the sample cloth is compared with the standard white sheet (magne sium oxide) with respect to the whiteness.
  • Washing condition 50 times amount of solution containing l g of the above described detergent of Zabu is used and the washing is effected by means of an automatic reversing washing machine at 40C for minutes and then water washing is performed at 40C for 15 minutes. This procedure is repeated several times.
  • Example 1 A crease proofing agent solution having the following composition was applied to a nylon tricot cloth to form longitudinal stripes, each having a width of 2 mm and arranged at 2 mm intervals, as shown in FIG. 1 by means of a gravure roll, and the solvent was removed by means of a drier attached to the gravure roll. Then, a hygroscopic agent solution having the following composition was applied to the cloth to form another stripes as not to double on the two kinds of stripes by means of a roll, and dried, after which the cloth was heat treated at 150C for 3 minutes. The thus obtained cloth had an excellent crease resistance and hygroscopicity as shown in the following Table l.
  • Example 2 An elastic processing agent solution having the following composition was applied to a woven fabric prepared from polyester finished yarns in the form of a spot composed of squares having a dimension of 5 X 5 mm arranged at 3 mm intervals as shown in FIG. 5, and dried in the same manner as described in Example 1. Then, an antistatic agent solution having the following composition was applied to the fabric in the space between the spots after which the cloth was dried and cure d aTl60C for 2 minutes. i
  • the thus obtained cloth had an excellent elastic property and antistatic property as shown in the following Table 2.
  • Organosiloxane diol having a polymerization degree of 800 2 parts Catalyst PC (made by Shinetsu Kagaku K.K.) 0.02 part Catalyst PD (made by Shinetsu Kagaku K.K.) 0.02 part Perchlene 100 parts TABLE 2 Compression Frictional elasticity charge Compression Elasti- (V) degree city Not treated l0,000 21.9 85.2 Present invention 1,000 23.5 94.0 Conventional method 4,100 22.9 89.8
  • Example 3 A stain proofing agent solution having the following composition was applied to a cotton/polyester blended yarn fabric in the form of a spot as shown in FIG. 3, and dried. Then a soil releasing agent (SR agent) having the following composition was further applied to the fabric in the form of a spot composed of circles, each having a diameter of 1 mm, by means of a printing roll, and dried at 100C for 45 seconds, after which the fabric was heat treated at 160C for 2 minutes.
  • SR agent soil releasing agent
  • the thus obtained cloth had an excellent resistance against both oily stain and aqueous stain as shown in the following Table 3.
  • Stain proofing agent solution Scotch guard FC-3 l0
  • a softener solution having the following composition was applied to a polyethylene film so as to form longitudinal stripes, each having a width of 2 mm and arranged at 1 mm intervals as shown in FIG. 1 by means of a gravure roll, and dried. Then-an antistatic agent solution having the following composition was further applied to spaces between the above obtained stripes of the softener by means of the same roll, and dried at 160C for 2 minutes.
  • the thus obtained film had an excellent softness and antistatic property as shown in the following Table 4.
  • a crease proofing agent solution having the following composition was applied to the portion 1 of the surface of a scoured and dyed tricot knitted from polyester f n ished yarns as shown in FIG. 5 by means a gravure roll, and dried by means of a drier attached to the roll. Then, an antistatic agent solution having the following composition was further applied to the portion 2 of the tricot surface so as not to double on the two port-ions l and 2, and dried by the drier. Then, a stain proofing agent solution having the following composition was further applied to the portion 3 of the tricot surface, and dried by the drier. The treated tricot cloth was heat treated at lC for 2 minutes.
  • the thus obtained cloth contained the above described crease proofing agent, antistatic agent and stain proofing agent in amounts of 0.4 percent, 2.0 percent and 3.2 percent as a solid component respectively, and had an excellent crease resistance, antistatic property and stain proofing property as shown in the following Table 5.
  • Control 2 The above described crease proofing agent was diluted with trichlene and adhered to the tricot in an amount of 0.4 percent by padding.
  • Example 6 A printing bath was made from parts of an emulsion composed of 47 percent of Kerosene, 51 percent of water and 2 percent of polyethylene glycol oleyl ether (H.L.B: 14), 20 parts of ethylene glycol diglycidyl ether and 5 parts of 25 percent aqueous solution of magnesium borofluoride.
  • This printing bath was printed only on one surface of a scoured and bleached broad cloth composed of cotton yarns of 40 counts by means of a gravure roll engraved a pattern of 150 meshes on its entire surface. After the printed cloth was dried by a drier attached to the gravure roll, a dispersion having the following composition was printed on the other surface of the cloth by means of the above described gravure roll.
  • This dispersion was composed of 92.5 parts of the above described emulsion, 5 parts of 50 percent emulsion of an emulsion copolymer (polymerization degree: 300) prepared from vinyl acetate and maleic acid anhydride in a mixing ratio of 1:1 2 parts of ethylene glycol diglycidyl ether and 05 part of 50 percent aqueous solution of zinc borofluoride.
  • a conventional padding method is shown.
  • the above described broad cloth was immersed in an aqueous solution composed of 3 parts of the above described vinyl acetate/maleic acid anhydride copolymer, [.2 parts of ethylene glycol diglycidyl ether, 0.3 part of 50 percent aqueous solution of zinc borofluoride and 95.5 parts of water, and the solution was squeezed to 60 percent based on the weight of the cloth by means of a padder.
  • the cloth was further immersed in an aqueous solution composed of 12 parts of ethylene glycol diglycidyl ether, 3 parts of 50 percent aqueous solution of magnesium borofluoride and parts of water, and the solution was squeezed to 60 percent based on the weight of the Cloth.
  • the resulting cloth was dried and heat treated in a dry state at C for 3 minutes.
  • Example 7 A printing bath was prepared from 77 parts of the emulsion described in Example 6, 18 parts of 1,4- butane diol diglycidyl ether and 5 parts of 25 percent aqueous solution of magnesium borofluoride. This printing bath was printed only on upper surface of a scoured and bleached gaberdine cloth composed of polyester/cotton blended yarns (mix spinning ratio: 65:35) of 45 counts by means of a gravure roll engraved a pattern of 150 meshes on its entire surface. After the printed cloth was dried by means by a drier attached to the gravure roll, a dispersion having the following composition was printed to the under surface of the cloth by means of a gravure roll engraved a pattern of 180 meshes on its entire surface.
  • This dispersion was composed of 88 parts of the above described emulsion, 10 parts of stearoylmethylamide-methylenepyridinium chloride and 2 parts of sodium acetate.
  • the treated cloth both surfaces of which were effected with different printings, was dried and heat treated in a dry state at 150C for 3 minutes.
  • the above procedure is the present invention.
  • a treating bath was produced from 10 parts of 1,4-butane diol diglycidyl ether, 3 parts of 50 percent aqueous solution of magnesium borofluoride and 82 parts of water.
  • the above'described gaberdine cloth was immersed in the bath and the liquid was squeezed to 60 percent based on the weight of the cloth.
  • the cloth was immersed in a treating solution composed of 6 parts of stearoylmethylamidemethylenepyridinium chloride, 1.5 parts of sodium acetate and 92.5 parts of water, and the solution was squeezed to 60 percent based on the weight of the cloth. Then, the cloth was dried and heat treated in a dry state at 150C for 3 minutes;
  • the under surface has water absorbing property, but the upper surface has water repelling property. Further, the cloth has an excellent wash wear resistance and a unique cloth.
  • Example 8' A printing bath was prepared from 75 parts of the emulsion described in Example 6, 20 parts of diglycerol dibutyl ether and 5 parts of 50 percent aqueous so1ution of zinc borofluoride. This printing bath was printed on the same gabardine cloth as used in Example 7 to form a longitudinal stripe by means of a gravure roll having engraved portions of 1 mm width (150 meshes) and non-engraved portions of 1 mm width, and dried by means of a drier attached to gravure roll.
  • Example 9 A printing bath was prepared from parts the emulsion as described in Example 6, 20 parts of propylene glycol diglycidyl ether and 5 parts of 25 percent aqueous solution of zinc borofluoride. This printing bath was printed on the upper surface of a broad cloth composed of 40 count yarns by means of a gravure roll hav ing a spotted pattern wherein 100 circles having a diameter of 1 mm were spotted per 400 cm". After the printed cloth was dried by means of a roller attached to the gravure roll, a solution composed of 85 parts of the above described emulsion, and 15 parts of aniline salt of hydroxymethanephosphonic acid was printed on the under surface of the printed cloth by means of a gravure roll engraved a pattern of meshes on the entire surface. Then the cloth was dried and heat treated in a dry state at C for 2 minutes. This procedure is the present invention.
  • a conventional padding method is shown.
  • the above described broad cloth was immersed in an aqueous solution composed of 12 parts of propylene glycol diglycidyl ether, 3.5 parts of 25 percent aqueous solution of zinc borofluoride and 84.5 parts of water, and the solution was squeezed to 60 percent based on the weight of the cloth by means of a padder.
  • the cloth was dried and heat treated in a dry state at 150C for 2 minutes. Then, the cloth was further immersed in 9 percent aqueous solution of aniline salt of hydroxymethanephosphonic acid, and the solution was squeezed to 60 percent based on the weight of the cloth by means of a padder and dried.
  • Example 10 A first printing bath was prepared from 2 parts of [3-(acryloxyethyl)-diethylmethylammonium metasulfate (polymerization degree: 200), 10 parts of water, 1.5 parts of lauryl sulfate and 86.5 parts of the emulsion described in Example6. This printing bath was printed on one surface of a scoured and bleached polyester/- cotton mix spun tasah cloth (mix spinning ratio: 65:35) by means of a first gravure roll having a transverse stripe composed of engraved portions of 0.5 mm Width and non-engraved portions of 0.7 mm width and dried by means of an attached drier.
  • a second printing bath composed of 20 parts of diethylene glycol, 5 parts of 2.5 percent aqueous solution of magnesium borofluoride and 75 parts of the above described emulsion was printed on the same surface as described above of the cloth by means of a second gravure roll having a transverse stripe composed of engraved portions of 0.5 mm width and non-engraved portions of 0.7 mm width so as not to double on the two stripes, and dried by means of an attached roll.
  • a third printing bath composed of parts of stearoylmethylamidemethylenepyridiniurn chloride, 2 parts of sodium acetate and 88 parts of the above described emulsion was printed on the other surface of the above treated cloth, on which the first and second printing baths were not printed, by means of a third printing gravure roll engraved a pattern of 150 meshes on the entire surface, and dried by means of an attached drier. Then, the thus treated cloth was heat treated in a dry state at 150C for 3 minutes. The thus obtained cloth, which was treated with three processing agents of the antistatic agent, the crease proofing agent and the water repelling agent simultaneously, developed no static electricity, and had a crease resistance. Further, one surface of the cloth had water absorbing property, but the other surface had water repelling property. Consequently, this cloth was a unique finished cloth.
  • Example 1 1 An antistatic agent solution having the following composition was applied to the upper surface of a scoured and dyed tricot composed of 40 denier nylon yarns to form longitudinal stripes, each stripe having a width of 1 mm and arranged at 1' mm intervals, as shown in P10. 1 by means of a gravure roll, and dried by means of an attached drier. Then, a crease proofing agent solution having the following composition was applied to the same surface in the form of a stripe so as not to double on the former and latter stripes and not to penetrate to the under surface, and dried by an attached drier. Further, a water absorbing agent solution having the following composition was applied to the entire under surface of the cloth, and dried. The thus treated cloth was heat treated at 130C for 3 minutes.
  • the thus obtained cloth contained the above described antistatic agent, crease proofing and water absorbing agent in amounts of 0.8 percent, 0.4 percent and 0.5 percent as a solid component respectively, and had an excellent antistatic property, crease resistance and water absorbing property as shown in the following Table 10.
  • Control 1 z The above described antistatic agent was diluted with water and adhered to the cloth in an amount of 0.8 percent as a solid component by padding.
  • Control 2 The above described crease proofing agent was diluted with water and adhered to the cloth in an amount of 0.4 percent as a solid component by padding.
  • Control 3 The above described water absorbing agent was diluted with water and adhered to the cloth in an amount of 0.5 percent as a solid component by padding.
  • Example 12 An antistatic agent solution having the following composition was applied to the upper surface of a scoured polyester tricot in the form of longitudinal stripes, each having a width of 10 mm arranged at 1 mm intervals as shown in FIG. 1, by means a gravure roll, and dried by means of an attached drier. A stain proofing agent solution having the following composition was applied to the entire under surface of the treated cloth and dried by means of an attached drier. Then the treated tricot was heat treated at 150C for 1 minutes. The thus obtained cloth contained the antistatic agent and the stain proofing agent in amounts of 1.0 percent and 4.2 percent as a solid component, respectively, and had an excellent antistatic property and stain proofing property as shown in the following Table 11.
  • Scotch guard FC-2l8 (made by Surnitomo-3M K.K.) 25 parts Acetone 100 parts TABLE 1 l Frictional Oil repelling charge property (g Not treated 8500 0 Present 100 6 invention Control 1 0 Control 2 1000 7 Note: Control 1: The above described antistatic agent was diluted with water and adhered to the cloth in an amount of 1.0 percent as a solid component by padding. 7
  • Control 2 The above described stain proofing agent was diluted with water and adhered to the cloth in an amount of 4.0 percent as a solid component by padding.
  • Example 13 An antiflaming agent solution (A) having the following composition was applied to the upper surface of a lace stitched certain cloth prepared from a fluorescently whitened ground weave of polyethylene terephthalate filaments and a pattern of rayon filaments in the form of spots as shown in FIG. 2 by means of a gravure roll, and dried by means of an attached drier. Then, an ultraviolet absorbing agent solution having the following composition was further applied to the upper surface so as not to double on the two agents, and dried by means of an attached drier. Further, antiflaming agent solution (B) having the following composition was applied to the entire under surface of the cloth, and dried by means of an attached drier. The resulting cloth was heat treated at 120C for 5 minutes.
  • the thus obtained cloth contained the above described antiflaming agent (A), antiflaming agent (B) and ultraviolet absorbing agent in amounts of 4.1 percent, 2.1 percent and 0.1 percent as a solid component respectively, and had an excellent flame resistance and light resistance as shown in the following Table 12.
  • Antiflaming agent solution (A) Tris-2,3-dibrornopropyl Note: Control 1: The above described antiflaming agent (A) was diluted with perchlene and adhered to the cloth in an amount of 4.2 percent as a solid component by padding.
  • Control 2 The above described ultraviolet absorbing agent was diluted with acetone and adhered to the cloth in an amount of 0.1 percent as a solid component by padding.
  • Example 14 An antifusing agent solution having the following composition was applied to the entire upper surface of a broad cloth composed of blended yarns of 65 percent of polyester and 35 percent of cotton in the form of spots by means of an gravure roll, and dried by means of an attached drier. Then, a softening agent solution having the following composition was applied to the surface in the form of spots so as not to double on the two agents, and dried by an attached drier. The resulting cloth was heat treated at 150C for 2 minutes.
  • the thus obtained cloth contained the above described antifusing agent and softening agent in amounts of 7.0 percent and 3.2 percent as a solid component respectively, and had an excellent fuse resistance and softness as shown in the following Table 13.
  • Example 15 An antipilling agent solution having the following composition was applied to the upper surface of a scoured and dyed ester/rayon staple mix spun serge in the form of stripes having a 1.5 mm width at 1.5 mm intervals as shown in FIG. 1 by means of a gravure roll, and dried by means of an attached drier. Then, a softening agent solution having the following composition was applied to the surface so as not to double on the two agents, and dried by means of an attached drier. The resulting cloth was heat treated at C for 5 minutes.
  • the thus obtained cloth contained the above described antipilling agent and softening agent in amounts of 2.5 percent and 2.0 percent as a solid component respectively, and had an excellent anitpilling property and softening as shown in the following Table 14.
  • Polyurethane prepolymer (average molecular weight 18,000; NCO content 1.8%) prepared from 6 moles of polypropylene ether glycol (M.W. 2,000), 12 moles of tolylene diisocyanate, and
  • Control 1 The above described antipilling agent was diluted with water and adhered to the cloth in an amount of 2.5 percent as a solid component by padding.
  • Control 2 The above described softening agent was diluted with water and adhered to the cloth in an amount of 2.0 percent as a solid component by padding.
  • Example 16 A moth proofing agent solution having the following composition was applied to the entire upper surface of a scoured and dyed serge made of worsted yarns in the form of spots by means of a gravure roll, and dried by means of an attached drier. Then, a shrinkproofing agent having the following composition was applied to the entire under surface, and dried by means of an at- (1) Moth proofing agent solution:
  • the thus obtained cloth contained the above described antipilling agent and stain proofing agent in amounts of 2.5 percent and 4.0 percent as a solid component respectively, and had an excellent antipilling property and stain proofing property as shown in the following Table 16.
  • Polyurethane prepolymer (average molecular weight 20,000; NCO content 1.7. 96) prepared from 6 moles of polypropylene ether 3 PHMM- 892 l molea of hexamethylbne diisocyanate, and
  • Control I The above described antipilling agent was diluted with trichloroethylene and adhered to the cloth in an amount of 2.5 percent as a solid component by padding.
  • Control 2 The above described stain proofing agent was diluted with perchloroethylene and adhered to the cloth in an amount of 4.0 percent as a solid component by padding.
  • Example 18 A stain proofing agent solution having the following composition was applied to the entire upper surface of a scoured and dyed denier nylon taffeta so as not to penetrate to the under surface by means of a gravure roll, and dried by means of an attached drier. An antiflaming agent solution having the following composition was further applied to the entire under surface of the tafieta, and dried by means of an attached drier. Then, the treated taffeta was heat treatedat l50C for 1 minute.
  • the thus obtained cloth contained the above described stain proofing agent and antiflaming agent in amounts of 3.0 percent and 4.0 percent as a solid component respectively, and had an excellent stain proofing property and flame resistance as shown in the following Table 17.
  • Control 2 Only the above described anti-flaming agent was printed and adhered to the cloth in an amount of 4.0 percent as a solid component.
  • Example 19 An antiflaming agent solution having the following composition was applied to the entire under surface of a scoured and dyed twill curtain fabric composed lOO percent nylon by means of a gravure roll, and dried by means of an attached drier. An ultraviolet absorbing agent solution having the following composition was further applied to the entire upper surface of the fabric, and dried by means of an attached drier. The thus treated curtain fabric was heat treated at C for 7 m u es The thus obtained cloth contained the above described antiflaming agent and ultraviolet absorbing agent in amounts of 5.2 percent and 0.1 percent as a solid component respectively, and had an excellent flame resistance and light resistance as shown in the following Table 18.
  • Tetraquis-hydroxydimethylphosphonium chloride 25 parts Ethanol 100 parts
  • Ultraviolet absorbing agent solution 2,2,4,4'-tetrahydroxybenzophenone 0.5 part
  • Methanol 100 parts TABLE 18 Flame resistance Light (vertical test) resistance remained carbonized grade fire(sec.) length (in.) Not treated completely I burned Present 0 4.2 3 invention Control 1 0 3.6 l
  • Example 20 A water repelling agent solution having the following composition was applied to. the entire under surface of a scoured and dyed woven fabric composed of polyester finished yarns by means of an gravure roll, and dried by means of an attached drier. Then an antifusing agent solution having the following composition was applied to the entire upper surface of the woven fabric, and dried by means of an attached drier. The thus treated fabric was heat treated at 150C for 2 minutes.
  • the thus obtained cloth contained the above described water repelling agent and antifusing agent in amounts of 3.0 percent and 5.8 percent as a solid component respectively, and had an excellent water repelling property and fuse resistance as shown in the following Table 19.
  • Water repelling agent solution :
  • Methyl-hydrogempolysiloxane (viscosity 100 centistokes) 10 parts Perchloroethylene 90 parts (2) Antifusing agent solution:
  • Methyl-hydrogen-polysiloxane diol (polymerization degree 1,500) 90 parts Dibutyltin dioctoate 0.9 part Perchloroethylene 30 parts Butylated melamine 10 parts TABLE 19 Water repell- Fuse ing property resistance (sec.) Not treated Present invention 100 32 Control 1 100 Control 2 80 27 Note: Control 1: The above described water repelling agent was diluted with perchlene and adheredto the cloth in an amount of 3.0 percent as a solid component by padding.
  • Control 2 The above described antifusing agent was diluted with perchlene and adhered to the cloth in an amount of 5.8 percent as a solid component by padding.
  • Scourol 400 made by Kao Sekken K.l(.,non-ionic surfactant
  • an soil releasing agent solution composed of 3 parts of Serogen 7 (made by Daiichi Kogyo K.K.) 1 part of polyethylene glycol diglycidyl ether (polymerization degree of polyethylene glycol: 400), 0.2 part of zinc borofluoride and 96 parts of water was further printed on the other surface of the broad by means of the same roll, and dried.
  • the printed broad was heat treated in a dry state at 150C for 3 minutes.
  • the thus treated cloth had a crease resistance and a soil releasing property, and further a soft texture as shown in the following Table 20.
  • the thus obtained cloth had a crease resistance and an antistatic property as shown in the following Table 21.
  • Example 23 A solution of 15 parts of tetraoxane and 4 parts of 50 percent aqueous solution of zinc borofluoride dissolved in dimethylformamide was printed on a woolen tropical suiting by means of a gravure roll engraved a pattern of 200 meshes on its entire surface. After dried, the
  • the thus treated wool was excellent in the wash and wear property as shown in the following Table 22.
  • composition of the first bath and pattern of the first roll i. Composition of the first bath and pattern of the first roll:
  • the first bath is the same as the tetraoxane dispersion in Example 22.
  • the first roll has a transverse linear stripe pattern having engraved portions of v 0.5 mm without mesh and non-engraved portions of 0.5 mm width.
  • composition of the second bath and pattern of the second roll ii. Composition of the second bath and pattern of the second roll:
  • the second bath is a emulsion having the following composition, wherein Permalose T is used as a water absorbing agent.
  • the second roll has a longitudinal stripe pattern having engraved portions of 1 mm width, each engraved portion being patterned to 120 meshes, and non-engraved portions of 1 mm width.
  • composition of the third bath and the pattern of the third roll :
  • the third bath is a dispersion having the following composition, wherein vinyl acetate/maleic acid anhydride copolymer is used as a soil releasing Namely, the above described polyester/cotton mix spun broad was printed on its upper surface by using the first bath and roll and the second bath and roll, and was printed on its under surface by using the third bath and roll, after which the printed broad was heat treated in a dry state at 150C for 3 minutes. The obtained result is shown in the following Table 23.
  • the thus obtained cloth had an excellent crease resistance, water absorbing property and soil releasing property.
  • a crease proofing agent solution having the following composition was applied to the entire upper surface of a cotton twill fabric cloth (count: warp 36/2 weft 24/2 density: warp l 1 1.5/inch, weft 57/inch; 264.4g/m so as not to penetrate to the under surface by means of an intaglio roll, and dried at 80C. Then,
  • a catalyst solution having the following composition was further applied to the under surface of the cloth by means of the above described roll, and dried.
  • the cloth was heat treated at 150C for 3 minutes, washed with a bath composed 1 g of Scourol 400 (made by Kao Sci:-
  • the thus obtained cloth contained the creasing proofing agent resin in an amount of 3.2 as a solid component, which was set only in the middle layer of the cloth, and had an excellent crease resistance, wash and wear property,
  • Zinc nitrate 8 parts The third roll in engraved to 150 meshes on its en- 22:? Emmy 3O pans tire surface. Water 62 parts Crease Crease resistance Tensile Tear whiteness resistance (percent) Wash strength strength after water (percent) (after washing) and (K8) (9 Washing absorbwear ing prop- Upper Under prop- Dry Wet Dry Wet erty Warp Weft Warp Weft surface surface erty Not treated 51 45 52 45 1 101 42 2,400 2,950 115 115 7 Present invention.
  • Control l-A cloth was treated with a processing soiution containing both of the above described crease proofing agent and catalyst so as to obtain pick up by padding method. dried and heat treated, whereby 3.2% of solid resin was applied to the cloth.
  • Control 2 A processing solution containing both of the above described crease proofing agent and catalyst was applied to the upper surface of a cloth, and 3.2% of solid resin was set to the upper surface layer and the middle layer of the cloth.
  • Example 26 A crease proofing agent solution having the following composition was applied to the entire upper surface of a mix spun broad cloth (count: warp 45 weft 45 density: warp l41/inch, weft 73/inch; 122.9 g/m composed of 65 percent of polyethylene terephthalate and 35 percent of cotton so as to penetrate as far as the middle layer of the cloth by means of an intaglio roll, and dried at 80C for 7 minutes.
  • a catalyst solution having the following composition was applied to the under surface of the cloth by means of the same roll, and dried.
  • the cloth was further heat treated at 140C for minutes, washed with a bath composed of 1 g of Emal NC (made by Kao Sekken K.l(.; anionic surfactant), 1 g of soda ash and 1 l of water at 50C for l minute, and dried.
  • Emal NC made by Kao Sekken K.l(.; anionic surfactant
  • soda ash made by Kao Sekken K.l(.; anionic surfactant
  • 1 g of soda ash made by Kao Sekken K.l(.; anionic surfactant
  • the thus obtained cloth contained the crease proofing agent resin in an amount of 3.0 percent as a solid component, which was set only in the middle layer, and had an excellent crease resistance, wash and wear property, abrasion resistance, tensile strength and tear strength, and further had substantially the same water absorbing property as that of the untreated cloth. Even when the cloth was washed repeatedly, there was no difference between the both surfaces in the whiteness.
  • Example 27 10 having the following composition was further applied to the under surface of the cloth so as to penetrate as far as the middle layer by means of a roll having a pattern of longitudinal lines, and dried.
  • the cloth was heat treated at 160C for 2 minutes, washed with a bath composed of 2 g of Scourol 100 (made by Kao Sekken K.l(.; non-ionic surfactant) and 1 lot water at 70C for 15 seconds, and dried.
  • the thus obtained cloth contained the crease proofing agent resin in an amount of 3.2 percent as a solid 2 component, which was set in a pattern of lines in the middle layer of the cloth, and had an excellent crease resistance, wash and wear property, abrasion resistance, tensile strength and tear strength, and further had substantially the same excellent water absorbing property as that of untreated cloth. Even when the cloth was washed repeatedly, there was no difference between the both surfaces of the cloth in the whiteness. The obtained result is shown in Table 26.
  • Catalyst solution (1) Crease proofing agent solution: Magnesium chloride 1.2 parts lmidazolidone resin Kerosene viscosity increasing (trade mark: Permafresh D.C.) 30 parts agent 30 parts 1% aqueous solution of hydroxy- Water 69 parts ethyl-cellulose (trade mark: (2) Crease proofing agent solution: cellosize QP 15.000) 90 pans Dimethylolethyl carbamate 20 parts (2) Catalyst solution: Kerosene viscosity increasing Zinc nitrate catalyst (trade mark: Catalyst F) 2 parts agent parts 0.3% aqueous solution of Bicron K 43 (softener 2 parts hydroxyethyl-cellulose 98 parts V W ater i W W WV 20 parts TABLE 25 Crease resistance Crease (percent) Wash Abrasion at Abrasion at Tensile Tear Water Whiteness after resistance (after and plane fold strength strength absorbwashing (percent) washing) wear (kg) (8 ⁇ ing prop- Upper Under
  • Control l-A cloth was treated with a processing solution containing both of the above described crease proofing agent and catalyst so as to obtain 60% pick up by padding method, dried and heat treated, whereby 3.0% of solid resin was applied to the cloth.
  • Control 2-A processing solution containing both of the above crease proofing agent and catalyst was applied to the upper surface of a cloth, and 3.0% of solid resin was set to the upper surface layer and the middle layer of thecloth.
  • Control 1- A cloth was treated with a processing solution containing both of the above described catalyst and crease proofing agent so as to obtain 60% pick up by padding method, dried and heat treated, whereby 3.2% of solid resin was applied to the cloth.
  • (l) Crease proofing agent solution E l 30 Dimethyl-polysiloxane diol 2.5 parts d' th th is! l l ZJ IZLZdQZEZ g -$25 0, 3 pm
  • An antistatic agent solution composed of 20 g of a Trichlene P 30 cationic antistatic agent prepared by copolymeri'zation I y of 3 parts of 2-methacryloyloxyethyl-trimethyiammoni- Viscosity of this solution is 110 centistokes.
  • Control 1 -A cloth was treated with a processing solution containing both of the above described crease proofing agent and catalyst so as to obtain 130% pick up by padding method, dried and heat treated, whereby 2.8% of solid resin was applied to the cloth.
  • Control 2-A processing solution containing both of the above described crease proofing agent and catalyst was applied to the upper surface of a cloth. and 2.8% of solid resin was set to the upper surface layer and the middle layer of the cloth.
  • Example 29 50 texture which was prepared from polyester false twist I R 0 yarns of l00d/32f/2p, and dried at 100C. Then, an an- An antistatic agent solution prepared from 15 parts tipilling agent composed of 10 parts of a prepolymer of a cationic antistatic agent of a polymer, which was prepared from 1 mole of polypropylene ether glycol a polymerization product of quaternary ammonium salt (molecular weight: 2,000), 2 moles of tolylene diisocyof diethylarninoethyl methacrylate with dimethyl sul- 55 anate and 1.6 mole of polypropylene ether triol (mofate, and parts of 45 percent aqueous solution of lecular weight 4,000) and parts of xylene as a solhydroxyethyl-cellulose was applied to one surface of a vent was further applied to the upper surface of thescoured and dyed cloth of nylon jersey knitted from nycloth, and the cloth was heat treated at
  • the thus obtained cloth contained the above deiution composed of 2 g of a reaction product, which scribed antistatic agent and antipilling agent in was obtained by reacting 31 g of ethylene oxide with 60 amounts of 1 percent and 1 .2 percent as a solid compog of dimer or trimer of caprolactam, and l g of water nent respectively, and both the processing agents did was further applied to the other surface of the cloth, not penetrate from the applied surface to the other surafter'which the cloth was heat treated at 130C for 5 65 face of the cloth. minutes.
  • the cloth had an excellent antipilling property and
  • the thus obtained cloth contained the above deantistatic property as shown in Table 29.

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Cited By (40)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4806410A (en) * 1986-09-18 1989-02-21 Ranpak Corp. Processes for the production of antistatic or static dissipative paper, and the paper products thus produced, and apparatus utilized
US5198287A (en) * 1991-04-01 1993-03-30 Graniteville Company Insect repellent tent fabric
US5252387A (en) * 1991-04-01 1993-10-12 Graniteville Company Fabrics with insect repellent and a barrier
WO1995017091A1 (en) * 1993-12-23 1995-06-29 Tucci Associates, Inc. Slow-release insect-repellent formulations and uses
US5654073A (en) * 1991-11-13 1997-08-05 Hunter Douglas Inc. Treated fabric panel
EP0794280A2 (en) * 1996-02-09 1997-09-10 J.W. Suominen Oy Finishing treatment method for nonwoven, a nonwoven fabric treated according to the method and a product containing the nonwoven fabric
US5871816A (en) * 1996-08-09 1999-02-16 Mtc Ltd. Metallized textile
US5922625A (en) * 1993-06-25 1999-07-13 Canon Kabushiki Kaisha Print medium for use in ink jet printing method
US5981066A (en) * 1996-08-09 1999-11-09 Mtc Ltd. Applications of metallized textile
US5985301A (en) * 1997-09-30 1999-11-16 Kenji Nakamura Antibacterial cellulose fiber and production process thereof
US6015570A (en) * 1993-12-23 2000-01-18 Tucci Associates, Inc. Slow-release insect-repellent compositions and uses
US6210516B1 (en) 1994-02-18 2001-04-03 Ronald Sinclair Nohr Process of enhanced chemical bonding by electron seam radiation
US6217707B1 (en) 1996-12-31 2001-04-17 Kimberly-Clark Worldwide, Inc. Controlled coverage additive application
US6231719B1 (en) 1996-12-31 2001-05-15 Kimberly-Clark Worldwide, Inc. Uncreped throughdried tissue with controlled coverage additive
WO2001050859A1 (en) * 2000-01-10 2001-07-19 Tucci & Associates, Inc. Slow-release insect-repellent composition and uses
US6489395B2 (en) * 1999-12-08 2002-12-03 Clariant Gmbh Emulsions
US20030026833A1 (en) * 2001-07-10 2003-02-06 Payne Stephen A. Synergistic antimicrobial textile finish
US6613821B2 (en) * 1998-10-09 2003-09-02 Canon Kabushiki Kaisha Cloth treating agent, cloth, textile printing process and print
US20030199018A1 (en) * 2002-04-18 2003-10-23 The Cupron Corporation Method and device for inactivating HIV
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US20040010857A1 (en) * 2001-01-26 2004-01-22 Shigeru Nakashima High-whiteness hygroscopic fiber and process for its production
US20040167484A1 (en) * 2003-02-21 2004-08-26 The Cupron Corporation Disposable feminine hygiene products
US6787184B2 (en) 2001-06-16 2004-09-07 Kimberly-Clark Worldwide, Inc. Treated nonwoven fabrics
US20040197386A1 (en) * 2003-04-01 2004-10-07 The Cupron Corporation Disposable paper-based hospital and operating theater products
US20040224005A1 (en) * 2000-04-05 2004-11-11 The Cupron Corporation Antimicrobial and antiviral polymeric materials
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WO2007119137A2 (en) * 2006-04-14 2007-10-25 In.Pro.Di.-Inghirami Produzione Distribuzione S.P.A. Process for processing fabrics
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US20100014705A1 (en) * 2003-11-19 2010-01-21 Gustafson Ammon E Optimized Digital Watermarking Functions for Streaming Data
US20100132245A1 (en) * 2007-06-29 2010-06-03 Mikkel Vestergaard Frandsen Insecticidal barrier partly with synergist
US20110183852A1 (en) * 1999-05-26 2011-07-28 Rhodia Inc. Block polymers, compositions and methods for use for foams, laundry detergents, and shower rinses and coagulants
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Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CH643779A5 (de) * 1978-01-27 1984-06-29 Herbert Glatt Gewebekonditionierkoerper und verfahren zur herstellung eines gewebekonditionierkoerpers.
DE3241820C2 (de) * 1982-11-11 1994-04-21 Bluecher Hubert Flammwidrig ausgerüstetes, flexibles Textilmaterial oder dergleichen
US5846604A (en) * 1988-03-14 1998-12-08 Nextec Applications, Inc. Controlling the porosity and permeation of a web
EP0436463A1 (en) * 1989-11-24 1991-07-10 Sicpa Holding S.A. Auxiliary support and process for the finishing of textile fabrics by heat transfer
FR2664303A1 (fr) * 1990-07-06 1992-01-10 Finet Alain Composition hydrophobe et procede de fabrication de motifs hydrofuges sur un tissu au moyen de ladite composition.
FI106696B (fi) * 1995-06-14 2001-03-30 Suominen Oy J W Menetelmä kuitukankaan nesteenkuljetuskyvyn suuntaamiseksi, tämän menetelmän mukaisesti käsitelty kangas, sekä kangasta sisältävä tuote

Citations (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2911756A (en) * 1955-12-08 1959-11-10 Robert J Geary Insect combatting device
US3127281A (en) * 1964-03-31 Means and method of making multi-test indicator
US3293066A (en) * 1962-12-19 1966-12-20 Ibm High speed antistatic magnetic member
US3336153A (en) * 1963-05-22 1967-08-15 Prototech Inc Fire-retardant tape utilizing an intumescent coating
US3347362A (en) * 1964-09-28 1967-10-17 Minnesota Mining & Mfg Pressure sensitive adhesive tapes with anti-static edge coatings
US3357849A (en) * 1963-05-01 1967-12-12 J F Scholten En Zonen N V Selectively finished textile web
US3437508A (en) * 1967-08-23 1969-04-08 Owens Corning Fiberglass Corp Structural panel and method of production
US3521638A (en) * 1969-02-10 1970-07-28 Du Pont Fabrics having water soluble discrete areas and methods of making
US3553005A (en) * 1968-01-25 1971-01-05 Edward L Moragne Method for producing a plastic impregnated article
US3615745A (en) * 1969-03-10 1971-10-26 Abbott Lab Antimicrobial coatings and method using diiodomethyl sulfones
US3617188A (en) * 1968-11-26 1971-11-02 Crompton Shenandoah Co Soil release fabrics and method for producing same
US3620797A (en) * 1969-01-14 1971-11-16 Dhj Ind Inc Impregnation of a nonwoven fabric

Patent Citations (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3127281A (en) * 1964-03-31 Means and method of making multi-test indicator
US2911756A (en) * 1955-12-08 1959-11-10 Robert J Geary Insect combatting device
US3293066A (en) * 1962-12-19 1966-12-20 Ibm High speed antistatic magnetic member
US3357849A (en) * 1963-05-01 1967-12-12 J F Scholten En Zonen N V Selectively finished textile web
US3336153A (en) * 1963-05-22 1967-08-15 Prototech Inc Fire-retardant tape utilizing an intumescent coating
US3347362A (en) * 1964-09-28 1967-10-17 Minnesota Mining & Mfg Pressure sensitive adhesive tapes with anti-static edge coatings
US3437508A (en) * 1967-08-23 1969-04-08 Owens Corning Fiberglass Corp Structural panel and method of production
US3553005A (en) * 1968-01-25 1971-01-05 Edward L Moragne Method for producing a plastic impregnated article
US3617188A (en) * 1968-11-26 1971-11-02 Crompton Shenandoah Co Soil release fabrics and method for producing same
US3620797A (en) * 1969-01-14 1971-11-16 Dhj Ind Inc Impregnation of a nonwoven fabric
US3521638A (en) * 1969-02-10 1970-07-28 Du Pont Fabrics having water soluble discrete areas and methods of making
US3615745A (en) * 1969-03-10 1971-10-26 Abbott Lab Antimicrobial coatings and method using diiodomethyl sulfones

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4806410A (en) * 1986-09-18 1989-02-21 Ranpak Corp. Processes for the production of antistatic or static dissipative paper, and the paper products thus produced, and apparatus utilized
US5198287A (en) * 1991-04-01 1993-03-30 Graniteville Company Insect repellent tent fabric
US5252387A (en) * 1991-04-01 1993-10-12 Graniteville Company Fabrics with insect repellent and a barrier
US5654073A (en) * 1991-11-13 1997-08-05 Hunter Douglas Inc. Treated fabric panel
US5690778A (en) * 1991-11-13 1997-11-25 Hunter Douglas Inc. Method of fabricating honeycomb panel for window covering
US5691031A (en) * 1991-11-13 1997-11-25 Hunter Douglas Inc. Cellular panel
US5922625A (en) * 1993-06-25 1999-07-13 Canon Kabushiki Kaisha Print medium for use in ink jet printing method
WO1995017091A1 (en) * 1993-12-23 1995-06-29 Tucci Associates, Inc. Slow-release insect-repellent formulations and uses
US6015570A (en) * 1993-12-23 2000-01-18 Tucci Associates, Inc. Slow-release insect-repellent compositions and uses
US6210516B1 (en) 1994-02-18 2001-04-03 Ronald Sinclair Nohr Process of enhanced chemical bonding by electron seam radiation
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EP0794280A2 (en) * 1996-02-09 1997-09-10 J.W. Suominen Oy Finishing treatment method for nonwoven, a nonwoven fabric treated according to the method and a product containing the nonwoven fabric
US5981066A (en) * 1996-08-09 1999-11-09 Mtc Ltd. Applications of metallized textile
US5871816A (en) * 1996-08-09 1999-02-16 Mtc Ltd. Metallized textile
US6217707B1 (en) 1996-12-31 2001-04-17 Kimberly-Clark Worldwide, Inc. Controlled coverage additive application
US6231719B1 (en) 1996-12-31 2001-05-15 Kimberly-Clark Worldwide, Inc. Uncreped throughdried tissue with controlled coverage additive
US5985301A (en) * 1997-09-30 1999-11-16 Kenji Nakamura Antibacterial cellulose fiber and production process thereof
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US20080260860A1 (en) * 2004-08-31 2008-10-23 Sanitized Ag Method for the Acaricidal Finishing of Textile Materials
US9403041B2 (en) 2004-11-09 2016-08-02 Cupron Inc. Methods and materials for skin care
US9931283B2 (en) 2004-11-09 2018-04-03 Cupron Inc. Methods and materials for skin care
WO2007119137A3 (en) * 2006-04-14 2008-03-13 In Pro Di Inghirami Produzione Process for processing fabrics
WO2007119137A2 (en) * 2006-04-14 2007-10-25 In.Pro.Di.-Inghirami Produzione Distribuzione S.P.A. Process for processing fabrics
US20100132245A1 (en) * 2007-06-29 2010-06-03 Mikkel Vestergaard Frandsen Insecticidal barrier partly with synergist
US10132029B2 (en) * 2013-12-20 2018-11-20 Sanitized Ag Method for reducing adhesion of microorganisms to fabrics

Also Published As

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DE2105019A1 (es) 1971-08-19
GB1351002A (en) 1974-04-24
CA941692A (en) 1974-02-12
DE2105019C3 (de) 1979-08-30
DE2105019B2 (de) 1975-11-27

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